(3 Hours) (Total Marks: 80) N.B.: 1) Question No.1 Is Compulsory

8 D E
FB BA8 093 32F8 83D 989 95B A53 3BE 754 4DE
0 9 A 7 8
BAA80 932 2F83 3D9 895 5BA 53B BE7 54DDE8 8A8
8 93 F8 D 89 BA 53 E 54 E 8A 9F
A8 093 2F 3D 989 5B 5 BE 754 DE 88A 89 B
0 8 9 A 3 7 F A
80 932 2F83 3D9 895 5BA 53B BE7 54DDE8 88A8 89F BA 809
9 8 5 B 8
4
3
2
1
09 32F F83DD98 95B BA5 53BE E75 4DE E88 8A89 9FB A8 093 32F8
32 83 9 95 A 3B 7 4D 8 A8 F A 09 2F 3D
32 F83 D9 895 BA 53B E7 54D E8 8A8 9F BA 809 32F 83D 98
F 8 B 5 5 8 B 8 3 9
2F 83DD98 95B A5 3BE E75 4DE E88 A89 9FB A8 093 2F8 83D 989 5BA
83 98 95 A 3B 75 4D 88 A8 FB A8 093 2F 3D 98 5B 5
72533
83 D98 95 BA 53B E75 4D E88 A8 9FB A8 093 2F 83D 98 95B A5 3BE
D B 5 8 9 3
3D 989 95B A5 3BE E754 4DE E88AA89 9FB A80 0932 2F8 3D9 989 5BAA53 BE7 754
9 5 A 3 B 7 D 8 F A 9 F 3 8 5 B 5 B D
i)
D9 895 BA 53 E7 54D E8 8A 89F BA 809 32F 83 D98 95 A5 3B E75 54D E88
89 BA 53 BE 54 E 8A 89F BA 80 32 83 D9 95 BA 3B E7 4D E8 A8
T =[
5B 5 BE 75 DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F
A5 3B 75 4D 88 A8 FB A8 93 2F8 3D 989 5B 53 BE 754 DE 88A 89 BA
𝑘2
3B E75 4D E8 A8 9FB A8 09 2F 3D 98 5B A5 BE 75 DE 88 89 FB 80
𝑘1
E7 4D E8 8A 9F A 09 32F 83D 98 95B A5 3B 75 4D 88 A8 FB A8 93
that set up.

𝑅 ln 2
54 E 8A 89F BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F
DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83
]
88 A89 FB A8 93 2F8 3D 989 5BA 53 BE 754 DE 88A 89 BA 80 932 F83 D9
A8 FB A8 09 2F 3D 98 5B 5 BE 75 DE 88 89 FB 8 93 F8 D 89
10 (𝐾)𝐸 1/2
9F A 09 32F 83D 98 95B A5 3B 75 4D 88 A8 FB A8 093 2F8 3D 989 5B
BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F 3D 98 5B A5
80 932 F83 D9 895 BA 53B E7 54D E8 8A8 9F BA 809 32F 83D 98 95B A5 3B
93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83 9 95 A 3B E7
A + B → R (desired)
2F 3D 98 5B 5 BE 75 DE 88 89 B 8 93 F8 D 89 BA 53 E 54
for first order reaction.
A + B → S (undesired )
83 98 95 A 3B 75 4D 88 A8 FB A8 093 2F 3D 98 5B 5 BE 75 DE
D9 95 BA 53 E7 4D E8 A 9F A 09 2F 83 98 95 A5 3B 75 4D 88
𝑑𝑡
𝑑𝐶𝑅
𝑑𝑡
𝑑𝐶𝑠
5B 5 BE 75 DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F
(d) Short note on Recycle Reactor.

N.B.: 1) Question No.1 is compulsory.
54 E 8A 89F BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F
DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83
first order with k= 3.07 s-1 at 1100 K
Plug flow and ii) mixed flow

BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F 3D 98 5B A5
= 1.0 𝐶𝐴 0.5 𝐶𝐵
4) Figures to the right indicate full marks.
93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83 9 95 A 3B E7
Page 1 of 2
1.8
(3 Hours)
2F 3D 98 5B 5 BE 75 DE 88 89 B 8 93 F8 D 89 BA 53 E 54
3) Assume suitable data and justify the same.
83 98 95 A 3B 75 4D 88 A8 FB A8 093 2F 3D 98 5B 5 BE 75 DE
D9 95 BA 53 E7 4D E8 A 9F A 09 2F 83 98 95 A5 3B 75 4D 88
(a) Consider the competitive liquid phase reactions :

