Академический Документы
Профессиональный Документы
Культура Документы
Based upon Regulation (EC) No. 1907/2006, as amended by Regulation (EC) No. 453/2010
TEPPEKI
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier:
Product name : TEPPEKI
Synonyms : IKI-220 50% WG
Registration number REACH : Not applicable (mixture)
Product type REACH : Mixture
1.2 Relevant identified uses of the substance or mixture and uses advised against:
1.2.1 Relevant identified uses
Insecticide
3.2 Mixtures:
methylnaphthalenesulfonic 81065-51-2 <5 % Xi; R41 Eye Dam. 1; H318 (1) Constituent
acid/formaldehyde, copolymer, sodium salt
docusate sodium 577-11-7 <5 % Xi; R38 - 41 Skin Irrit. 2; H315 (1) Constituent
209-406-4 Eye Dam. 1; H318
silicon dioxide 7631-86-9 <10 % (2) Constituent
231-545-4
isotridecanol, ethoxylated 69011-36-5 <5 % Xn; R22 Acute Tox. 4; H302 (1) Constituent
500-241-6 Xi; R41 Eye Dam. 1; H318
kaolin 1332-58-7 <15 % (2) Constituent
310-194-1
(1) For R-phrases and H-statements in full: see heading 16
(2) Substance with a Community workplace exposure limit
4.2 Most important symptoms and effects, both acute and delayed:
4.2.1 Acute symptoms
After inhalation:
No effects known.
After skin contact:
Not irritating.
After eye contact:
Irritation of the eye tissue.
After ingestion:
No effects known.
4.2.2 Delayed symptoms
No effects known.
4.3 Indication of any immediate medical attention and special treatment needed:
If applicable and available it will be listed below.
The Netherlands
Belgium
Kaolin (fraction alvéolaire) Time-weighted average exposure limit 8 h 2 mg/m³
USA (TLV-ACGIH)
Kaolin Time-weighted average exposure limit 8 h (TLV - Adopted Value) 2 mg/m³ (R,E)
R,E: Respirable fraction. The value is for particulate matter containing no asbestos and < 1% crystalline silica
France
Kaolin Time-weighted average exposure limit 8 h (VL: Valeur non 10 mg/m³
réglementaire indicative)
UK
Kaolin, respirable dust Time-weighted average exposure limit 8 h (Workplace exposure limit 2 mg/m³
(EH40/2005))
b) National biological limit values
If limit values are applicable and available these will be listed below.
8.1.2 Sampling methods
If applicable and available it will be listed below.
Silica, Amorphous (Respirable) NIOSH 7501
8.1.3 Applicable limit values when using the substance or mixture as intended
If limit values are applicable and available these will be listed below.
8.1.4 DNEL/PNEC values
DNEL - Workers
docusate sodium
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 44.1 mg/m³
Long-term systemic effects dermal 31.3 mg/kg bw/day
isotridecanol, ethoxylated
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 294 mg/m³
Long-term systemic effects dermal 2080 mg/kg bw/day
DNEL - General population
docusate sodium
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 13 mg/m³
Long-term systemic effects dermal 18.8 mg/kg bw/day
Long-term systemic effects oral 18.8 mg/kg bw/day
isotridecanol, ethoxylated
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 87 mg/m³
Long-term systemic effects dermal 1250 mg/kg bw/day
Long-term systemic effects oral 25 mg/kg bw/day
PNEC
docusate sodium
Compartments Value Remark
Fresh water 0.0066 mg/l
Marine water 0.00066 mg/l
Aqua (intermittent releases) 0.066 mg/l
STP 122 mg/l
Fresh water sediment 0.653 mg/kg sediment dw
Marine water sediment 0.0653 mg/kg sediment dw
Soil 0.138 mg/kg soil dw
Acute toxicity
TEPPEKI
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Oral LD50 > 2000 mg/kg Rat Experimental value
Dermal LD50 > 2000 mg/kg Rat Experimental value
Inhalation LC50 > 5.36 mg/l 4h Rat Experimental value
flonicamid
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Oral LD50 884 mg/kg Rat (male) Experimental value
Oral LD50 1768 mg/kg bw Rat (female) Experimental value
Dermal LD50 > 5000 mg/kg Rat Experimental value
Inhalation LC50 > 4.9 mg/l 4h Rat Experimental value
docusate sodium
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Oral LD50 > 2000 mg/kg Rat
Dermal LD50 > 10000 mg/kg Rabbit
isotridecanol, ethoxylated
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Oral category 4 Literature
Judgement is based on the relevant ingredients
Conclusion
Not classified for acute toxicity
Corrosion/irritation
TEPPEKI
No (test)data on the mixture available
flonicamid
Route of exposure Result Method Exposure time Time point Species Value Remark
determination
Eye Not irritating Rabbit Experimental value
Skin Not irritating Rabbit Experimental value
TEPPEKI
No (test)data on the mixture available
flonicamid
Route of exposure Result Method Exposure time Observation time Species Value determination Remark
point
Skin Not sensitizing Experimental value
Judgement is based on the relevant ingredients
Conclusion
Not classified as sensitizing for skin
TEPPEKI
No (test)data on the mixture available
TEPPEKI
No (test)data on the mixture available
TEPPEKI
No (test)data on the mixture available
Carcinogenicity
TEPPEKI
No (test)data on the mixture available
Reproductive toxicity
TEPPEKI
No (test)data on the mixture available
Judgement is based on the relevant ingredients
Conclusion CMR
Not classified for mutagenic or genotoxic toxicity
Not classified for carcinogenicity
Not classified for reprotoxic or developmental toxicity
TEPPEKI
No (test)data on the mixture available
TEPPEKI
No effects known.
