JEE MAINS MODEL PRACTICE TEST

JR. PART TEST-I

(KEY SHEET)

PHYSICS

01) 3 02) 2 03) 4 04) 2 05) 3

06) 4 07) 1 08) 4 09) 4 10) 1

11) 1 12) 2 13) 1 14) 2 15) 1

16) 2 17) 2 18) 4 19) 3 20) 2

21) 1 22) 3 23) 4 24) 2 25) 2

CHEMISTRY

26) 1 27) 3 28) 2 29) 2 30) 3

31) 3 32) 1 33) 3 34) 3 35) 4

36) 2 37) 4 38) 2 39) 4 40) 3

41) 2 42) 4 43) 4 44) 4 45) 3

46) 3 47) 2 48) 3 49) 3 50) 4

MATHEMATICS

51) 1 52) 2 53) 2 54) 1 55) 3

56) 3 57) 4 58) 1 59) 3 60) 4

61) 2 62) 4 63) 3 64) 4 65) 4

66) 1 67) 2 68) 4 69) 4 70) 3

71) 3 72) 2 73) 1 74) 1 75) 3

PHYSICS HINTS & SOLUTIONS

01. Hint: After freely falling through 50m it acquires a velocity v  2  9.8  50

Since, v 2  u 2  2as

 (3)2  (2  9.8  50)  2  2  S

and H  50  S .
02. Hint: y  Ax  Bx 2 T 2 T
After sec , Y  A cos   
12  T 12 
g
A  tan  , B  .
2u cos2 
2
3A
 Y
From the given equation 2

u  ucos i  u sin j 3A
From mean position displacement  A  .
u cos   1 , u sin   2 . 2
 vx
03. Hint: v B  v x i  v y j B 13. Hint: a   w 2 y
 Magnitude of acceleration is
v  2i  3j vy
4 2  2 T 
2u sin  2ucos  a 2
 A sin    .
04. Hint: t1  , t2  T  T 8
g g
m
and t1t2  R . 14. Hint: TA  2
k
05. Hint: m(g  a)  Mg
k1k 2
20(g  a)  250 . In case of B, k ef 
k1  k 2
dp
06. Hint: F   F  2m sin  k 1  4k , k 2  k
dt

(2m sin )n 4k  k m

Pressure  . k eff  ; T2  2 .
A 5k  4k 
 
 5 
07. Hint: t rough  nt smooth
a
2 2 15. Hint: From the graph tan37 
n x
g(sin    cos  ) g sin  .
3 a x
08. Hint: T.E. at Orbit = T.E on the Earth   .  T  2 .
4 x a
GMm 1 Ve2 GMm 1
 m   mv 2 dw
R 2 3 R 2 16. Hint: Angular acceleration  
dt
1 2GM 1
 m  mv 2 w2 3
2 3R 2  dw   dt
w1 0
2gR 2 2gR
  v2  v  . 3
3R 3
 w 2  w1   ( 10  5t)dt .
0
09. Hint: Work done  KE  PE
17. Hint: At the height point v  u cos 
PE
 10  4  PE .  Potential  .
M M M
 Mv cos    v cos   v 1 .
2 2
GMmx
10. Hint: F   x  8R .
(R 2  x 2 )3/2 2 L
18. Hint: I  mR 2 ; R 
3 2
dv
11. Hint: E   dv  E  dr m
dr Since,    m   .

  dv    Edr .
2 L2
12. Hint: Displacement after starting from rest is  I   2 .
3 4
Y  A coswt
 1 3
CHEMISTRY HINTS & SOLUTIONS
19. Hint: Power P  Av
2 26. Sol. The work done on the gas can be
calculated from P, V graph. Work done is
3
P1  v  equal to the area ABVi Vf .
   v .  P   2v  .
3

2  
27. Sol: 1) Zn  2HC  ZnC 2  H2
Power output 1 mole of Zn produces 2 g of H2
20. Hint:   Power input
0.5 mole of Zn will produce 1 g of H2
2) C70H22
 10000  10  180 
80  60  60

