Академический Документы
Профессиональный Документы
Культура Документы
A simple and efficient solar cell parameter extraction method from a single
current-voltage curve
Chunfu Zhang,1 Jincheng Zhang,1 Yue Hao,1,a) Zhenhua Lin,2 and Chunxiang Zhu2
1
Wide Bandgap Semiconductor Technology Disciplines State Key Laboratory, School of Microelectronics,
Xidian University, 2 South Taibai Road, Xi’an 710071, China
2
Silicon Nano Device Laboratory, Department of Electrical and Computer Engineering,
National University of Singapore, 10 Kent Ridge Crescent 119260, Singapore
(Received 12 January 2011; accepted 1 August 2011; published online 19 September 2011)
In this work, a simple and efficient method for the extraction of all the parameters of a solar cell
from a single current-voltage (I-V) curve under the constant illumination level is proposed. With the
help of the Lambert W function, the explicit analytic expression for I is obtained. By reducing
the number of the parameters, the expression for I only depends on the ideality factor n, the series
resistance Rs, and the shunt resistance Rsh. This analytic expression is directly used to fit the
experimental data and extract the device parameters. This simple solar cell parameter
extraction method can be directly applied for all kinds of solar cells whose I-V characteristics follow
the single-diode model. The parameters of various solar devices including silicon solar cells,
silicon solar modules, dye-sensitized solar cells, and organic solar cells with standalone, tandem, and
multi-junction structures have been successfully extracted by using our proposed method. V C 2011
I. INTRODUCTION the parameters from a single I-V curve measured under the
condition of one constant illumination level. This is essen-
Solar cells are promising devices for clean electric
tially important for the recently emerging organic solar cells,
power generation. Various intensive research efforts have
whose parameters have been shown to be greatly influenced
been devoted to their continuous performance improvement.
by different illumination levels.12
To estimate solar cell performance and thus further to simu-
Recently, Ishibashi et al. introduced one method to
late, design, fabricate, and quality control solar cells, an
extract all the parameters of a solar cell under one constant
accurate knowledge of their parameters from experimental
illumination level.13 However, their method needs to calcu-
data is of vital importance. The electrical characteristic of a
late the differential value dV/dI from the experimental data,
solar cell can be described by the equivalent circuit of the
which requires a very smooth I-V curve. Thus, the polyno-
single-diode model, the two-diode model,1 or the three-diode
mial approximation or other method to smooth the experi-
model.2,3 Among these circuit models, the single-diode
mental curve is inevitable. Furthermore, in their method,
model has the simplest form as shown in Fig. 1. Although
only a part of the experimental data can be used to extract
the single-diode mode is simple, it can well describe the
the parameters because the differential dV/dI will have a
characteristics of various solar cells, satisfy most of the
very large error when I is close to the short circuit current
applications, and thus becomes the most widely used circuit
(ISC). Till now, the most used way to extract the solar cell pa-
model.4–21 In the single-diode model, the relation of the cur-
rameters is still the curve fitting approach.14–17 The least-
rent I and the voltage V is given as
squares method, which is the most commonly used method
in the curve fitting, extracts the parameters by minimizing
qðV Rs IÞ V Rs I
I ¼ I0 exp 1 þ Iph ; (1) the squared error between the calculated target variable and
nkB T Rsh
the experimental data. However, in the conventional curve
where I0 is the saturation current, Iph the photocurrent, Rs the fitting methods, the expressions for the target variable are
series resistance, Rsh the shunt resistance, n the ideality usually implicit functions and include the independent and
factor, q the electron charge, kB the Boltzmann constant, and dependent variables at the same time. For example, in Eq.
