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AITS-FT-IV-(Paper-2)-PCM (Sol)-JEE(Advanced)/18

FIITJEE JEE(Advanced)-2018

ANSWERS, HINTS & SOLUTIONS

FULL TEST – IV
(Paper-2)
ALL INDIA TEST SERIES

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

1. A, B, D 21. A, B, C 41. A, B, D

2. B, C 22. A, B, C, D 42. A, C

3. A, B 23. A, C 43. B, C

4. A, B, C, D 24. A, B, C 44. A, B, C, D

5. B, D 25. A, B, C 45. B, C, D

6. A, C, D 26. A, C, D 46. B, C

7. B, D 27. C 47. A, B, C, D

8. A, B, D 28. B, C, D 48. A, B, C

9. A 29. A 49. A

10. A 30. B 50. B

11. C 31. A 51. D

12. A 32. D 52. A

13. 2 33. 8 53. 6

14. 1 34. 2 54. 2

15. 2 35. 4 55. 6

16. 8 36. 9 56. 5

17. 7 37. 9 57. 4

18. 3 38. 2 58. 2

19. 7 39. 9 59. 6

20. 2 40. 5 60. 9

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AITS-FT-IV-(Paper-2)-PCM (Sol)-JEE(Advanced)/18

Physics PART – I
SECTION – A

1. A, B, D
2
K  0.5     4cm


L   2cm
2

 L    4cm

3
L   6cm
2

 L  2  8cm

2. B, C
When the switch ‘S’ is opened,
  RC  1.5 sec
Voltage across the capacitor,
Vc  10 1  e t/1.5  for t < T
dQ dVc
The current, i  C
dt dt
200

3
 106 e t/1.5 for t < T  
Voltage drop across 100 k  resister,
20  t/1.5
V  iR  e for t < T
3
After t = T,
  100 k  10 F  1 sec
Voltage across capacitor,
Vc  Vo t
   t  T  / 

 10 1  e
  T/1.5 
,e    t  T  /1

The charge on capacitor, Q  Vc  C


dVc
The current through 100 k  resistor, i  C
dt
 
 10 3 1  e  T/1.5 1  e  
 t  T /1

3. A, B
2
  X

2 
  4 
16 2

I  4I0 cos2  2I0
4

4. A, B, C, D
Electric field lines kill off on surface of conductor

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AITS-FT-IV-(Paper-2)-PCM (Sol)-JEE(Advanced)/18

5. B, D
Since maximum current passing through two circuits is same and equal to V/R1 in (b) and V/R2 in
(c) then R1 = R2
Current growth equation of L – R circuit is :
i  i0 1  e  t /  
 tR
 
i  i0  1  e L 
 
di i0R  tR /L
Now,  e
dt L
At t = 0 slope of I vs t curve:
di i0R

dt L
From graph (a) : slope of curve (b) > slope of curve (c)
R1 R 2

L1 L 2
Since, R1 = R2
L1 < L2
6. A, C, D
Momentum conservation.
MV0  2MV
V
V 0
3
Angular momentum conservation about centre of mass,
2
1 4  MR2 4  1  2 
MR 2  0  MV0R    M  R    2M R 2  2M  R2   
2 3  2 3  2  3  
3 8 V0
 0 
25 25 R
For   0
8V0
0 
3R
The energy loss,
E  Ei  Ef
1 1  MR2  2 1 19
 MV0 2   2
     3M V  MV0 2
2 2 2  2 9
7. B, D
T
V1   10 2
1
T 10 2
V2  
2 3
Reflection coefficient
V  V1
R 2  2 3
V1  V2
Transmission coefficient,
2V2
T  3 1
V1  V2

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AITS-FT-IV-(Paper-2)-PCM (Sol)-JEE(Advanced)/18

8. A, B, D
Initially,
Pgas  P0 A  mg  112.5 kPa
x
w  Pgas A dx
0
x
   P0 A  mg  kx dx  56.5 J
0

Q  m u  w  118 J

9. A
Time of flight of A is 4 seconds which is same as the time P Q
of flight if wall was not there.
Time taken by B to touch the inclined roof is 1 second.
1
Hence, S  20t  gt 2  20  1  5  12 = 15 m
2 O R

