[𝐶𝑑 〖𝐶𝑙〗 ^+]=21[ 〖𝐶𝑑〗 ^(+2)] 〖𝐶𝑑〗 ^(+2) [1+21[ 〖𝐶𝑙〗 ^− ]+165.9[ 〖𝐶𝑙〗 ^− ]^2+ 204.

05[ 〖𝐶𝑙〗 ^− ]^
[ 〖𝐶𝑙〗 ^−] 71.42[ 〖𝐶𝑙〗 ^− ]^4= 〖〖𝐶𝑑〗 _𝑇𝑜𝑡𝑎𝑙 〗 ^(+2)
[𝐶𝑑 〖𝐶𝑙〗 _2]=165.9[ 〖𝐶𝑑〗 ^(+2)
] 〖 [ 〖𝐶𝑙〗 ^−] 〗 ^2 〖𝐶𝑑〗 ^(+2)/ 〖〖𝐶𝑑〗 _𝑇𝑜𝑡𝑎𝑙 〗 ^(+2) =1/𝑓
[𝐶𝑑 〖〖𝐶𝑙〗 _3 〗 ^−]=204.057[
〖𝐶𝑑〗 ^(+2)] 〖 [ 〖𝐶𝑙〗 ^−] 〗 ^3
[𝐶𝑑 〖〖𝐶𝑙〗 _4 〗 ^(−2)]=71.42[
〖𝐶𝑑〗 ^(+2)] 〖 [ 〖𝐶𝑙〗 ^−] 〗 ^4
pCl [Cl-] f α1 α2 α3 α4
-2 100 7347718101 2.85803E-07 0.00022578 0.02777148 0.97200245
-1.9 79.4328235 2946600603 5.661063E-07 0.00035524 0.03470805 0.96493614
-1.8 63.0957344 1183849305 1.119239E-06 0.00055789 0.04329673 0.95614426
-1.7 50.1187234 476736765 2.207703E-06 0.00087411 0.05388562 0.94523806
-1.6 39.8107171 192537826 4.342134E-06 0.00136562 0.06687063 0.9317594
-1.5 31.6227766 78039414 8.509525E-06 0.00212585 0.08268705 0.91517858
-1.4 25.1188643 31772103.9 1.660249E-05 0.00329458 0.1017901 0.89489869
-1.3 19.9526231 13006655.5 3.221467E-05 0.00507786 0.12461946 0.87027039
-1.2 15.8489319 5360668.93 6.208695E-05 0.00777369 0.15154182 0.84062221
-1.1 12.5892541 2227695.28 0.0001186762 0.01180295 0.18276613 0.8053118
-1 10 935058 0.000224585 0.01774221 0.21822924 0.76380289
-0.9 7.94328235 397234.296 0.0004199258 0.02635115 0.25745703 0.71576937
-0.8 6.30957344 171187.972 0.0007740091 0.03858097 0.29941824 0.66122094
-0.7 5.01187234 75025.6967 0.0014028436 0.0555439 0.34240607 0.60063386
-0.6 3.98107171 33528.9595 0.0024934417 0.0784199 0.38400017 0.53505665
-0.5 3.16227766 15321.2568 0.0043343592 0.10828093 0.42116969 0.46614975
-0.4 2.51188643 7177.87476 0.0073489183 0.14583122 0.4505631 0.39611745
-0.3 1.99526231 3456.17339 0.0121233815 0.19109568 0.46898179 0.32750982
-0.2 1.58489319 1714 0.019418178 0.24312833 0.4739589 0.26291116
-0.1 1.25892541 876.917385 0.0301481463 0.29983871 0.46429373 0.20457905
6.38378E-16 1 463.377 0.0453194699 0.35802381 0.44036929 0.15412936
0.1 0.79432823 253.060294 0.0659166742 0.41363986 0.40413595 0.11235589
0.2 0.63095734 142.872192 0.09274096 0.46227316 0.35875981 0.0792268
0.3 0.50118723 83.3926794 0.1262093025 0.49971048 0.30805167 0.05403709
0.4 0.39810717 50.3227442 0.1661326446 0.52249492 0.25585104 0.03564967
0.5 0.31622777 31.397832 0.2115045104 0.52838043 0.20551893 0.02274679
