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Date of publication xxxx 00, 0000, date of current version xxxx 00, 0000.
Digital Object Identifier 10.1109/ACCESS.2017.Doi Number

Classification and review of the charging


strategies for commercial lithium-ion
batteries
Yizhao Gao1,Student member IEEE, Xi Zhang1*,Senior member IEEE, Qiyu Cheng1, Bangjun Guo1,Jun
Yang1
1
School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai, China
Corresponding author: Xi Zhang (braver1980@sjtu.edu.cn)

This research is supported by the National Natural Science Foundation of China (NSFC) under the Grant number of 51677118 and National
Key R&D Plan Key Special Project (2017YFE0102000)

ABSTRACT The growing demand for lithium-ion battery in electric vehicles has expedited the need for
new optimal charging approaches to improve speed and reliability of the charging process without
deteriorating battery performances. Many efforts have been deployed to develop optimal charging strategies
for commercial lithium-ion batteries over the last decade. The active optimal charging strategies have great
potential to meet the requirement. The present paper is a review of the studies on the constructing of
optimal charging algorithms for Li-ion batteries. The battery models on which these protocols rest are
stated, the generalized structures are examined, the advantages and the drawbacks of the mathematical
controller algorithms are discussed and their applications are presented. Suggestions for overcoming the
shortcomings of the proposed strategies are proposed. Challenges and future directions in the development
of optimal charging strategies for commercial Li-ion batteries are also discussed.

INDEX TERMS Fast charging, Optimal charging strategies, Lithium-ion battery

I. INTRODUCTION in order to figure out the most suitable charging strategy.


Lithium-ion (Li-ion) batteries have been commercialized In general, the available Li-ion battery charging strategy
for plug-in hybrid (PHEVs) and electrical vehicles (EVs) as can be divided into three classes based on the internal
a result of their higher energy density, longer lifespan mathematical models. The first category is a model-free
compared to their lead-acid and nickle-metal hydride methodology, including constant-current (CC), CC
alternatives[1],[2],[3]. Different from fuel-driven internal constant-voltage (CCCV), multi-stage CCCV and pulse
combustion engine, battery charging process is much more charging techniques[18],[5],[19].These approaches can be
complicated, due to its slow charging speed and unclear characterized by their predefined charging profiles with
effects of charging strategies on battery performances[4], fixed current, voltage, and/or power constraints but
[5],[6]. Lithium-ion battery charging speed becomes a ignoring the responses of battery dynamics. Considering the
bottleneck of EVs popularization [7],[8]. The US operability of model-free methods, the corresponding
Department of Energy (DOE) has set a charge goal of 10 programs are viewed as heuristic. Hence, this motivates the
miles of range per minute for fast charge [9]. For an EV necessity to explore advanced charging strategies in order
with 100 mile range (24 kWh battery pack), the DOE goal to meet fast charging requirements and alleviate the impact
is to charge full in 10 min (6C rate). However, simply on battery state-of-health (SOH) meanwhile.
increasing the charging rates may cause striking The second category of charging strategies utilizes
temperature rise and accelerate side reactions[10],[11],[12]. empirical models such as equivalent circuit-based models
The trade-off between fast charge and battery health should and neural network models[20]. These models predict
be taken into account at the same time[13],[14]. Therefore, battery states and calculate electrical elements using past
the battery optimal charging scheme has gained much experimental data. By means of different circuit models,
attention in the research field of EVs/PHEVs[15],[16],[17]. Kalman-type filters [21], recursive least squares [3], sliding
An appropriate optimal charging protocol is desirable to mode observers [22] and moving horizon estimations [23]
improve the charging efficiency, minimize any were adopted to estimate battery states. Meanwhile,
performances attenuation, and sustain a safe operation of a frequency optimization [24], multi-objective optimization
LIB system. Over these years, many studies have been done

