Part Test 4

ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI
IIT – JEE - 2013 PART TEST – 4 MARKS: 148
SECTION - I PHYSICS
PART I: Single Correct Answer Type
This section contains 16 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct. (+3, –1)
1. The circuit below is made up using identical light bulbs. The light
bulbs of maximum brightness of the following will be
(A) A (B) C (C) D (D) B
2. In the diagram shown, all the wires have resistance R. The equivalent
resistance between the upper and lower dots shown in the diagram is
(A) R/8 (B) R (C) 2R/5 (D) 3R/8
3. A wire bent in the form of a regular polygon of n side inscribed in the circle of radius r. If current I
flows in the wire, the magnetic field at the centre of the circle is
i    ni   20 ni    ni  
(A) 0 tan   (B) 0 tan   (C) tan   (D) 0 tan  
2 r n 2 r n r n 2r n
4. A charge is uniformly distributed on a wire such that linear charge density is  λ.

Shape of the wire is shown in the figure, straight section is semi infinitely large. C
is the centre of the semicircular portion of radius R. Considering all physical
 1 
quantities in SI units, magnitude of electric field at C is:  K  
 4 o 
2K  2K 
(A) (B)
R R
K
(C) (D) Zero
R

5. A uniform magnetic field B exists in circular region of radius R as
shown which is decreasing with time at a constant rate. There is a
concentric wooden ring which have uniformly distributed charge Q
and radius 2R and another concentric copper ring of radius 3R, then
select incorrect statement. (Assume rings are placed on frictionless
surface)
(A) There will be induced current in the copper ring.
(B) Induced electric field at 2R is more in magnitude than at 3R.
(C) Induced electric field at 2R is less in magnitude than at 3R.
(D) Wooden ring will rotate
6. A non-conducting ring of radius 0.5m carries a total charge of 1.111010 C distributed non-

uniformly on its circumference producing an electric field E everywhere in space. The value of the
l 0
 
line integral   E.dl (l = 0 being centre of the ring) in volts is
l 
(A) +2 (B) -1 (C)-2 (D) Zero
7. Figure shows the path of an electron in a region of uniform magnetic field.

The path consists of two straight sections, each between a pair of uniformly
charged plates, and two half-circles. The plates are named 1, 2, 3 & 4. Then
(A) 1 and 3 at higher (positive) potential and 2 and 4 at lower (negative)
potential
(B) 1 and 3 at lower potential and 2 and 4 at higher potential
(C) 1 and 4 at higher potential and 2 and 3 at lower potential
(D) 1 and 4 at lower potential and 2 and 3 at higher potential

8. A particle having charge q enters a region of uniform magnetic field B
(directed inwards) and is deflected a distance x after travelling a distance y.
The magnitude of the momentum of the particle is:
qBy qBy
(A) (B)
2 x
qB  y 2
 qBy 2
(C)   x (D)
2  x  2x
9. The mutual inductance between the rectangular loop and the long straight wire as
shown in figure is M.
 a  c
(A) M= zero (B) M  0 ln 1  
2  b 
 a  a c  a  b
(C) M  0 ln   (D) M  0 ln 1  
2  b  2  c 
10. In the shown AC circuit phase difference between currents I1 and I2 is

 X   X  XC 
(A)  tan 1  L  (B) tan 1  L 
2  R   R 
 X   X  XC  
(C)  tan 1  L  (D) tan 1  L 
2  R   R  2
Head Office: Andheri: 26245223 MUMBAI / NASHIK / AKOLA / DELHI / KOLKATA / LUCKNOW
11. A metal rod of resistance R is fixed along a diameter of conducting ring of radius r. There is a magnetic
field of magnitude B perpendicular to the plane of the loop. The ring spins with an angular velocity
 about its axis. The centre of the ring is joined to its rim by an external wire W. The ring and W
have no resistance. The current in W
Br 2 Br 2 2Br 2
(A) Zero (B) (C) (D)
2R R R
12. In the circuit shown, the equivalent capacitance
between the points A and B is
10 15
(A) F (B) F
3 4
12 25
(C)  F (D) F
5 6
13. Conducting sphere of radius a is surrounded by another spherical conducting shell of radius b. The
space between them is filled with dielectric material of conductivity  and dielectric constant K.
The charge Q1 and Q2 are given to the inner and outer shell at time t = 0. Charge on outer shell at
time t is
  t     t 
(A) Q1  Q2  1  exp     (B) Q2  Q1 1  exp    
  oK     o K  
  t    t 
(C) Q1  Q2  1  exp     (D) Q2  Q1 1  exp    
  oK    oK  
14. An air filled parallel plate capacitor with the plate area A is connected
to a battery with an emf E and small internal resistance. One of the
plates vibrates so that the distance between plates varies as
d  do  a cos t (a << d0). The capacitor breaks down when the
instantaneous current in the circuit reaches the value I. Maximum
possible amplitude of vibration a is
Ido2 Id o2
(A) (B)
EA o 2 EA o
IA IA
(C) 2
(D)
2 Edo  o Edo2 o
15. PQ is an infinite current carrying conductor. AB and CD are smooth conducting rods on which a
conductor EF moves with constant velocity V as shown. The force needed to maintain constant speed
of EF is (No gravity is there)
2 2
1   0 IV  b   1   0 IV  b 
(A) ln    (B) ln  
VR  2  a  R  2  a 
2 2
V  0 IV  b  V   IV  b  
(C) ln   (D)  0 ln   
R  2  a  R  2  a  
16. The switch in circuit shifts from 1 to 2 when VC > 2V/3 and goes back to 1 from 2 when VC < V/3.
The voltmeter reads voltage as plotted. What is the period T of the wave form in terms of R and C?
(A) RC ln 3 (B) 2 RC ln 2 (C) RC ln 3 (D) 2 RC ln 3
PART II: Multiple Correct Answer(s) Type
This section contains 10 multiple choice questions. Each question has four choices
(A), (B), (C) or (D) out of which ONE or MORE are correct. (+4, –1)
17. Voltmeter and ammeter shown in circuit diagram are ideal, then
the correct statements are
(A) Reading of voltmeter is 4 volt.
(B) Reading of ammeter is 1.0 A.
(C) Current through 1  resistance is 1.0A.
(D) Current through 1  resistance is zero .
18. A thin conducting rod AB is introduced in between the two

charges q 1 and q2 as shown in figure. For this situation mark
the correct statement(s)
(A) The total force experienced by q 1 is vector sum of electric
force experienced by +q 1 due to -q2 and due to induced
charges on rod.
(B) The end A will become negatively charged
(C) The total magnitude of force acting on +q1 will be greater than as compared to the case without
rod
(D) The total magnitude of force acting on -q2 will be greater than as compared to the case without
rod
19. A thin metallic spherical shell contains a charge Q over it. A point
charge +q is placed inside the shell at point T separated from the centre
by distance a. Another point charge q 1 is placed outside the shell at a
distance b from the centre as shown in the adjacent figure. Now select
the correct statement(s) from the following.
(A) Electric field at the centre due to charge over outer surface of the
shell is zero.
(B) Electric field at the centre due to charge over outer surface of the
q1
shell is
4 ob2
1  q q Q q1 
(C) Electric potential at the centre due to all charges in space is
4 o  a  R  R  b 
1  q Q q1 
(D) Electric potential at the centre due to all charges in space is
4  a  R  b 
20. Two circular coils X and Y having equal number of turns and
carrying equal currents in same sense are placed co- axially,
such that they subtend the same solid angle at O. Let B be the
magnetic field at O due to smaller coil X, then
(A) Magnetic field at O due to larger coil = 2B
(B) Magnetic field at O due to larger coil = B/2
(C) Total magnetic field at O is 3B/2
5B
(D) Total magnetic field at O is
2
21. In an RLC series circuit shown in figure the readings of voltmeters V1

and V2 are 64 V and 120 V respectively. The source voltage is 130 V,
for this situation mark out the correct statements (s).
(A) Voltage across resister, Inductor and capacitor are 50 V, 40 V and
160 V respectively.
(B) Voltage across resistor inductor and capacitor are 10 V, 90 V and
30 V. respectively.
5
(C) Power factor of the circuit is
13
(D) The circuit is capacitive in nature.
22. A resistor and an inductor in series are connected to a battery