0.6 0.25118864 20.2609575 0.2603510475 0.51663809 0.15962155 0.0140333
0.7 0.19952623 13.5287243 0.3097151499 0.48819074 0.11981044 0.00836687
0.8 0.15848932 9.35292382 0.3558540377 0.44555261 0.08685686 0.00481806
0.9 0.12589254 6.69816831 0.3946964668 0.3925458 0.06078486 0.00267833
1 0.1 4.970199 0.4225182935 0.33378945 0.0410561 0.00143696
1.1 0.07943282 3.81996157 0.4366769826 0.27402324 0.02677272 0.00074432
1.2 0.06309573 3.03785895 0.4361658802 0.21740963 0.01687267 0.00037261
1.3 0.05011872 2.49535503 0.4217809396 0.16699907 0.01029483 0.00018059
1.4 0.03981072 2.11201336 0.3958426932 0.12449437 0.00609614 8.49421E-05
1.5 0.03162278 1.83650258 0.3615994427 0.09033475 0.00351366 3.88891E-05
1.6 0.02511886 1.63543449 0.3225419013 0.0640049 0.00197751 1.73855E-05
1.7 0.01995262 1.48668327 0.2818388391 0.04442505 0.00109027 7.6138E-06
1.8 0.01584893 1.37531664 0.2420006864 0.03030007 0.00059068 3.27655E-06
1.9 0.01258925 1.29107666 0.2047704412 0.02036547 0.00031535 1.38953E-06
2 0.01 1.22679477 0.1711777756 0.01352304 0.00016633 5.82167E-07
2.1 0.00794328 1.17737907 0.1416781851 0.00889058 8.68631E-05 2.41492E-07
2.2 0.00630957 1.13915701 0.1163149953 0.00579779 4.49954E-05 9.93656E-08
2.3 0.00501187 1.10944227 0.0948668729 0.00375614 2.31551E-05 4.06177E-08
2.4 0.00398107 1.08624474 0.0769647051 0.00242058 1.18529E-05 1.65155E-08
2.5 0.00316228 1.06807329 0.0621753502 0.00155326 6.04158E-06 6.68681E-09
2.6 0.00251189 1.05379961 0.05005659 0.00099332 3.06898E-06 2.69812E-09
2.7 0.00199526 1.04256259 0.0401899214 0.0006335 1.55471E-06 1.08572E-09
2.8 0.00158489 1.03370029 0.0321976856 0.00040314 7.85881E-07 4.35938E-10
2.9 0.00125893 1.02670077 0.0257498916 0.0002561 3.96559E-07 1.74733E-10
3 0.001 1.0211661 0.0205647249 0.00016246 1.99827E-07 6.99397E-11
3.1 0.00079433 1.01678567 0.0164055153 0.00010295 1.00582E-07 2.79634E-11
3.2 0.00063096 1.0133162 0.0130759818 6.51781E-05 5.05832E-08 1.11706E-11
3.3 0.00050119 1.01056663 0.0104148817 4.12365E-05 2.54206E-08 4.45918E-12
3.4 0.00039811 1.00838656 0.00829072 2.60747E-05 1.2768E-08 1.77907E-12
3.5 0.00031623 1.00665738 0.0065968653 1.64803E-05 6.41017E-09 7.09477E-13
3.6 0.00025119 1.00528543 0.0052472276 1.04125E-05 3.21708E-09 2.82833E-13
