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a) the size of the orbital b) The shape of the orbital c) the way the orbital is oriented in space d)the spin
of the electron that occupy an orbital
a) 4 b) 6 c) 10 d)18
a) 6S b) 3P c) 2d d) 4f
4. Which of the following neutral atom can have the largest number of unpaired electrons?
a) Na b) Mg c) Al d)K f)Ca
10. In which of the following molecules central atom is in SP3 hybrid state
a) N 3- b) F - c) Al3+ d) Mg 2+
13. Which of the following molecules does not exist as resonance hybrid?
a) 2 b) 4 c)6 d)14
a) 8 b) 18 c)24 d)32
a)K b) N c) O d)F
23. Which of the following solution have the same colligative properties as 0.1M AlCl3
24.Which of the following solution have the same colligative properties as 0.1M AlCl3
a) 12 b) 4 c) 10 d)11
a) 5 b) 4 c) 10 d)11
27. pOH 0f 0.00005 M Ba(OH)2 is
a) 12 b) 4 c) 10 d)11
a) Mg 2+ b) Ca2 + c) Zn 2+
a) CO b) O3 c) N2O3 d) NO2
a) Si b) O2 c) Al d) N2
40. Which of the following is not solid at room temperature?
41. Which of the following will react with water at room temperature?
a) Mg b) Al c) Ga d) Na
42. which of the following reactions can be used for industrially receive carbon dioxide
43. Which of the following compound is able to express oxidative as well as reductive properties?
45. which of the following reactions can be used for industrially receive H2
46. which one of the following elements has greater tendency to catenation
a) O b) N c) S d) Cl
a) NO+ O2 b) N2 + O2 c) N2 + H2 d) NH3 + O2
a) Na b) Ba c) Cr d) Ca
49. Nitrogen has a reasonable oxidation number in all of following compounds and yet one of them is
impossible. Which of them is impossible?
54.Which of the following is the correct equilibrium constant expression for the reaction
d) b) Kc =[ClF3]/[Cl2] [F2]
55. the following data were obtained for the reaction 2HI(g) =H2(g) + I2(g)
1 1 10 -2 4 10-6
2 2 10 -2 8 10-6
Kc = [H2O] / [HCl]2
Kc = 1/ [SO3]
c)H2(g) +Cl2(g)=2HCl(g)
Kc = [HCl ]/ [H2] [Cl2]
d)H2(g) +S(s)=H2S(g)
Kc = [H2S]/[H2][S]
60. In which of the following reaction the rate of reaction can be determined by measuring the decrease
in pressure in time interval
a) H2+Cl2=2HCl
c) CaO(s)+CO2 =CaCO3(s)
d) H2(g) +S(s)=H2S(g)
61. The rate of reaction slows down with time at constant temperature because
A B C rate
a)rate=K(A)(C)2
b)rate=K(A)(C)
c)rate=K(A)(B)
d)rate=K(A)2(B)(C)2
f)rate=K(A)(B)(C)2
Which of them is correct?
a)DE
b)J
c)G
d)L
f)C
65.Given the reaction: P+N = 2C
Doubling the concentration of N doesn’t change the rate but doubling the concentration of P doubles the
rate of the reaction. The equation is
a) rate =K [N] b)rate = K[P] [N]2 c). rate = K[P] 2 d). rate = K[P]
A. It lowers the energy of activation B. It change the reaction mechanism C. It increases the yield of
reaction D. It decreases the number of molecules with necessary energy to react
A. rate = [X] [Y] B. rate = [Y] C. rate= [X]2 [Y] D. rate = [Y]2 E. rate=[X] [Y]2
68. Given the reaction 2NO+O2=2NO2 H= -21.6 Kcal
b). Addition of O2
c)removal of NO2
69. Which of the following procedures lead to a change in the value of the equilibrium constant of a
chemical reaction?
