FT/GN/61/04/18.03.

16
Date: 31-07-18
DEPARTMENT : CHEMICAL ENGINEERING
Academic Year: 2018 - 2019
UG /PG: B Tech Specialisation(for PG): N/A
Sub Code: CH16502 Sub Name :CHEMICAL ENGINEERING THERMODYNAMICS II MARKS: 40
Student Branch: CH Semester : V ASSIGNMENT :I /II/ III

Instructions: Students are asked to adhere to following:

1. Assignment should be hand written
2. Submit with a cover sheet in a presentable form
3. On the Cover Sheet fill Name, University Register Number, Semester and Date of Submission.
4. Date of Submission: 31st July, 2018

Rubrics for Marking and Assignment – I Details are as given below

Content 30
ASSIGNMENT-I
Timely submission 5
Presentation 5

Student Roll
Number Allotted Assignment
Sec A Sec B
Consider any binary mixture namely ethanol-water system and explain
the partial
1-6 59-64 molar property of each, total molar property and pure component molar
65-
7-12 69,81 How does the activity coefficient vary with respect to pressure and
temperature
14-18, 70-
21 74,84 Apply tangent-intercept method for a binary solution
20,22,2 75-
3,25,27 80,82,
, 29 85 Derive an expression for excess molar volume
24,30,3 83,86,87
2,33, , Prove that all property changes of mixing are zero for ideal solution
34,40 90,91,92
26, 35- Relate chemical potential to enthalpy, entropy and Helmholtz free
39 93-98 energy
31,42,4 99-
3,45,46 104,106 Derive an expression for excess molar enthalpy
,48
44,49,5 105,107 Prove that the rate of change of chemical potential with pressure is
0,52,53 -110 equal to partial
,54 molar of the solution
The enthalpy of binary liquid mixture containing components 1 and 2
51,56,5 111,113, at 298K and 1
7,301,3 114,307, bar is given by H = 400x1 + 600x2 + x1x2(40x1 + 4x2)
02,303 308,309 where H is in J/mol. Determine a) Pure component enthalpies and b)
Partial molar enthalpies
55,58, Calculate the concentration of nitrogen in water exposed to air at 298 K
303,30 and 1 bar if Henry’s law constant for nitrogen in water is 8.68 x 104 bar
5, 112,115, at this temperature. Express the results in moles of nitrogen in per kg of
306 310-313 water (Air is 79 percent nitrogen by volume)
Prepared By
Ms G Thayanidhi, Asst. Professor / CH
Ms S Swathi, Asst.Professor / CH