T the temperature. The methods to determine the unknown (1), the expression for I includes both V and I. This implicit
parameters of I0, Iph, n, R, and Rsh have been the subject of nature of the target variable expression increases the com-
many studies.4–21 Some methods use the measurements of plexity and difficulty of the parameter extraction. With the
illuminated I-V characteristics at different illumination help of the Lambert W function, the explicit analytic expres-
levels4–6 and some utilize dark and illuminated sions for I or V can be obtained.18–21 In one previous work
measurements.7–10 However, it should be noted that the de- from Jain et al.,18 Lambert W function has been used to
vice parameters are widely influenced by the different illumi- study the properties of solar cells. However, their study is
nation levels.11 Therefore, it is very important to estimate all validated only on simulated I-V characteristics instead of the
parameter extraction from the experimental data. Another
a)
Author to whom correspondence should be addressed. Electronic mail: work from Ortiz-Conde et al.21 proposed an efficient method
yhao@xidian.edu.cn. to extract the solar cell parameters from the I-V
Downloaded 19 Sep 2011 to 123.138.79.4. Redistribution subject to AIP license or copyright; see http://jap.aip.org/about/rights_and_permissions
064504-2 Zhang et al. J. Appl. Phys. 110, 064504 (2011)
Downloaded 19 Sep 2011 to 123.138.79.4. Redistribution subject to AIP license or copyright; see http://jap.aip.org/about/rights_and_permissions
064504-3 Zhang et al. J. Appl. Phys. 110, 064504 (2011)
expression for I. However, this expression seems a little And around the open circuit condition (I ¼ 0 and V ¼ VOC)
complicated. It can be greatly simplified if we make the
assumption dV nkB T=q
¼ þ Rs
dI V nkB T ðI þ ISC ÞRs
ISC þ I þ þ
qðRs ISC VOC Þ Rsh qRsh Rsh
D ¼ exp 1: (6) nkB T=q
nkB T þ Rs : (12)
V
ISC þ I
Using this assumption, Eqs. (4a) and (4b) are reduced to Rsh
dV nkB T=q The proposed method is first applied to extract the pa-
¼ þ Rs : (9) rameters of a 57-mm-diameter commercial (R.T.C. France)
dI Iph þ I0 þ I ðV Rs I nkB T=qÞ=Rsh
silicon solar cell.14 The value of dV/dI at short circuit condi-
tion gives the initial value of Rsh at about 36 X. Figure 2(a)
Substituting (7b) into (9),
shows the plot of dV/dI and (ISC þ I – V/Rsh)1kBT/q. The
y-intercept and the slope give the initial values of Rs and n at
dV
¼
nkB T=q
þ Rs : (10) about 0.0396 X and 1.25, respectively. Using these initial
dI V nkB T ðI þ ISC ÞRs values, the parameters extracted by our proposed method are
ISC þ I þ þ
Rsh qRsh Rsh summarized in Table I. It is shown that the initial values are
close to the extracted values and thus confirms the validity of
At short circuit condition (I ¼ ISC and V ¼ 0) the method to set the initial values. The corresponding I-V
curves rebuilt with the extracted parameters are shown in
Fig. 2(b). It is clearly shown that the rebuilt curves are in
dV
¼ Rsh þ Rs Rsh : (11) very good agreement with the experimental data (open
dI I¼ISC ;V¼0 circles). Dashed line represents the curve calculated using
Downloaded 19 Sep 2011 to 123.138.79.4. Redistribution subject to AIP license or copyright; see http://jap.aip.org/about/rights_and_permissions
064504-4 Zhang et al. J. Appl. Phys. 110, 064504 (2011)
FIG. 2. (Color online) (a) Plot of dV/dI as a function of (ISC þ I – V/ Iwith noise ¼ Iwithout noise ð1 þ percent randomÞ: (13)
Rsh)1kBT/q. The y-intercept and the slope of the plot of dV/dI give the ini-
tial values of n and Rs. (b) Experimental data of a silicon solar cell (R.T.C Thus, the data with noise are used in our method to extract
France) (open circles) and the I-V curves calculated using the value of the device parameters. To extract the parameters, ISC and VOC
parameters derived by our method based on Eq. (5) (dashed line) and Eq. (8)
are firstly obtained by the cubic spline interpolation method.
(solid line).
TABLE I. Extracted parameters by our method and the previous work of a silicon solar cell, a silicon solar module, and a DSSC.
