Академический Документы
Профессиональный Документы
Культура Документы
P(atm)= 12
R= 82.06 8.134
PUROS Componente Yi Tc Pc Zc W Vc
Metano 0.17 588 62.3 0.224 0.346 173
Etano 0.35 305.4 48.2 0.285 0.098 148
Propano 0.48 369.8 41.9 0.281 0.152 203
0.10153577
0.095446
0.17991442
dB/dT= 0.3768962
comp Yi Hº ( J / mol )
metano (1) 34.942 -0.039957
etano (2) 28.146 0.034447
propano (3) 28.177 0.116
K Tr B(0) B(1) B C(0) C(1) C
0 1.03741497 -0.31357826 -0.0135715 -246.502858 0.03388468 0.02107941 24700.6549
0 1.99738048 -0.05695313 0.09355231 -24.8453495 0.01757269 -0.0192383 4240.88229
0 1.64954029 -0.10916339 0.09095772 -69.047757 0.02004256 -0.0136502 9424.58245
dC/dT
111 -0.39192813 113 -2.21174338
222 -0.22681705 122 -0.95136403
333 -2.12648739 133 -3.96364228
123 -3.86653655 223 -1.44012245
112 -1.07189919 233 -3.03466274
Hm= 2.5246E+11
dC/dT -19.2852032 Sm= 441491184
HR/RT= -0.07294493
HR= -361.933785
SR/R -0.05578999 S*= 441491185
SR= -0.463838 H*= 2.5246E+11
C123 8955.24348
C113 16745.1079
C112 11994.8969 CM= 8481.91615
C122 6666.72341 BM= -71.9769417
C133 12145.2325 Z= 0.98278569
C223 5481.44059 V= 4099.57584
C233 7153.13922 fm= 11.7006668
suma YiBij YiYjCijk
-78.9367832 2336.23335
-53.688163 1541.24465
-116.480496 4343.40699
Si* ( J / mol - K )
3034451.1
6036667.82
5875568.06
ComponenteYi Pc (atm) Tc (K) w m Tr α
Metanol (1) 0.2 79.9 512.6 0.559 1.30369823 1.26804526 0.69828759
Etanol (2) 0.5 63 516.2 0.635 1.40746033 1.25920186 0.68573386
Agua (3) 0.3 217.6 647.3 0.344 1.00039244 1.00417117 0.99583588
Componente ɑij Aij ComponenteCp A Cp B Cp C Cp D
1-2 7428764.01 0.065278 Metanol (1) 40.046 -3.63E-02 2.45E-04 -2.17E-07
1-3 6040335.86 0.05307761 Etanol (2) 27.01 1.11E-01 1.10E-04 -1.50E-07
2-3 6788350.12 0.05965056 Agua (3)
K 1= 0 D11= 464516.022 D21= 1305100.19 D31=
K2= 0 D12= 1416845.87 D22= 3980757.88 D32=
K3= 0 D13= 364076.569 D23= 1022906.37 D33=
K (1-2)= 0
K (1-3)= 0 T= 650
K (2-3)= 0 P= 25
Ecuación cúbica para Z R= 82.06
a b c d R= 8.314
1 1 0.04101085 0.00130318 6.08305E-05 To= 298.15
Po= 1
ɑc ɑi Ai bi Bi ln (Øi) Øi fi
9466274.43 6610181.98 0.05808496 45.6122797 0.02137848 -0.03086147 0.96960988 4.8480494
12174864 8348716.4 0.0733618 58.2542221 0.02730377 -0.02432919 0.97596438 12.1995547
5542695.11 5519614.64 0.04850193 21.1493329 0.0099127 -0.04350185 0.95743078 7.18073088
Cp E Ho (J/mol) So (J/molK) Hi* (J/mol) Si* (J/molK)
5.99E-11 -201170 239.7 -180729.685 256.921842
4.66E-11 -234810 282.59 -203162.028 323.596322
0 -26.7617336
636707.006
1942055.06 ɑ mezcla = 7095449.84
499035.75 b mezcla = 44.5943668
A mezcla= 0.0623491
K B mezcla = 0.02090139
atm Z= 0.95870679
Vol. Molar= 2045.45846 cm^3/mol
f mezcla= 24.228335
K D= 11632000.7
atm Hr= 1140.79782 Joul/mol
Sr= 0.63240863 Joul/molK
H*(mez)= -137726.951
S* (mez)= 213.714544
Hm= -136586.153
Sm= 214.346953
Datos del sistema
Temperatura 550 K
Presión del s 15 atm
Método de calculo
Método Tsonopoulos
ComponenteB° B1 B2 C° C1