. Molar mass  862
 
100 Pi
Mass of atoms  862 / 6.023  1023  1.43  1021 g
21. Hint: Acceleration of system
3) 71 g of C 2  6.023  1023 molecules
unbalanced mass
a g
total mass 35.5 g of C 2  3.01  1023 molecules
 Mg sin53  Mg sin37  4) Molar mass of SO2  64  1 mole
 g .
 2M 
64g of SO2  6.023  1023 molecules .
4A 28. Conceptual/Basic Question.
22. Hint: Average speed V 
T
29. Sol: Z  12 , 1s2 2s2 2p6 3s2 (n  3) ; Z  17 ,
 Vmax  A
1s2 2s2 2p6 3s2 3p5 (n  3) .
A  2 A V
 Vmax    max . 30. Conceptual/Basic Question.
T T 2
31. Sol. For free expansion (i.e., in vacuum),
23. Hint: A 1  10 m , A 2  4 m , A 3  7 m
Pext  0 . Thus, W  Pex V  0
Phase angle between A 1 & A 3 is 180°
For adiabatic change, q  0
 A1  10  4  3 m
 U  q  W  0 which is true for isothermal
Between A 1 & A 2 is 90°
process where T is constant i.e, T  0 .
 A 2  32  42  5 m .
32. Sol: 2Mg  O2   2MgO
2  24 2  16 2(24  16)
2S 3S
5 5 48 g of Mg requires 32 g of O2
24. Hint:
V1 V2 32
1 g of Mg requires  0.66 g of O2
48
Oxygen available = 0.5 g
total displacement
Vavs  Hence, O2 is limiting reagent
total time
Since, T  t1  t 2 32 g of O 2 reacts with 48 g of Mg

2S 3S 48
T  0.5 g of O2 will react with  0.5  0.75 g of
5V1 5V2 . 32
Mg.
25. Hint: Angular momentum  mvr
Excess of Mg  (1.0  0.75)  0.25 g .
L  5  3 2[A sin ]
From the equation y  x  4 33. Sol. Increasing size of hydrated ion
Cs  Rb  K   Na   Li .
tan   1 & Amplitude  4
  45 .  L  5  3 2  4 sin45 . 34. Sol. 2A  2NaOH  2H2O 

 2NaAO2  3H2

Sn  2NaOH  H2O   Na 2SnO3  2H2
 
Zn  2NaOH   Na 2 ZnO2  H2 . 45. Sol: Probability of finding 1s electron is
maximum near the nucleus and goes on
35. Sol. (1): CH4( g )  2O2( g )  CO2( g )  2H2O shows increasing till it reaches a maximum value at
combustion reaction a distance 52.9 pm and then begins to
decrease abruptly. Even at large distance from
(2): H2( g )  2H( g ) shows bond dissociation. the nucleus, there is a finite though small
probability of finding an electron of a given
(3): NaC ( s)  Na (g )  C ( g ) energy.
shows dissociation of NaC NUMERICAL VALUE QUESTIONS
(4): NaC ( s)  Na 
(aq)  C 
( aq )
46. Sol. Strength of the solution = 34 g/L

