Carburetting-resistant coating for steel work piece

Abstract

The present invention relates to a masking paste which can be extensively used for anti-carburizing protection of tool
steel, low-alloy steel and bearing steel products, and its composition is composed of (wt%) 5-25% of anti-carburizer, 10-
35% of loosening agent and 40-85% of adhesive; the anti-carburizer can selectively used copper oxide, the loosening
agent can selectively use glass powder, titanium dioxide and white alundum, etc. and their mixture, and the adhesive
can selectively use water glass, refractory clay and quartz powder and their mixture, and its anti-carburizing effect is
reached to the requirements of standard JB3999-1999.
CN1450195A

Description

Anti-carburizing steel parts paint

The present invention relates to a material clad or coated steel member before or during the heat treatment a temporary
chemical applications, in particular rock drill bit roller cone, palm tooth temporarily applied before or during the
carburization seepage carbon coatings.

Carburizing is a chemical treatment method for steel, mild steel is generally the member on the heating medium
carburizing the activated surface of the steel nascent penetrate, then quenching and tempering, the surface of the steel
member has a very high hardness and strength, while the interior remains the original toughness. In many cases, it is not
necessary for the entire surface of the steel member is carburized, the carburized only its face or bearing surface, it is
necessary to solve the problem of anti-carburizing other surface portions. In the prior art, the method of the anti-
carburizing steel parts are mainly three:-

1) Machining method, plating method and the coating method. Method is to increase the machining allowance of
the work piece, to be carburized layer is removed by machining process, the waste material is present, the
disadvantage of increasing the cost of machining and the like; copper plating is first in the anti-carburizing the work
piece surface copper after carburizing, carburizing prevention its excellent special effects, but the process is
complicated, costly and toxic and pollution of the environment; coating process on the work piece is first coated
with the anti-carburizing surface after carburizing anti-carburizing paint which anti-carburizing effect is very good,
its simple, low cost, and non-polluting; but anti-carburizing paint at home and abroad there are still three major
chronic disease:-
reptiles appeared during carburizing caused by anti-carburizing was extended or reduced, Effect of the furnace
carburizing atmosphere, after carburizing the carbon black paint layer is formed much like a sponge and the like;
anti-carburizing paint abroad more or less the above problems, even the best anti-carburizing paint there is a
problem in which .

Object of the present invention is a steel member needs to social demands coating with anti-carburizing paint anti-
carburizing carburizing process according to the conventional solution coating is present anti-carburizing paint creep at
high temperatures, the influence furnace a steel member having a desired anti-carburizing effect of seepage of excess
carbon black coating after forming spongy three major chronic disease after carburizing and carburizing atmosphere,
there is provided a carburized for 15 to 30 hours at 900 ~ 1000 ℃ a carbon coating, a mixture of inorganic material which
is environmentally friendly, has good manufacturability and workability, and has good economic and social benefits,
which can be widely used in tool steel, bearing steel and low alloy steel member anti-carburizing protection.

Object of the present invention are achieved by the following technical solution:

The present invention is a mixture of inorganic material, the main component of the
carburizing resistance agent, and a binder composed of loose; carburizing agent can be
selected resistance copper oxide; relaxer optional glass frit, titanium dioxide and the like,
and corundum The mixture; optional water glass binder, chamotte and quartz powder, and
mixtures thereof. In the components of the anti-carburizing paint, the amount of resistance
carburizing agent is from 5 to 25% by weight; content of the fluffy agents are 10 to 35% by weight; content of
the binder is 40 to 85% by weight. In the relaxer component, the content of glass frit with respect to the loose agent is 35
to 75% by weight, preferably 40 to 60% by weight; the content of titanium oxide with respect to the loose agent is 15 to
35% by weight, preferably 20 to 30% by weight; content relative to the loose corundum agent is 10 to 30% by weight,
preferably 20 to 30% by weight. In the binder component, the content of the binder with respect to the water glass is 55
to 90% by weight, preferably 65 to 85% by weight; content of the binder relative refractory clay is from 5 to 25% by
weight, preferably 10 to 20% by weight; the content of silica powder with respect to the binder is from 5 to 20% by
weight, preferably 5 to 15% by weight.

