Вы находитесь на странице: 1из 15

SAFETY DATA SHEET

PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE


1.
COMPANY/UNDERTAKING
PRODUCT NAME : NALCO® EC1021A

APPLICATION : CORROSION INHIBITOR

COMPANY IDENTIFICATION : NALCO EUROPE B.V.


Postbus 627
2300 AP Leiden, The Netherlands

EMERGENCY TELEPHONE NUMBER(S) : See section 16, for Emergency Telephone Numbers.

Date issued : 23.11.2010


Version Number : 2.21

COMPANY CONTACT TELEPHONE NUMBERS.


NALCO EUROPE B.V. +31 71 5241 100 NALCO NORGE AS (NO) +47 51 96 36 00
NALCO AB (SE) +46 (0)31-707 22 70 Distributor Nalco Mobotec Polska PRZEMYS ŁOWA 55
Sp. z o.o. PL-43-110 TYCHY
TEL:+48 (0)32-3262750
FAX: +48(0)32 329 13 11
e-mail: office@nalco.pl
NALCO ANADOLU KIMYA (TR) +90 216 5743464 NALCO PORTUGUESA LDA. (P) +351 214121852
NALCO APPLIED SERVICES +31 (0)73 6456980 NTD S.r.l (IT) +39 (0) 313351325
OF EUROPE BV
NALCO BELGIUM BVBA +32 (0)3-450 69 10 Nalco Switzerland AG (CH) +41 (0)52 235 38 38
NALCO DANMARK ApS +45-48195800 Nalco Company OOO +7 (0)495 980 72 80
NALCO DEUTSCHLAND GmbH +49 (0)69-79340 NALCO ÖSTERREICH + 43(0)1 27026350
(D) Ges.m.b.H. (A)
NALCO ESPAÑOLA S.L. (E) +34 93-4095555 First Distributor: Nalco Czechia Hlavní 1222/60,141 00 Praha
s.r.o. (CZ) 4,Czech Republic,+420 267 912
350 & +420 272 913 512
NALCO FINLAND OY (FI) +358 (0)9 2519 5600 Local Support: Nalco Hungary Kft. +36 1 8805610
(HU)
NALCO FRANCE SAS +33 (0)3 20 11 70 00 Local Support: Nalco Österreich +385 (0)1 377 95 21
Ges.m.b.H., Representation Office
Predstavnistvo Zagreb (HR)
NALCO HELLAS S.A. (GR) +30 210 238 9620 Local Support: Nalco Österreich +40 (0) 21 224 17 93
Ges.m.b.H. Representation Office
ROMANIA (RO)
NALCO ITALIANA S.R.L.(I) +39 06-54565000 NALCO LIMITED +44 (0)1606 74488
NALCO NETHERLANDS B.V. +31 (0)13-5952200

For Product Safety information please contact Jacqueline Dudley, e-mail EUProductSafety@nalco.com

2. HAZARDS IDENTIFICATION

HAZARD CLASSIFICATION :

This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.

Causes burns. Limited evidence of a carcinogenic effect. Harmful: may cause lung damage if swallowed.
Vapours may cause drowsiness and dizziness. Toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.

HUMAN HEALTH HAZARDS - ACUTE :

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
1 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

INHALATION :
Irritating, in high concentrations, to the eyes, nose, throat and lungs. Product mist or vapors may cause headache,
nausea, vomiting, drowsiness, stupor or unconsciousness. Can cause central nervous system depression.

SKIN CONTACT :
May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid
administered. Frequent or prolonged contact with product may defat and dry the skin, leading to discomfort and
dermatitis.

EYE CONTACT :
Corrosive. Will cause eye burns and permanent tissue damage.

INGESTION :
Not a likely route of exposure. Corrosive; causes chemical burns to the mouth, throat and stomach. May cause
nausea and vomiting. Can cause chemical pneumonia if aspirated into lungs following ingestion. Can cause
central nervous system depression.

HUMAN HEALTH HAZARDS - CHRONIC :


This product contains naphthalene. The International Agency for Research on Cancer (IARC) has evaluated
naphthalene and determined it to be possibly carcinogenic to humans (Group 2B, based on sufficient evidence in
experimental animals and inadequate evidence in humans).