10. A
Vertical component = usin  = 20 m/s

11. C
 r  r2 
dm   2rdr  0  1    20  r   dr dr
 R  R
R
 R 2 R2  50R3 r
M   dm  20   
0  2 3  3
R
 r4   R4 R 4  9
dI  dmr 2  20   r 3   dr  20    0R 4
0
R   4 5  10
3
 r 
d  grdm  20 g  r 2   dr
 R
R
 r3   R3 R3  7
  20 g  r 2   dr  20    g  0 gR
3

0 R   3 4  6
7 9
  I  0 gR3  0R4 
6 10
35g

27R

12. A
  0  t
dE   dmgr  0  t  dt  dmCdT
dT gr
   0  t 
dt C

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AITS-FT-IV-(Paper-2)-PCM (Sol)-JEE(Advanced)/18

SECTION – C

13. 2
M  m  g  FE sin  FE
27Qq
 
2560R2
M  m  g  3mg

M  2m    2

M  m  g

14. 1
P0 V0  nRT0
W1  P0  4V0  V0   3nRT0
W2  mRT0 ln 4  2nRT0 ln2
W1 3nRT0 3 3 2
       1
W2 2nRT0 ln2 2ln 2 2 3

15. 2
6.62  10 34
1.67  1027 v 0   v 0  6.5 m/s  n  2
61 10 9

16. 8
1
L  4   16  L = 8 H
2
4R = 320  R  80
When connected to the battery, Rnet = 100  , L = 8 H
8
  100  8
100

17. 7
K  2P0  3 1 4aq 7 7aq +q C
E 3
1  3
 –q D
x 4 4 0 x 2 20 x3
7 +q
–q 160
o
E B 2p0

–q +q
F A

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AITS-FT-IV-(Paper-2)-PCM (Sol)-JEE(Advanced)/18

18. 3
1 C 2 CV 2CV
E  V Qi  Qf 
2 2  2 3
2CV CV CV
Q f  Qi   
3 2 6
2
E CV 4 3 2E
   3
W CV 2 6 2 W

19. 7
m 0R2 mR2 mR2
 0  m0R2  mR2  
2 2 2
3 20 0R
 0      v0  v  R
2 3 2
0 
2 4v
 v  R  0R  0 A
3 3
16v 20
  v 02  2gx
9
7v 2 7v 02 702R2
2gx  0  x   =7m
9 18g 72g

20. 2
1 2
K0  x 0
2
6
 1 1
Kinetic energy just after 3rd collision =   K 0  K0
2
  64
1 1 2 1 2
 x 0   x
64  2  2
x 02 x
 x2  x 0
64 8
x 0
F  x  2N
8

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AITS-FT-IV-(Paper-2)-PCM (Sol)-JEE(Advanced)/18

Chemistry PART – II
SECTION – A

21. A, B, C
OH
(A) H+ H+

Shift
OH
OH
OH

(A)
(B) (C)

22. A, B, C, D
(A) Electrolysis Zn
(B) CH3CBr2CHBr2
KOOC COOK dust

(D) NaNH2/
(C) alc KOH Br
CHBr2
Br 
NaNH2/

23. A, C
H H
O
I2 O O O O
COOH I I
C
O
I

24. A, B, C
AlBr3 H+
Br
(A) (C)

OH
H+
(B)

25. A, B, C
Presence of strong electron withdrawing group inhabitants the fried craft alkylation.

26. A, C, D

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AITS-FT-IV-(Paper-2)-PCM (Sol)-JEE(Advanced)/18

Me Me Me
H+
Me C O OH Me C O Ph C O Me

Ph Ph OH

+
H3O
OH

O
NaOI
Ph COONa CHI 3 Ph
(P4) (P3) (P1) (P2) Me

CHI 3 Ag HC CH

sodalime
Ph COONa Ph H

27. C
Fact

28. B, C, D
Br2  ON  0  reduces to Br   ON  1 and oxidises to BrO3  ON  5 

29. A
Meq. Of KI  meq. of CuSO4  meq. of I2  meq. of hypo
0.4  103  1 50  0.2  1
 40  10 (limiting reagent)
 meq. of hypo  10  M  x  VmL
 0.4  2  VmL  12.5mL