Specific embodiments of the present invention are:-

the present invention as an anti-carburizing steel parts with a coating, you must first have a barrier function and the
need for carburization resistance carburizing agent;

secondly must be coated on the steel surface and the need for bonding agent;

third member must be removed from the surface of the steel and need supernatant loosely agent.

The present invention as an anti-carburizing steel parts with a coating, must also meet the following
quality requirements:-

1) 15 to 30 hours after the carburizing treatment at a high temperature 900 ~ 1000 ℃, clear coating, the
surface of the anti-carburizing cross section for metallographic examination, non-carburized layer;

2) paint pollution, no climb stretch, affecting the coating furnace atmosphere and excess carbon black
forming spongy three major chronic disease;

3) a coating thickness of about 0.2mm, uniform and smooth coating surface wrinkle;

4) the coating does not chemically change in the air, do not crack upon drying from the skin;

5) the coating should have a certain impact resistance capability, no harmful corrosion of metals;

6) anti-carburizing surface should have a good anti-carburizing performance, turning, milling, planning and
other machining.

In order to meet the resistance 900 ~ 1000 ℃ for 15 to 30 hours technical requirements, the present invention must be
inorganic mixture.

In order to meet the 15 to 30 hours for carburization treatment at 900 ~ 1000 ℃ After reaching the surface anti-
carburizing without the technical requirements of the carburized layer, barrier carburizing agent selected critical. The fact
that the copper plating having an excellent anti-carburizing effect, i.e. in view of a high temperature copper oxide at 1026
deg.] C was decomposed, and good compatibility with materials such as glass and other characteristics, so the choice of
copper oxide as the carburizing agent is particularly desirable barrier of.

In order to meet the 15 to 30 hours for carburization treatment at 900 ~ 1000 ℃, in order to present the components of
the anti-carburizing paint bonded, and can be coated on the surface of the steel member does not fall off, so as to
achieve the anti-carburizing technical requirements, selection of the binder must satisfy high temperature, chemical
stability, good bonding properties with good compatibility with the components of the paint and other technical
requirements. 

In the binder component, a water glass containing sodium oxide and different ratios of silicon dioxide is usually used as
a refractory material and a viscous liquid adhesive, its viscosity can be adjusted using required; Fireclay The major
components of aluminosilicates refractoriness higher than 1580 deg.] C, plasticity and water, dried and calcined, as a
compact mass; i.e. silica powder, quartz powder, which melting point is 1670 ~ 1710 ℃, for paint from bonding and
densification.

In order to meet the carburizing for 15 to 30 hours at 900 ~ 1000 ℃ after carburizing prevention surface capable of
coating easily peeled off the steel member, loose agent selected must meet high temperature, chemical stability, good
stripping performance with good compatibility with the components of the paint and other technical requirements.  Loose
component, the glass frit is ground to a fine powder of ordinary glass, whose main component is silicon dioxide, calcium
oxide and sodium oxide, having a high temperature resistance, good chemical stability, especially dense and brittle
properties , thereby blasting the coating peeled off easily; titania-chemical properties quite stable, does not effect occurs
with most chemical agents in general, temperature, density and good chipping resistance; temperature corundum, brittle,
easily peeled .

The coating is carried out in which solid components of ingredients and ground to determine the proportion of powder,
and then determine the ratio of liquid glass by stirring to uniformly mix.

The present invention over the prior art has the following advantages:-

Because of the conditions of use of the coating, technical analysis and quality requirements as well as measures taken
for the deficiencies of the prior art, especially the three major chronic disease carried out very correctly, We received the
results of the right medicine. First, 15 to 30 hours for carburizing at 900 ~ 1000 ℃, the sampled test, chemical analysis,
metallographic identified, which the anti-carburizing effect to JB3999-1999 standards; secondly, to overcome the anti-
carburizing copper face depression cannot be removed copper layer and the flaws in welding, to solve the chronic
problem of the three existing paint; third, it is environmentally friendly products with good craft and maneuverability, good
economic and social benefits, can be widely used to protect the anti-carburizing tool steel, bearing steel and low alloy
steel member, thereby to achieve a successful task invention.