5B 5 BE 75 DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F
= 1.0 𝐶𝐴 𝐶𝐵 0.3 mol/l/min

54 E 8A 89F BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F
mol/l.min
DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83
stream for XA = 0.90, if the flow pattern in the reactor is

88A89FBA80932F83D9895BA53BE754DE
BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F 3D 98 5B A5
2) Attempt any three questions out of remaining five questions.
93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83 9 95 A 3B E7
How much faster is the decomposition at 650 0C than at 5000C.?
2F 3D 98 5B 5 BE 75 DE 88 89 B 8 93 F8 D 89 BA 53 E 54
83 98 95 A 3B 75 4D 88 A8 FB A8 093 2F 3D 98 5B 5 BE 75 DE
D9 95 BA 53 E7 4D E8 A 9F A 09 2F 83 98 95 A5 3B 75 4D 88
89 BA 53 BE 54 E 8A 89F BA 80 32 83 D9 95 BA 3B E7 4D E8 A8 with 80 mole% A and 20 mole % inerts, decreases by 20 %in 3 min.
between activation energy and temperature for which the rule holds is
5B 5 BE 75 DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F
converted in 5 minutes. How long it would take to reach 75 % conversion.

54 E 8A 89F BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F
DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 8
88 A89 FB A8 93 2F8 3D 989 5BA 53 BE 754 DE 88A 89 BA 80 932 F83
Paper / Subject Code: 31704 / Chemical Reaction Engineering - I (CRE-I)
A8 FB A8 09 2F 3D 98 5B 5 BE 75 DE 88 89 FB 8 93 F8
9F A 09 32F 83D 98 95B A5 3B 75 4D 88 A8 FB A8 093 2F8 3D
BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F 3D 9
C2H6  C2H2 + H2 find the volume of reactor to achieve 80% conversion of ethane.
results in 96 % conversion of A. If a mixed flow reactor ten times as large as the

occurs only at a specific temperature for a given activation energy (for specific
Equal volumetric flow rates of the A and b streams are fed to the reactor . each
combination of temperature and activation energy ). Show that the relationship
P, if by keeping the pressure constant, the volume of the reaction mixture, starting
plug flow reactor were placed in series with the existing reactor, which reactor
ethane in a plug flow reactor operated at 1100 K and 6 atm. The cracking reaction is
(a) Liquid A decomposes by first order kinetics. In a batch reactor, 50 % of A is
stream has concentration of 20 mol/l. Find the concentration of R in the product

(c) Derive performance equation of a mixed flow reactor for constant density system
should come first and by what fraction could the production rate be increased for
(b) The pyrolysis of ethane proceeds with an activation energy of about 300 kJ/mol.
plug flow reactor using equimolar amounts of A and B , CA0 = CB0 = 1 mol/l and
80 932 F83 D9 895 BA 53B E7 54D E8 8A8 9F BA 809 32F 83D 98
93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83 9
2F 3D 98 5B 5 BE 75 DE 88 89 B 8 93 F8 D 89
83 98 95 A 3B 75 4D 88 A8 FB A8 093 2F 3D 98
12
(b) The elementary irreversible liquid phase reaction A + B  R + S takes place in a 10
(a) It is required to produce 9.5 kg /s of ethylene by cracking a feed stream of pure 10
(b) Find the first order reaction rate constant k, (referred to A) of the gas reaction 2A 10
(a) The rule of thumb that the rate of reaction doubles for a 10 0C in temperature 10
05
05
05
05
D9 95 BA 53 E7 4D E8 A 9F A 09 2F 83 98 95
(Total Marks: 80)
89 BA 53 BE 54 E 8A 89F BA 80 32 83 D9 95 B
5B 5 BE 75 DE 88 89 B 80 93 F8 D 89 BA
A5 3B 75 4D 88 A8 FB A8 93 2F8 3D 989 5B
3B E75 4D E8 A8 9FB A8 09 2F 3D 98 5B A5
E7 4D E8 8A 9F A 09 32F 83D 98 95B A5
54 E 8A 89F BA 80 32 83 9 95 A 3
DE 88 89 B 80 93 F8 D 89 BA 53
88 A89 FB A8 93 2F8 3D 989 5BA 53 B
A8 FB A8 09 2F 3D 98 5B 5 BE
9F A 09 32F 83 98 95 A5 3B 7
8 D E
FB BA8 093 32F8 83D 989 95B A53 3BE 754 4DE
0 9 A 7 8
BAA80 932 2F83 3D9 895 5BA 53B BE7 54DDE8 8A8
8 93 F8 D 89 BA 53 E 54 E 8A 9F
A8 093 2F 3D 989 5B 5 BE 754 DE 88A 89 B
0 8 9 A 3 7 F A
80 932 2F83 3D9 895 5BA 53B BE7 54DDE8 88A8 89F BA 809
9 8 5 B 8
09 32F F83DD98 95B BA5 53BE E75 4DE E88 8A89 9FB A8 093 32F8
6
5
32 83 9 95 A 3B 7 4D 8 A8 F A 09 2F 3D
32 F83 D9 895 BA 53B E7 54D E8 8A8 9F BA 809 32F 83D 98
F 8 B 5 5 8 B 8 3 9
2F 83DD98 95B A5 3BE E75 4DE E88 A89 9FB A8 093 2F8 83D 989 5BA
83 98 95 A 3B 75 4D 88 A8 FB A8 093 2F 3D 98 5B 5
72533
83 D98 95 BA 53B E75 4D E88 A8 9FB A8 093 2F 83D 98 95B A5 3BE
D B 5 8 9 3
3D 989 95B A5 3BE E754 4DE E88AA89 9FB A80 0932 2F8 3D9 989 5BAA53 BE7 754
9 5 A 3 B 7 D 8 F A 9 F 3 8 5 B 5 B D
D9 895 BA 53 E7 54D E8 8A 89F BA 809 32F 83 D98 95 A5 3B E75 54D E88
i)
m3/h,
5B 5 BE 75 DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F
ii)
iii)
54 E 8A 89F BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F
flow reactor
= -350 kJ/kg
DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83
two methods.
atm
BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F 3D 98 5B A5
find XA, CB, and XB
N2O4 (g) ⇌ 2 NO2 (g)