Tsonopoulos1 1 -0.29319463 0.00421744 0.02566289 0.03254349 0.01710013
Tsonopoulos2 2 -0.29726019 0.00074207 0.02557233 0.0328247 0.01790747
Tsonopoulos3 3 -0.28813357 0.00844148 -0.01920779 0.03218867 0.01609793
Tsonopoulos1.2 1.2 -0.29231506 0.00495967 0.02518801 0.03248219 0.01692572
Tsonopoulos1.3 1.3 -0.28293222 0.01266517 0.00293474 0.03181922 0.01507184
Tsonopoulos2.3 2.3 -0.29146159 0.0056766 0.00241779 0.03242256 0.01675657
Componentes Polares
Componente B C C #
Polares1 1 -139.597844 11668.163 1.2.3 19115.7053
Polares2 2 -182.351534 19978.7626 1.1.3 15979.6712
Polares3 3 -273.820691 30005.697 1.1.2 13929.7353
Polares1.2 1.2 -157.923193 15219.9438 1.2.2 16664.7279
Polares1.3 1.3 -191.658159 18700.3836 1.3.3 21892.8138
Polares2.3 2.3 -223.382807 24541.8566 2.2.3 22915.4191
2.3.3 26242.559
Bm -209.437832
Cm 21412.9932
Z 0.93275596
Cálculo de la fugacidad
f1 4.35800354
f2 2.97489321 fm 13.6486442
f3 6.31574749
Hr -13698.4211 cm3*atm/mol
Sr -19.1942793 cm3*atm/mol*K
Hr -1387.99289 J/mol
Sr -1.94486087 J/mol*K
H -194143.436 J/mol
S 315.687437 J/mol*K
Constantes y conversiones
R 82.057 cm3*atm/mol*k
R 8.314 J/mol*K
T de referenc 298.15 K
b kij Tr P de referenc 1 atm
0.056 --------------- 1.07296137
0.0572 --------------- 1.0654785
0 --------------- 1.08246408
0.0566 0.00501059 1.07459775
0.028 0.01350342 1.09245412
0.0286 0.00209434 1.07619162
SUMA 1 SUMA 2 SUMA 3
-0.10458373 -0.08033785 -0.24545784
SUMANDO
-0.10167502 -0.07801582 -0.24146858
TOTAL
-0.03206335 -0.00840415 -0.1718569
MATRIZ dB/dT
0.08373778 0.0653137 0.17330296
0.0653137 0.05248041 0.14105477
0.17330296 0.14105477 0.38405758
1.27961862
onstantes y conversiones
m3*atm/mol*k
Smith-Van NePitzer y Curl Tsonopoulos
B° B1 B° B1 B° B1
Smith-Van Ness1 -0.29403174 0.01103969
Smith-Van Ness2 -0.2982773 0.00722266
Smith-Van Ness3 -0.2887499 0.01569185
Smith-Van Ness1.2 -0.29311354 0.01185609
Smith-Van Ness1.3 -0.28332564 0.02035895
Smith-Van Ness2.3 -0.29222268 0.0126451
Pitzer y Curl1 -0.29316007 -0.01527484
Pitzer y Curl2 -0.29722364 -0.02029116
Pitzer y Curl3 -0.28810137 -0.00911343
Pitzer y Curl1.2 -0.29228092 -0.01419742
Pitzer y Curl1.3 -0.2829023 -0.00287748
Pitzer y Curl2.3 -0.29142785 -0.01315462
Tsonopoulos1 -0.29319463 0.00421744
Tsonopoulos2 -0.29726019 0.00074207
Tsonopoulos3 -0.28813357 0.00844148
Tsonopoulos1.2 -0.29231506 0.00495967
Tsonopoulos1.3 -0.28293222 0.01266517
Tsonopoulos2.3 -0.29146159 0.0056766
Polares No polares
B C
Polares1 -139.597844 11668.163
Polares2 -182.351534 19978.7626
Polares3 -273.820691 30005.697
Polares1.2 -157.923193 15219.9438
Polares1.3 -191.658159 18700.3836
Polares2.3 -223.382807 24541.8566
No polares1 -153.10777 11668.163
No polares2 -199.545001 19978.7626
No polares3 -256.561344 30005.697
No polares1. -172.98103 15219.9438
No polares1. -193.707215 18700.3836
No polares2. -225.268839 24541.8566
Z
De 0 a 15 at 0.93039057
de 15 a 200 0.93275596
dB/dT
Polares1 0.93041973
Polares2 1.31201017
