Chapter 24

Chemical shift in NMR spectroscopy is expressed as delta ( δ ) or tan(t). choose the correct relationship
between δ ∧t :
δ =10−t , δ =10+t , t=δ−1 0 , t=10−δ , 4
The water formed in the combustion analysis is usually absorbed by:
Mg(NO3)2, Mg(CiO4)2, Mg(OH)2, Mg(CIO2)2, 2
The infrared spectra commonly referred as IR spectra is usually expressed as:
Wavelength, Wave number, Frequency, All of the above, 2
The electronic transition that is involved in the visible region is:
σ −σ , d−d , π−π , π−π , 2

Tetramethylsilane (TMS) is added to the compound as standard while carrying out its NMR spectra the TMS
is a:
Non volatile compound, Less volatile compound, Highly volatile compound, Highly reactive compound, 3
Secondary structure of proteins is elucidated by which of the following technique?
Infrared spectroscopy, NMR spectroscopy, X-rays diffraction technique, All of the above, 4
Benzene molecule have six carbon atoms and six hydrogen atoms the NMR spectrum of benzene will show:
12 peaks, 6-peaks, 3-Peaks, Only a single peak, 4
Molar extinction coefficient (( ε) a constant in Beer-Lambert law is the characteristics of the:
Solute, Solvent, Concentration, All of the above, 1
Which region of electromagnetic spectrum is involved in nuclear magnetic resonance (NMR spectroscopy)?
Micro wave, Radio wave, Infrared region, X-rays, 3
The electronic transition that is involved in the visible region is:
σ −σ , π−π , π−σ , d−d , 4
Choose the correct statement:
The most direct and accurate method for determining atomic masses uses mass spectroscopy, The
indirect by accurate method for determining molecular mass uses mass spectroscopy, The first application
of the mass spectroscopy was demonstration to detect various isotopes of Argon, Collision between the
atoms produces negative ions by absorption of electrons byatoms or molecules, 1
A sample containing aluminum weighing 10.0 g yielded 2.0 g of aluminum sulphide. What is the percentage
of aluminum(atomic mass = 27.0) in the sample? Sulphur (atomic mass = 32.0)
( 2.0× 100 ) 2.0 2 ×27 2.0 2 ×27 2.0 150
, × , × ×100, × ×100 , 2
10.0 10 150 10 1500 10 3 ×27
The sample of a compound contains 0.100 g of hydrogen and 4.20 g of nitrogen. The simplest formula for
the compound is;
HN2, NH3, HN3, NH2, 2
Natural chlorine occurs as a mixture of isotopes if a mixture contains 75% Cl 35 and 25% Cl37 what will be its
correct atomic weight?
35.50, 34.50, 72.00, 70.00, 1
The atoms of an element having same atomic number but different mass number are called:
Isotones, Isotopes, isobar s , isomers , 2
100% transmission in IR spectroscopy means:
No absorption, 50% absorption, 75% absorption, 100% absorption, 1