30. B
meq. of hypo  meq. of Cu2+  meq. of Cu
w Cu
12.12 × 0.1 =  1000  w Cu  0.076g
63.5 / 2
0.076
 % purity   1000  6.99  7%
1.1

31. A
The rate of the reaction = Rate = K [A0]
= 0.0462 × 100 = 4.62 bacterias per minute

32. D
0693 0.693
t1/2    15min
K 0.0462

SECTION – C
33. 8
Fact

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AITS-FT-IV-(Paper-2)-PCM (Sol)-JEE(Advanced)/18

34. 2
Fact.

35. 4
3
Volume of the unit cell, a3  5  108  
o
 1.25  10 22 cm3 ( a  5 A)
Density () = 4.0 g cm -3
Mass of unit cell  V    1.25  1022  4.0
 5.0  10 22 g
5.0  10 22 g
Number of FeO molecules per unit cell 
1.195  10 22 g
= 4.19  4
Thus, there are four Fe2+ ions and four O2– ions in each unit cell.

36. 9
238 206
In conversion of 92 U to 82 Pb, 8-particles and 6 particles are ejected.
The number of gaseous moles initially = 1 mole
The number of gaseous moles finally = 1 + 8 moles; (1 mole from air and 8 mole of 2He4)
So the ratio = 9/1 = 9

37. 9
For AgCl, molarity = normality
  3.41 10 6  1.60  10 6  1.81  10 6  1cm 1
For saturated solution of sparingly soluble salt,
 V    and solubility = normality
1000  
 V   
s
1000   1000  1.81 106
 s   1.31 105
 138.3
Now,
2

K sp( AgCl)  s2  1.31 10 5   0.1716  109
 x9

38. 2
Considering the reduction reaction
A (x  n)   ne  A x 
Oxidized form Reduced form
x
 [A ]  24.4  [A ( x n) ]  75.6, ERP  0.101V
Now from Nernst’s equation
0 0.059 [OF]
ERP  ERP  log
n [RF]

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AITS-FT-IV-(Paper-2)-PCM (Sol)-JEE(Advanced)/18

0 0.059 75.6
0.101  ERP  log ....(i)
n 24.4
If [A x  ]  48.8; [A (x  n)
]  51.2, E  0.115
0 0.059 51.2
 0.115  ERP  log ...(ii)
n 48.8
By eqs. (ii) – (i),
0.059  51.2 75.6 
 0.0014  log  log
n  48.8 24.4 
0.059
 n [0.49  0.020]
0.014
n  1.98  2

39. 9
In Layer M
nA  x nB  y
x y y
 0.2   1  5   4  y  4x
xy x x
In layer N
i  x   0.6
1  x  3  y 
3y 1 3y 4 2
1   
1 x 0.6 1 x 6 3
9  3y  2  2x
9  12x  2  2x
7  10x  x  0.7,y  2.8
w M  0.7  20  0.7  4  40  14  7  16  126
w N  0.3  20  0.2  40  14
wM / wN  9

40. 5
mass mole moler ratio
6w
C 6w 0.5=3
12
w
H w 1=6
1
7w 7w 1
N 2
1.5 1.5  14 3
M.wt.  C3H6N2 n
  100  n  2

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AITS-FT-IV-(Paper-2)-PCM (Sol)-JEE(Advanced)/18

Mathematics PART – III


SECTION – A

41. A, B, D
a b c 2s
  
1   2 2
 2 2
1   1    2 2
2  22
s a sa a
   
1  2
1   2 2 2
 1   2
 1   2 2

 sa 

a 1   2 2 
2 2
1  

similarly s - b 

b 1  2 
2 2
 

sc 
c 2
&s 

b 1  2 
2 2 2
1   

b 1  2  . c 2

 s  b  s  c   2  2 1   2
 tan2  A / 2   
s s  a b 1   2  a 1   2  2
2   2 1   2 2

Q a 

c 1   2 2  


 
1   2 1  2   

2

2
A  2 tan1   /  
B  2 tan1   
1 1 2 tan  A / 2  bc
 Re qd area = bc sin A = bc.  2
2 2 1  tan  A / 2    2
2

42. A, C
3 b
a2  a1  b1  48, b2  1  16
2 2
3 16
a3  48   16  72, b3  8
2 2
1
So, the three loops from i = 1 to i = 3 are alike Now, area of ith loop (square) =  diagonal 2
2