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[25], fuzzy control [26], linear quadratic control [27] and A. Constant-current constant voltage related charging
model predictive control [28] were formulated to improve methods.
charging performances. The empirical models are The constant current constant voltage (CC/CV) charging
computationally fast and simple, but unable to reflect algorithm is widely adopted in charging Li-ion batteries
physics-based parameters and battery aging[28]. Therefore, because of its simplicity and easy implementation
an empirical model oriented charging control protocol may [37],[38],[39] . Under the CC/CV algorithm, the battery is
fail to work properly after certain cycles[29],[30]. initially charged with constant current until the battery
The charging algorithms based on electrochemical voltage reaches a preset maximum charging voltage, then the
models governed by kinetics and transport equations are charging voltage is held constant until the current is reduced
more sophisticated[31]. The closed-loop optimization to a preset minimum value[40]. The charging curve of the
problems can be formulated to minimize charging time and CC/CV is shown in Fig.2.
compensate for model uncertainties and disturbances [32]. Pre-installed charge
In addition, temperature variation can also be predicted
with thermal-related relations. Thus, the electrochemistry-
command
based control algorithm is close to actual battery
mechanism when used as a state observer. However, the
intractable computation complexity associated with full- Charge the Battery
order nonlinear partial-differential equations (PDEs) limits
the further application to a real-time charging controller
[33].
As a result, proposing an appropriate optimal charging
Upper
limits are No
scheme of commercial Li-ion battery is a challenging task.
This target means that the battery should be charged as reached
soon as possible while the temperature rise and aging
Yes
effects are kept within the acceptable range. Recently, the
diversity and multitude of existing studies dealing with Charge
optimal charging strategies provide a large amount of terminated
information.
In this review, we intend to summarize the recent results FIGURE 1. Passive charging structure
on various battery optimal charging algorithms. The first
aspect presented here is the passive charging strategies Voltage
Vmax
including constant-current (CC), CC constant-voltage
(CCCV), multi-stage CCCV and pulse charging technique.
Their characteristics are summarized and compared. Then we
move on to the generalized structure of active optimal
charging protocol. Moreover, the reviewed optimal charging
protocols in the text including their data, results, the
investigated battery type and charging methods are Imax
summarized. Based on the information, their pros and cons Current
were compared and discussed. Furthermore, two tables for
passive charging protocols and active charging protocols, Time
respectively were presented. The suggestions and challenges
for battery optimal charging strategies are proposed in the
FIGURE 2. Constant current-Constant voltage curve
end. Many variants of the CC/CV charging strategy were
developed. A proposed multistage fast charging profile is
II. Passive charging profiles
split into three different stages, referred as CC-Ⅰ, CC-Ⅱ and
The passive charging strategies are characterized by
CV-Ⅰ depicted in Fig.3. The algorithm is based on the
charging the battery under pre-set instructions as shown in
evolution of internal resistance during charging [18, 41].
Fig.1. The charging protocol is stopped when the battery
Due to the cell’s smaller resistance in lower SOC range, the
reaches the terminal condition. Although the passive
highest current is applied. The last two stages are used as
charging algorithm is easy to operate, feedbacks of battery
the cell’s internal resistance increases rapidly. Experimental
states and health-related optimization constraints are not
results verify that the procedure is useful for avoiding a
considered during the charging process, which may shorten
considerable temperature rise and extending the cycle life.
the lifespan of battery[34],[35],[36].

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[42]. Compared to the conventional CC-CV method, this


SOC 100%
pattern can provide 57% more cycles and reduce 11%
CC-Ⅰ charging time.
Internal resistance

CC-Ⅱ
Current
B. Pulse charge based charging curve.
The pulse charge have been claimed to be a fast and
CV-Ⅰ
efficient charging algorithm for lithium-ion batteries
Time [44],[45],[46].
FIGURE 3. Current, state of charge, resistance profiles of the fast B.K.Purushothaman et.al concluded that by proper
charging technique selection of the current waveform parameters, the side
Another form of the multistage CC/CV method is reactions caused by lithium saturation at the particle
introduced in Fig.4, where a Vmax voltage is utilized to interface can be prevented [47]. A nonlinearly decreasing
charge the battery in the initial CV-mode during a very current density which conforms to the mass transfer
short period t 0 , subsequently followed by a standard coefficient variation could provide complete charging in
CCCV process [36]. This boost-charging technique ensures 3
less than hour [48]. However, this technique was based
that the fully discharged battery can be recharged to one- 4
third of its rated capacity without inducing any extra on simulation analysis, no corresponding experiments were
degradation effects. carried out. In addition, tracking the diffusion coefficient
t0
variation in real-time was computationally complex.
Vmax
Voltage

Current

Imax

tc tr

Current Time

Time FIGURE 6. Nonlinearly decreasing pulse charge technique

FIGURE 4. Voltage and current characteristics of boost-charging


Similarity, a state of charge(SOC) governed fast charging
technique method was used to charge the battery, which attempted to
minimize the parasitic reactions as well [49].The first
Stage1 Stage2 Stage3 Stage4 Stage5 charging stage consists of gradually increasing current
pulses concerning its higher impedance at lower SOC levels.
Voltage At the final stage of charging, the charging amplitude
gradually decreases to make up for the lower charge
acceptance by the battery at higher SOC levels. The
drawback of this strategy is insufficient theory support and
the value of pulse amplitude and width is arbitrary chosen.
In 2016, Bo Lu et al. demonstrated the design of
Current charging strategies for lithium ion batteries considering the
balance between diffusion induced stress and total charge
time based on the pulsed currents charging method [50].For
the two-stage charge methods, the galvanostatic operation
Time is first used and then followed by a potentiostatic operation.
FIGURE 5. Five-step constant current charging algorithm Moreover, two connective galvanostatic stages with
different currents followed by a potentiostatic stage were
Taguchi-based approaches are also applied to determine introduced in the three-stage charge methods.
the optimal charging pattern[6],[42],[43]. A five-step
constant current charging method was proposed in Fig.5 C. Summary of the reviewed passive optimal charging