3.7 0.00019953 1.00419666 0.0041725401 6.577E-06 1.61411E-09 1.1272E-13
3.8 0.00015849 1.00333244 0.0033172213 4.15338E-06 8.09667E-10 4.49133E-14
3.9 0.00012589 1.00264637 0.0026367655 2.6224E-06 4.06073E-10 1.78925E-14
4 1E-04 1.00210166 0.0020955958 1.65552E-06 2.03629E-10 7.12702E-15
4.1 7.94328E-05 1.00166914 0.0016653097 1.04501E-06 1.021E-10 2.83854E-15
4.2 6.30957E-05 1.00132567 0.0013232562 6.59585E-07 5.11889E-11 1.13043E-15
4.3 5.01187E-05 1.00105291 0.0010513862 4.16284E-07 2.56622E-11 4.50156E-16
4.4 3.98107E-05 1.00083629 0.0008353265 2.62714E-07 1.28644E-11 1.79249E-16
4.5 3.16228E-05 1.00066424 0.0006636375 1.6579E-07 6.44857E-12 7.13726E-17
4.6 2.51189E-05 1.0005276 0.000527218 1.04621E-07 3.23238E-12 2.84178E-17
4.7 1.99526E-05 1.00041907 0.0004188296 6.60183E-08 1.6202E-12 1.13146E-17
4.8 1.58489E-05 1.00033287 0.0003327168 4.16583E-08 8.12095E-13 4.5048E-18
4.9 1.25893E-05 1.0002644 0.0002643045 2.62864E-08 4.0704E-13 1.79352E-18
5 1E-05 1.00021002 0.0002099559 1.65865E-08 2.04014E-13 7.1405E-19
5.1 7.94328E-06 1.00016682 0.0001667811 1.04658E-08 1.02254E-13 2.84281E-19
5.2 6.30957E-06 1.00013251 0.0001324835 6.60372E-09 5.125E-14 1.13178E-19
5.3 5.01187E-06 1.00010525 0.0001052382 4.16678E-09 2.56866E-14 4.50582E-20
5.4 3.98107E-06 1.00008361 8.359552E-05 2.62912E-09 1.2874E-14 1.79384E-20
5.5 3.16228E-06 1.00006641 6.640342E-05 1.65889E-09 6.45242E-15 7.14153E-21
5.6 2.51189E-06 1.00005275 5.274683E-05 1.0467E-09 3.23391E-15 2.84313E-21
5.7 1.99526E-06 1.0000419 4.189875E-05 6.60432E-10 1.62081E-15 1.13188E-21
5.8 1.58489E-06 1.00003328 3.328165E-05 4.16708E-10 8.12339E-16 4.50615E-22
5.9 1.25893E-06 1.00002644 2.643673E-05 2.62927E-10 4.07136E-16 1.79394E-22
6 1E-06 1.000021 2.099956E-05 1.65897E-10 2.04053E-16 7.14185E-23
]^2+ 204.05[ 〖𝐶𝑙〗 ^− ]^3+ ([𝐶𝑑 〖𝐶𝑙〗 ^+])/ 〖〖𝐶𝑑〗 _𝑇𝑜𝑡𝑎𝑙 〗 ^(+2)
=(𝐾_1 [ 〖𝐶𝑙〗 ^−])/𝑓 ([𝐶𝑑 〖𝐶𝑙〗 _2])/
〖〖𝐶𝑑〗 _𝑇𝑜𝑡𝑎𝑙 〗 ^(+2) =(𝐾_2 [ 〖𝐶𝑙〗 ^−])/𝑓

([𝐶𝑑 〖〖𝐶𝑙〗 _3 〗 ^−])/

〖〖𝐶𝑑〗 _𝑇𝑜𝑡𝑎𝑙 〗 ^(+2) =(𝐾_3 [ 〖𝐶𝑙〗 ^−])/𝑓

([𝐶𝑑 〖〖𝐶𝑙〗 _4 〗 ^(−2)])/ 〖〖𝐶𝑑〗 _𝑇𝑜𝑡𝑎𝑙 〗

K1= 21 ^(+2) =(𝐾_4 [ 〖𝐶𝑙〗 ^−])/𝑓
K2= 165.9
K3= 204.057
K4= 71.42

Especies Posibles de Cd con Cl

1
0.9
Fracción de Cada especie

0.8
0.7
0.6 CdCl+
0.5 CdCl2
CdCl-
0.4
CdCl-2
0.3
0.2
0.1
0
-3 -2 -1 0 1 2 3 4 5 6 7
pCl