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3/1
Check that this booklet contains pages 2-29 in the correct order and none of these pages is blank.
Page 30 has been left blank deliberately.
YOU MUST HAND THIS BOOKLET TO THE SUPERVISOR AT THE END OF THE
EXAMINATION.
SECTION A
(40 marks)
Answer all the questions in this section. Write the LETTERS of the best answers in the
boxes on the fold-out flap provided on the back flap of this booklet. Each question is worth 2
marks.
17
1. The atoms of the isotope of oxygen denoted by 8 O have the composition denoted by which
2. Which of the species listed below does not have the electron configuration (main energy
levels) 2, 8, 8?
A. Ar
B. Al3+
C. Cl-
D. Ca2+
6. Given the following data: cH°(CH3OH(l)) = -715 kJmol-1 and M(CH3OH(l)) = 32 g/mol
calculate the maximum possible energy released when three moles of the sample methanol are
completely combusted.
A. 1072.5 kJ
B. 2145 kJ
C. 4290 kJ
D. 6435 kJ
A. 1
B. 3
C. 5
D. 6
A. 0.05
B. 0.1
C. 0.2
D. 0.4
4
10. An aqueous solution containing ONE of the following salts is acidified with a little dilute
nitric acid. When a few drops of barium nitrate solution are added a white precipitate forms.
The original solution contains
A. barium nitrate.
B. barium chlorine.
C. barium sulphate.
D. barium carbonate.
From the key list below, select the compound that best fits the properties given in questions 11
and 12.
KEY LIST
A. Iodine B. Silicon dioxide C. Sodium chloride D. Potassium iodide
A. NaCl
B. SO2
C. Al2O3
D. PCl3
15. The systematic name for the molecule with the following structure is
A. pentanal.
B. pentan-2-ol.
C. pentan-2-one.
D. methyl pent-2-ene.
5
16. When a mixture of ethanol, ethanoic acid and sulphuric acid is warmed in a test tube
17. Which of the following statements is correct when applied to the reaction between
magnesium metal and dilute hydrochloric acid?
18. The fastest reaction between marble (CaCO3(s)) and hydrochloric acid (HCl(aq)) would take
place between
19. If the pH of a sodium hydroxide solution is 10, then the concentration of hydroxide ions,
[OH-] will be
A. 10-2 molL-1.
B. 10-4 molL-1.
C. 10-5 molL-1.
D. 10-10 molL-1.
SECTION B
(160 marks)
If you are unable to calculate a value for a question and need that value in a later question,
select a convenient value and use where needed.
(i) P (1 mark)
(ii) Zn (1 mark)
(iii) Xe (1 mark)
2. The term ‘Ionisation Energy’ refers to the energy required to remove an electron from an
atom.
(i) Explain why ionization energy tends to increase from Group I to Group VIII.
(2 marks)
(1 mark)
(iii) Explain why isotopes of the same element show the same chemical properties.
(2 marks)
7
Element Na Mg Al Si P S Cl
Electronegativity 0.9 1.2 1.5 1.8 2.1 2.5 3.0
Chloride NaCl MgCl2 Al2Cl6 SiCl4 PCl3 SCl2 Cl2
Melting point of
801 712 190 -68 -111 -80 -101
chloride (°°C)
(i) Give TWO trends that can be determined from the table above.
(2 marks)
(ii) Explain why the melting point of sodium chloride is much higher than that of
phosphorus trichloride.
(2 marks)
(iii) Predict the bond types of magnesium chloride and sulphur dichloride and give
reasons for your choice.
magnesium chloride
Reason
(2 marks)
sulphur dichloride
Reason
(2 marks)
8
B. 1. Complete the table, filling in the blanks with the appropriate item(s) from the list
provided below.
(ii)
diamond macromolecular
(iii) (iv)
carbon dioxide
(v)
ionic ionic lattice
(5 marks)
9
2. Sketch and complete this graph of atomic radii of the alkali metals to show the general
trend of this property down a group of the periodic table.
(2 marks)
3. (i) Describe a test of a physical property which could show a solid to be a metal.