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The data and results of the passive optimal charging commercial cylindrical batteries as the investigated battery
protocols reviewed in this paper are summarized in Table Ⅰ, type for passive optimal charging strategies ranging from
including the investigated battery type, charging methods, LMO to LFP. This cell type has a low energy but high
and parameters needed to be optimized. Their strengths and power density. In Ref [35], the prismatic LP battery was
limits were also presented. also used for validation.
As can be seen from Table Ⅰ, most studies chose the
TABLE Ⅰ
COMPARISON OF THE REVIEWED PASSIVE CHARGING STRATEGIES
Resistance Diffusion Taguchi- SOC Boost Pulse charging
evolution stress based based five governed charging based
based three- charging step multi-stage
stage CC/CV charging fast
charging charging
Reference [18] [50],[45] [42],[34] [49] [36] [47],[103],[104],[105]
Investigated Nanophosphate Not specified Commercial Commercial Cylindrical Not specified
battery type high power (LiMn2O4) (LiMn2O4) (US18500,);
LFP cell battery battery prismatic
(LP423048)
Charging Step1: CC-Ⅰ Two-stage Step1: CC-Ⅰ Step1: High pulse Nonlinearly
method Step2: CC-Ⅱ method: Step2: CC- Multistage currents decreasing charging
Step3: CV-Ⅰ Switching Ⅱ CC followed by current tracking the
the CC mode Step3:CC- Step2: CC-CV mode. mass transfer
to CV when Ⅲ Multistage coefficient evolution.
Csurf = 0 ; Step4:CC- CC-CV
Ⅳ Step3:
Three-stage Step5:CC-Ⅴ Multistage
method: CC- CC
Ⅰ, CC-Ⅱ, CV- Step4:CV
Ⅰ.
Charging 100% SOC 100% SOC 95% SOC 80% SOC in 30% SOC 100% SOC in 43.2
result within 20 min within 18 in 130.7 41.6 min within 5 min min
(Vmax=3.6 V, min (Imax=8 min (Imax=2 C) (Vmax=4.3 V, (Imax=8 C)
Imax=4 C) C) for two- (Imax=1.4 C) Imax=4.5 C)
stage method
or 15.6 min
(Imax=5 C)
for three-
stage
method.
Parameter 1.Number of 1.Minimum 1.Number 1.Swithing 1.Volatge 1.Initial charging
need to be stage. value of Li+ of stage. point of each threshold at the current.
optimized 2.Current concentration 2.Current charging initial pulse 2.Current decreasing
magnitude. at particle magnitude. stage. charging stage. rate.
3.Voltage surface. 3.Charging 3.Pulse
threshold. 2. Number of duration at frequency,magnitude
stage. each stage. and duty ratio.
Advantages 1.Easy 1.Accelerate 1.57% more 1.Reducing 1. Easy 1.The reactant
implementation the charging cycles, the charging implementation concentration buildup
2. Extended process and 11.2% less time and 2. No at the electrode and
cycle life (over lower the charging providing significant the concentration
5000 cycles) peak stress. time and optimum impact on overpotential are
3.Invariable improved battery cycle life. minimized
power charging performance
capability. efficiency and thermal
by 1.02% management.
compared to
CCCV
mode
Disadvantages 1. Charge rate 1.Battery 1. Requires 1.SOC 1. Charge rate 1. Hard to choose the
is not degradation very stable during is not proper parameters for
optimized. is not current and charging optimized. pulse sequence.
2. Charge considered. temperature, process 2. Charge 2. No corresponding
termination is 2. currents needs to be termination is experiment was
based only on Temperature must be estimated based only on carried out.
the cell voltage is not low. precisely. the cell voltage
measurement. controlled. measurement.
3. Temperature 3. Temperature
is not is not
controlled. controlled.

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The resistance evolution based, diffusion stress based, For the resistance based protocol, the charging process
Taguchi based, SOC governed and boost charging changes with cell internal resistance. For the diffusion
strategies are the variances of standard CC-CV method. The stress based protocol, the ion concentration at surface is
difference between them is the charging switching terms.

viewed as a trigger to activate the next charging stage. The Control


Input I(k)
Measurable variables
z(k)
Battery model
Taguchi Orthogonal Arrays based charging method divides
the charging process into five CC stages. At each stage, the +
Noise w(k)
Noise v(k)
+
current was optimized. The SOC governed multi-stage Estimated variables
charging method tried to decide the charging current based State estimation x(k)

on the SOC change while charging. In boost charging, a


short period of high current was applied to the battery to Optimal Solution
reach the identified voltage threshold. The number of stages, I(k)
Controller Constrains and
current magnitude in each stage, and stage duration were Reference

three critical parameters needed to be optimized for the


multi-stage charging algorithm. Due to the model-free FIGURE 7. Active optimal charging structure

characteristic, these methods could be implemented easily


and were proved to have a better performance in charging Generally speaking, the battery model is carefully
speed, cycle life or power capability compared to CC-CV designed to be lower-order and easy implementable for an
charging. However, battery health related indexes such as outstanding controllability[14],[50],[51]. The aim of
constituting such a battery model is to simulate the real
battery degradation and temperature were not considered
battery system dynamics under the specified loading current
and well controlled.
profile. The output variables of the model integrated with the
In nonlinear decreasing pulse charging profile, the
noise vector are used as input for observer. Given that the
charging current waveform is varying regarding pulse battery contains a lot of state variables, many of which are
frequency, duty ratio and current magnitude. From Table Ⅰ, unmeasurable, such as concentration and overpotential. Thus,
the pulse-based charging method requires 5 parameters to a robust and effective model-based estimator is required to
be optimized online to achieve the ideal performance. As a observe internal states of the battery system [51]. Based on
result, the computation stress on the controller is the highest the reduced-order battery model and state estimator, an active
among the reviewed passive optimal charging strategies. charging strategy is formulated with optimal control
Therefore, the implementation of pulse-based charging algorithm. Meanwhile, for better charging performances,
algorithm could be complicated in the real applications. constraints of battery health-related variables (temperature
To the best of our knowledge, the existing passive rise, side reaction rate and so on) need to be considered as
charging techniques are unable to fulfill the overall optimal outputs references.
charging objective in terms of implementation, charging
duration and health-conscious requirements, which urge the
development of the active charging algorithm. A. Commonly-used battery model
For controlling and estimating battery states online, it is
imperative to rely on a fast and accurate real-time
III. Generalized active optimal charging structure simulation on BMS[52],[53],[54]. Fig.8 shows the general
The commonly-used active battery charging management classification of control-oriented Li-ion battery models.
structure is often composed of three important elements.
They are the battery model, state estimator, and model
based controller. Taken the process noise into consideration, Control-oriented Li-ion
Battery Model
a closed-loop control structure for the battery optimal
charging strategy is formed as depicted in Fig.7.