through a switch. After the switch is closed (at t = 0)
(A) joule heat dissipation in the resistor changes at fastest rate
L
at t  (n 2)
R
(B) when the rate of increase of magnetic energy stored in the
V 
coil is at maximum, current in the circuit is  
 2R 
(C) power dissipated in resistor increases continuously but rate of change of power initially
increases, it later reaches a maximum, and beyond a point decreases to zero
V 
(D) the fastest increase of current takes place at t=  
 2R 
23. Two bulbs consume same power when operated at 200V and 300V respectively when the bulbs are
connected in series across a D.C source of 500V, then
(A) ratio of potential difference across them is 3/2
(B) ratio of potential difference across them is 4/9
(C) ratio of power consumed across them is 4/9
(D) ratio of power consumed across them is 2/3
24. The adjacent figure shows a resistance network with value of each
resistance is R. The equivalent resistance across ‘A and B’, ‘A and C’
and ‘C and B’ are RAB, RAC and RCB respectively then
(A) RAB = RAC=RCB (B) RAB = 2RAC
(C) RAB =RCB (D) RAB =R/2
25. A short electric dipole is placed in the electric field due to a point charge. Then
(A) The dipole must experience a force
(B) The dipole may experience a force
(C) The dipole must experience a torque
(D) The dipole may experience a torque
26. In the circuit shown

(A) the current through NP is 0.5 A
(B) the value of R1  40
(C) the value of R  14
(D) the potential difference across R  49V
PART III: PARAGRAPH TYPE
This section contains 6 multiple choice questions relating to three paragraphs with two
questions on each paragraph. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct. (+3,0)
PARAGRAPH-1
A circuit is shown in the adjacent figure and switch S is closed at t = 0.
27. Charge stored in C as a function of ‘t’ is.

t t t t
      CV    CV   
(A) CV  1  e 3 RC  (B) CV 1  e 7 RC  (C)  1  e 7 RC
 (D)  1  e 3 RC

    3   3  
28. Amount of heat energy released at 6R, if the capacitor (after it is completely charged) is allowed to
discharge by replacing the cell by a connecting wire is.
CV 2 CV 2 CV 2 CV 2
(A) (B) (C) (D)
54 27 18 81
PARAGRAPH-2
A region in space contains a total positive charge Q that is distributed spherically such that the
volume charge density  ( r ) given by
Here  is a positive constant having units of C/m3.
29. The value of  in terms of Q and R is

6Q 7Q 8Q 9Q
(A) 3
(B) (C) (D)
5 R 5 R 3 5 R 3 5 R 3
30. The correct statement from the following is
R 8Qr R 8Qr
(A) Electric field at r  is 3
(B) Electric field at  r  R is
2 15 o R 2 15 o R3
R Q 2KQ
(C) Electric field at r  is 2
(D) Electric field at r > R is
2 60 o R R2
PARAGRAPH-3

A magnetic field B   Bo y / a  kˆ is acting into the paper in the + z direction.
B0 and a are positive constants. A square loop EFGH of side a, mass m and
resistance R is x-y plane starts falling under the influence of gravity. Note the
directions of x and y in the figure.
31. The induced current in the loop is as a function of velocity V

2 Bo aV B aV B aV 4 Bo aV
(A) (B) o (C) o (D)
R R 2R R
32. The total Lorentz force acting on the loop as a function of velocity V
 Bo2 a 2V ˆ 2 Bo2 a 2V ˆ  Bo2 a 2V ˆ Bo2 a 2V ˆ
(A) j (B) j (C) j (D) j
R R 2R 2R
SECTION IV: Integer Answer Type
This section contains 6 questions. The answer to each question is a single digit
integer, ranging from 0 to 9 (both inclusive) (+6, –1)
33. A rod of mass m  2 kg and length l  3 m rotates about an axis passing

through one end O and perpendicular to its length. The other end of rod A,
slides without friction on a circular conducting rail (negligible resistance).
A resistor R is connected to the rod and rail as shown. The whole set up
lies in horizontal plane with uniform magnetic field B directed in to the
plane of ring. The rod is given an angular speed 0 and released. The total
heat generated in the resistor R is 27 J. Find the value of 0 in rad/s.
34. The initial charge across capacitors A and B are shown with Q  CE .
Find the ratio of final charge in capacitor A to the final charge in
capacitor B, when cells are switched on.
35. In the circuit shown in the adjacent diagram initially switch K1 is

closed and switch K2 is open. After long time, K2 is also closed. The
XE
current through the cell of emf E immediately after K2 is closed is
11R
. Find X.
36. A battery of e.m.f. 10 V and internal resistance 2  is connected in primary circuit with a 100 cm
long uniform potentiometer wire and a rheostat whose resistance is fixed at 998  . A battery of
unknown e.m.f. E is being balanced on this potentiometer wire and balancing length is found to be
50 cm. When area of cross section of potentiometer wire is doubled, then balancing length is found
n
to be 75 cm. Area of cross-section (initially) is 100 cm2. If the e.m.f of the battery E= Volts, Find n.
2
37. An A.C. source of angular frequency ω is fed across a resistor R and a capacitor C in series. The
current registered is I. If now the frequency of source is changed to ω/3 (but maintaining the same
voltage), the current in the circuit is found to be halved. If the ratio of reactance to resistance at the
original frequency ω is r, find the value of 5r2.
38. A large metal sheet carries an electric current along its surface. Current per unit length is  .

Magnetic field near the metal sheet is o . Find the value of 2x.
x
PART V: Matrix Match Type
This section contains 1 question. Each question contains statements given in two columns, which have
to be matched. The statements in Column-I are labelled A, B, C and D, while the statements in
Column - II are labelled p, q, r, s and t. Any given statement in Column-I can have correct matching
with ONE OR MORE statement(s) in Column- II. The appropriate bubbles corresponding to the
answers to these questions have to be darkened as illustrated in the following example: If the correct
matches are A - p , s and t ; B - q and r ; C - p and q ; and D - s and t. (+6, 0)
39.
Column I Column II
(a) Removal of dielectric when battery is (p)
present
Potential difference between plates increases.
(b) Insertion of dielectric when battery is (q)

present
Capacitance increases.
(c) Removal of dielectric when battery is not (r)

present but capacitor is charged
Stored energy increases.
(d) Insertion of dielectric when battery is not (s)

present but capacitor is charged
Charge present on plates decreases.
(t) Electric field remains constant.
PHYSICS ANSWER KEY
1.B 2.D 3.B 4.D 5.C 6.A 7.C
8.C 9.D 10.C 11.D 12.A 13. D 14.A
15.A 16.B 17.ABD 18.ABCD 19.BD 20.BC 21.ACD
22.ABC 23.BC 24.ACD 25.AD 26.BCD 27.D 28.D
29.C 30.A 31.B 32.A 33. 3 34.1 35.3
36.5 37.3 38.4
39. a s,t bq,r,t cp,r dq
IIT – JEE - 2013 PART TEST - 4 MARKS: 148
(ADVANCED PATTERN) PHYSICAL CHEMISTRY DATE: 27/04/13
SECTION-I
This section contains 16 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out which ONLY ONE is correct. (+3, - 1)
1. A hydrate of iron(III) thiocyanate, Fe(SCN)3 was found to contain 19% H2O. The empirical formula
of the hydrate is
(a) Fe(SCN)3.H2O (b) Fe(SCN)3.2H2O
(c) Fe(SCN)3.3H2O (d) Fe(SCN)3.4H2O
2. 2 litre carbogen (at S.T.P.) is passed through a solution of lime water to get 0.5 g white precipitate.
The percentage of carbon dioxide gas in carbogen by volume is
(a) 8 (b) 11.2 (c) 5.6 (d) 22.4
3. The rate constant, the activation energy and the Arrhenius parameter of a chemical reaction at 25°C
are 3.0  10-4 s-1, 104.4 kJ mol-1 and 6.0  10 14 s-1 respectively. The value of the rate constant as T
  is
(a) 2.0  1018 s1 (b) 6.0  1014 s1 (c) infinity (d) 3.6  1030s1
4. PCl5 is 50% dissociated into PCl3 and Cl2 at 1 atmosphere. It will be 40% dissociated at:
(a) 1.75 atm (b) 1.84 atm (c) 2.00 atm (d) 1.25 atm
5. For the reaction