shows dissolution of NaC . 1 L of the solution contains 34 g of H2O 2

36. Sol: ‘a’ represents covalent radius which is 200 mL of the solution contains
the distance between the nuclei of two 34
bonded atoms. ‘b’ represents vander Waals’  200  6.8 g of H2O 2
1000
radius which is the distance between nuclei
of two closest molecules. 2H2O2  2H2O  O2
37. Conceptual/Basic Question. 2  34g 32g
38. Sol: On moving down the group, the stability
of –3 oxidation state decreases. This is due 68 g of H2O 2 gives 32 g of O2
to the following reasons:
32
(i) On descending a group the size of the atom 6.8 g of H2O 2 gives   6.8  3.2 g of O2.
or ion increases. As a result, attraction of the 68
nucleus per newly added electron decreases. 47. Conceptual/Basic Question.
(ii) A large anion cannot fit easily into lattice 48. Sol: 2.5  1.25  3.125
of a small cation.
Since 2.5 has two significant figures, the result
(iii) As the negative charge on the ion should not have more than two significant
increases, it becomes more and more figures. Hence, the answer will be 3.1.
susceptible to polarisation.
39. Sol. H2  50 volumes , CO  40 volumes , r0  n2
49. Sol: Radius of nth orbit is given by rn 
Z
N2 and CO2  5 volumes etc .
40. Sol: There is more repulsion for the incoming r0 0.53 o
For 3 Li2 , r    0.176 A .
electron when the size of atom is smaller. 3 3
41. Conceptual/Basic Question.
50. Sol. Cgraphite  Cdiamond
42. Sol. Na 2O2  2H2O  2NaOH  H2O2 ; 391.25 kJ 393.12 kJ
(W)
Hcombustion
2KO2  2H2O  2KOH  H2O2  O2 ;
H  393.12  ( 391.25)  1.87 kJ .
(X) (Y)

Na 2O  CO2  Na 2CO3 .
(Z) MATHEMATICS HINTS & SOLUTIONS
43. Conceptual/Basic Question. i  j, i  j
51. Sol: a ij  
44. Sol: 2NaC  MnO2  3H2SO4  2NaHSO4  i  j, i  j
2 moles MnSO4  C 2  2H2O  a 11  0 , a12  3 , a 22  0
(2  58.5  117 g) 1 mole
22.4 L (STP) 0 3 
A   A  9
3 0 
117 g of NaC  22.4 L of C 2
T
22.4  0 3   0 3 
50 g of NaC   50  9.57 L of C 2 at STP.. adj( A )     
117  3 0   3 0 
 Substituting the value of  in equation (i) then
1 1  0 3   0 1 / 3   
A    . point of intersection is r  4c .
9  3 0  1 / 3 0 
52. Sol:  a, b, c, d are in A.P.. 54. Sol: We have, AC  16  1  1  3 2 and
 b  a   , c  a  2 , d  a  3  BD  0  9  9  3 2
x a x b x a c Direction of AC are (4, 1,  1) and direction
(x )  x  b x  c x 1 ratios of BD are (0, 3, 3)
x c x d x bd If the acute angle between AC and BD is '  ' ,
033
Applying R 2  R 2  R1 and R 3  R 3  R1 then cos    0  sin   1
3 2 3 2
x a x b x a c  Area of the quadrilateral to
 (x )    1  2 1
 3 2  3 2.1  9 sq.units .
2 2 4 2
55. Sol: 3  3 cos   3
Again, applying C2  C2  C1 and
 3  3 cos   3  1  2  3cos   5
C3  C3  C1
For 1  2  3cos   0  1  f(  )  
xa    c
1
 For 0  2  3cos   5  f(  ) 
5
 (x )   0 1  
 1 
Thus range of f(  ) is, ( ,  1]   ,   .
2 0 2 5 

56. Sol: [cot1 x]  [cos1 x]  0

2 2 2
 (2  2  2 )  2
 [cot1 x]  0 , [cos1 x]  0
2 2
2
  (x)dx  16   2 dx  16
0
as cos1 x  0 and cot1 x  0
0

2 2
Now, [cot 1 x]  0  x  (cot1,  ) ,
 4   16    4
   2 . and [cos1 x]  0  x  (cos1, 1]
53. Sol: Equation of line joining  x  (cot1, 1] .

