SLOVENSKI STANDARD

SIST EN ISO 584:1999

01-maj-1999

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Plastics - Unsaturated polyester resins - Determination of reactivity at 80 °C

(conventional method) (ISO 584:1982)
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Kunststoffe - Ungesättigte Polyesterharze - Bestimmung der Reaktivität bei 80°C
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(Herkömmliches Verfahren) (ISO 584:1982)
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Plastiques - Résines de polyesters non saturés - Détermination conventionnelle de la

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réactivité a 80°C (ISO 584:1982)

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Ta slovenski standard je istoveten z: EN ISO 584:1997

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83.080.10 Duromeri Thermosetting materials

SIST EN ISO 584:1999 en

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
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SIST EN ISO 584:1999

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SIST EN ISO 584:1999

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SIST EN ISO 584:1999

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 SIST EN ISO 584:1999

International Standard
INTERNATIONAL ORGANIZATION FOR STANDARDIZATIONWVlE)I(CIYHAPO~HAR OPrAHM3AlWlR fl0 CTAH&‘WTM3ALWll4WIRGANISATION INTERNATIONALE DE NORMALISATION

Plastics - Unsaturated Polyester resins - Determination

of reactivity at 80 OC (conventional ) EW method)

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Plastiques - Rksines de polyesters non saturks - Determination conventionnelfe de Ia rtGactivit6 6 80 OC
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First edition - 1982-12-01
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UDC 678.674 : 543.878 Ref. No. ISO 584-1982 (E)

Descriptors : plastics, Polyester resins, Chemical analysis, determination, Chemical reactivity.

Price based on 3 pages

 SIST EN ISO 584:1999

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of
national Standards bodies (ISO member bodies). The work of developing International
Standards is carried out through ISO technical committees. Every member body
interested in a subject for which a technical committee has been authorized has the
right to be represented on that committee. International organizations, governmental
and non-governmental, in liaison with ISO, also take part in the work.
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Draft International Standards adopted by the technical committees are circulated to

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the member bodies for approval before their acceptance as International Standards by

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the ISO Council.
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International Standard ISO 584 was developed by Technical Committee ISO/TC 61,
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Hastics, and was circujated to the member bodies in July 1980.

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ft has been approved by the member bodies sf the following countries :

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Australia Hungary New Zealand

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Austria India Poland

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Canada Iran Romania

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China Ireland South Africa, Rep. of

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Czechoslovakia Israel Spain

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Egypt, Arab Rep. of Italy Sweden

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ßinland Japan USA

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France Korea, Rep. of USSR

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Germany, ß. R. Netherlands

The member bodies of the following countries expressed disapproval of the document
on technical grounds :

Belgium
United Kingdom

This International Standard tan cels and repl aces ISO Recommendation R 5844967 of
which it constitutes a technical revision

0 international Organization for Standardization, 1982

Printed in Switzeriand
 SIST EN ISO 584:1999

INTERNATIONAL STANDARD ISO 5844982 (E)

Plastics - Unsaturated Polyester resins - Determination

of reactivity at 80 OC (conventional method)

0 lntroduction the mixture to rise from 65 OC to this maximum temperature,

and also, if the maximum temperature exceeds 90 OC, by the
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The processing of unsaturated Polyester resins depends on time taken for the temperature to rise from 65 to 90 OC.

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their reactivity, i.e., their rate of polymerization in the presence
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of a catalyst. The evaluation of their reactivity tan be carried These characteristics give an indication of the processing
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behaviour of unsaturated Polyester resins and tan be used to
out by various methods. This International Standard is limited
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to measuring certain characteristics relating to the Change in compare resins of similar type. As the test results depend very
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temperature as a function of time of a resin-catalyst mix. Using much on the conditions under which the test is carried out,
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arbitrarily standardized test conditions, these characteristics these conditions are described in detail.
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allow comparison of similar types of unsaturated Polyester

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resins. NOTES
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1 If the method is used to test commercial benzoyl peroxide catalyst,

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The results obtained in this test are dependent upon the the results should be compared with those obtained for the same resin
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following test conditions : using pure benzoyl Peroxide.

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2 By agreement between the interested Parties, certain test con-

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a) quantity and spatial Parameters of the test Portion ditions tan be modified : such as the test temperature (temperature of
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examined (test-tube diameter, height of resin in the tube); the thermostatically controlled bath) and the quantity and type of
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catalyst System (mixtures of catalysts, combinations of catalysts and

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b) Speed of heating the test Portion placed in a accelerators).