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AITS-FT-IV-(Paper-2)-PCM (Sol)-JEE(Advanced)/18

1 y
Ai   2bi 2  2bi2
2
2
A i1 2  bi1  1
  2

Ai 2  bi  4 x
0 48 72 80
32
So, the areas form a G.P series
 sum of the G.P up to infinite term is
Ai 2 1 8 2
 2  32   1   32  sq. units
1 r 1 3
1
4

43. B, C
a  1, b  4,a.b  2 & c  3b  2a  b

Q a.b  2
 a b cos   2
2 1 
 cos    
a b 2 3
2 2
Again c  3b  2a  b
2 2 2 2
 c  9 b  2c.3b  4 a b sin2 
2
 c  144  6b.c  48
Also, c  2a  b  3b
2

 b.c  b. 2a  b  3 b 
 b.c  0  3  16  48
2
 c  96  6  48  0
2
 c  192

 c 8 3

b.c | b || c | cos   48  4  8 3 cos 


6 3
 cos    
4 3 2
5

6

44. A, B, C, D
1 + x is never zero, so 1 + f(x) is never zero. It is 1 for x = 0, so it is always positive. Hence
f "  x  is always positive f '  0   0 so f '  x   0, x  0
Hence so in particular, 1  f  x   2, x
1 x
f "  x 
2

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x x2 x x 2
Integrating f '  x   f '  0     
2 4 2 4
Again integrating
x 2 x3
f  x   f 0 
4 12
1 1 4
Hence f 1  1   
4 12 3

45. B, C, D

Let angle between a & b be  a  b  1 ,
2

a  b  2cos  1 4 
2  2 tan 3 ,5 
 
a  b  2sin
  0,5 
2
3     0,3   , 4 
F      2cos   2  2sin 
2 2  2
   4
 3 cos  4 sin ,   0,     2 tan1 ,   
2 2 3
3  
F'      sin  2cos
2 2 2
 4
F'     0  tan   
2 3
 F 0  3
 4 3 4
F  2 tan1   3    4    5
 3 5 5
F     4  Range 3,5
Hence possible integer (s) in the range of F    in  0,  are 3

46. B, C
1 1 1
f k   1    ..... 
2 3 k
f 1  1
1
f  2  1 
2
1 1 1
f  2017   1   ........... on adding
2 3 2017
1 1 1
 1 2017   2016   2015  ...........  1
2 3 2017
1 1 1
 1 2017   2017  1   2017  2   ..........   2017  2016 
2 3 2017
 1 1 1  1 2 2016 
 2017  1    ......       .....  
 2 3 2017   2 3 2017 
 1 1 1 1 
 2017f  2017   1   1   1   .....  1  
 2 3 4 2017 

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 1 1 
 2017f  2017   1 2016   1   ..........  
 2 2017 
 2017f  2017   2016  f  2017 
 2018f  2017   2017
a  2018, b  2017, c  2017

47. A, B, C, D
 1  sin2   sin   sin2 
x2  x   0
 1  sin   1  sin 
 
 1  sin    1  sin  
x 2  x  sin     sin   0
 1  sin    1  sin  
1  sin 
 x  sin ,
1  sin 
1  sin 
      sin ,     
1  sin 
Hence the results follows.