(1 mark)
(1 mark)
p. 6-9
25
10
A 2.50 g sample of the hydrated salt was heated to constant mass. This constant mass
was 1.60 g.
(1 mark)
(1 mark)
(iii) Calculate the mass of water and hence the number of moles of water lost in the
reaction.
(2 marks)
(2 marks)
11
(2 marks)
(2 marks)
3. The reaction between magnesium carbonate and dilute hydrochloric acid is represented
by the equation:
(2 marks)
(ii) Calculate the number of molecules of carbon dioxide in 0.2 mole of CO2.
(2 marks)
(iii) Calculate the mass of magnesium carbonate that will be needed to produce 8.8 g of
CO2.
__________________________________________________________ (2 marks)
12
B. 1. A 2.65 g of anhydrous sodium carbonate was dissolved in water and made up to 500 mL
in a standard (graduated) flask. 20 mL portions of this required 18.5 mL of a solution of
hydrochloric acid when titrated using methyl orange indicator.
(i) Calculate the concentration of the standard sodium carbonate solution in molL-1.
M(Na) = 23 g/mol M(C) = 12 g/mol M(O) = 16 g/mol
(2 marks)
(2 marks)
(iii) Calculate the number of moles of hydrogen chloride gas which would be present
in 250 mL of this solution.
(2 marks)
(2 marks)
13
(2 marks)
(2 marks)
p. 10-13
28
14
(i) CH3C(CH3)2CH2CH2CH3
(ii) CH3CCl(CH3)CH3
(iii) CH3CH2CCH
(iv) CH3CH2CH2OH
(v) CH3CHOCH3
(vi) CH3CH2CH(CH3)CHO
(6 marks)
(1 mark)
(ii) branched chain hydrocarbons
(1 mark)
(1 mark)
(iv) polymerisation
(1 mark)
15
3. Siaki was given two labeled gas cylinders, A and B. It was known that one cylinder
contained propane and the other contained acetylene. In order to identify them, Siaki
carried out a test with each of the gases. A sample of each gas in turn was bubbled
through separate solutions of bromine.
Br2
A B
propane acetylene
(1 mark)
(ii) Gas from cylinder B bubbled in Br2 solution:
(1 mark)
(iii) Write the equation for the reaction which occurred for gas from cylinder B.
(2 marks)
4. Many chloroalkanes are used as monomers in the plastic industry. List any TWO
monomers.
(i)
(ii)
(2 marks)
16
B. Soap making involves the alkaline hydrolysis of triesters of glycerol. Complete the following
hydrolysis and name the two products formed.
(i) (1 mark)
(ii) (1 mark)
(iii) (1 mark)
(iv) (1 mark)
p. 14-16
20
17
A. 1. Complete the diagram below by writing the correct names for the parts labeled (i)-(iii).
(i) (1 mark)
(ii) (1 mark)
(iii) (1 mark)
(1 mark)
(1 mark)
(iii) Why is there no similar impurity during the production of propanone from
propan-2-ol?
(1 mark)
18
B. Carbohydrates are naturally occurring organic compounds including glucose which is the
building unit for cellulose and starch. Glucose exists in two forms, cyclic form and an open
chain form as shown in the diagram below.
(1 mark)
(ii) When functional group X reacts with Fehling’s solution does it undergo
substitution, addition, oxidation, reduction, hydrolysis or elimination?
(1 mark)
(1 mark)
(iv) What is the colour of the precipitate that is formed in the reaction in (ii)?
(1 mark)
19
(1 mark)
(1 mark)
(1 mark)
(1 mark)
D. The carboxylic acids used to make triacylglycerols, the fatty acids, generally have just one
carboxyl group on an unbranched chain of an even number of carbons.
(2 marks)
(ii) Give any difference between vegetable oils and animal fat.
(1 mark)
(1 mark)
(iv) List any TWO common fatty acids.
(1 mark)
(1 mark)
p. 17-19
20
20
A. 1. The following table summarises the reactions of a number of pairs of solutions. Several
spaces have been filled with descriptions of what happens when the solutions are mixed.
Fill in the missing descriptions (i)-(iv).