Conclusion
Harmful to aquatic organisms
Not classified as dangerous for the environment according to the criteria of Regulation (EC) No 1272/2008
May cause long-term adverse effects in the aquatic environment
Conclusion
No straightforward conclusion can be drawn based upon the available numerical values
flonicamid
Log Kow
Method Remark Value Temperature Value determination
0.3
methylnaphthalenesulfonic acid/formaldehyde, copolymer, sodium salt
Log Kow
Method Remark Value Temperature Value determination
No data available
Conclusion
No (test)data on mobility of the components available
flonicamid
Global warming potential (GWP)
Not included in the list of fluorinated greenhouse gases (Regulation (EC) No 517/2014)
Rail (RID)
14.1 UN number:
Transport Not subject
14.2 UN proper shipping name:
14.3 Transport hazard class(es):
Hazard identification number
Class
Classification code
14.4 Packing group:
Packing group
Labels
14.5 Environmental hazards:
Environmentally hazardous substance mark no
14.6 Special precautions for user:
Special provisions
Limited quantities
Sea (IMDG/IMSBC)
14.1 UN number:
Transport Not subject
14.2 UN proper shipping name:
14.3 Transport hazard class(es):
Class
14.4 Packing group:
Packing group
Labels
14.5 Environmental hazards:
Marine pollutant -
Environmentally hazardous substance mark no
14.6 Special precautions for user:
Special provisions
Limited quantities
Reason for revision: 2.2 Publication date: 2012-12-20
Date of revision: 2015-05-18
Air (ICAO-TI/IATA-DGR)
14.1 UN number:
Transport Not subject
14.2 UN proper shipping name:
14.3 Transport hazard class(es):
Class
14.4 Packing group:
Packing group
Labels
14.5 Environmental hazards:
Environmentally hazardous substance mark no
14.6 Special precautions for user:
Special provisions
Passenger and cargo transport: limited quantities: maximum net quantity
per packaging
The informa on in this safety data sheet is based on data and samples provided to BIG. The sheet was wri en to the best of our ability and
according to the state of knowledge at that me. The safety data sheet only cons tutes a guideline for the safe handling, use, consump on,
storage, transport and disposal of the substances/prepara ons/mixtures men oned under point 1. New safety data sheets are wri en from
me to me. Only the most recent versions may be used. Old versions must be destroyed. Unless indicated otherwise word for word on the
safety data sheet, the informa on does not apply to substances/prepara ons/mixtures in purer form, mixed with other substances or in
processes. The safety data sheet offers no quality specifica on for the substances/prepara ons/mixtures in ques on. Compliance with the
instruc ons in this safety data sheet does not release the user from the obliga on to take all m easures dictated by com m on sense,
regula ons and recommenda ons or which are necessary and/or useful based on the real applicable circum stances. BIG does not guarantee
the accuracy or exhaus veness of the informa on provided and cannot be held liable for any changes by third par es. This safety data sheet
is only to be used within the European Union, Switzerland, Iceland, Norway and Liechtenstein. Any use outside of this area is at your own
risk. Use of this safety data sheet is subject to the licence and liability lim i ng condi ons as stated in your BIG licence agreem ent or when
this is failing the general condi ons of BIG. All intellectual property rights to this sheet are the property of BIG and its distribu on and
reproduc on are limited. Consult the men oned agreement/condi ons for details.