NH2COONH4(s) 2NH3(g) + CO2(g)
The equilibrium constant Kp = 2.9  105 atm3. The total pressure of gases at equilibrium when 1.0
mole of reactant was heated will be:
(a) 0.0194 atm (b) 0.0388 atm (c) 0.0580 atm (d) 0.0667 atm
6. The pH of a solution obtained by dissolving 5  10 4 moles of Ca(OH)2 (strong electrolyte) to 100

ml solution at 298 K will be
(a) 11 (b) 12 (c) 9.8 (d) 2
7. The pH of a solution of M(OH)2 is 10.6. The Ksp value of M(OH)2 is

(a) 3.15  1011 (b) 3.15  105 (c) 3.16  106 (d) none of these
8. The work done during expansion of a gas is independent of pressure if the expansion takes place
(a) isothermally (b) adiabatically
(c) in both the above cases (d) in none of the above cases
9. The amount of heat required to raise the temperature of 1 mole diatomic gas by 1°C at constant
pressure is 60 cal. The amount of heat which goes as internal energy of the gas is nearly.
(a) 60 Cal (b) 30 Cal (c) 42.6 Cal (d) 49.8 Cal
10. A compound XY crystallizes in bcc lattice with unit cell edge-length of 480 pm. If the radius of Y is
225 pm, then the radius of X+ is
(a) 190.7 pm (b) 225 pm (c) 127.5 pm (d) None
CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

11. If three elements X, Y & Z crystallized in cubic lattice with X atoms at corners, Y atoms at cube
centre & Z atoms at the centre of edges, then the formula of the compound is
(a) XYZ (b) XY3Z (c) XYZ3 (d) X3YZ
12. 0.2 g of a gas X occupies a volume of 0.44 L at same pressure and temperature. Under identical
conditions of P and T, 0.1 g of CO2 gas occupies 0.32 L. Gas X can be
(a) O2 (b) SO2 (c) NO (d) C4H10
13. A flask containing 12 g of a gas of molecular mass 120 at a pressure of 100 atm was evacuated by
means of a pump until the pressure was 0.01 atm. Which of the following is the best estimate of the
number of molecules left in the flask (No = 6  1023 mol1).
(a) 6  1019 (b) 6  1018 (c) 6  1017 (d) 6  1013
14. If the speed of electron in the Bohr's first orbit of hydrogen atom is x, the speed of the electron in the
third Bohr's orbit is
(a) x/9 (b) x/3 (c) 3x (d) 9x
15. The quantum numbers of most energetic electron in Ne atom when it is in first excited state is
(a) 2, 1, 0, ± 1/2 (b) 3, 1, 1, ± 1/2 (c) 3, 0, 0, ± 1/2 (d) 3, 1, 0, ± 1/2
16. When a river meets the ocean they generally form delta due to
(a) Coagulation of sand (b) sedimentation of common salt
(c) deposition of MgCl2 (d) mutual coagulation
SECTION-II
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out which ONE OR MORE is/are correct. (+4, 0)
17. Which of the following statements is correct about angular nodes?

(a) These nodes are directional in nature
(b) These nodes are dependent on angle  and 
(c) These nodes are independent from the radial wave function (R)
(d) These nodes are dependent on the radial wave function
18. Which of the following statement are true regarding the log K vs/ 1/T plot shown in the given
diagram?
K  Ae  Ea / RT
P
log10 K
1/T
(a) Plot P shows that the energy of activation is independent of temperature

(b) Plot Q describes the behaviour of temperature dependence of energy activation
(c) Arrhenius behaviour is described by P
E
(d) The slope of curve P give s the value  a
R

19. Which of the following statements is/are correct?
(a) Electron in motion behave as if they are waves
(b) s-orbital is non-directional
(c) An orbital can accommodate a maximum of two electrons with parallel spins
(d) the energies of the various sub-levels in the same shell are in orders s  p  d  f
20. Select the correct statements about galvanic cells

(a) electron is are fed into anode by the oxidation reaction that takes place at the electrode
(b) The anode pushes these electrons into the external circuit and thus, acts as a source of negative
charge
(c) the cathode acts as an electron sink and thus, called positive electrode
(d) the algebraic sum of EOP of anode and EOP of cathode gives the +ve value for spontaneous
process
21. Select the correct statements

(a) The value of Qc for a given reaction is constant
(b) A change in the physical state of a gaseous product shows a change in the value of equilibrium
constant of that reaction
Q
(c) The value of ratio c can be used to predict the direction in which a system will proceed
Kc
spontaneously towards equilibrium
(d) The rate constants for forward and backward reaction for a reversible reaction always increases
 K 
with temperature but their ratio  i.e., f  may increase or decrease with temperature.
 Kb 
22. Correct statements are

(A) I.E. for hydrogen atom = 13.6 ev
(B) I.E. of Li2+ in the first excited state is 30.6eV
(C) I.E. of Be3+ in the first excited state is 54.4 eV
(D) I.E. of Li2+ in the first excited state in 10.6 eV
23. Which of the following statement(s) is/are true?

(A) When (Gsystem)T,P < 0; the reaction must be exothermic
(B) f H° (S, monoclinic)  0
(C) If dissociation energy of CH4(g) is 1656 kJ/mole and C2H6 (g) is 2812 kJ/mole, then value of C–
C bond energy will be 328 kJ/mole
(D) If H+(aq) + OH–(aq)  H2O(l) rH° = –56 kJ/mol
f H°(H2O, g) = –242 kJ/mole;Enthalpy of vaporization of liquid water = 44 kJ/mol then,
f H°(OH–, aq) will be –142 kJ/mole
24. Which of the following mixtures will act as buffer?

(a) H2CO3  NaOH 1.5 : 1 molar ratio  (b) H2CO3  NaOH 1.5;2 molar ratio 
(c) NH4OH  HCl  5 : 4 molar ratio  (d) NH4OH  HCl  4 : 5 molar ratio 
25. Which of the following statements is/ are correct for fluorite structure  CaF2  ?
(a) Ca2 ions are in ccp with fcc unit cell and F ions occupies all tetrahedral void
(b) Ca2 ion is surrounded by 4F ions
(c) Mass of one unit cell  mass of 4 Ca2  + mass of 4F 
(d) Co.no of F  4,Co.no.Ca2   8

26. You are given one molal solution of each of the following compounds.
(A) Glucose, (B) NaCl, (C) BaCl2 (D) Na3PO4 , (E) C6H5COOH
Assuming 100% ionization in (B), (C), (D) and 100% dimer formation in (E) predict the correct order of the
following properties of the given solutions.
(a) Boiling point: E    A   B    C   D 
(b) Freezing point: D   C   B    A   E 
(c) Osmotic pressure: D    C   B    A   E 
(d) Vapor pressure: D    C   B    A   E 
SECTION-III (Paragraph Type)

This section contains 2 groups of questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct. (+3, -1)
PASSAGE-1
For hydrogen atom or 1-electron ions, the wave functions of 1s and 2s atomic orbitals are given as
under:
Zr
1 
1s  3
 e a0
a 0
1/ 2 Zr
 Z   Zr   a0
 2s    2 e
 2a 0   a0 
The wave functions for any 1-electron system is given by
 = k e–kr where k and k are constants.
The number of angular nodes are given by the value of angular quantum number and angular node is
directional in nature. Total number of nodes is nothing but it is the sum of radial nodes (n – – 1) and
angular nodes ().
On the basis of the above write up, answer the following questions.
27. Which of the following is the correct representation of plot radial function (r.f.) in Y-axis vs distance
from the nucleus in X-axis for 1-elelectron of 3p-atomic orbital?
Y Y
(a) (b)
r.f.
r.f.
r X r X
Y Y
(c) (d)
r.f.
r.f.
r X r X
28. If the nodes at infinity is not neglected, then what is the total number of radial and angular nodes of
3px-orbitals?
(a) 4 (b) 3 (c) 5 (d) infinity