Equivalent Circuit Electrochemical model

First-order Second-order Single Particle Other simplified


P2D Model
RC RC Model model

FIGURE 8. Classification of commonly-used battery models

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Recently, the equivalent circuit models have been widely +


RO C1 C2
used in BMSs due to its advantage of fast computation
[55],[56],[57].
R1 R2
Xiaosong Hu et al. presented a dual-objective optimal
charging strategy for LiNMC and LiFePO4 batteries based Uocv UL
on the first-order RC model [58]. The influences of the
charging voltage threshold, temperature, and health status
on the charging results were analyzed for the two types of
batteries. -
dz (t )  I (t ) (1)
= FIGURE 9. Equivalent circuit model
dt 3600Cn
dU (t ) U (t ) R1 (2) These electrochemical-based models have significant
=− + I (t )
dt 1 1 advantages over those equivalent circuit models because of
dh(t ) their physical based equations[51],[59],[60]. The Partial-
= −  I (t ) h(t ) +  I (t ) H (3) Two-Dimensional (P2D) model is unquestionably rigorous
dt and accurate[61],[37]. The Single-Particle-Model (SPM) is
V (t ) = Voc ( z(t )) + R0 I (t ) + U (t ) + h(t ) (4) useful in realizing quick responses but it is unsuitable for
where I, U, Cn, z and h are the current, output voltage, simulating high (dis)charge rates [20],[62],[63].The
nominal capacity, SOC and hysteresis voltage for LiFePO4 drawbacks of the SPM and P2D have motivated the
cell, respectively. development of simplified versions of the P2D model to be
In 2017 [33], an equivalent circuit composed of an ideal used in battery charging control.
voltage source ,an internal resistor, and two resistor- H.E.Perez et al. developed an optimal fast charging
capacitor (RC) pairs was put forward for model-based protocol via a coupled single particle model with electrolyte
charging management as illustrated in Fig.9. For battery and thermal dynamics[64]. In the coupled model, the anode
thermal modelling, the average cell temperature is and cathode solid concentration dynamics were described
approximately equal to the radial average temperature: with two PDE single particle subsystems. The electrolyte
1 concentration in three different domains (anode, separator
Ta = (Ts + Tc )
2 (5) cathode) was captured with a three-PDE electrolyte
where Ts is the surface temperature, Tc is the core subsystem. The temperature was fed back into the voltage
output and solid/electrolyte dynamics. Due to the coupled
temperature and Ta is the average temperature. The
electrochemical-thermal dynamics, the optimization
governing equations for Ts and Ta are expressed as: problem is highly nonlinear.
Changfu Zou et al. have done considerable work on
dTs ( t ) T f − Ts ( t ) 2 (Ts ( t ) − Ta ( t ) ) (6) proposing physics-based low-order battery models to
= − simulate charging strategies[33]. In 2018, a PDE-based
dt Ru Cs RsCs
SPM with electrolyte states was formulated to simulate the
battery dynamics as expressed in Eq.8-11. The model order
dTa ( t ) T f − Ts ( t ) Ts ( Cs − Cc ) − Ta ( Cs − Cc ) Q (t ) (7) was reduced based on three assumptions [52].
= + +
dt 2 Ru Cs RsCcCs 2Cc
where T f is the ambient temperature, RC and Ru are 3 (8)
Cs− (t ) = − I (t )
separately the heat conduction resistance and convection FR as− L−

p

resistance. Cs and CC are the surface heat capacity and Cs+ (t ) = [ns − L− s−Cs− (t )] / ( L+ s+ ) (9)
core heat capacity, respectively. However, its model 
C (t ) = C
ss

s (t ) + 1 (t ) + 2 (t )

1

2
(10)
parameters need to be firstly determined according to
dCe ( 0, t )

De   1 − tc0 (11)
experimental results and battery aging factors are not
= Ce ( 0, t ) − Ce0  I (t )
considered. dt L ,2 e  FL  e
In particular, the electrolyte concentration Ce and the
anode over-potential of side reactions s− were included in
the output vector considering aging effects. The state-space
function of battery model is listed as:

u ( t ) := I ( t ) (12)

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x ( t ) := [Cs− ( t ) , 1− ( t ) , 2− ( t ) , 1+ ( t ) , 2+ ( t ) , (13) included in solving the problem. The cost function for
C ( 0, t ) − C ,

C ( 0, t ) − C ,T ]
− + + T tracking a reference trajectory SOC r with input current
e e0 e e0
u(k) and corresponding overall optimization current were
y ( t ) := [SOC (t ) ,T (t ) , Ce− ( 0, t ) ,s− (t )]T (14) organized as below:
z ( t ) := [V (t ) ,T ( t )] T
(15)
N (16)
u * ( k ) = arg min  y1 ( k + i ) - y1r ( k + i )
2

system input vector is u(t), x(t) is state vector, z(t) is u ( k ), s


i =0
Q

measurable system output vector and controllable output + u ( k + i )


