PRESION DE BURBUJA

acetona (1)/agua (2)

K grupo Rk Qk Vk1 Vk2 Qk*Vk1
1 1 0.9011 0.848 1 0 0.848
2 7 0.92 1.4 0 1 0
3 9 1.6724 1.488 1 0 1.488

q1
∑ 2.336

T(°C) 60 60 60 60 60 60 60
T(K) 333.15 333.15 333.15 333.15 333.15 333.15 333.15
x1 0 0.1 0.2 0.3 0.4 0.5 0.6
x2 1 0.9 0.8 0.7 0.6 0.5 0.4

θ1 0 0.0848 0.1696 0.2544 0.3392 0.424 0.5088

θ2 1.4 1.26 1.12 0.98 0.84 0.7 0.56
θ3 0 0.1488 0.2976 0.4464 0.5952 0.744 0.8928

J1 2.79728261 2.37112452 2.05764772 1.81737933 1.62735551 1.47330757 1.34590241

J2 1 0.84765283 0.73558807 0.64969457 0.58176299 0.52669243 0.48114638

L1 1.66857143 1.56400643 1.47177419 1.38981437 1.31650135 1.25053533 1.1908646

L2 1 0.93733262 0.88205645 0.8329367 0.7889991 0.74946467 0.7137031

S11 2.22115191 2.22115191 2.22115191 2.22115191 2.22115191 2.22115191 2.22115191

S21 0.37651706 0.37651706 0.37651706 0.37651706 0.37651706 0.37651706 0.37651706
S31 1.69093671 1.69093671 1.69093671 1.69093671 1.69093671 1.69093671 1.69093671

S12 0.56891569 0.56891569 0.56891569 0.56891569 0.56891569 0.56891569 0.56891569

S22 1.4 1.4 1.4 1.4 1.4 1.4 1.4
S32 2.51681654 2.51681654 2.51681654 2.51681654 2.51681654 2.51681654 2.51681654

η1 0.56891569 0.73413931 0.89936293 1.06458655 1.22981017 1.3950338 1.56025742

η2 1.4 1.29765171 1.19530341 1.09295512 0.99060682 0.88825853 0.78591024
η3 2.51681654 2.43422855 2.35164057 2.26905259 2.18646461 2.10387662 2.02128864

ɣR1 3.768767 2.61786537 2.06153067 1.73684641 1.52246786 1.36785798 1.24908917

ɣR2 1 1.01810605 1.06121151 1.12314321 1.20546432 1.31584626 1.47075477

ɣC1 2.9967083 1.93400156 1.49107942 1.2717579 1.15210307 1.08339208 1.04322291

ɣC2 1 1.02153227 1.06828476 1.12555097 1.18632516 1.24691599 1.30528587

ɣ1 11.2938953 5.0629557 3.07390597 2.20884814 1.75403989 1.48192649 1.30307844

ɣ2 1 1.04002818 1.13367608 1.26415493 1.43007265 1.64074975 1.91975542

PB 20.0070447 77.0299173 88.9407593 94.012833 97.9619865 101.739411 105.397591

Y1 0 0.75688535 0.79598548 0.811681 0.82475941 0.83867337 0.85423336
Y2 1 0.24311465 0.20401452 0.188319 0.17524059 0.16132663 0.14576664

T(ºC)
60
i A B C PSAT
1 14.3145 2756.22 228.06 115.155691
2 16.3872 3885.7 230.17 20.0070447

x1 x2 ɣ1 ɣ2 T P y1
0 1 11.2938953 1 56.2001696 20.0070447 0
0.1 0.9 5.0629557 1.04002818 60.5800637 77.0299173 0.75688535
0.2 0.8 3.07390597 1.13367608 64.9599578 88.9407593 0.79598548
0.3 0.7 2.20884814 1.26415493 69.3398519 94.012833 0.811681
0.4 0.6 1.75403989 1.43007265 73.719746 97.9619865 0.82475941
0.5 0.5 1.48192649 1.64074975 78.0996401 101.739411 0.83867337
0.6 0.4 1.30307844 1.91975542 82.4795341 105.397591 0.85423336
0.7 0.3 1.17754215 2.31805181 86.8594282 108.833685 0.87216081
0.8 0.2 1.08697704 2.95184192 91.2393223 111.9488 0.89449171
0.9 0.1 1.02551576 4.12782494 95.6192164 114.543136 0.92790002
1 0 1 6.88583576 99.9991105 115.155691 1

120

120 100
110 T
100 E
M 80
90 P
80 E
PRESION

60
70 R
60
A
T 40
50 U
40 R
A 20
30
20
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0
X1-Y1 0 0.2
 70 R