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temperature controlled bath. ßor example, the replacement

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of water in the bath by another fluid with a lower heat

capacity (glycol, Oil, etc.) leads to slower heating; 2 Brinciple

c) type of temperature measuring element placed in the Placing of a mixture of 100 Parts of resin with 1 part of catalyst
test Portion and its ability to respond to rapid changes in in a test-tube of defined size. Heating of the test-tube and its
temperature. Thermometers with a slow response and contents in a water-bath at 80 OC for the duration of the
thermocouples with large junctions between the resistance reaction, and noting (or recording) the rise in temperature with
leads are unsatisfactory; time.

d) accurate centring of the thermocouple in the test

Portion, both in height and in line with the axis. 3 Reagent

These conditions which are mandatory are specified in the During the analysis, use only reagents of recognized analytical
text of this International Standard. grade.

Benzoyl Peroxide, catalyst.

1 Scope and field of application WARNING - Attention is drawn to the dangers involved
in handling pure benzoyl Peroxide.
This International Standard specifies a method for the deter-
mination of the reactivity of unsaturated Polyester resins as A mixture of 50 % (mlm) of benzoyl peroxide catalyst in
characterized by the maximum temperature reached by a solu- dibutyl phthalate having an active Oxygen content between
tion of unsaturated Polyester resin and catalyst when heated in 3,25 and 333 % bnlm), as measured by known analytical
a water-bath at 80 OC, by the time taken for the temperature of methods.
 SIST EN ISO 584:1999

ISO -1982 (E)

4 Apparatus 5.3 If a recorder is used, Start and allow the recorder to run
during the complete reaction. Alternatively, note the maximum
4.1 Water-bath,l) mai ntained at 80 + 0,5 OC and provided temperature reached, as weil as the time taken for the
with a thermostat and a circulation pump or stirrer. temperature of the mixture, determined by the thermocouple,
to rise from 65 OC to the maximum temperature, and in the
4.2 Test-tube, of borosilicate glass or any other glass giving case where this temperature is greater than 90 OC, the time to
the same results, of internal diameter 18 It: 1 mm, length rise from 65 to 90 OC.
210 + 5 mm and wall thickness 1 I!Z 0,2 mm.

5.4 Repeat the test, beginning at 5.1, until two consecutive

4.3 lron-constantan thermocouple,
consisting of wires of
determinations do not differ by more than 5 OC in temperature
1 I: 0,05 mm thickness, with a welded junction of 2 mm
and 10 % in time.
diameter maximum and a meter for measuring temperatures up
to 250 OC, graduated in divisions of 2 OC.

NOTE - lt is desirable to use screened thermocouples that tan be

positioned centrally. 6 Test report

4.4 IQ available a recorder, permitting the readings of The test report shall include the following information :
temperature on the graph Paper to the nearest 1 OC and the
time to the nearest 15 s. a) a reference to this International Standard;

b) a complete identification of the resin tested;

4.5 Device, for locating the thermocouple centrally in the
test- tube (sec the figure).
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values of the maximum temperature
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4.7 Stop watch. reached in the two tests a n d the average value;
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e) the individual values of the time taken for the tempera-

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5 Procedure
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ture to rise from 65 OC to the maximum temperature

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in the two tests and the average value;

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5.1 Weigh 2 + 0,Ol g of the benzoyl Peroxide-dibutyl

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phthalate mixture (clause 3) into a glass beaker of capacity f) if the maximum temperature is above 90 OC, the in-
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250 ml and add 100 $r 1 g of resin at a temperature between 15 dividual values of the time taken for the temperature to rise
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and 30 OC. Continue stirring for 2 to 3 min. from 65 to 90 OC in the two tests and the average value;
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5.2 Then immediately pour part of the mixture into the test- g ) ifa recorder is used, the graphs giving the temperature
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tube (4.2) to a height of 7 to 8 cm. Introduce the thermocouple

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P#lotted against time.

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into the mixture in a Position on the axis of the tube and

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equidistant from the bottom and the surface of the mixture (sec h) any deviations from the Standard test conditions speci-
the figure). Then place the tube in the water-bath at fied in this International Standard, for example type and
80 -+ 0,5 OC, so that the surface of the resin is weil beneath the temperature of the heating medium, catalyst System used,
level of the surface of the water. thermocouple System used, etc. (see note 2 to clause 1).

1) The water in the bath may be replaced by another fluid agreed upon by the interested Parties.