48. A, B, C
D(x) can at most be polynomial of degree 2
D  x   ax 2  bx  c
D  x   x2  x  1
D 1  3
D  2   4  2  1  3
D  3   9  3  1  7

49. A

50. B
r1  b  x1  OP  OA
AP1  a / 2 P
D C
2
a 2
r12  x12      b  x1 
2
  r1
a2
x12   b2  x12  2bx1 b
4 O
r1 r1
4b2  a2 x1
x1 
8b P1
2 2 A B
4b  a
r1  b  x1  a
8b
4a2  b2
similarly r2 
8a

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a3  b3  4ab  a  b 
r1  r2 
8 ab
a  b   a 2
 3ab  b2 

8 ab
 a  b 2  5ab 
 a  b   
 
 8  ab
2
But  a  b   0
a  b 5ab
r1  r2  .
8 ab
5 a  b
 r1  r2 
8

51. D

52. A
f h   1
f '  0   lim  In a
h 0 h
f  x   f  h   1 f  h   1 f  x 
f '  x   lim    2 In a
h 0 2
 h h  2
f 'x
 In a  In f  x   In a x  C
f x
f  0   1  C  0  f  x   ax
2
dy  x  y
 put x  2  X, y  2  Y 
dx  x  2 y  2
2
dY  X  Y 

dX XY
y2 1 2  y  2
  In 1   2 In  x  2   C
x2 2 x2

SECTION – C

53. 6
 
Q  x   x 3  2x 2  x  1  x  1  0    1
      2, + +=1

 
p  x   x2  1 Q  x   x 2  x  1

p     p     p     p  1   2  2   2  1         1  4

54. 2
 10k 1   k 10k 1 
Let log10 4x   k  log10 x  then x  10k ,  , for k > 0 & k = 0  10 ,  is beyond (0, 1)
 4   4 
but for k < 0, the whole interval is in (0, 1).

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So favourable x is obtained for k  1, 2, 3,.....................


 1 1
for k =  1, x   , 
10 4 
 1 1 
for k  2, x   ,  .........
100 40 
sum of lenght of these intervals
1 1   1 1 
      ..............
 4 10   40 100 
3  1 1  1
 1    ....  
20  10 100  6
1
1
Required probability  6 
1 0 6

55. 6
2
f '  x   f '  x   f  x 
Either f’(x) = 0 at least 4 roots
f(x) = 1 at least 5 roots
f(x) = - 1 at least 2 roots
at least 11 roots. 7 8

56. 5
2
f(x) will be below y  5 & y 
x  2 
2/ 5 1  , 5
2 A B 
5 
I 

0
5dx 
 x dx
2
5
2
y 5
C 2
5
y
 2   2  x
 5   2 ln 1  2 ln  
 5   5
 5 x
 2  2 ln  1/ 2 D
 2 
 

57. 4
40 10
There are C4 ways of drawing 4 slips C2 ways to choose a & b. After a & b have been
4 4
chosen there are C2 ways of choosing 2 slips labelled a & C2 ways of choosing 2 slips
labelled b
10
C2 4 C2 4 C2 36.10 C2
 Required Probability  40
 40
C4 C4

58. 2
Since

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2
b  b b
2
 f  x  g  x  dx  
   f  x  dx  g2  x  dx
a  a a
b b
1
 xf  x f '  x  dx 

a
2 
x f 2  x  ' dx
a

b
1  2 b  1
 xf  x   f 2  x  dx  


2 

a
a

 2

Hence by Schwartz’s inequality
b b
1 2

4

  f '  x   dx. x2 f 2  x  dx

a a

59. 6
3
sin x  1  In x 1
3
sin x  In x 

No of solutions 6

60. 9
An denotes no. of n digit sequence that end in 0 or 4
Bn denotes no. of n digit sequence that end in 1 or 3
Cn denotes no. of n digit sequence that end in 2
A n 1  Bn ( each sequence in An+1can be converted into a sequence in Bn by deleting its last
digit). Bn+1= An + 2 Cn (  each sequence in An can be converted into a sequence in Bn+1 by
adding a 1 (if it ends with 0) or a 3 (if it ends with 4) to its end, 8 each sequence in Cn can be
converted into a sequence in Bn+1 by adding a 1 or a 3 to it. Cn+1  Bn (by deleting 2 at its end)
Bn 1  3Bn 1 for n  2 , B1  2, B2  4
 A10  B10  C10  2B9  B10  4.3 4  4.34  648

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