Al Basra University

Engineering collage
Chemical engineering

Physical chemistry lab

PH measurement

Name : Ali Mohammad Hashem

Stage : Second Stage

No.of.exp : Tenth

Date of.exp : 20/5/2013

- Number : - 44

:Theory
 The pH is a measure of hydrogen ion concentration
and is considered one of the key factors for Analytical
Chemistry and Industrial where most operations
depositional Awaldhubanyh or reactions or prevent their
occurrence depends on the organization of the hydrogen
ion concentration within certain limits one who is
appointed hydrogen ion concentration and control kits
workflow processes in chemical.
[ H ] =10−7

[ OH ] = 10

The method adopted in this experiment are appointed

pH measurement of electromotive force using hydrogen
pole. Can clarify the relationship between the
electromotive force of the electrochemical cell as
follows:
[ H ][ OH ] =10−14
PH =−log [ H ]

:The purpose of experiment

 Study curved pH and appoint the equivalence point
using electro-chemical cell and a normative account
sour anonymous
:A Tools and Matriales

:A Tools
1 - pH measuring device

2 - pole glass

3 - peristaltic

4 – thermometer

A Matriales:
1 - hydrochloric acid

2 - sodium hydroxide
:Procedure

1 - Clean all glassware with distilled water and

dried

2 - Calibration pH measuring device by buffer solution

3 - Take (0.1N) hydrochloric acid solution in Baker and
record read device

4 - add 1 ml of sodium hydroxide solution ((0.1 N to

solution Hedrocleok and note change pH

5 - repeat the process and to reach the break-even point

6 - take three READINGS after the break-even point for
the acidic function and the size of the base added
:Discussion

The pHscale(in English: pH meter) isanelectronictool usedto

measurepH(acidityor alkaline) foragivenmass. Usuallyconsists
ofaspecialpole(pole glass) isconnected to electronic measuring
scale and display shy drogen exponent

Pole the measures the pH depending on the activity of

hydrogen ionssur rounding glass Balbeselh (bulb) with thin wall.
These bulbs are on the tip of the pole. Pole produces small
teams latency (approximately (0.06) volts per unit of (pH). This
difference in latency is measured and displayed on the screen of
the device as (pH) units

Calibration of the device and its use

Calibration through at least Mahloulinorganizers, but better

use of three solution so rganization Calibration device need
satalmoste very use. There are some modern-made device
sthatcanretain calibration for a month. System at ice solution is
chose nsecond depending on (pH), which will be the
measurements .Most often,(pH 10) solutions basaland 4 of
.acidic solutions
These types of numeroussimple andin expensive, which are
similar inform to the pento the in stalled devices complex and
.prohibitive price, which is delivered with computers
:Calculation

N1 (NaoH) = 0.1N

VNaoH = 80mL

N1 * V1 = N2 * V2

N2 * 50 = 80 * 0.1

N2 = 0.16N