2
+ s
2

vector is y(t). R P

N (17)
J ( x(k ), u(k ) ) =  y1 (k + i) − y1r (k + i)
2

Q
i =0

+ u (k + i)
2
Cs(r,t)- Cs(r,t)+ R
Rs- Rs+ r
s.t. i  0,..., N  , (18)
xˆ (k + i + 1) = Ak xˆ (k + i )
+ k u (k + i ) + ˆ (k )
Li+
yˆ1 ( k + i ) = Cxˆ ( k + i ) + d
xˆ (k ) = xˆ k | k
0- x
0+

FIGURE 10. Single particle model u ( k + i )  L


 k xˆ ( k + i ) + Fk u (k + i )  S k + s
s0
B. Classification of optimal charging strategies
Both the computational efficiency and charging rate of
The optimal charging targets are often related to the battery the MPC-based charging strategies are higher than
health-aware performances in two aspects, which are the traditional CCCV counterparts. However, the proposed
temperature rise and aging rate. Therefore, the optimal charging strategy applied a maximum current of 15 C to
charging strategy is formulated considering battery charge the battery in the beginning, and the cell voltage
performances and charging speed at the same time. exceeded the upper bound of 4.2V during charging. In Ref
The battery aging associated properties are selected from [33], the possibly fastest charging mode of the MPC-based
part of battery internal states. The overpotential of side algorithm is investigated by setting the weight factor to zero.
reactions occurring at cathode electrode or anode electrode It is found that the time required to charge the investigated
and the solid electrolyte interface (SEI) growth  SEI are battery from 10% SOC to the specified capacity level is no
considered as side effects results[4],[65],[66].The less than 788 s.
electrolyte concentration Ce is also viewed as an incentive Kailong Liu et al. implemented the generalized
predictive control (GPC) assisted with a proper battery
to side effects[31],[67],[68].Considering the particle
model to control the battery internal within certain range
mechanical stress induced by diffusion, the lithium
during the charging process[69]. A controlled auto-
concentration at the surface of particles Cs is limited no
regressive integrated moving average (CARIMA) model
less than zero[50],[64]. Based on empirical equations was used as an online self-tuning predictive model for a
between capacity loss and total discharge Ah throughout, GPC controller. The predictive control sequence was
the state of health (SOH) is selected as degradation obtained by minimizing a multistage cost function which
representatives[64]. The sharp temperature rise may lead to combined both battery charging time and energy loss:
battery thermal runaway. Hence, battery temperature
control is taken into account along with aging prevention in t =t f (19)
most cases[33],[51].
In order to solve the optimal charging problem, it is
J = (1 − a1 )  t f + a1  
t =0
i(t) *(V (t ) - U OCV (t ))

necessary to formulate an effective charging strategy based + i(t )  Tin (t )  dU OCV (t ) / dTin (t )dt
on the battery model.
Changfu Zou et al. employed a linear time-varying (LTV)
t f denotes the time when the battery reaches its final
model predictive controller (MPC) to optimize charging
profiles[51]. By using a fast moving horizon estimation SOC level. 0  a1  1 is the weighting factor to balance the
(MHE) to observe battery internal states in the presence of two objectives (charging time and energy loss). The main
model mismatch, noise, and disturbances, the fast charging drawback of the GPC-based control strategy is that many
process was formulated as a constrained LTV-MPC tuning parameters should be chosen carefully in advance
problem. Meanwhile, health-related constrains were also

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and the polynomial matrices are high-dimension, which power P and battery aging cost caging are the variables to be
adds up difficulties to real-time application.
optimized. The electricity price is reflected by pr and t is
Xianke Lin et al. developed the optimal charging
strategies using the dynamic programming (DP) the time step. n park and t are indices for the number of the
technique[70]. Both charging time and battery degradation parking events of a car and the charging time respectively.
were traded off and optimized. The charging time t f , SEI The main drawback of Annette’s strategy is that the
growth  SEI and lithium plating  plating were considered in tremendous information on vehicle usage history is needed
[71].
the cost function in SOC domain :
arg min  ( P ( n , t )  pr (t )  t + c (n ,t ) ) (24)

SOChi
min (  tchar +    SEI +    plating ) (20) P , caging n park t
park aging park

I ( SOC ) SOClo

In 2016, Sourav Pramanik et al. introduced an optimal


By fixing different weight factors ( ,  ,  ) at specified strategy for charging under Pontryagins principle with both
values, the minimum time strategy and health-conscious state and input constrains [72]. The proposed charging
fast charging strategy were investigated. For the minimum algorithm is capable of shortening the charging time while
time strategy, it took 19 min 18 s to achieve a target SOC of satisfying the temperature constraint compared with
61% from 1.7% SOC and the charging duration increased standard CCCV charging. The performance index was
to 29 min 7 s for the health-conscious strategy. defined as:
Unfortunately, the weight factors for the recyclable lithium T f
(25)
P.I . =   ( I max − I (t )) +  (Tmax − T (t )) +  I (t ) dt
2 2 2
consumed in SEI growth and lithium plating were treated as
equal at random. 0