Technical present invention by the following examples described in more detail as follows:

BX article is an inorganic anti-carburizing paint mixture, which contains 5 to 25% by weight of hindered carburizing
agent, 10 to 35% by weight of relaxer, 40 to 85% by weight of a binder; carburizing agent can be selected resistance
copper oxide; relaxer optional glass powder, corundum and titanium oxide, etc. and mixtures thereof; water glass binder
Alternatively, chamotte and quartz powder, and mixtures thereof. In the carburizing blocking agent, anti-carburizing paint
for copper oxide with a content of 5 to 25% by weight, preferably 7 to 20% by weight. Loose agent, the glass frit with
respect to the content of the fluffy agent is 35 to 75% by weight, preferably 40 to 60% by weight; the content of titanium
oxide with respect to the loose agent is 15 to 35% by weight, preferably 20 to 30% weight; content relative to the loose
corundum agent is 10 to 30% by weight, preferably 20 to 30% by weight.  In the binder, relative to the water glass binder
content is 55 to 90% by weight, preferably 65 to 85% by weight; refractory clay with respect to the content of the binder is
5 to 25% by weight, preferably 10 to 20% by weight; the content of silica powder with respect to the binder is from 5 to
20% by weight, preferably 5 to 15% by weight.

As an example, now according to the anti-carburizing paint component content range and Sample Preparation: 4 g of
copper oxide, glass powder 6 grams, 4 grams of titanium dioxide, corundum 3 g, 5 g chamotte, quartz powder 3 grams
mixed and ground into a fine powder, and then stirring was added 33 g of liquid water glass mixed evenly.

This anti-carburizing paint to use:-

1, the work piece surface clean grease is preferably first work piece shot blasting, and then hot water washed and
dried.

2, the work piece can also be coated with cold-heat coating, i.e. cold coating: coated on the surface with a brush;
thermal coating: placing the work piece 70 ~ 90 ℃ water immersed 5 to 10 minutes, dried hot brush.

3, drying, and drying the coated work piece into the dryer 80 ~ 100 ℃ for 30 minutes, after dry and harden the coating,
strong adhesion, this time to the carburizing furnace.

4, clear coatings, baked after the work piece by shot blasting or sand blasting the coating to be cleaned.
 Claims (9)

1.An anti-carburizing paint steel parts, characterized by being a mixture of one kind of inorganic material, which contains
5 to 25% by weight of hindered carburizing agent, 10 to 35% by weight of the bulk agent, 40 to 85% by weight of binder.

2. The anti-carburizing paint according to claim 1, wherein the carburizing agent can be selected resistance copper
oxide; relaxer optional glass powder, corundum and titanium oxide, etc. and mixtures thereof; optional water glass
binder, chamotte and quartz powder, and mixtures thereof.

3. The anti-carburizing paint according to claim 1, characterized in that the barrier carburizing agents, anti-carburizing
paint for copper oxide with a content of 5 to 25% by weight, preferably 7 to 20% by weight.

4. The anti-carburizing paint according to claim 1, characterized in that the loose agent, the glass frit with respect to the
content of the fluffy agent is 35 to 75% by weight, preferably 40 to 60% by weight.

5. The anti-carburizing paint according to claim 1, characterized in that the bulk agent, with respect to the titanium
dioxide content of the fluffy agent is 15 to 35% by weight, preferably 20 to 30% by weight.

6. The anti-carburizing paint according to claim 1, characterized in that the loose agent, relative to the content of the
fluffy white corundum agent is 10 to 30% by weight, preferably 20 to 30% by weight.

7. The anti-carburizing paint according to claim 1, characterized in that the binder, relative to the water glass binder
content is 55 to 90% by weight, preferably 65 to 85% by weight.

8. The anti-carburizing paint according to claim 1, characterized in that the binder, with respect to the chamotte content
of the binder is 5 to 25% by weight, preferably 10 to 20% by weight.

9. The anti-carburizing paint according to claim 1, characterized in that the binder, the silica powder with respect to the
content of the binder is 5 to 20% by weight, preferably 5 to 15% by weight.