Polares3 1.53623032
Polares1.2 1.08856161
Polares1.3 1.15535309
Polares2.3 1.41054768
No polares1 1.01677261
No polares2 1.41537781
No polares3 1.34794653
No polares1. 1.18363227
No polares1. 1.14266488
No polares2. 1.38603601
Componente
1
2
3
1.2
1.3
2.3
ComponenteYi Pc (atm) Tc (K) w Tr m α
Metano (1) 0.17 45.4 190.6 0.008 3.20041973 0.38696081 0.48260653
Etano (2) 0.35 48.2 305.4 0.098 1.99738048 0.52318917 0.61429958
Propano (3) 0.48 41.9 369.8 0.152 1.64954029 0.60282729 0.68656055
ComponenteK ij ɑij A ij
1-2 -0.0026 2091520.52 0.02086793
1-3 0.014 2824067.29 0.02817684
2-3 0.0011 5019543.17 0.05008198
ComponenteCp A Cp B Cp C Cp D Ho* So* Hi*
1 39.942 -0.039957 1.92E-04 -1.53E-07 -74850 186.27 -60227.0271
2 28.146 4.34E-02 1.89E-04 -1.91E-07 -84680 229.12 -63317.8057
3 28.277 1.16E-01 1.96E-04 -2.33E-07 -103850 270.2 -73105.4255
ɑ mezcla = 4468657.14
b mezcla = 45.7605663
Si* A mezcla= 0.04458557
192.579467 B mezcla = 0.02285441
250.13233 Z mezcla= 0.98023925
312.054266 V molar= 1962.69777
D= 4212449.25
Hr= 538.284954 J/mol
T= 610 K Sr= 0.45363679 J/molK
P= 25 atm H* mezcla= -67490.4308 J/mol
R= 82.06 S*mezcla= 278.559264 J/molK
R= 8.314 H mezcla= -66952.1459 J/mol
To= 298.15 K S mezcla= 279.0129 J/molK
Po= 1 atm fm= 24.480195 atm
f
4.30231329
8.61464189
11.5632398
ComponenteYi Pc (atm) Tc (K) w Tr m α
Metano (1) 0.2 45.4 190.6 0.008 3.7250787 0.38696081 0.40973894
Etano (2) 0.3 48.2 305.4 0.098 2.32481991 0.52318917 0.52629773
Propano (3) 0.5 41.9 369.8 0.152 1.91995673 0.60282729 0.58910953
ComponenteK ij ɑij A ij
1-2 -0.0026 1783794.38 0.01576472
1-3 0.014 2410408.57 0.02130258
2-3 0.0011 4303763.85 0.03803557
ComponenteCp A Cp B Cp C Cp D Ho* So* Hi*
1 39.942 -0.039957 1.92E-04 -1.53E-07 -74850 186.27 -54922.2532
2 28.146 4.34E-02 1.89E-04 -1.91E-07 -84680 229.12 -54884.5217
3 28.277 1.16E-01 1.96E-04 -2.33E-07 -103850 270.2 -60797.658
ɑ mezcla = 3789860.61
b mezcla = 45.6690011
Si* A mezcla= 0.03349383
199.114082 B mezcla = 0.02351543
261.41028 Z mezcla= 0.99207568
329.208843 V molar= 1926.69696
D= 4166635.81
Hr= 455.63065 J/mol
T= 710 K Sr= 0.41423207 J/molK
P= 30 atm H* mezcla= -57848.6362 J/mol
R= 82.06 S*mezcla= 291.410857 J/molK
R= 8.314 H mezcla= -57393.0055 J/mol
To= 298.15 K S mezcla= 291.825089 J/molK
Po= 1 atm fm= 29.7232277 atm
f
6.07654225
8.94385488
14.7028305
ComponenteYi Pc (atm) Tc (K) w m Tr α
N-butano (1) 0.3 37.5 425.2 0.193 0.77874434 1.434619 0.71571393
n-pentano (2) 0.4 33.3 469.6 0.251 0.86472286 1.29897785 0.7729483
n-exano (3) 0.3 29.3 507.4 0.296 0.93070667 1.20220733 0.82852108
Componente ɑij Aij ComponenteCp A Cp B Cp C Cp D
1-2 11849887.8 0.14188764 Metanol (1) 40.046 -3.63E-02 2.45E-04 -2.17E-07
1-3 14586356.1 0.17465343 Etanol (2) 27.01 1.11E-01 1.10E-04 -1.50E-07
2-3 17570598 0.21038601 Acetona (3) 35.918 9.39E-02 1.87E-04 -2.16E-07
K 1= 0 D11= 985524.882 D21= 1567793.81 D31=
K2= 0 D12= 1594035.82 D22= 2642541.87 D32=
K3= 0 D13= 1471770.37 D23= 2363842.41 D33=