6a  4b   5c and 4c is

       57. Sol: A   2R  a
r  (6a  4b  5c)  ( 6a  4b  c) 2
   A
 a(6  6 )  b( 4  4 )  c( 5   ) ––––– (i) Also, r  (s  a)tan
   2
and equation of line joining a  2b  3c and
   1
a  2b  5c is  (s  a)  (b  c  a)
2
      
 r( a  2b  3c)  (2a  4b  2c) 1
    r  2R  (a  b  c) .
 a( 1  2 )  b( 2  4 )  c( 3  2 ) ––––– (ii) 2

Comparing equations (i) and (ii), then 58. Sol: arc( AC)  3 , arc( AB)  4 , arc(BC)  5
6  6  1  2 Let radius of the circle be ‘r’
4  4  2  4 and 5    3  2 3 4 5
 r  3    , ,
r r r
1
After solving, we get   1 and  
2 Now, 3  4  5  2r  r  6  1  
 r 6
 ABC  OCA  OAB  OBC  a  c  10  sinA : sinC  1 :1 .
A 
AC OA 1 9  4
60. Sol: CB    9  1  4  1
OB
17
 c is the mid-point of A and B
15

r O
r C
D
B 19
(i  3j  2k)
 (3i  j  2k)


1  3 4  5 
 r 2  sin    sin    sin   
2  r r  r 
A C B
1 36   2  
  2  sin  sin  sin 
2   2 3 6   
 OA  OB
 OC   2i  2j  2k .
18  3 1  9 3(1  3 ) 2
 1 
2 
  .
  2 2  2  
a b
   2
59. Sol: Let linear function is F(x )  Ax  B 61. Sol: Projection of a on b is b

 [1, 2]  [4, 6]
     
Required projection  (i  2j  3k)  (i  2j  2k)
 F(1)  4  A  B  4 1 4  4

and F(2)  6  2A  B  6 1 4  6
  3 .
 A 2, B2 3
Then, one function is 62. Sol:  f(x ) is continuous function and sinx
F(x )  2x  2  f(x ) (say)
and cos x are always positive.
F(1)  6  A  B  6 Hence, f(x) is minimum when sin x  0 and
A  2, B  8
F(2)  4  2A  B  4
cos x  1
then other function is F(x )  2x  8  g(x )  Minimum value  0  3  3 and f(x) is
(say)
maximum when sinx  1 and cosx  0
 c  f(1)  g(1)  4  6  10
 Maximum value  2  0  2
Now, x 2  y 2  xy  10  Required range  [3, 2] .

 y
2 63. Sol: 27cos x  81sin x
x   y2
2
  2
1  3 3cosx  3 4 sin x  2  3 3cosx  34 sin x
( 10 )2  10 
  1 ( 3cosx  4 sin x )  25 2
 3   2  32  23  .
9 3
is an ellipse whose centre (0, 0).
64. Sol: 1  sin   3 cos 
Maximum distance from origin on any point
on ellipse = Semi major axis  10   1
or 3 cos   sin   1 or cos     
 6 2
 r  10

Then, a  r2  10  
or    2n 
6 3
 or   2n 

, 2n  
67. Sol: x 1  sin2 , x x
1 2  cos2 ,
6 2
x x x1 2 3  cos  , and x 1x 2 x 3 x 4   sin 
 When   2n   there are solutions for  tan1 x1  tan1 x 2  tan1 x 3  tan1 x 4
6
   x1   x1x 2 x 3 
n  0, 1 and when   2n  , for n  1 . But  tan1  
2  1   x1x 2  x1x 2 x 3 x 4 
this value does not satisfy the given equation.
65. Sol:  [y]  [sin x]  1, 0, 1  sin2  cos  
 tan 1  
( 1  sinx  1 )  1  cos2  sin  

 [y]  1  cos (2sin   1) 

 tan 1  1
  tan cot 
 1  y  0  [sin x]  1, 0, 1  sin (2sin   1) 
[sinx]  1  1  sinx  0   
 tan1 tan        .
Then, x  {(2n  1), (2n  2)} , n  I and 2  2
[y]  0  0  y  1 2 2 2 2
68. Sol: cosec x  25sec x  26  cot x  25 tan x
[sin x]  0  26  10  (cot x  5tan x )2  36 .
0  sin x  1
  
  a  2k  2j  i
69. Sol: We must have (i  3j  5k)

