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Temperatura vs Concentración molar x,y

PT 1atm = 1.01325 bar


Constantes de Antoine A B C Cp=cal/mol°C
C7 4.02023 1263.909 216.432 53.77
C8 4.05075 1356.36 209.635 60.74

𝑦_𝐶7=𝑥_𝐶7∗𝑃_𝐶7=𝑃_𝐶7 ∗
〖𝑃𝑣〗 𝑥_𝐶7=(𝑃_𝑇−𝑃_𝐶8)/(𝑃_𝐶7−𝑃_𝐶8 )
〖𝑃𝑣〗 _𝐶7=10^(𝐴 − 𝐵/(𝑇(° 𝐶)+𝐶)= [𝑏𝑎𝑟] ) _𝐶8=10^(𝐴 − 𝐵/(𝑇(° 𝐶)+𝐶)= [𝑏𝑎𝑟] )
T °C (Suposición)
98.3 1.01019179507628 0.442643614770377 1.0053884498794
100 1.06164292639915 0.467990956752023 0.9184826651415
102.5 1.14100633653523 0.507367378706849 0.7983767649434
105 1.22492813313578 0.549351188374836 0.6866705787145
107.5 1.31358265655238 0.594063992350064 0.582592264114
110 1.40714670002326 0.641630200802134 0.4854497578772
112.5 1.5057994013117 0.692176975487931 0.3946216504382
113.5 1.5467258608212 0.713259242824718 0.3599313406173
115 1.60972213240781 0.745834174408134 0.3095491991937
117.5 1.71909838753179 0.802734293267091 0.229729327077
120 1.83411366967169 0.863012403897563 0.15470847521
122.5 1.95495537588345 0.926806089814092 0.0840771971125
125 2.08181268157481 0.994255379060395 0.0174653978192
125.68 2.11738348359287 1.01325257692736 -2.333896591E-06

128 1
0.9
123 0.8
0.7
118
0.6
0.5
T (°C)

y
113
0.4
0.3
108
0.2

103 0.1
0
0
98
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x,y
T(°C) 𝑥_𝐶7 𝑦_𝐶7
𝐻_𝐿=(𝑥_𝐶7 〖𝐶𝑝〗 _𝐶7 𝑇)+(𝑥_𝐶8 〖𝐶𝑝〗 _𝐶8 𝑇)=[𝑥_𝐶7 〖𝐶𝑝〗 _𝐶7+ 〖
98.3 1.005388449879 1.0156351629326 5281.89909817668
100 0.918482665141 0.9751006244677 5433.81758239639
102.5 0.798376764943 0.910952947743 5655.46967970529
105 0.686670578714 0.841122110064 5875.1601369678
107.5 0.582592264114 0.7652830939818 6093.02818130595
110 0.485449757877 0.6830990248239 6309.20567063558
112.5 0.394621650438 0.5942210449744 6523.81729835018
113.5 0.359931340617 0.5567151126529 6609.25011609432
115 0.309549199194 0.4982881970112 6736.9808393863
117.5 0.229729327077 0.3949273157468 6948.80742435715
120 0.15470847521 0.2837529291968 7159.40183133434
122.5 0.084077197112 0.1643671684843 7368.86278717544
125 0.017465397819 0.0363596866688 7577.28327215001
125.68 -2.33389659E-06 -4.94175409E-06 7633.80524446914

15200
14200
13200
12200
Entalpía (cal/mol)

11200
10200
9200
8200
7200
6200
5200
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Composición x,y

5281.899098177 1.005388449879 5.2668990981767 12858.0128 1.0156351629 12.843012764671


5433.817582396 0.918482665141 5.4188175823964 13003.0664 0.9751006245 12.988066370707
5655.469679705 0.798376764943 5.6404696797053 13224.2311 0.9109529477 13.209231130283
5875.160136968 0.686670578714 5.8601601369678 13455.3767 0.8411221101 13.440376732299
6093.028181306 0.582592264114 6.078028181306 13697.2489 0.765283094 13.682248877454
6309.205670636 0.485449757877 6.2942056706356 13950.6325 0.6830990248 13.935632493004
6523.81729835 0.394621650438 6.5088172983502 14216.3529 0.594221045 14.201352943731
6609.250116094 0.359931340617 6.5942501160943 14326.2882 0.5567151127 14.311288221872
6736.980839386 0.309549199194 6.7219808393863 14495.2772 0.498288197 14.480277243372
6948.807424357 0.229729327077 6.9338074243572 14788.3153 0.3949273157 14.77331526535
7159.401831334 0.15470847521 7.1444018313343 15096.421 0.2837529292 15.081420951697
7368.862787175 0.084077197112 7.3538627871754 15420.5935 0.1643671685 15.405593519055
7577.28327215 0.017465397819 7.56228327215 15761.8787 0.0363596867 15.746878660702
7633.805244469 -2.33389659E-06 7.6188052444692 15857.8106 -4.94175E-06 15.842810647172
0 0 0
λ_𝑉=cal/mol
7593
8224

𝑦_𝐶7=𝑥_𝐶7∗𝑃_𝐶7=𝑃_𝐶7 ∗ (𝑃_𝑇−𝑃_𝐶8)/(𝑃_𝐶7−𝑃_𝐶8 )
8)/(𝑃_𝐶7−𝑃_𝐶8 )

1.01563516293262 0.3
0.975100624467682 2
0.910952947742952 4.5
0.841122110064008 7
0.765283093981787 9.5
0.683099024823935 12
0.594221044974406 14.5
0.556715112652897 15.5
0.498288197011187 17
0.39492731574675 19.5
0.283752929196764 22
0.164367168484253 24.5
0.036359686668787 27
-4.94175409328874E-06 27.68

1
0.9
0.8
0.7
0.6
0.5
y

0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x
8 𝑇)=[𝑥_𝐶7 〖𝐶𝑝〗 _𝐶7+ 〖 (1−𝑥𝐻_𝑉=𝑦_𝐶7 〖〗
〗 _𝐶7) 〖(𝐶𝑝 𝐶𝑝〗 _𝐶7 𝑇+λ_(𝑉,𝐶7) )+𝑦_𝐶8 ( 〖𝐶𝑝〗 _𝐶8 𝑇+λ_(𝑉,𝐶7) )=𝑦_𝐶7 ( 〖𝐶𝑝〗 _𝐶7 𝑇+λ_(𝑉,𝐶7) )
_𝐶8]∗T
1.89909817668 12858.0127646711
3.81758239639 13003.0663707069
5.46967970529 13224.2311302829
5.1601369678 13455.3767322993
3.02818130595 13697.2488774543
9.20567063558 13950.6324930036
3.81729835018 14216.3529437306
9.25011609432 14326.2882218719
6.9808393863 14495.2772433716
8.80742435715 14788.3152653501
9.40183133434 15096.4209516967
8.86278717544 15420.5935190554
7.28327215001 15761.8786607018
3.80524446914 15857.810647172
𝐶7 ( 〖𝐶𝑝〗 _𝐶7 𝑇+λ_(𝑉,𝐶7) )+(1−𝑦_𝐶7)( 〖𝐶𝑝〗 _𝐶8 𝑇+λ_(𝑉,𝐶7) )
646711
707069
302829
322993
774543
930036
437306
218719
433716
653501
516967
190554
607018
647172