PASSAGE – 2
The thermal decomposition of N2O5 occurs as : 2N2O5  4NO2 + O2

Experimental studies suggest that rate of decomposition of N2O5, rate of formation of NO2 or rate of
formation of O2 all becomes double if concentration of N2O5 is doubled.
29. The ate of reaction is given by:

d[N 2O 5 ] 1 d[O 2 ]
(a)   K1[N 2 O 5 ] (b)  K 2 [N 2 O 5 ]
dt 2 dt
1 d[NO2 ] d[N 2 O5 ]
(c)   K 3[N 2 O5 ] (d)   K1[N 2 O5 ]2
4 dt dt
30. If rate constants for decomposition of N2O5, formation of NO2 and formation of O2 are K1 . K2 and
K3 respectively, then
(a) K1 = K2 = K3 (b) 2K1 = K2 = 4K3
(c) K1 = 2K2 = K3 (d) K1 = K2 = 2K3
PASSAGE – 3
Solid AgNO3 is gradually mixed with equimolar solution of NaBr and NaCl, each having molarity
0.02 M.
K sp(AgBr ) = 5 × 10–16,
K sp(AgCl) = 1.0 × 10–10.
31. The minimum [Ag+] required for just the start of precipitation of AgBr.
(a) 5 × 10 –14 M (b) 2 × 10 –15 M
–14
(c) 2.5 × 10 M (d) 5 × 10 –15 M
32. [Ag+] required to just start the precipitation of AgCl is

(a) 5 × 10 –8 M (b) 2.5 × 10–8 M
–9
(c) 5 × 10 M (d) 2.5 × 10–9 M
SECTION-IV (Integer Answer Type)

This section contains 5 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is be bubbled. (+6, –1)
33. Lattice energy of NaCl  s  is 790 kJ mol1 and enthalpy of hydration is 785 kJ mol1 . Calculate
enthalpy of solution of NaCl  s  .
34. If 50% of CO2 converted to CO at the following equilibrium:

1 1  CO  g 
C  s   CO2  g  
2 2
and the equilibrium pressure is 12 atm. Calculate K p .

1
35. Figure shows a graph in log10 K vs where K is rate constant and T is temperature. The straight line
T
1
BC has slope, tan    and an intercept of 5 on y-axis. thus Ea what is energy of activation
2.303
(incalory).
B
log10K
B
1/T
36. The chemical reaction between K2C2O4 and HgCl2 is

2HgCl2 + K2C2O4  2KCl + 2CO2 + Hg2Cl2
The weight of Hg2Cl2 are precipitated from different solution in given times are as
Time HgCl2 mol litre–1 K2C2O4 mol litre–1 Hg2Cl2 mol litre–1
60 0.0418 0.404 0.0032
65 0.0836 0.404 0.0068
120 0.0836 0.202 0.0031
Find the reaction of order is
H
37. For any acid catalysed reaction, A   B . Half-life period is independent of concentration of A
at given pH. At same concentration of A half-life time is 10 min at pH  2 and half-life time is 100
x y
min at pH  3 . If the rate law expression of reaction is r  k  A   H   then calculate the value of
 
x  y .
38. Molar conductivities at infinite dilution of KCl, HCl and CH3COOK are 0.013, 0.038 and 0.009
Sm 2 mol1 respectively at 291K . If conductivity of 0.001M CH3COOH is 2.72 10 3 Sm1 then
find % degree of ionization of CH3COOH

SECTION-V (Matrix Match Type)
39.
COLUMN-I COLUMN-II
ELECTROLYTE WHICH ARE CHARACTERISTICS
ELECTROLYSED
A) NaCl (aq) p) H2 liberates
B) AgNO3(aq) q) O2 liberates
C) CuSO4 (aq) (Pt. electrode) r) pH increases
D) H2SO4(aq) s) pH decreases

ANSWER KEY
1. (c) 2. (c) 3. (b) 4. (a) 5. (c)
6. (b) 7. (a) 8. (d) 9. (c) 10. (a)
11. (c) 12. (b) 13. (b) 14. (b) 15. (c)
16. (a) 17. (a, b, c) 18. (a, b, c, d) 19. (a, b) 20. (a, b, c)
21. (b, c, d) 22. (A, B, C) 23. (B, C) 24. (a,b,c,) 25. (a,d)
26. (a,b,c,d) 27. (d) 28. (b) 29. (a) 30. (b)
31. (c) 32. (c) 33. (5) 34. (4) 35. 2
36. (3) 37. (2) 38. (8)
39. A – P, R; B – Q, S; C – Q, S; D – P, R

SECTION – I
Single Correct Choice Type
1. A hydrate of iron(III) thiocyanate, Fe(SCN)3 was found to contain 19% H2O. The empirical formula
of the hydrate is
(a) Fe(SCN)3.H2O (b) Fe(SCN)3.2H2O
(c) Fe(SCN)3.3H2O (d) Fe(SCN)3.4H2O
2. 2 litre carbogen (at S.T.P.) is passed through a solution of lime water to get 0.5 g white precipitate.
The percentage of carbon dioxide gas in carbogen by volume is
(a) 8 (b) 11.2
(c) 5.6 (d) 22.4
3. The rate constant, the activation energy and the Arrhenius parameter of a chemical reaction at 25°C
are 3.0  10-4 s-1, 104.4 kJ mol-1 and 6.0  10 14 s-1 respectively. The value of the rate constant as T
  is

(a) 2.0  10 18 s1 (b) 6.0  1014 s1
(c) infinity (d) 3.6  1030s1
4. PCl5 is 50% dissociated into PCl3 and Cl2 at 1 atmosphere. It will be 40% dissociated at:
(a) 1.75 atm (b) 1.84 atm
(c) 2.00 atm (d) 1.25 atm
5. For the reaction

NH2COONH4(s) 2NH3(g) + CO2(g)
The equilibrium constant Kp = 2.9  105 atm3. The total pressure of gases at equilibrium when 1.0
mole of reactant was heated will be:
(a) 0.0194 atm (b) 0.0388 atm
(c) 0.0580 atm (d) 0.0667 atm
6. The pH of a solution obtained by dissolving 5  10 4 moles of Ca(OH)2 (strong electrolyte) to 100

ml solution at 298 K will be
(a) 11 (b) 12
(c) 9.8 (d) 2
7. The pH of a solution of M(OH)2 is 10.6. The Ksp value of M(OH)2 is

(a) 3.15  1011 (b) 3.15  105
(c) 3.16  106(d) none of these
8. The work done during expansion of a gas is independent of pressure if the expansion takes place
(a) isothermally (b) adiabatically
(c) in both the above cases (d) in none of the above cases
9. The amount of heat required to raise the temperature of 1 mole diatomic gas by 1°C at constant
pressure is 60 cal. The amount of heat which goes as internal energy of the gas is nearly.
(a) 60 Cal (b) 30 Cal
(c) 42.6 Cal (d) 49.8 Cal
1
10. A compound XY crystallizes in bcc lattice with unit cell edge-length of 480 pm. If the radius of Y is
225 pm, then the radius of X+ is
(a) 190.7 pm (b) 225 pm
(c) 127.5 pm (d) None
11. If three elements X, Y & Z crystallized in cubic lattice with X atoms at corners, Y atoms at cube
centre & Z atoms at the centre of edges, then the formula of the compound is
(a) XYZ (b) XY3Z
(c) XYZ3 (d) X3YZ
12. 0.2 g of a gas X occupies a volume of 0.44 L at same pressure and temperature. Under identical
conditions of P and T, 0.1 g of CO2 gas occupies 0.32 L. Gas X can be
(a) O2 (b) SO2
(c) NO (d) C4H10
13. A flask containing 12 g of a gas of molecular mass 120 at a pressure of 100 atm was evacuated by
means of a pump until the pressure was 0.01 atm. Which of the following is the best estimate of the
number of molecules left in the flask (No = 6  1023 mol1).
(a) 6  10 19 (b) 6  10 18
(c) 6  10 17 (d) 6  10 13
14. If the speed of electron in the Bohr's first orbit of hydrogen atom is x, the speed of the electron in the
third Bohr's orbit is
(a) x/9 (b) x/3
(c) 3x (d) 9x
15. The quantum numbers of most energetic electron in Ne atom when it is in first excited state is
(a) 2, 1, 0, ± 1/2 (b) 3, 1, 1, ± 1/2
(c) 3, 0, 0, ± 1/2 (d) 3, 1, 0, ± 1/2
16. When a river meets the ocean they generally form delta due to
(a) Coagulation of sand (b) sedimentation of common salt
(c) deposition of MgCl2 (d) mutual coagulation
SECTION – II
Multiple Correct Choice Type
17. Which of the following statements is correct about angular nodes?