In[64], the Legendre-Gauss-Radau (LGR) pseudo-


spectral method with adaptive multi-mesh-interval The performance index was chosen as such to minimize the
collocation was employed to solve the resulting nonlinear effort and to keep the current and bulk cell temperature
multi-state optimal charging problem. The objective close to the maximum thresholds. Combined with battery
function J is given by: model, the Hamiltonian function was constructed:
H(C s ,T,1 ,2 , t)= ( I max − I (t )) +  (Tmax − T (t )) +  I (26)
2 2 2


tf
min 1 dt (21)
I ( t ), x ( t ), t f t0
 6i0 F 
+ 1  − sinh(  (t )) 
where ( t f − t0 ) is the charge time to reach a desired  RF RT 
 1
+ 2  avg  hcell (Tmax − T ( t ) ) + I ( t )V ( t )
target SOC. The optimization variables are the input
current I(t) and final time tf, with state variables:  c
 p

n   
+

3 U
0

x(t ) = [cs+ (r, t ), cs− (r, t ), ce+ ( x, t ), cesep ( x, t ), ce− ( x, t ), Tc (t ), Ts ((22)


t )]T −   FJ (t )(U i (t ) − T (t ) ) dx   
 
i =1  0−R T  
• H ( • ) (27)
Two charging strategies were proposed using the linear 1 = =0
quadratic control theory by Huazhen Fang in 2017[27]. One Cs
of them is based on linear quadratic control with fixed • H ( • ) h (28)
terminal charging rate. The other one is formed with 2 = = 2  (Tmax − T ) + 2
T  cp
avg

tracking a reference charging path. A linear quadratic state-


 n  0 3 U   
+
feedback formulation for tracking a reference trajectory rN h 
-2     FJ (t )  U i (t ) − T (t )  dx  
can be expressed as:  c p  i = 0  0 R
avg
 − T   
F  6i0   F 
1 (23) +1  cosh  
min ( xN − rN )T S N ( xN − rN )  RF  RT  
2
RT
u0 ,u1 ,..., uN −1 2

1 N −1
+  ( xk − rk )T Q( xk − rk ) + ukT Ruk  where  ,  are tunable parameters which gives the
2 k =0 flexibility to tune the charging performance based on
s.t. xk +1 =Axk +Bu k , x0 charging current and maximum rated limit. By solving the
equation, the optimal current trajectory at each time step
Another form of the quadratic constraint program was was obtained:
presented by Annette E.Trippe et al. in 2014, which
minimized total charging cost, charging electricity cost and V (t ) 1 (29)
I (t ) = I max − 2 
battery aging cost. Eq.18 describes the linear objective  c p 2
avg

function of the optimization problem, where charging

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C. SUMMARY AND COMPASIRON used electrochemical model in battery optimal charging.


Both of them are often coupled with thermal and aging
The characteristics of the reviewed active charging dynamics, which are of great importance to control and
strategies are summarized in Table Ⅱ. Their pros and cons optimize charging curve.
are highlighted. In order to demonstrate the connections and Generally, thermal effect is incorporated into the
differences among the reviewed optimal charging strategies controller via a two-stage approximation of the radially
more clearly, we intend to analyze them from two crucial distributed thermal model for equivalent circuit models[73].
aspects, which are internal battery model and optimal However, the energy dissipated by electrode is assumed to
control algorithms. represent the Li ion contribution and have an impact on the
total heat generation [74],[75],[76].
1) ASSESSMENT OF THE REVIEWED BATTERY An empirical equation between input current and
MODELS capacity fade is adopted to indicate the aging effects for
As can be seen in Table Ⅱ, the commonly-used battery equivalent second-order RC model[73]. In SPM, the Li ion
type are LiFePO4, LiCoO2, and NMC. Many different kinds concentration in both solid and electrolyte phase and the
of battery models are utilized to estimate the battery overpotential of side reactions are constrained within a
internal states. The first-order RC [69] model and second- narrow range to prevent the battery from degradation. As
order RC model[27] have been used in control and optimal for the SOC estimation method, the equivalent circuit
applications due to its simple circuitry representation and model calculates the SOC by coulomb counting, while the
easy to configure and identify the parameters compared to
other mechanism models. The SPM is the most frequently

TABLE Ⅱ
COMPARISON OF THE REVIEWED ACTIVE OPTIMAL CHARGING STRATEGIES

Model Generalized Dynamic Legendre- Pontryagins Linear Linear


Predictive Predictive Programmin Gauss- minimum Quadratic optimization
Control Control g (DP) based Radau principle based
(MPC) based (GPC) based pseudo- based
spectral
based
Reference [51],[32],[33], [69] [70] [64],[73] [72] [27] [71]
[77]
Investigated Not specified LiFePO4 LiFePO4 LiFePO4 LiCoO2 Not 18650 NMC
battery type specified
Battery model SPM with First-order SPM with SPM with SPM Second Not specified
electrolyte RC model electrolyte electrolyte order
RC model
Characteristic 1.Model- 1.Cell 1.DP was first 1.Solid 1.A 1.Health- 1.Several
based, closed internal employed to and performance aware and Electric
loop and temperature the optimal electrolyte index that user vehicles in
health-aware. was within a charging phase aims at involved. Singapore
2. Battery desirable problem. concentrat balancing and four
internal states range. 2. The ion the cell different
were CARIMA constraints temperature scenarios
observed by model was and and charging were
MHE developed as temperatur current was evaluated.
algorithm. online self- e defined.
tuning tool. constraints
were
satisfied.
2.Differen
t input
current
bounds for
fast
charging
is
provided.
Charging 100% SOC in 80% SOC in 100% SOC in 50% SOC 100% SOC 95% SOC Constant
result 781s 1498.21s 1158s in 4.4822 in 2758s in 2h power
(Imax=15C) (Imax=3C) (Imax=6C) for min (Imax=2C) (Imax=3C) constant
fast charging (Imax=8.5C voltage mode
or 1747s ) (CPCV) with
(Imax=5C) for Icut-off=110mA
health-
conscious
charging