ENVIRONMENTAL HAZARDS :
Keep out of waterways. This product may pose a risk to the aquatic ecosystem if released.

PHYSICAL AND CHEMICAL HAZARDS :


Combustible.

3. COMPOSITION/INFORMATION ON INGREDIENTS

This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.

Hazardous Substance(s) EINECS / CAS NO SYMBOL R-PHRASES / % (w/w)


ELINCS NO NOTAS
Heavy Aromatic Naphtha 265-198-5 64742-94-5 Xn, N R51/53, R65, 30 - 60
R66, R67
Fatty acid amine condensate 263-171-2 61791-39-7 C R34 30 - 60
Naphthalene 202-049-5 91-20-3 Xn, N R22, R40, 5 - 10
R50/53
1,2,4-Trimethylbenzene 202-436-9 95-63-6 Xn, N R10, R20, 1- 5
R36/37/38,
R51/53

Refer to Section 16 for descriptions of relevant risk phrases and Notas.

4. FIRST AID MEASURES

INHALATION :
Get medical attention. Remove to fresh air, treat symptomatically.

SKIN CONTACT :
Get immediate medical attention. Immediately flush with plenty of water for at least 15 minutes. For a large splash,
flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with plenty of
water. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
2 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

EYE CONTACT :
Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush
eye with water for at least 15 minutes while holding eyelids open.

INGESTION :
Get immediate medical attention. DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to
drink.

NOTE TO PHYSICIAN :
Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the
patient, the physician's judgement should be used to control symptoms and clinical condition.

5. FIRE FIGHTING MEASURES

FLASH POINT : 68 - 70 °C PMCC

EXTINGUISHING MEDIA :
Foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires, use water
spray or fog, thoroughly drenching the burning material.
Water mist may be used to cool closed containers.

UNSUITABLE EXTINGUISHING MEDIA :


Do not use water unless flooding amounts are available.

FIRE AND EXPLOSION HAZARD :


Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may
contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of
ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire
conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING :


In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS :
Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment
recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so.
Ventilate spill area if possible. Remove sources of ignition. Ensure clean-up is conducted by trained personnel
only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available.
Notify appropriate government, occupational health and safety and environmental authorities.

METHODS FOR CLEANING UP :


SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or
by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces
with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered
material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS :
Prevent material from entering sewers or waterways. This product may pose a risk to the aquatic ecosystem if
released.

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
3 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

7. HANDLING AND STORAGE

HANDLING :
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe
vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills,
leaks, etc.) readily available. Ensure all containers are labeled. Do not use, store, spill or pour near heat, sparks or
open flame.

STORAGE CONDITIONS :
Store in suitable labeled containers. Store the containers tightly closed. Store away from heat and sources of
ignition. Have appropriate fire extinguishers available in and near the storage area. Connections must be
grounded to avoid electrical charges. Store separately from oxidizers.

SUITABLE CONSTRUCTION MATERIAL :


Perfluoroelastomer, PTFE, FEP (encapsulated), Carbon Steel C1018, Stainless Steel 304, Stainless Steel 316L,
Surface-modified HDPE (high density polyethylene)

UNSUITABLE CONSTRUCTION MATERIAL :


Neoprene, MDPE (medium density polyethylene), Nitrile, EPDM, TFE, HDPE (high density polyethylene),
Fluoroelastomer, Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested
prior to use.

SPECIFIC USE(S) :
CORROSION INHIBITOR

For specific dosages and customized applications please contact your representative.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

OCCUPATIONAL EXPOSURE LIMITS

Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are
shown below.
Country/Source Substance(s) Category: ppm mg/m3

Manufacturer's Heavy Aromatic Naphtha TWA 100


Recommendation

AUSTRIA Naphthalene MAK 10 50


Skin*

Trimethylbenzene MAK 20 100


MAK STEL 30 150

BELGIUM Naphthalene TWA 10 53


STEL 15 80
Skin*

Trimethylbenzene TWA 20 100

BULGARIA Naphthalene TWA 50


STEL 75

DENMARK Naphthalene GV 10 50

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
4 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