(a) These nodes are directional in nature
(b) These nodes are dependent on angle  and 
(c) These nodes are independent from the radial wave function (R)
(d) These nodes are dependent on the radial wave function
18. Which of the following statement are true regarding the log K vs/ 1/T plot shown in the given
diagram?
2
K  Ae  Ea / RT
log10 K P
1/T
(a) Plot P shows that the energy of activation is independent of temperature

(b) Plot Q describes the behaviour of temperature dependence of energy activation
(c) Arrhenius behaviour is described by P
E
(d) The slope of curve P give s the value  a
R
19. Which of the following statements is/are correct?

(a) Electron in motion behave as if they are waves
(b) s-orbital is non-directional
(c) An orbital can accommodate a maximum of two electrons with parallel spins
(d) the energies of the various sub-levels in the same shell are in orders s  p  d  f
20. Select the correct statements about galvanic cells

(a) electron is are fed into anode by the oxidation reaction that takes place at the electrode
(b) The anode pushes these electrons into the external circuit and thus, acts as a source of negative
charge
(c) the cathode acts as an electron sink and thus, called positive electrode
(d) the algebraic sum of EOP of anode and EOP of cathode gives the +ve value for spontaneous
process
21. Select the correct statements

(a) The value of Qc for a given reaction is constant
(b) A change in the physical state of a gaseous product shows a change in the value of equilibrium
constant of that reaction
Q
(c) The value of ratio c can be used to predict the direction in which a system will proceed
Kc
spontaneously towards equilibrium
(d) The rate constants for forward and backward reaction for a reversible reaction always increases
 K 
with temperature but their ratio  i.e., f  may increase or decrease with temperature.
 Kb 
22. Correct statements are

(A) I.E. for hydrogen atom = 13.6 ev
(B) I.E. of Li2+ in the first excited state is 30.6eV
(C) I.E. of Be3+ in the first excited state is 54.4 eV
(D) I.E. of Li2+ in the first excited state in 10.6 eV
23. Which of the following statement(s) is/are true?

(A) When (Gsystem)T,P < 0; the reaction must be exothermic
3
(B) f H° (S, monoclinic)  0
(C) If dissociation energy of CH4(g) is 1656 kJ/mole and C2H6 (g) is 2812 kJ/mole,
then value of C–C bond energy will be 328 kJ/mole
(D) If H+(aq) + OH–(aq)  H2O(l) rH° = –56 kJ/mol
f H°(H2O, g) = –242 kJ/mole;Enthalpy of vaporization of liquid water = 44
kJ/mol then, f H°(OH–, aq) will be –142 kJ/mole
24. Which of the following mixtures will act as buffer?

(a) H2CO3  NaOH 1.5 : 1 molar ratio  (b) H2CO3  NaOH 1.5;2 molar ratio 
(c) NH4OH  HCl  5 : 4 molar ratio  (d) NH4OH  HCl  4 : 5 molar ratio 
25. Which of the following statements is/ are correct for fluorite structure  CaF2  ?
(a) Ca2 ions are in ccp with fcc unit cell and F ions occupies all tetrahedral void
(b) Ca2 ion is surrounded by 4F ions
(c) Mass of one unit cell  mass of 4 Ca2  + mass of 4F
(d) Co.no of F  4,Co.no.Ca2   8
26. You are given one molal solution of each of the following compounds.
(A) Glucose, (B) NaCl, (C) BaCl2 (D) Na3PO4 , (E) C6H5COOH
Assuming 100% ionization in (B), (C), (D) and 100% dimer formation in (E) predict the correct order of the
following properties of the given solutions.
(a) Boiling point: E    A   B    C   D 
(b) Freezing point: D   C   B    A   E 
(c) Osmotic pressure: D    C   B    A   E 
(d) Vapor pressure: D    C   B    A   E 
SECTION – III
Linked Comprehension Type
Passage - 1
For hydrogen atom or 1-electron ions, the wave functions of 1s and 2s atomic orbitals are given as
under:
Zr

1 a0
1s   e
a 30
1/ 2 Zr
 Z   Zr   a0
 2s    2 e
 2a 0   a0 
The wave functions for any 1-electron system is given by
 = k e–kr where k and k are constants.
The number of angular nodes are given by the value of angular quantum number and angular node is
directional in nature. Total number of nodes is nothing but it is the sum of radial nodes (n – – 1) and
angular nodes ().
On the basis of the above write up, answer the following questions.
27. Which of the following is the correct representation of plot radial function (r.f.) in Y-axis vs distance
from the nucleus in X-axis for 1-elelectron of 3p-atomic orbital?
4
Y Y
(a) (b)
r.f.
r.f.
r X r X
Y Y
(c) (d)
r.f.
r.f.
r X r X
28. If the nodes at infinity is not neglected, then what is the total number of radial and angular nodes of
3px-orbitals?
(a) 4 (b) 3
(c) 5 (d) infinity
Passage - 2
The thermal decomposition of N2O5 occurs as : 2N2O5  4NO2 + O2
Experimental studies suggest that rate of decomposition of N2O5, rate of formation of NO2 or rate of
formation of O2 all becomes double if concentration of N2O5 is doubled.
29. The ate of reaction is given by:
d[N 2O 5 ] 1 d[O 2 ]
(a)   K1[N 2 O 5 ] (b)  K 2 [N 2 O 5 ]
dt 2 dt
1 d[NO 2 ] d[N 2 O 5 ]
(c)   K 3[N 2 O 5 ] (d)   K1[N 2 O5 ]2
4 dt dt
30. If rate constants for decomposition of N2O5, formation of NO2 and formation of O2 are K1 . K2 and
K3 respectively, then
(a) K1 = K2 = K3 (b) 2K1 = K2 = 4K3
(c) K1 = 2K2 = K3 (d) K1 = K2 = 2K3
Passage - 3
Solid AgNO3 is gradually mixed with equimolar solution of NaBr and NaCl, each having molarity
0.02 M.
K sp(AgBr ) = 5 × 10–16,
K sp(AgCl) = 1.0 × 10–10.
31. The minimum [Ag+] required for just the start of precipitation of AgBr.
(a) 5 × 10 –14 M (b) 2 × 10 –15 M
–14
(c) 2.5 × 10 M (d) 5 × 10 –15 M
32. [Ag+] required to just start the precipitation of AgCl is

(a) 5 × 10 –8 M (b) 2.5 × 10–8 M
–9
(c) 5 × 10 M (d) 2.5 × 10–9 M
SECTION –IV
Integer Answer Type
5
33. Lattice energy of NaCl  s  is 790 kJ mol1 and enthalpy of hydration is 785kJ mol1 . Calculate
enthalpy of solution of NaCl  s  .
34. If 50% of CO2 converted to CO at the following equilibrium:

1 1  CO  g 
C  s   CO2  g  
2 2
and the equilibrium pressure is 12 atm. Calculate K p .
1
35. Figure shows a graph in log10 K vs where K is rate constant and T is temperature. The straight line
T
1
BC has slope, tan    and an intercept of 5 on y-axis. thus Ea what is energy of activation
2.303
(incalory).
C
log10K
B
1/T
36. The chemical reaction between K2C2O4 and HgCl2 is

2HgCl2 + K2C2O4  2KCl + 2CO2 + Hg2Cl2
The weight of Hg2Cl2 are precipitated from different solution in given times are as
Time HgCl2 mol litre–1 K2C2O4 mol litre–1 Hg2Cl2 mol litre–1
60 0.0418 0.404 0.0032
65 0.0836 0.404 0.0068
120 0.0836 0.202 0.0031
H
37. For any acid catalysed reaction, A   B . Half-life period is independent of concentration of A
at given pH. At same concentration of A half-life time is 10 min at pH  2 and half-life time is 100
x y
min at pH  3 . If the rate law expression of reaction is r  k  A   H   then calculate the value of
 
 x  y  .
38. Molar conductivities at infinite dilution of KCl, HCl and CH3COOK are 0.013, 0.038 and 0.0009
Sm 2 mol1 respectively at 291K . If conductivity of 0.0001M CH3COOH is 2.72 10 3 Sm1 then
find % degree of ionization of CH3COOH
SECTION – V
Matrix Match Type
39. Column-I Column-II
6
Electrolyte which are electrolysed Characteristics
A) NaCl (aq) p) H2 liberates
B) AgNO3(aq) q) O2 liberates
C) CuSO4 (aq) (Pt. electrode) r) pH increases
D) H2SO4(aq) s) pH decreases
1. In 100 g of the hydrate, there are 19 g of H2O and 81 g of Fe(SCN)3.