93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83 9 95 A 3B E7
2F 3D 98 5B 5 BE 75 DE 88 89 B 8 93 F8 D 89 BA 53 E 54
83 98 95 A 3B 75 4D 88 A8 FB A8 093 2F 3D 98 5B 5 BE 75 DE
D9 95 BA 53 E7 4D E8 A 9F A 09 2F 83 98 95 A5 3B 75 4D 88
5B 5 BE 75 DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F
AR , First order reaction.

of N2O4 is dissociated , calculate

54 E 8A 89F BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F
DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83
Equilibrium constant Kp
BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F 3D 98 5B A5
required to saponify 95 % of ester at 400C
N2O4 in 10 litres vessel at 270C

93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83 9 95 A 3B E7
Page 2 of 2
2F 3D 98 5B 5 BE 75 DE 88 89 B 8 93 F8 D 89 BA 53 E 54
83 98 95 A 3B 75 4D 88 A8 FB A8 093 2F 3D 98 5B 5 BE 75 DE
D9 95 BA 53 E7 4D E8 A 9F A 09 2F 83 98 95 A5 3B 75 4D 88
5B 5 BE 75 DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F
____________________
54 E 8A 89F BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F
DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83
88A89FBA80932F83D9895BA53BE754DE
BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F 3D 98 5B A5
93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83 9 95 A 3B E7
2F 3D 98 5B 5 BE 75 DE 88 89 B 8 93 F8 D 89 BA 53 E 54
83 98 95 A 3B 75 4D 88 A8 FB A8 093 2F 3D 98 5B 5 BE 75 DE
D9 95 BA 53 E7 4D E8 A 9F A 09 2F 83 98 95 A5 3B 75 4D 88
5B 5 BE 75 DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F
54 E 8A 89F BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F
DE 88 89 B 80 93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 8
and temperature of the reaction mixture if the reactor is operated adiabatically.
88 A89 FB A8 93 2F8 3D 989 5BA 53 BE 754 DE 88A 89 BA 80 932 F83

Paper / Subject Code: 31704 / Chemical Reaction Engineering - I (CRE-I)
A8 FB A8 09 2F 3D 98 5B 5 BE 75 DE 88 89 FB 8 93 F8
9F A 09 32F 83D 98 95B A5 3B 75 4D 88 A8 FB A8 093 2F8 3D
BA 80 32 83 9 95 A 3B E7 4D E8 A8 9F A 09 2F 3D 9
The initial concentration of ethyl acetate is 5 g/l and that of caustic is 0.1 normal.
(c) what is the percentage difference in rate of reaction at 600 K predicted by these
What will be the degree of dissociation when we start with 73.6 g of