VOLUME XX, 2017 9

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10.1109/ACCESS.2019.2906117, IEEE Access

Parameter SOC I SOC I I V SOC


need to be T V Ce  T I
controlled
online Ce SOC  Ce
 side V Cs
T

Parameter Not specified Not specified tchar t char SOC SOC Pch arg ing
need to be
 SEI caging
optimized
 plating
Advantage 1.Promoting 1.Battery fast 1.Charging 1.Constrai 1.Battery 1.Meeting 1.Optimizing
the charging charging and time and nt temperature user- the charging
rate by 22%. internal battery satisfactio was defined process cost
2.Safety temperature degradation n to ensure controlled charging and battery
related control were were traded battery and abusive objectives aging cost.
constraints tackled off and safety and conditions with
could be simultaneousl optimized. longevity. were awareness
satisfied. y 2.Easy 2. Both SEI 2.Obtainin prevented. of the
3.Computatio Implementati growth and Li g new 2.Higher hazards.
n time < 10 on plating were optimal efficiency
ms. considered charging without
for aging protocols compromisin
mechanism. as the cell g
is cycled. electrochemi
cal kinetics.
Disadvantage 1.Hardware- 1.Battery 1.Battery 1.Aging 1. Battery 1.Only 1.Battery
in-the-loop degradation temperature dynamics aging factor simulation aging model
validation effects were was not was not was not validation, is simple
experiment not controlled incorporat considered. lacking without
was not considered. and ed. 2.No correspondi calendar
carried out. optimized. correspondin ng aging and CV
g experiment experiment. charging
was aging.
conducted.
I=Current, V=Voltage, SOC=State of charge,  = Electrode stoichiometric, C e =Electrolyte concentration, C s =Solid concentration, T =Temperature,
 side = Overpotential of side reactions, t char =Charging time,  SEI = Solid e electrolyte interphase growth,  plating =Li+ plating, Pch arg ing =Charging power,
caging =Aging cost.

SPM predicts it based on the Li ion concentration the impact of all environmental variables occurring in real
distribution and integration[64]. life conditions is not taken into account, which produces
Methods like electrochemical models and equivalent some errors.
models perform well but cannot be directly extended to Each of the presented algorithm can perform well in
other batteries (technology, design, materials)[77],[78],[79]. finding out a balanced solution for the two competing
Moreover, these two approaches are not performant to objectives: charging time and battery state-of-health. As is
model all degradation mechanisms occurring during the illustrated in Table Ⅱ. It is seen that the MPC-based control
battery life[80],[81],[82]. strategy is the most popular method to be
employed[86],[87],[33],[51]. There are two reasons for the
2) OPTIMAL CONTROL ALGORITHMS SUMMARY popularity of MPC techniques. First, its performance in
Every presented method tries to solve the optimal constraint and nonlinearity handling and model-based
charging problem by different manners but each one has its optimal or suboptimal control makes it applicable to a wide
own disadvantages. Most studies choose the maximum range of industrial problems[88]. Second, it has a good
current (up to 6C) [70] to charge the battery in the robustness and stability over many kinds of noises[89],[90].
beginning, this might bring high stress on power However, it has two limits:1) Hardware-in-the-loop
electronics[83],[84],[85]. In addition, many studies validate experiment was not conducted to validate the strategy .2)
the effectiveness of optimal charging with accelerated life The sensitivity of the proposed MPC framework to
tests[71], but this methodology has one main drawback. An parameter uncertainties including the weighting matrices
accelerated life test is usually done with a test bench. Hence, and initial values were not studied. Due to the high