19
Moles of H2O = = 1.05
18
81
Moles of Fe(SCN)3 = = 0.352
230
Moles of H 2 O 1.05
  3
Moles of Fe(SCN ) 3 0.352
There are three mole of H2O per mole of Fe(SCN)3. Thus, the empirical formula is Fe(SCN)3.3H2O.
 (c)
2. Ca(OH)2 + CO2  CaCO3 + H2O
0.5 g
5
 no. of moles of CO2 in 2 lit carbogen =
1000
5 22.4
 % of CO2 in carbogen by vol =   100
1000 2
= 5.6
 (c)
3. The Arrhenius equation is
k = A e (  E a / RT )
As T   , e ( E a / RT )  1. Hence
k=A
where A, the Arrhenius parameter, is 6.0  1014 s-1
 (b)
4. PCl5 PCl3 + Cl2
Let x = degree of dissociation of PCl5 at pressure p
y = degree of dissociation of PCl5 at pressure p'
px 2 p' y 2
Kp =  .
(1  x 2 ) (1  y 2 )
Given x = 0.50, p = 1 atm
y = 0.40, p' = ?
1  0.25 p'  0.16

0.75 0.84
p' = 1.75 atm
7
 (a)
5. NH2COONH4(s) 2NH3(g) + CO2(g)

Initially 1 0 0
At equilibrium (1 x) 2x x
Total moles of gaseous substances at equilibrium = 3x
Equilibrium pressure = p
2 p
p NH 3 = p , p CO 2 
3 3
2
Kp = (p NH ) p CO 2
3
5 4 3
2.9  10 = p
27
p = 0.0580 atm
 (c)
5  10 4  1000
6. [Ca(OH)2] =  5  10  3 mole L1
100
[OH] = 2  5  103 = 10 2 mole L1
1014
[H+] = 2
= 10 12
10
pH = log 1012 = 12
 (b)
7. Let the solubility is x moles/litre.

M(OH)2(s) M2+ + 2OH
x 2x
pH = 10.6
pOH = 14  10.6 = 3.4
[OH] = Antilog (3.4) = 3.98  104 M
3.98  10 4
x = = 1.99  10 4 M
2
Ksp = [M2+]  [OH]2
= x  (2x)2 = 4 x 3 = 4  (1.99  10 4)3 = 3.15  1011
 (a)
8. During isothermal expansion

V  Vf P
Work done, W = nRT loge f ; we also know for isothermal change   i
Vi  Vi Pf 
While during adiabatic expansion
P V  Pi Vi
Work done, W = f f
1
We see in both these cases work done depends on pressure.
 (d)
9. For a diatomic gas Cp = 7/2 R and CV = 5/2 R
8
5
Only = 0.71 of energy supplied increases the internal energy of the gas. The rest is used to do
7
work against external pressure
0.71  60 = 42.6 Cal
 (c)
10. For bcc structure,
2 (r  r ) = 3 a
or 2 (r+ + 225) = 3  480
 r+ = 190.7 pm
(a)
11. Atom X is shared by 8 corners.

One atom of Z is shared by 4 unit cells and atom Y is present at centre of the unit cell.
1
Hence, effective number of atoms of X per unit cell = 8  = 1
8
12
Effective number of atoms of Z per unit cell = =3
4
Effective number of atoms of Y per unit cell = 1
Hence, the formula of the compound is XYZ3 .
 (c)
0.1
12. 0.1 g CO2 = moles of CO2 occupies = 0.32 L
44
0.2
moles of X occupies = 0.44 L
M
PV = nRT
Vn
V (CO 2 ) n (CO 2 )

V (X) n (X )
0.32 0.1  M

0.44 44  0.2
M = 64
 (b)
n
13. P1 = 1 RT
V
n
P2 = 2 RT
V
[Volume of the flask and temperature remain constant]
n 2 P2

n 1 P1
P 12 0.01
n2 = n1  2 = 
P1 120 100
Number of molecules left in the flask = n2  No = 6  10 18
 (b)
14. According to Bohr’s model for hydrogen and hydrogen like atoms the velocity of an electron in an
2 Ze
atom is quantised and is given by v .
nh
9
 (b)
15. The electronic configuration of Ne atom is 1s2, 2s2, 2p 6. In its first excitation state the electron from
2p will unpair and shift to 3s where its quantum numbers will be 3,0,0 ± ½.
 (c)
16. Sand is a negatively charged colloidal particles, which is carried by river to the ocean which is a vast
reservoir of Na  , K  , Mg   ion. These cations coagulate sand particles at the meeting point of river
and ocean. In this way delta is formed
 (a)
17. (a), (b), (c)
Angular nodes being directional, only depends upon  and  but not on the radial wave function (R).
18. (a, b, c, d)
19. (a, b)
20. (a, b, c)
21. (b, c, d)
22. (A), (B), (C)
13.6Z2
H    13.6 eV
n2
13.6  32
 Li2   30.6 eV
22
13.6  16
 Be3   54.4 eV
22
 Li2  30.6 eV not 10.6 eV.
23. (B), (C)
24. (a,c)
25. (a,c,d)
26. (a,b,c,d)
The greater the value of I, the greater is the value for Tb , Tf ,  and P
27. (d)
No. of radial nodes = n –  – 1
28. (b)
29. (a)
Rate of reaction
d[N 2O 5 ]
  K1[N 2 O 5 ]
dt
30. (b)
1 1 d[NO 2 ] d[O 2 ]
Rate of reaction =  d[N 2O 5 ]  
2 4 dt dt
d[N 2O 5 ]
  K1[N 2 O 5 ] ;
dt
d[NO2 ] d[O 2 ]
  K 2 [N 2 O5 ] and  K 3 [N 2 O5 ]
dt dt
K1 K 2
   K3
2 4
31. (c)
10
K sp(AgBr) 5 1016
[Ag+] required = 
= 2
= 2.5 × 10–14
[Br ] 2 10
32. (c)
K sp(AgCl) 1.0 1010
[Ag+] required for AgCl = = = 0.5 × 10–8 = 5 × 10 –9 M
[Cl  ] 2 102
33. (5)
34. (4)
35. 2
Ea
2.303 log 10K = –  2.303log10 A1
RT
 Ea 1
Thus  tan   
2.303R 2.303
Ea = R = 2 cal.
36. 3
Rate = K[HgCl2]m [K2CrO4]n
0.0032
  K[0.0418]m [0.404]n … (i)
60
0.0068
 K0.0836]m [0.404]n … (ii)
65
0.0031
 K[0.0836]m [0.202]n … (iii)
120
Solving eq. (i), (ii) & (iii)
we get m = 1, n = 2
order = m + n = 1 + 2 = 3
37. (2)
38. (8)
39. 18) A – P, R; B – Q, S; C – Q, S; D – P, Q, S
11
IIT – JEE - 2013 PART TEST – 4 MARKS: 148
SECTION - III MATHS
PART I: Single Correct Answer Type
This section contains 16 multiple choice questions. Each question has four choices ((A), ((B),
((C) and ((D) out of which ONLY ONE is correct. (+3, –1)
1. Equation of circle of minimum radius which touches both the parabolas y  x 2  2x  4 and
x  y 2  2y  4 is
(a) 2x 2  2y2  11x  11y  13  0 (b) 4x 2  4y2  11x  11y  13  0
(c) 3x 2  3y 2  11x  11y  13  0 (d) x 2  y 2  11x  11y  13  0
x 2 y2 x2 y2
2. The angle of intersection between the curves   1 and   1,  a  k  b  0 
a 2 b2 a 2  k 2 k 2  b2
is
b  b   a 
(a) tan 1   (b) tan 1   (c) tan 1   (d) None of these
a  ka   kb 
3. A triangle is inscribed in the curve xy  c 2 and two of its sides are parallel to y  m1x  0 and
y  m 2 x  0 respectively. Then the third side touches the hyperbola
2
(a) 4m1m2 xy  c2 m1  m 2
  (b) m1m 2 xy  c2  m1  m 2 
(c) 2m1m 2 xy  c 2  m1  m 2  2 (d) 4m1m 2 xy  c 2  m1  m 2 2
x 2 y2
4. Image of the ellipse   1 in the line x  y  10 is:
25 16
(a)
 x  10 2   y  10 2  1 (b)
 x  10 2   y  10 2  1
16 25 25 16
(c)
 x  5 2   y  5 2  1 (d)
 x  5 2   y  5 2  1
16 25 25 16
x 2 y2
5. Length of common tangent to x 2  y 2  16 and  1
25 7
9 9 9 9
(a) (b) (c) (d)
4 2 4 2 2 2
Head Office: Andheri: 26245223 MUMBAI / DELHI/ AKOLA / KOLKATA / LUCKNOW