70. Assuming equilibrium reaction 2CO (g) + O2 (g) = 2 CO2 (g) H=-135,2 Kcal.
73. Which of the following is not an extensive parameter of thermodynamic system state?
a) concentration b)volume c) mass d)pressure
80. Which of the following change will produce an increase in the entropy of the system?
a) the production of entropy system always tends to minimum b)S=0 c)G=0 d) G=H
a.) temperature b,) enternal energy c,) enthalpy . d). pressure c,) volume f.) heat g. work
a.) water boiling b). ice forming c.) water evaporating d,) snow melting e,) water condensing
c) Processes that take place without any change in entropy are irreversible
d)T S is change of the part of internal energy , that can make the work
a) G = H +T S
b) E = Q- p V
c) Q- T S = 0
d) E+ p V- T S = 0
b) The free energy change of a system is equal to zero at equilibrium during constant P and T
c) The entropy of any object will be the equal to zero at room temperature
d) The reactions that take place with decrease of a free energy of system are called the egzergonic
reaction
a) Na b)Mg c) Al d)Cl
a)N b)K c) O d) B
a) 18 b) 32 c)8 d) 48
a) 3s< 4s< 5s b) 5s< 5p< 5d c) 5s< 4d< 5p d) 6 s< 4f< 5d e) 6s< 5f< 6p
103. Which pair of quantum numbers determines the energy of an electron in an orbital
105. As atomic orbital are filled according to Aufbau principle the 6p orbital are filled after which of the
following orbital
a) 4f b) 4d c) 6s d) 7s
106. Which of the following elements should have the largest ionization energy
a) Na b) Mg c) Al d) Si c) P
107. Which of the following atoms has the largest covalent radius
a) N b) O c) F d) P e) S
108. Which of the following ions has the electron configuration [ Ar] 3d 4
a) K+ b) Li + c) Be+2 d) O-2 e) F-
a) HCO2-
114 Which of the following elements would form a linear compounds with the formula XO2
a) Li b) Be c) C d) F
115. Which element forms a compound with the following Lewis structure C- X= O
a) Be b) B c) C d) N e) O f)F
116) Which element forms an ion with the formula XF 6 -2 that has no lone pair electrons in the valence
shell of the central atom
a) Ca b) C c) Si d) S e) P
118. In which of the following the central atom has SP3 hybrid orbitals
121) Which of the following molecules can act as both a Bronsted acid and base?
124) Which of the following ions is the conjugate base of a strong acid
a) 12 b) 10 c) 3 d) 9
128) Which of the following compound would be the most soluble in nonpolar solvent such as CCl4
a) H2O b) CH3OH c) CH3(CH2)2OH d) CH3(CH2)4OH
129) Which of the following compound would give the largest freezing point depression when 100g are
dissolved in 1Kg of water?
130) Which of the following mixtures would make the best buffer
a) HCl and NaCl b) NH4OH and NH4Cl c) NH4Cl and CH3COOH d) Na OAc and NH3
a) Mg 2+ b) Na+ c) Ba 2+ d) Zn 2+
a) Si b) O2 c) Al d) N2
135. Which of the following will react with oxygen at room temperature?
a) Mg b) Al c) Ga d) Li
136) which of the following reactions can be used for industrially receive carbon dioxide
137) Which of the following are able to express oxidative as well as reductive properties
138) which of the following reactions can be used for industrially receive CO
139) which one of the following elements has the greatest tendency to catenation
a) C b) N c) S d) Se
x y z rate
A. rate=K(x)(z)2
B. rate=K(x)(z)
C. rate=K(x)(y)
D. rate=K(x)2(y)(z)2
E. rate=K(x)(y)(z)2
145. The compound X is with formula C3H6O gives on oxidation the compound with formula
C3H6O2. X is most likely to be
151. The following data given for alcohols : I. a Aldehyde formed when it oxidized in the present
of suitable catalyst. II. 0.5 mol of H2 is liberated when 1. Mol alcohol is react with Na. Which
one of the following is this alcohol
155. the compound X is with formula C3H8O gives on oxidation the compound with formula
C3H8O. X is most likely to be
161. The following data given for alcohols : I. a keton formed when it oxidized in the present of
suitable catalyst. II. 0.5 mol of H2 is liberated when 1. Mol alcohol is react with Na. Which one