PRES
60
A
T 40
50 U
40 R
A 20
30
20
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0
X1-Y1 0 0.2
T 60
Qk*Vk2 Rk*Vk1 Rk*Vk2 parametros de interaccion akl
0 0.9011 0 0 1318 476.4
1.4 0 0.92 300 0 -195.4
0 1.6724 0 26.76 472.5 0

q2 r1 r2
1.4 2.5735 0.92

60 60 60 60
333.15 333.15 333.15 333.15
0.7 0.8 0.9 1
0.3 0.2 0.1 0

0.5936 0.6784 0.7632 0.848

0.42 0.28 0.14 0
1.0416 1.1904 1.3392 1.488

1.23877831 1.14744962 1.06866267 1

0.44285061 0.41020153 0.382036 0.3574898

1.13662904 1.08711839 1.04174099 1

0.68119891 0.65152643 0.62433107 0.59931507

2.22115191 2.22115191 2.22115191 2.22115191

0.37651706 0.37651706 0.37651706 0.37651706
1.69093671 1.69093671 1.69093671 1.69093671

0.56891569 0.56891569 0.56891569 0.56891569

1.4 1.4 1.4 1.4
2.51681654 2.51681654 2.51681654 2.51681654

1.72548104 1.89070466 2.05592828 2.22115191

0.68356194 0.58121365 0.47886535 0.37651706
1.93870066 1.85611267 1.77352469 1.69093671

1.15437886 1.07892039 1.023897 1

1.70406166 2.09142702 2.83056911 4.58761167

1.02006558 1.00746732 1.00158098 1

1.36030982 1.41140087 1.45830213 1.50096308

1.17754215 1.08697704 1.02551576 1

 2.31805181 2.95184192 4.12782494 6.88583576

108.833685 111.9488 114.543136 115.155691

0.87216081 0.89449171 0.92790002 1
0.12783919 0.10550829 0.07209998 0

p(Kpa)
101.33
Tsat
56.2001696
99.9991105

120

100
T
E
M 80
P
E 60
R
A T-X1
T 40 T-Y1
U
R
A 20

0
0 0.2 0.4 0.6 0.8 1 1.2
X1-Y1
R
A T-X1
T 40 T-Y1
U
R
A 20

0
0 0.2 0.4 0.6 0.8 1 1.2
X1-Y1
interaccion akl ENERGIA FRACCIONAL Г=EXP(-α/T)
1 0.01913615 0.23931215
0.40636835 1 1.7977261
0.92281714 0.24213011 1
 T(ºC) p(Kpa)
60 101.33
i A B C PSAT Tsat
1 14.3145 2756.22 228.06 115.155691 56.2001696
2 16.3872 3885.7 230.17 20.0070447 99.9991105

PARAMETROS DE WILSON y NRTL

i Vi a12 a21 Psati Λ12
1 74.05 291.27 1448.01 115.155691 0.15715968
2 18.07 20.0070447
MODELO WILSON
X1 ganma1 ganma2 P Y1
0 10.9209453 1 20.0070447 0
0.1 4.80416476 1.03982022 74.0460477 0.74713901
0.2 2.99002022 1.12855152 86.9267535 0.79220224
0.3 2.17225807 1.25412056 92.6082357 0.81034222
0.4 1.72195344 1.42032283 96.3669726 0.82307344
0.5 1.44486262 1.63886696 99.5865185 0.83537488
0.6 1.26351746 1.93026978 102.748333 0.84965598
0.7 1.14199317 2.32883525 106.032842 0.86817355
0.8 1.06232734 2.89352624 109.444613 0.89420967
0.9 1.01584883 3.73140384 112.748133 0.93378661
1 1 5.05198599 115.155691 1

MODELO NRTL

Tau12 tau21 G12 G21

0.9532923 1.80895164 0.60088959 0.38040346

X1 ganma1 ganma2 P Y1
0 10.8240992 1 20.0070447 0
0.1 4.88857144 1.03966589 75.0152598 0.75044307
0.2 2.97920271 1.13256175 86.7418 0.7910192
0.3 2.14302849 1.26251766 91.716051 0.80721506
0.4 1.70024254 1.42895254 95.4705121 0.82032703
0.5 1.43459747 1.64120649 99.018877 0.83419479
0.6 1.26173181 1.91958121 102.539418 0.85018387
0.7 1.14433292 2.30139927 106.056773 0.86975599
0.8 1.0651237 2.85540659 109.549694 0.8957035
0.9 1.01706896 3.71518256 112.842133 0.93412937
1 1 5.16251446 115.155691 1
 R(cal/mol-K) T(°C) T(|K)
1.987 60 333.15

Λ21 b12 b21 𝛼12

0.45981037 631.05 1197.47 0.5343

140

120

100

80
presion
60
P-Y1
40 P-X1

20

0
0 0.2 0.4 0.6 0.8 1 1.2
X1-Y1

140

120

100

80
presion
60 P-Y1
P-X1
40
 140

120

100

80
presion
60 P-Y1
P-X1
40

20

0
0 0.2 0.4 0.6 0.8 1 1.2
X1-Y1