Silicon solar cells (33 C) Silicon solar module (45 C) DSSC (20 C)**
Para- Previous Previous Previous This This work Previous Previous Previous This Previous Previous This
meters worka workb workc work (with noise)* worka workb workc work workd workc work
Isc (A) 0.7608 — 0.76 0.7604 0.7602 1.030 — 1.0 1.0309 0.00206 0.0021 0.002057
Voc (V) 0.5728 — 0.57 0.5737 0.5736 16.778 — 17 16.782 0.704 0.70 0.7065
Iph (A) 0.7608 0.7609 0.77 0.7611 0.7618 1.0318 1.0359 1.0 1.0332 — 0.0021 0.002085
I0 (lA) 0.3223 0.4039 0.20 0.2422 0.1195 3.2876 6.77 2.3 1.597 0.035 0.023 0.015143
N 1.484 1.504 1.4 1.4561 1.392 48.45 51.32 47 45.862 2.5 2.5 2.3865
Rs (X) 0.0364 0.0364 1.037 0.0373 0.0384 1.2057 1.146 1.3 1.313 43.8 42 44.7
Rsh (kX) 0.0538 0.0495 0.032 0.042 0.0205 0.549 0.2 0.83 0.6023 3.736 3.2 3.285
D 8.9107 — 5.6 107 6.8 107 3.6 107 8.3 106 — 6.3 106 9.4 107 6.0 105 4.9 105 1.3e 105
*
Random noise with 5% relative intensity.
**
No information on the temperature T in the reference.
a
See Ref. 14.
b
See Ref. 15.
c
See Ref. 13.
d
See Ref. 17.
Downloaded 19 Sep 2011 to 123.138.79.4. Redistribution subject to AIP license or copyright; see http://jap.aip.org/about/rights_and_permissions
064504-5 Zhang et al. J. Appl. Phys. 110, 064504 (2011)
Downloaded 19 Sep 2011 to 123.138.79.4. Redistribution subject to AIP license or copyright; see http://jap.aip.org/about/rights_and_permissions
064504-6 Zhang et al. J. Appl. Phys. 110, 064504 (2011)
TABLE II. Extracted parameters by our method and the previous work of two standalone polymer solar cells, a tandem polymer cell, and a multi-junction
small molecule cell (27 C was used in the parameter extraction).
Standalone and tandem polymer cells Multi-junction small molecule cell under different illumination
P3HT cell PCPDTBT cell Tandem cell 18 mW=cm2 58 mW=cm2 116 mW=cm2 372 mW=cm2
Para- Previous This Previous This Previous This This This Previous This This
meters worka work worka work worka work work work workb work work
Isc (mA=cm2) 10.8 10.8 9.2 9.22 7.8 7.792 0.7091 2.2755 4.6 4.5728 17.509
Voc (V) 0.63 0.63 0.66 0.66 1.24 1.24 0.9355 1.1294 1.2 1.2217 1.3431
Iph (mA) — 10.861 — 9.49 — 7.8273 0.7116 2.3162 4.7 4.7219 15.326
I0 (mA) — 3.48 106 — 3.81 107 — 8.84 107 9.0 103 1.7 103 9.2 104 1.04 103 4.04e 104
n — 1.65 — 1.746 — 3.0243 8.611 6.3756 5.8 5.8847 5.162
Rs (Xcm2) — 1.2 — 5.4 — 5.6 35.4 50.9 48 46.9 23.1
Rsh (kXcm2) — 0.6833 — 0.1797 — 1.2357 17.196 2.9868 1.4 1.4024 0.4119
D — 6.9 107 — 1.8 106 — 3.1 107 1.8 102 2.4 103 1.1 103 1.5 103 1 103
a
See Ref. 23.
b
See Ref. 13.
Downloaded 19 Sep 2011 to 123.138.79.4. Redistribution subject to AIP license or copyright; see http://jap.aip.org/about/rights_and_permissions
064504-7 Zhang et al. J. Appl. Phys. 110, 064504 (2011)
IV. CONCLUSION
In this work, we have proposed a simple method to
extract all the parameters of a solar cell just from a single I-
V curve under one constant illumination level. With the help
of the Lambert W function, the explicit analytic expression
for I can be obtained. By reducing the number of parameters,
the expression for I only depends on three parameters of n,
Rs and Rsh. This analytic expression for I is directly used in
the numerical method to fit the experimental data and then
determine the values of the parameters. It has been shown
that our method can be easily used to analyze various solar
FIG. 7. (Color online) Experimental data of a DSSC (C4) (open circles) and
devices, including silicon solar cells, silicon solar modules,
the I-V curve calculated using the value of the parameters derived by our dye-sensitized solar cells, and organic solar cells with stand-
method (solid line). alone, tandem, and multi-junction structures.
Downloaded 19 Sep 2011 to 123.138.79.4. Redistribution subject to AIP license or copyright; see http://jap.aip.org/about/rights_and_permissions