K (1-2)= 0.0204
K (1-3)= -0.0111 T= 610
K (2-3)= 0 P= 30
Ecuación cúbica para Z R= 82.057
a b c d R= 8.314
1 1 0.1131466 0.0107679 4.7079E-09 To= 298.15
Po= 1
ɑc ɑi Ai bi Bi ln (Øi) Øi fi
13876890.3 9931883.65 0.11892193 80.6113263 0.04831387 -0.12778989 0.88003827 7.9203444
19061139.3 14733275.3 0.17641261 100.257745 0.06008883 -0.11230487 0.89377174 10.7252608
25291245.5 20954330.1 0.25090198 123.116687 0.07378918 -0.09428778 0.91002084 8.19018755
Cp E Ho (J/mol) So (J/molK) Hi* (J/mol) Si* (J/molK)
5.99E-11 -201170 239.7 -183520.39 250.975842
4.66E-11 -234810 282.59 -207556.24 315.104777
6.32E-11 -217570 295.35 -186583.231 336.187381
1447380.72
2363580.4 ɑ mezcla = 14823544
2114302.01 b mezcla = 101.221502
A mezcla= 0.17749346
K B mezcla = 0.06066645
atm Z= 0.88601374
Vol. Molar= 1478.30712 cm^3/mol
f mezcla= 26.8357928
K D= 16550772.3
atm Hr= 2657.98947 Joul/mol
Sr= 1.80601166 Joul/molK
H*(mez)= -194053.582
S* (mez)= 311.243992
Hm= -191395.593
Sm= 313.050004
ComponenteYi Pc (atm) Tc (K) w m Tr α
agua(1) 0.5 217.6 647.3 0.44 1.13760563 1.00417117 0.99526541
metanol (2) 0.2 79.9 512.5 0.559 1.30369823 1.26829268 0.69804826
etanol (3) 0.3 63 516.2 0.635 1.40746033 1.25920186 0.68573386
Componente ɑij Aij ComponenteCp A Cp B Cp C Cp D
1-2 6512187.91 0.05722805 Metanol (1) 40.046 -3.63E-02 2.45E-04 -2.17E-07
1-3 6861232.86 0.0602954 Etanol (2) 27.01 1.11E-01 1.10E-04 -1.50E-07
2-3 7425498.86 0.06525408 Acetona (3) 35.918 9.39E-02 1.87E-04 -2.16E-07
K 1= 0 D11= 1575775.36 D21= 744137.306 D31=
K2= 0 D12= 1144382.01 D22= 464266.562 D32=
K3= 0 D13= 1962905.82 D23= 849733.875 D33=
K (1-2)= -0.0789
K (1-3)= -0.0111 T= 650
K (2-3)= 0 P= 25
Ecuación cúbica para Z R= 82.057
a b c d R= 8.314
1 1 0.04068164 0.0010176 2.96907E-09 To= 298.15
Po= 1
ɑc ɑi Ai bi Bi ln (Øi) Øi fi
5542289.85 5516049.35 0.04847415 21.1485597 0.0099127 -0.05317886 0.9482104 11.85263
9461889.49 6604855.46 0.0580424 45.6017143 0.02137431 -0.04064627 0.96016871 4.80084353
12173973.8 8348105.98 0.0733618 58.2520924 0.02730377 -0.03416278 0.96641418 7.24810635
Cp E Ho (J/mol) So (J/molK) Hi* (J/mol) Si* (J/molK)
5.99E-11 -201170 239.7 -180729.685 256.921842
4.66E-11 -234810 282.59 -203162.028 323.596322
6.32E-11 -217570 295.35 -181573.773 345.655575
1176033.17
782926.482 ɑ mezcla = 6646403.4
1432968.06 b mezcla = 37.1702504
A mezcla= 0.05840751
K B mezcla = 0.01742234
atm Z= 0.95867181
Vol. Molar= 2045.30906 cm^3/mol
f mezcla= 23.9015799
K D= 10133128.6
atm Hr= 1047.09756 Joul/mol
Sr= 0.57148471 Joul/molK
H*(mez)= -185469.38
S* (mez)= 305.437393
Hm= -184422.282
Sm= 306.008878
Datos del sistema
Temperatura 650 K
Presión del s 25 atm
Método de calculo
Método Tsonopoulos
ComponenteB° B1 B2 C° C1
Tsonopoulos1 1 0.03551994 0.08149516 5.27541E-05 0.01485369 -0.02518301
Tsonopoulos2 2 -0.04237902 0.09287702 0.00080871 0.01700274 -0.020509
Tsonopoulos3 3 -0.09030222 0.09285465 -0.0010478 0.0190748 -0.01585345