Heat capacity of reactants and products =1.95 kJ/kg.K, Volumetric flow rate = 0.33
activation energy for this reaction (a) from Arrhenius law (b) from collision theory
Feed Temperature = 200C, conversion expected = 95 %, Calculate the reactor size

Rate constant at 1650C =0.7 h-1, Activation energy =120000 J/mol, Heat of reaction
stream leaves the reactor at T = 400 K, P = 4 atm. For C A at the reactor exit =20 ,
(l/mol) (min)-1 respectively. The reaction is irreversible . Calculate the time
Percent dissociation of N2O4 at 27 0C when total pressure becomes 0.2

The values of second order rate constant at 00C and 20 0C are k= 0.235 and 0.924
a flow reactor in which the gas phase reaction A+ B  5R occurs. The Product
80 932 F83 D9 895 BA 53B E7 54D E8 8A8 9F BA 809 32F 83D 98

93 F8 D 89 BA 53 E 54 E 8A 9F BA 80 32 83 9
2F 3D 98 5B 5 BE 75 DE 88 89 B 8 93 F8 D 89
83 98 95 A 3B 75 4D 88 A8 FB A8 093 2F 3D 98
(b) N2O4 gas dissociates according to the following reaction at 270C and 1 atm , 20 % 10
(a) An irreversible isomerisation reaction is carried out in the liquid phase in a mixed 10
(b) At 500 K the rate of a biomolecular reaction is ten times the rate at 400 K. Find the 08
(a) An aqueous solution of ethyl acetate is to be saponified with sodium hydroxide. 12
(b) Consider a gaseous feed at T0 = 1000 K, P0 = 5 atm, CA0= 100 , CB0= 200 entering 08
D9 95 BA 53 E7 4D E8 A 9F A 09 2F 83 98 95
89 BA 53 BE 54 E 8A 89F BA 80 32 83 D9 95 B
5B 5 BE 75 DE 88 89 B 80 93 F8 D 89 BA
A5 3B 75 4D 88 A8 FB A8 93 2F8 3D 989 5B
3B E75 4D E8 A8 9FB A8 09 2F 3D 98 5B A5
E7 4D E8 8A 9F A 09 32F 83D 98 95B A5
54 E 8A 89F BA 80 32 83 9 95 A 3
DE 88 89 B 80 93 F8 D 89 BA 53
88 A89 FB A8 93 2F8 3D 989 5BA 53 B
A8 FB A8 09 2F 3D 98 5B 5 BE
9F A 09 32F 83 98 95 A5 3B 7

(3 Hours) (Total Marks: 80) N.B.: 1) Question No.1 Is Compulsory

Загружено:

Сведения о документе

Исходное описание:

Оригинальное название

Авторское право

Доступные форматы

Поделиться этим документом

Поделиться или встроить документ

Параметры публикации

Этот документ был вам полезен?

Это неприемлемый материал?

Авторское право:

Доступные форматы

(3 Hours) (Total Marks: 80) N.B.: 1) Question No.1 Is Compulsory

Загружено:

Авторское право:

Доступные форматы

8 D E

that set up.

for first order reaction.

(d) Short note on Recycle Reactor.

first order with k= 3.07 s-1 at 1100 K

Plug flow and ii) mixed flow

(a) Consider the competitive liquid phase reactions :

= 1.0 𝐶𝐴 𝐶𝐵 0.3 mol/l/min

stream for XA = 0.90, if the flow pattern in the reactor is

E7 4D E8 8A 9F A 09 32F 83D 98 95B A5 3B 75 4D 88 A8 FB A8 93

results in 96 % conversion of A. If a mixed flow reactor ten times as large as the

stream has concentration of 20 mol/l. Find the concentration of R in the product

N2O4 (g) ⇌ 2 NO2 (g)

AR , First order reaction.

of N2O4 is dissociated , calculate

N2O4 in 10 litres vessel at 270C

88 A89 FB A8 93 2F8 3D 989 5BA 53 BE 754 DE 88A 89 BA 80 932 F83

What will be the degree of dissociation when we start with 73.6 g of

Feed Temperature = 200C, conversion expected = 95 %, Calculate the reactor size

(l/mol) (min)-1 respectively. The reaction is irreversible . Calculate the time

Percent dissociation of N2O4 at 27 0C when total pressure becomes 0.2

80 932 F83 D9 895 BA 53B E7 54D E8 8A8 9F BA 809 32F 83D 98

Вам также может понравиться