6. Let S   3, 4  and S'   9,12  be two foci of an ellipse. If the coordinates foot of the perpendicular
from focus S to a tangent of the ellipse is 1, 4  then the eccentricity of the ellipse is:
5 4 5 7
(a) (b) (c) (d)
13 5 7 13
7. Let ' P ' be 1, 0  and Q be any point on the parabola y2  8x . The locus of mid point of PQ must be
(a) y2  4x  2  0 (b) y2  4x  2  0 (c) x 2  4y  2  0 (d) x 2  4y  2  0
8. For a ABC , co-ordinates of the vertices B and C are  2, 0  and  8,0  respectively. The vertex A is
B C
varying in such way that 4 tan tan  1 , then the locus of A is
2 2
(a)
 x  5 2  y 2  1 (b)
 x  5 2  y 2  1
25 16 1 25
(c)
 x  5 2 
y2
1 (d)
2
 x  5  y2  1
25 9 9 25
9. If point P  x, y  is such that it moves on a hyperbola
 x  32   y  4 2  x 2  y 2  k 2  1 , then number of possible integral values of k is
(a) 2 (b) 3 (c) 4 (d) 5
10. Locus of the mid points of the chords of the hyperbola x 2  y 2  a 2 that touch the parabola
y2  4ax is
(a) x 2  x  a   y3 (b) y2  x  a   x 3
(c) x 3  x  a   y 2 (d) y3  x  a   x 2
11. The line 2px  y 1  p2  1,  p  1 for different value of p touches

2 3
(a) An ellipse of eccentricity (b) An ellipse of eccentricity
3 2
(c) Hyperbola of eccentricity 2 (d) none
12. The triangle formed by the tangent to the parabola y2  4x at the point whose abscissa lies in the
interval a 2 , 4a 2  , and the coordinate axes, has the greatest area equal to
 
(a) 12 a 3 (b) 8a 3 (c) 16a3 (d) none of these
13. One vertex and focus of hyperbola with eccentricity 3 2 are  3,0  and  6, 0  respectively. The
equation of the hyperbola is
(a) 4x 2  4y 2  30y  0 (b) 3x 2  7y3  10x  57  0
(c) 5x 2  4y 2  20x  135  0 (d) 5x 2  3y3  45  0

x 2 y2
14. The radius of the circle through the foci of the hyperbola   1 and having its centre at  0,3
16 9
is
(a) 34 (b) 5 (c) 4 (d) 7
15. The parabola y  x 2  8x  15 cuts the x  axis at P and Q. A circle is drawn through P and Q so
that the origin 'O' is outside. Then the length of the tangent to the circle from ‘O’ is
(a) 15 (b) 8 (c) 15 (d) 8
x 2 y2
16. Two tangents are drawn to an ellipse   1 from a variable point P  h, k  ; if the points in
a 2 b2
which these tangents meet the coordinate axes of the ellipse be concyclic, then the locus of P is
(a) an ellipse (b) rectangular hyperbola
(c) parabola (d) circle
PART II: Multiple Correct Answer(s) Type
This section contains 10 multiple choice questions. Each question has four choices
((A), ((B), ((C) or ((D) out of which ONE or MORE are correct. (+4, –1)
17. If  x, y  be a variable point on the line y  2x lying between the lines 2  x  1  y  0 and
x  3  y  1  0 then
 1 6  1 3  3  6
(a) x    ,  (b) x    ,  (c) y   1,  (d) y   1, 
 2 7  2 7  7  7
18. A ray of light travelling along the line x  y  1 is incident on the x  axis and after refraction it
enters the other side of the x  axis by turning  6 away from the x  axis. The equation of the line
along which the refracted ray travels is
 
(a) x  2  3 y  1  
(b) 2  3 x  y  1
(c) y   2  3  x  2  3 (d) none of these
19. The equation 2x 2  3xy  py 2  x  qy  1  0 represents two mutually perpendicular lines if

9
(a) p  3, q  2 (b) p  2, q  3 (c) p  2, q  3 (d) p  2, q  
2
20. Let the equation of a circle be x 2  y 2  a 2 . If h 2  k 2  a 2  0 then the line hx  ky  a 2 is the

(a) polar line of the point  h, k  with respect to the circle
(b) real chord of contact of the tangents from  h, k  to the circle
(c) equation of a tangent to the circle from the point  h, k 
(d) none of these

21. A focal chord PP’ of a parabola cuts the axis of the parabola at O. The feet of the perpendiculars
from P and P’ on the axis are M and M’ respectively. If V is the vertex then VM, VO, VM ' are in
(a) AP (b) GP (c) HP (d) none of these
22. Let there be two parabolas with the same axis, focus of each being exterior to the other and the latus
rectum being 4a and 4b . The locus of the middle points of the intercepts between the parabolas
made on the lines parallel to the common axis of symmetry is a
(a) straight line if a  b (b) parabola if a  b
(c) parabola for all a, b (d) none of these
23. If y  x and 3y  2x  0 are the equations of a pair of conjugate diameters of the ellipse
x 2 y2
  1 then its eccentricity is
a 2 b2
1 1 1 3
(a) (b) (c) (d)
2 3 3 2
24. A focus of the hyperbola 25x 2  36y 2  225 is

1   1 
(a)  61, 0  (b) 
2
61, 0 


(c)  61, 0  (d)  
 2
61, 0 

25. The point P on the ellipse 4x 2  9x 2  36 is such that the area of the PF1F2  10 where F1, F2
are foci. Then P has the coordinates
 3  3   3    
(a)  , 2 (b)  , 2  (c)   , 2  (d)   , 2 
 2  2   2   2 
26. A point on the ellipse x 2  3y 2  37 , where the normal is parallel to the line 6x  5y  2 , is
(a)  5, 2  (b)  5, 2  (c)  5, 2 (d)  5, 2 
PART III: PARAGRAPH TYPE
This section contains 6 multiple choice questions relating to three paragraphs with two
questions on each paragraph. Each question has four choices ((A), ((B), ((C) and ((D) out of
which ONLY ONE is correct. (+3,0)
PARAGRAPH – I
2
 x  1 y2
A tangent line L to the curve   1 passing from the point A  3, 2  cuts the circle
6 2
x 2  y 2  4x  6y  9  0 at points P and Q. Further the tangents drawn at P and Q intersect at point
R.
27. Co-ordinate of R may be

(a)  4, 6  (b)  6, 4  (c)  4, 1 (d)  4,1

28. The possible point of contact of line PQ with curve can be
(a) ( 2, 1) (b) (2, 1) (c) (4, 1) (d) (-2,1)
PARAGRAPH – II
Consider the circle x  y  9 and the parabola y 2  8 x . They intersect at P and Q in the first and
2 2
fourth quadrants, respectively. Tangents to the circle at P and Q intersect the x axis at R and the
tangents to parabola at P and Q intersect the x axis at S
29. The ratio of the areas of the triangles PQS and PQR is
(a) 1: 2 (b) 1: 2 (c) 1: 4 (d) 1:8
30. The radius of the incircle of the triangle PQR is