Tsonopoulos1.2 1.2 0.00340007 0.08749129 0.0002012 0.01555793 -0.02367998
Tsonopoulos1.3 1.3 -0.0103369 0.08956928 9.78799E-05 0.01593646 -0.02285804
Tsonopoulos2.3 2.3 -0.06377458 0.09367146 0.00038876 0.01785776 -0.01859964
Componentes Polares
Componente B C C #
Polares1 1 12.4792054 1738.87774 1.2.3 3816.54037
Polares2 2 -16.8809938 4052.84102 1.1.3 2853.98993
Polares3 3 -55.9356799 8740.65951 1.1.2 2266.56778
Polares1.2 1.2 3.5041687 2587.7275 1.2.2 3005.14582
Polares1.3 1.3 -1.56466713 3656.31943 1.3.3 4888.89626
Polares2.3 2.3 -31.7829953 5875.52812 2.2.3 5191.39963
2.3.3 6707.27336
Bm -3.6693834
Cm 3208.12898
Z 0.99898491
Cálculo de la fugacidad
f1 12.1066434
f2 8.64123634 fm 24.951688
f3 4.20380828
Hr -2210.05734 cm3*atm/mol
Sr -3.25895808 cm3*atm/mol*K
Hr -223.93412 J/mol
Sr -0.33021402 J/mol*K
H -179743.704 J/mol
S 322.449488 J/mol*K
Constantes y conversiones
R 82.057 cm3*atm/mol*k
R 8.314 J/mol*K
T de referenc 298.15 K
b kij Tr P de referenc 1 atm
0.056 --------------- 3.41028332
0.0572 --------------- 2.12835625
0 --------------- 1.75770687
0.0566 0.00670895 2.71231966
0.028 0.02120614 2.50136587
0.0286 0.00414994 1.94223347
SUMA 1 SUMA 2 SUMA 3
0.00649456 -0.01483209 -0.014243
SUMANDO
0.00783209 -0.01352364 -0.01194374
TOTAL
0.00884769 -0.01250803 -0.01092814
MATRIZ dB/dT
0.01477409 0.01743452 0.01125016
0.01743452 0.02098248 0.01387353
0.01125016 0.01387353 0.00948535
0.13035832
onstantes y conversiones
m3*atm/mol*k
Smith-Van NePitzer y Curl Tsonopoulos
B° B1 B° B1 B° B1
Smith-Van Ness1 0.02372825 0.13800503
Smith-Van Ness2 -0.0430206 0.1317932
Smith-Van Ness3 -0.08815837 0.12290269
Smith-Van Ness1.2 -0.00250019 0.13639686
Smith-Van Ness1.3 -0.01432601 0.1353425
Smith-Van Ness2.3 -0.06289156 0.12841569
Pitzer y Curl1 0.03551994 0.16244793
Pitzer y Curl2 -0.04237888 0.16867325
Pitzer y Curl3 -0.09030155 0.15492567
Pitzer y Curl1.2 0.00340009 0.16976731
Pitzer y Curl1.3 -0.01033686 0.17078427
Pitzer y Curl2.3 -0.06377428 0.16401915
Tsonopoulos1 0.03551994 0.08149516
Tsonopoulos2 -0.04237902 0.09287702
Tsonopoulos3 -0.09030222 0.09285465
Tsonopoulos1.2 0.00340007 0.08749129
Tsonopoulos1.3 -0.0103369 0.08956928
Tsonopoulos2.3 -0.06377458 0.09367146
Polares No polares
B C
Polares1 12.4792054 1738.87774
Polares2 -16.8809938 4052.84102
Polares3 -55.9356799 8740.65951
Polares1.2 3.5041687 2587.7275
Polares1.3 -1.56466713 3656.31943
Polares2.3 -31.7829953 5875.52812
No polares1 12.4610319 1738.87774
No polares2 -17.3014612 4052.84102
No polares3 -55.1768432 8740.65951
No polares1. 3.41858938 2587.7275
No polares1. -1.61449651 3656.31943
No polares2. -32.0220945 5875.52812
Z
De 0 a 15 at 0.9982801
de 15 a 200 0.99898491
dB/dT
Polares1 0.06412363
Polares2 0.17128552
Polares3 0.3282128
Polares1.2 0.1037769
Polares1.3 0.13786959
Polares2.3 0.23316854
No polares1 0.06428814
No polares2 0.17494944
No polares3 0.32120815
No polares1. 0.10454157
No polares1. 0.13830094
No polares2. 0.23510833
Componente
1
2
3
1.2
1.3
2.3