Then, x  [2n, (2n  1)  2n   , n  I and 3
 2
 3a  3(i  3j  5k)
  (2k  2j  i)
[y]  1 , sin x  1
 i(3  1)  j(2  9 )  k(15
   2)

x  2n 
2  3 a  (3  1)2  (2  9 )2  (15  2)2
1 y  2
 9  (3  1)2  (2  9 )2  (15  2)2
y
2
2  315 2  18  0    0 , 35
1
For   0 , a  i  2j  2k (not acceptable)
3 / 2
 / 2
x' x 2  41  88  40 
2  3  / 2  0 /2
2 /2 For   , a i j k.
35 105 105 105
y  cosx [y]  [sin x] 70. Sol: Using (x  4)  2 x  5
y'
 (x  5)  1  2( x  5 )  1  ( x  5  1)2
Hence, [y]  [sin x] and y  cosx intersect
infinite points. f(x )  (x  5)  1  (x  5)  1
Hence, number of solutions = infinite.
66. Sol: 0  cos1 i    cos1 i is non-negative x  5.
NUMERICAL VALUE QUESTIONS:
n
1
  cos 1
i  0  cos i  0 , 71. Sol: Let vertices are A, B, C, D and O is origin
i 1  
 OA  i  6j  10k ; OB  i  3j  7k
for i  1, 2, 3, ...,n  
OC  5i  j  k ; OD  7i  4j  7k
  i  cos0  1 for i  1, 2, 3,....,n
  
n  AB  OB  OA  2i  3j  3k
  i  n .   
i1 AC  OC  OA  4i  5j  (   10)k
   
AD  OD  OA  6i  2j  3k 1 1
1 ab 
Volume of tetrahedron a b
1 1
  a 2b2c2 1 bc 
 2 3 3  b c
1 
 
 
 1   1 1
 [AB, AC, AD]  6  4 5   10 1 ca 
6  6 2 3  c a
Applying R1  R1  R 2 , R 2  R 2  R 3 , we get
1
 {2( 15  2  20)  3( 12  6  60)  3(8  30)}
6
c a
1 0 b(a  c)
 {4  10  144  18   66} ac
6 ab
  a 2b2c2 0 c(b  a)
1 ab
 {22  88)  11 (given) 1 1
6 1 ca 
a c
 2  8  6   7.
 (a  c)(a  b) (a  c)(a  b 
 a 2 b2 c 2    0.
72. Sol: A 0 A1  2  1  cos60  1  A 1A 2  a a 
A4 A3 1  2(1  2x) 2 2
75. Sol: Given f(x)  f     ––– (1)
 1 x  x(1  x) x 1  x
A5 O A2
1
Replacing x by , we obtain
(1  x )
A6 A1  
 1   1  2
A 0 A12  A 1A 22  A 0 A 22 1  1  A 0 A 2
2 f   f   2(1  x ) 
cos1200   1 x  1 1  1
1
2A 0 A1  A1A 2 2 11  1 x  1 x

 A 0A2  3  A 0A4  1   1 2
 f   f 1    2x  ––––– (2)
1 x   x  x
 A 0 A1  A 0 A 2  A 0 A 4  1  3  3  3 .
73. Sol: 13cos   12sin   5 Again replacing x by 1  1 in equation. (1), we
x
13 12 5 obtain
or cos   sin  
2 2 2 2
13  12 13  12 13  122
2

 
5 13 1  1  2 2
or cos(    )  , where cos   
313 313 f 1    f   
 x   1  1  1
1
   1   1   1  1  
  x    x   x 
5
   2n  cos1 
313
 1 2x
 f  1    f(x )   2x ––––– (3)
5 13  x x 1
 2n  cos1  cos1
313 313 Subtracting Eq. (2) from Eq. (1), we get
5 13  1 2
As cos1  cos1 f(x)  f  1    2x 
313 313  x 1 x

We get   [0, 2] , when n  0 (one values, Now adding eqs. (3) & (4), we get

taking positive sign) and when n  1 (one 2x 2

2f(x )  
value, taking negative sign) x 1 1 x
74. Sol: Taking ab common from first row, bc x 1
common from second row and ca common  f(x )   f(2)  3 .
from third row, we get x 1

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