(ii)
a white precipitate of
barium chloride no reaction
barium carbonate
(iii) (iv)
(4 marks)
2. (i) When sodium oxide, Na2O is added to water, the solution turns litmus blue. Write
the equation for the reaction of sodium oxide with water.
___________________________________________________________ (1 mark)
(ii) Sulphur dioxide, SO2 when added to water, forms a solution which turns litmus red.
Describe this result using your knowledge of the properties of row three oxides.
____________________________________________________________________
____________________________________________________________________
(2 marks)
21
B. 1. The equilibrium between nitrogen dioxide and dinitrogen tetroxide is represented by:
Some of the equilibrium mixture is put into a syringe as shown in the diagram below.
(i) What would be the effect on the number of molecules of nitrogen dioxide if the
plunger was pushed into the 30 mL mark while the temperature was kept constant?
(2 marks)
(ii) List TWO observations that would be made when the syringe is placed in iced water
to cool it down.
Observation 1: __________________________________________________________
__________________________________________________________
Observation 2: __________________________________________________________
__________________________________________________________
(4 marks)
22
2. The reaction PCl3(g) + Cl2(g) ⇌ PCl5(g) is exothermic at 25°C. Giving brief reasons,
state the effect of the following changes on the equilibrium amount (number of moles) of
PCl5(g) in a closed container.
(2 marks)
(ii) The temperature is increased.
(2 marks)
(iii) The pressure is increased by decreasing the volume at constant temperature.
(2 marks)
(1 mark)
(1 mark)
p. 20-22
21
23
(1 mark)
2. Place the following compounds of manganese in order of increasing oxidation number for
manganese.
(1 mark)
(1 mark)
(1 mark)
(1 mark)
24
____________________________________________________ (1 mark)
___________________________________________________ (1 mark)
(iii) Combine your answers from (i) and (ii) into a fully balanced oxidation-reduction
equation.
___________________________________________________________________
___________________________________________________________________
(2 marks)
Use the list given below to answer question 5.
[NOTE: You may use any member of this list more than once.]
_________________________________________ (1 mark)
________________________________________ (1 mark)
________________________________________ (1 mark)
________________________________________ (1 mark)
25
B. 1. Use the schematic diagram below of a cell membrane which is used for the electrolysis of
concentrated sodium chloride solution to answer questions (i)-(vi).
_____________________________________________________ (1 mark)
_____________________________________________________ (1 mark)
____________________________________________________ (1 mark)
____________________________________________________ (1 mark)
____________________________________________________ (1 mark)
26
(1 mark)
(1 mark)
(ii) rusting
(1 mark)
(iii) corrosion
(1 mark)
(iv) alloy
(1 mark)
p. 23-26
25
27
(i) Represent the information from the above diagram as a balanced equation. Include
the enthalpy change term (H) with the appropriate sign.
(2 marks)
(ii) What does AB represent in the above diagram?
(1 mark)
2. Erica wishes to calculate the heat change for the following reaction:
(i) Give THREE types of measurements that Erica must make during the experiment
and their typical units.
1. (1 mark)
2. (1 mark)
3. (1 mark)
(ii) H for this reaction is -98.8 kJmol-1. Is this reaction exothermic or endothermic?
(1 mark)
28
3. Calculate the standard enthalpy of the reaction of acetylene (C2H2) from its elements:
________________________________________________________________________
(3 marks)
(1 mark)
2. For this amount of ethanol, calculate H, the enthalpy of reaction.
(1 mark)
29
(1 mark)
3. Equations (1) and (2) show aluminium hydroxide acting as a base and as an acid. State the
term used to describe this property.
(1 mark)
p. 27-29
21
30
Student Personal
SECTION A Identification Number
ANSWER SHEET
1. 11.
SECTION B
2. 12. (Markers Only)
Q21
3. 13. 25
4. 14.
Q22
28
5. 15. Q23 20
6. 16. Q24
20
7. 17.
Q25 21
8. 18.
Q26
25
9. 19.
Q27
21
10. 20.
For SECTION A
Number + =
Correct X 2
40 160 200