VOLUME XX, 2017 10

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nonlinearity of this problem, the electrolyte dynamics 2) SUGGESTIONS FOR THE CHARGING OPTIMIZATION
approximation, SEI and plating static map were developed ALGORITHMS
to make the Dynamic Programming (DP) based charging 1.Most of the optimal control strategies reviewed in this
optimization possible[70]. The inconvenience here is the paper are implemented by solving the optimal problem with
complexity to handle massive data in controller induced by series of new performance indexes and constrained linear
DP process. The Legendre-Gauss-Radau (LGR) pseudo- matrix inequalities. However, the implementation cost in
spectral based method transcribed this infinite-dimensional hardware is not paid much attention to. In fact, to achieve
optimal control problem into a finite-dimensional better charging performances, the computation burden also
optimization problem with algebraic constraints at the increases significantly[96],[97],[98]. Hence, it is imperative
discretized nodes [73], but the convexity and convergence to develop a simple and fast optimal algorithm that can be
was not guaranteed. For Pontryagins minimum principle simulated in BMSs effectively.
based strategy [72], the algorithm calculates the states and 2. As a result of the wide diversification in battery types
co-state values to produce the corrected input current at and sizes due to the wide range of applications, the
each iteration. Therefore, the initial value for state variables reviewed optimal charging method might not be directly
were required to be precise. Regarding the linear extended to other batteries (technology, design,
optimization based methods[27], they have more materials)[99],[100],[101]. Thus, it is meaningful to
computational appeal in terms of time and space develop universal optimal charging strategies. This feature
complexity because of their exceptional simplicity. may be realized by the controller to auto-detect the battery
Whereas the choice of the gain matrix is a multifaced issue, chemistry responses when they are biased to some external
because it needs to account for both battery health signal or by big data-driven approach[102].
protection and charging speed and more broadly, the
economic cost and user satisfaction. 3) CHARGING STRATEGIES AT LOW TEMPERATURES.
1. Fast charging at subzero temperatures is an
IV. SUGGESTIONS AND CHALLENGES challenging task due to the poor low-temperature
Based on the above review of the open literatures performance of Li-ion batteries [107]. The Li plating is
concerning the optimal strategies of battery charging, it assumed to be the major unwanted side reactions at low
seems that the most promising candidate for the health- temperatures [108]. Though some efforts have been
aware optimal charging would be closed-loop and model- deployed to overcome these problems. A two-phase
based. Two elements are essential for this: 1. A simplified charging protocol composed of constant current (CC)
and controllable battery model. 2. An optimization and constant voltage (CV) phase is presented to prevent
approach which is computationally efficient and well-fitted battery degradation from Li plating [109]. By adding a
with the battery model. In light of this, here is a list of rapid internal heating step before charging, the cell is
issues regarding the two aspects that should be addressed in charged above a temperature that can prevent Li plating
the future investigations: [110]. The related studies are still insufficient. It is
1) SUGGESTIONS FOR THE CONTROL-ORIENTED important to systematically investigate the battery
BTTERY MODLES electrochemical model characteristics and aging
1. The electrochemistry-based battery model can have a mechanisms under low temperatures, which finally lead
high fidelity in reproducing battery dynamics which plays to optimized charging strategies.
an important role in health-conscious charging protocol.
For battery aging prevention, most studies chose side
reaction related parameters as a part of cost
function[51],[91]. For instance, the overpotential of side
reactions is constrained below zero to alleviate degradation V. CONCLUSION
[51]. However, to the authors knowledge, the aging Battery optimal charging strategies have been intensively
mechanism of battery charging has not been investigated researched and developed in recent years. This paper has
thoroughly. What are the consequences on selecting higher presented a thorough review of recent optimal charging
or lower bonds? Apart from SEI growth, which parameter methodologies for commercial lithium-ion batteries. They
should be calculated and taken into consideration for a are commonly grouped based on their mathematical model
better optimal curve? and embedded structure: passive and active controllers.
2. The battery properties change as battery ages Every of them is described in detail along with their
[92],[93],[94],[95]. Therefore, the real-time controller advantages, disadvantages and examples. While passive
should update battery parameters based on the input history charging strategies are simple to implement, it is clear that
data such as current, voltage and temperature. Finally, the they do not provide an optimal solution to maximize
on-line observation and the battery control and optimization charging speed and minimize deterioration. They lack the
performances will be improved. ability to maintain a good robustness when noises occur.
Active charging algorithm will improve the performance of

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This article has been accepted for publication in a future issue of this journal, but has not been fully edited. Content may change prior to final publication. Citation information: DOI
10.1109/ACCESS.2019.2906117, IEEE Access

[107] J. Jaguemont, L. Boulon, and Y. Dubé, "A comprehensive Bangjun Guo received the B.S. degree in applied physics
review of lithium-ion batteries used in hybrid and electric
from the Shandong University, Shandong, China, in 2013,
vehicles at cold temperatures," Appl. Energy, vol. 164, pp. 99-
114, 2016. and the Ph.D. degrees in physical electronics from the East
[108] S. Tippmann, D. Walper, L. Balboa, B. Spier, and W. G. Bessler, China Normal University, Shanghai, China, in 2018. Since
"Low-temperature charging of lithium-ion cells part I: July 2018, he is currently a postdoctor with the School of
Electrochemical modeling and experimental investigation of
Mechanical Engineering, Shanghai Jiao Tong University,
degradation behavior," J. Power Sources, vol. 252, pp. 305-316,
2014. Shanghai, China.
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strategies.
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S A, vol. 115, no. 28, pp. 7266-7271, Jul 10 2018.

Jun Yang received the B.E. degree in


vehicle engineering from Shanghai
Jiaotong Unversity, Shanghai, China,in
2016, and she is currently working toward
Yizhao Gao received the B.E. degree in the Master’s degree in SJTU of BMS.
automotive engineering from Hunan Her research interests include state
University, Changsha, China in 2016.He is estimation and simulation for lithium-ion
currently working toward the PhD’s degree batteries.
in the School of Automobile Engineering in
Shanghai Jiao Tong University.
His research interests include Battery
modelling and optimal charging strategy for lithium-ion
batteries.

Xi Zhang received the B.S. degree in


applied mathematics, the B.E. degree in
information and control engineering, and
the M.E. and PhD degree in power
electronics and electric power drive from
Shanghai Jiao Tong University (SJTU),
Shanghai, China, in 2002, 2004, and
2007, respectively. From 2007 to 2009, he held a post-
doctoral position with the Department of Electrical and
Computer Engineering, University of Michigan-Dearborn,
Dearborn, MI, USA. He is currently a Professor with the
National Engineering Lab for Automotive Electronics and
Control Technology, Institute of Automotive Engineering,
SJTU.
His research interests include power management
strategies, power electronics devices, and electric motor
control systems for alternative-fuel vehicles.

Cheng Qiyu received the B.E. degree in vehicle


engineering from Hunan Unversity, Changsha, China,
in2018, and she is currently working toward the Master’s
degree in SJTU of BMS.
Her research interests include state estimation and
simulation for lithium-ion batteries.

VOLUME XX, 2017 15

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http://www.ieee.org/publications_standards/publications/rights/index.html for more information.

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