of the following is this alcohol
168 When a 3 liter mixture containing equal moles of ethane ethane and ethyne is burned . How many
many liters of CO2 is produced
a) 2 b) 3 c) 4 d) 6 c) 9
174 Which of the following is the product of the reaction between chlorine and ethylene
175 Which of the following does not rapidly react with Br2 dissolved in CCl4
176 Which of the following is the product of the reaction between water and ethyne
177. Which of the following is five member ring heterocyclic compound with two hetero atoms?
178. Which of the following is five member ring heterocyclic compound with one hetero atoms?
182. Which of the following statements is not correct regarding the predominant form d galactose
a)It is hemiacetal
185. Dextran is
186. Which of the following substances will not react with Ag2O
a) d)
a) b)
c) d)
194. Which of the following has the carbon atom in both Sp3 hybrid and Sp2 hybrid state
a) ethene b) toluene c) propane d) 1.3butadiene
195. Which is the number of possible isomers for the compound C3H5Br
a)1 b) 2 c) 3 d) 4 e) 5
196 Which of the following is the dihydroxydicarboxylic acid
a)succinic acid b)tartaric acid c) malonic acid d)lactic acid
197. What would you expect to receive while acting by sodium hydroxide on
198 Which of the following compound will not react with H2O
a) ethylamine b) aniline c) benzene 4) ethyne
199 The distance between C-C atoms is aromatic compound is equal to
a) 0.120 b) 0.130 c) 0.134 d) 0.140
200. Which of the substance given below provides disodium derivatives under the action of NaOH
solution
a) CH3-CH2-COOH b) HOCH2CH2COOH c) HO-C6H4-COOH d)HOCH2CH2OH
201 Which pairs of the compounds given bellow are not diastereomers
b) d)
a) b)
c) d)
212. Which of the following has the carbon atom only in Sp2 hybrid state
a) ethane b) benzene c) propanal d) butanol
218. Which pairs of the compounds given bellow are not diastereomers
a) Most carboxylic acids exist as cyclic dimmers b) Carboxylic acids are slightly dissociated in aqueous
solution c) acetic acid is much more stronger than nitric acid d) Carboxylic acids are much more
stronger than alcohols
225. In the production of hexane by Wurts reaction butane and octane are produced as by products
Which alkyl chlorides do you expect to be used
a) CH3CH2Cl+CH3CH2CH2CH2Cl b)CH3Cl+CH3(CH2)2Cl c) 2CH3(CH2)2Cl d) 2C2H5Cl
226 Which of the following is the same for two structuerl isomers
a) molecular formula b) physical properties c)chemical properties d) molecular weight
228 Which of the following compound liberates the same amount of hydrogen when reacted with eater
one of Zinc and sodium metal
a)CH3CH2OH b) HOOC-CH2OH c)HOOC-COOH d) CH3CHO
229 Which of the following statements is not correct about cholesterol? Cholesterol is
a) a secondary alcohol b)an unsaturated alcohol c) a cyclic alcohol d) a.polyhydric alcohol
236. Which of the following compound is formed if one of the isomer of ethylacetate is redused by one
step
a) ethanol b) propanol c) butanol d) pentanol
HO-CH2-CH2 –NH2
HOCH2-CH2N(CH3)3
HO-CH2-CH(NH2)-COOH
a) the size of the orbital b) The shape of the orbital c) the way the orbital is oriented in space d)the spin
of the electron that occupy an orbital
a) 4 b) 6 c) 10 d)18
a) 6S b) 3P c) 5d d) 2f
4. Which of the following neutral atom can have the largest number of unpaired electrons?
a) N b) Mg c) Al d)O f)C
10. In which of the following molecules central atom is in SP3d hybrid state
a) N 3- b) F - c) Al3+ d) Mg 2+
13. Which of the following molecules does not exist as resonance hybrid?
14. The maximum number of electrons that can fit into a 4f orbital is
a) 2 b) 4 c)6 d)14
a) 32 b) 18 c)24 d)8
a)B b) N c) O d)F
23. Which of the following solution have the same colligative properties as 0.2M glucose
24.Which of the following solution have the same colligative properties as 0.8M fructose
a) 12 b) 4 c) 10 d)11
a) 5 b) 4 c) 10 d)11
a) 12 b) 4 c) 3 d)11
a) Si b) O2 c) Al d) N2
41. Which of the following will react with water at room temperature?
a) Mg b)Cl2 c) Ga d) N2
42. which of the following reactions can be used for Laboratory receive carbon dioxide
43. Which of the following compound is able to express oxidative as well as reductive properties?
45. which of the following reactions can be used for laboratory receive H2
46. which one of the following elements has greater tendency to catenation
a) C b) N c) S d) Cl
a) NO+ O2 b) N2 + O2 c) N2 + H2 d) NH3 + O2
a) Na b) Mn c) Li d) Ca
49. Nitrogen has a reasonable oxidation number in all of following compounds and yet one of them is
impossible. Which of them is impossible?
54. In which of the complex ions given below the metal ion has not oxidation number equal to 3+
a)[Fe(CN)6]3- b) )[Fe(CN)6]4- c)[Cr(OH) 6]3- d)[Al(NH3)6]3+
58. In which of the complex ions given below coordination number is equal to 4
a)[Fe(CN)6]3- b) )[Fe(CN)6]4- c)[Cr(OH) 6]3- d)[Al(OH) 4]-
59 In which of the complex ions given below coordination number is equal to 4
a)[Fe(CN)6]3- b) )[Cu(en)2]4- c)[Cr(OH) 6]3- d)[Al(OH) 6]3-
60.