(a) 4 (3) 3 (c) 8/3 (d) 2
PARAGRAPH – III
Let ABCD be a square of side length 2 units. C2 is the circle through vertices A,B,C,D and C1 is the
circle touching all the sides of the square ABCD. L is a line though A
31. A circle touches the line L and circle C1 externally such that both the circles are on the same side of
the line, then the locus of centre of circle is
(a) ellipse (b) parabola (c) hyperbola (d) parts of straight line
PA2  PB 2  PC 2  PD 2
32. If P is a point of C1 and Q another point on C2 then is equal to
QA2  QB 2  QC 2  QD 2
(a) 3/4 (b) 5/4 (c) 1 (d) 1/2
PART IV: Integer Answer Type
This section contains 6 questions. The answer to each question is a single digit
integer, ranging from 0 to 9 (both inclusive) (+6,–1)
33. The straight line L : x  y  1  0 and L1 : x  2 y  3  0 are intersecting. M is the slope of the straight
line L2 such that L is the bisector of the angle between L1 and L2 . The value of |M| is
t 
34. If four distinct points (2,3) , (0, 2) , (4,5) , (0, t ) are concyclic, then   equals
5
35. Let A be the centre of the circle x 2  y 2  2 x  4 y  20  0 . The tangents at the points B(1,7) and
C(4,-2) on the circle meet at the point D. If  denotes the area of the quadrilateral ABCD, then the
number of factors of  is

36. If the length of the semi major Axis of an ellipse is 68 and the eccentricity is 1/2, then the area of the
rectangle formed by joining the vertices of the latera recta of the ellipse is A. The value of  A / 1000

37. Angle between the tangents drawn from (1,4) to the parabola y 2  4 x is , where m is equal to
m
1 1
38. If e1 and e2 and the eccentricies of a hyperbola and its conjugate, then 2  2 is
e1 e2
PART V: Matrix Match Type
39. Match the entries of col. I with col. II under the following conditions:
Column I Column II
(a) The x  co-ordinate of the point of intersection of (p) m  1
lines 3x  4y  9 and y  mx  1is an integer.
Then m  .............
(b) The line 2x  3y  6 cuts the axis of co-ordinates in (q) m  2
A  a, 0  and B  0, b  and the line y  mx  m 2
passes through  a, b  , then m  .....
(c) If the point  3, 4  lies on the locus of the point of (r) m  4
intersection of the lines x cos   y sin   m and x
sin   m and x sin   y cos   n such that
3m  4n  0 , then m 
8
(d) If the line y  mx  meets the curve y2  4x at (s) m  4
m
a point where the curve meets the line y  2 , then
m

PART TEST – 4 (ANSWER KEY)
PHYSICS
1.B 2.D 3.B 4.D 5.C 6.A 7.C
8.C 9.D 10.C 11.D 12.A 13. D 14.A
15. A 16.B 17.ABD 18.ABCD 19.BD 20.BC 21.ACD
22.ABC 23.BC 24.ACD 25.AD 26.BCD 27.D 28.D
29.C 30.A 31.B 32.A 33. 3 34.1 35.3
36.5 37.3 38.4 39. a  s, t; b  q, r, t;c  p, r; d  q
CHEMISTRY
1.(c) 2. (c) 3. (b) 4. (a) 5. (c) 6. (b) 7. (a)
8. (d) 9. (c) 10. (a) 11. (c) 12. (b) 13. (b) 14. (b)
15. (c) 16. (a) 17. (a, b, c) 18. (a, b, c, d) 19. (a, b) 20. (a, b, c) 21. (b, c, d)
22. (A, B, C) 23. (B, C) 24. (a,b,c) 25. (a,d) 26. (a, b, c, d) 27. (d) 28. (b)
29. (a) 30. (b) 31. (c) 32. (c) 33. (5) 34. (4) 35. 2
36. (3) 37. (2) 38. (8) 39. A – P, R; B – Q, S; C – Q, S; D – P, Q,S
MATHS
1. (b) 2. (d) 3. (a) 4. (a) 5. (b) 6. (a) 7. (a)
8. (3) 9. (b) 10. (b) 11. (b) 12. (d) 13. (c) 14. (a)
15. (c) 16. (b) 17. (b, d) 18. (b, c) 19. (b, d) 20. (a) 21. (b)
22. (a, b) 23. (c) 24. (b, d) 25. (a, d) 26. (b, d) 27. (d) 28. (a)
29. (c) 30. (d) 31. (b) 32. (a) 33. 2 34. 3 35. 6
36. 6 37. 3 38 . 1 39.  a    p,q  ,  b    p, q  ,  c    r,s  ,  d    q, r 

Part Test 4

Загружено:

Сведения о документе

Исходное описание:

Оригинальное название

Авторское право

Доступные форматы

Поделиться этим документом

Поделиться или встроить документ

Параметры публикации

Этот документ был вам полезен?

Это неприемлемый материал?

Авторское право:

Доступные форматы

Part Test 4

Загружено:

Авторское право:

Доступные форматы

ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT – JEE - 2013 PART TEST – 4 MARKS: 148

PART I: Single Correct Answer Type

4. A charge is uniformly distributed on a wire such that linear charge density is  λ.

(A) +2 (B) -1 (C)-2 (D) Zero

7. Figure shows the path of an electron in a region of uniform magnetic field.

10. In the shown AC circuit phase difference between currents I1 and I2 is

(A) RC ln 3 (B) 2 RC ln 2 (C) RC ln 3 (D) 2 RC ln 3

PART II: Multiple Correct Answer(s) Type

18. A thin conducting rod AB is introduced in between the two

21. In an RLC series circuit shown in figure the readings of voltmeters V1

22. A resistor and an inductor in series are connected to a battery

26. In the circuit shown

PART III: PARAGRAPH TYPE

A circuit is shown in the adjacent figure and switch S is closed at t = 0.

27. Charge stored in C as a function of ‘t’ is.

Here  is a positive constant having units of C/m3.

29. The value of  in terms of Q and R is

31. The induced current in the loop is as a function of velocity V

SECTION IV: Integer Answer Type

33. A rod of mass m  2 kg and length l  3 m rotates about an axis passing

35. In the circuit shown in the adjacent diagram initially switch K1 is

Potential difference between plates increases.

(b) Insertion of dielectric when battery is (q)

(c) Removal of dielectric when battery is not (r)

(d) Insertion of dielectric when battery is not (s)

Charge present on plates decreases.

(t) Electric field remains constant.

1.B 2.D 3.B 4.D 5.C 6.A 7.C

8.C 9.D 10.C 11.D 12.A 13. D 14.A

15.A 16.B 17.ABD 18.ABCD 19.BD 20.BC 21.ACD

22.ABC 23.BC 24.ACD 25.AD 26.BCD 27.D 28.D

29.C 30.A 31.B 32.A 33. 3 34.1 35.3

36.5 37.3 38.4

39. a s,t bq,r,t cp,r dq

5. For the reaction

6. The pH of a solution obtained by dissolving 5  10 4 moles of Ca(OH)2 (strong electrolyte) to 100

7. The pH of a solution of M(OH)2 is 10.6. The Ksp value of M(OH)2 is

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

17. Which of the following statements is correct about angular nodes?

(a) Plot P shows that the energy of activation is independent of temperature

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

20. Select the correct statements about galvanic cells

21. Select the correct statements

22. Correct statements are

23. Which of the following statement(s) is/are true?

24. Which of the following mixtures will act as buffer?

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

SECTION-III (Paragraph Type)

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

The thermal decomposition of N2O5 occurs as : 2N2O5  4NO2 + O2

29. The ate of reaction is given by:

32. [Ag+] required to just start the precipitation of AgCl is

SECTION-IV (Integer Answer Type)

34. If 50% of CO2 converted to CO at the following equilibrium:

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

36. The chemical reaction between K2C2O4 and HgCl2 is

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

1. (c) 2. (c) 3. (b) 4. (a) 5. (c)

6. (b) 7. (a) 8. (d) 9. (c) 10. (a)

31. (c) 32. (c) 33. (5) 34. (4) 35. 2