Trimethylbenzene GV 25 120
GV 25

FINLAND Naphthalene HTP 8H 1 5


HTP 15MIN 2 10

Trimethylbenzene HTP 8H 20 100

Heavy Aromatic Naphtha HTP 8H 100

FRANCE Naphthalene VME 10 50

GERMANY Naphthalene Skin*

Trimethylbenzene MAK 20 100


AGW 100

IRELAND Naphthalene TWA 10 50


STEL 15 75

Trimethylbenzene TWA 20 100


Skin*

ITALY Naphthalene TWA 10 50

Trimethylbenzene TWA 25

NETHERLANDS Naphthalene TGG 50


TGG 15 80

NORWAY Naphthalene ADM. NORM 10 50

Trimethylbenzene ADM. NORM 20 100

SPAIN Naphthalene VLA-ED 10 53


VLA-EC 15 80
Skin*

SWEDEN Naphthalene NGV 10 50


KTV 15 80

Trimethylbenzene NGV 25 120


KTV 35 170

SWITZERLAND Naphthalene TWA 10 50


Skin*

Trimethylbenzene TWA 20 100


STEL 40 200

UNITED KINGDOM Trimethylbenzene TWA 25 125

POLAND Naphthalene MAC-NDS 20


MAC-NDSC 50
h

Trimethylbenzene MAC-NDS 100


MAC-NDSC 170
h

HUNGARY Naphthalene ÁK 50
Skin*

LATVIA Naphthalene TWA 10 50

CZECH REPUBLIC Naphthalene PEL 50


NPK-P 100

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
5 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

Heavy Aromatic Naphtha PEL 200


NPK-P 1,000

CROATIA Naphthalene GVI 10 50

Trimethylbenzene GVI 25 125

ROMANIA Naphthalene TWA 9.5 50

RUSSIAN Naphthalene (Vapour.) CEIL 20


FEDERATION

SERBIA Naphthalene MAC 10 50

Trimethylbenzene MAC 25 125

SLOVAKIA Naphthalene TWA 10 50


Skin*

SLOVENIA Naphthalene TWA 10 50

* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and
the eyes.

MONITORING MEASURES :
A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed
or removed and analyzed as referenced below:
Substance(s) Method Analysis Absorbant
Naphthalene US NIOSH: 1501 Gas chromatography Charcoal

Heavy Aromatic Naphtha US NIOSH: 1550 Gas chromatography Charcoal

BIOLOGICAL EXPOSURE INDICES :


Heavy Aromatic Naphtha
A biological index of exposure to aromatic petroleum solvent, xylene based, is the detection of total xylene in the
blood post shift (Germany, 1.5 mg/l), or the detection of methylhippuric acid in the urine post shift (USA, 1.5g/g
creatinine; Germany, 2g/l).

ENGINEERING MEASURES :
General ventilation is recommended. The use of local exhaust ventilation is recommended to control emissions
near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of
confined spaces.

PERSONAL PROTECTION

GENERAL ADVICE :
The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the
way the product is handled. In general, we recommend as a minimum precaution that safety glasses with
side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area
where this product is handled should at least wear safety glasses with side-shields. The applicable European
standard can be found in EN 166.

RESPIRATORY PROTECTION :

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
6 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air
supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of
chemicals being handled. Consider the use of filter type: A-B-E-K-P The applicable European standard can be
found in EN 140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown
concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required,
institute a complete respiratory protection program including selection, fit testing, training, maintenance and
inspection.

HAND PROTECTION :
When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends on
work conditions and what chemicals are handled, but we have positive experience under light handling conditions
using gloves made from Nitrile Gloves should be replaced immediately if signs of degradation are observed.
Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standard
can be found in EN 374.

SKIN PROTECTION :
When handling this product, the use of a chemical resistant suit and rubber boots is recommended. When
handling this product, the use of overalls, a chemical resistant apron and rubber boots is recommended. The
applicable European standard can be found in EN ISO 20345.

EYE PROTECTION :
Wear a face shield with chemical splash goggles. The applicable European standard can be found in EN 166.

HYGIENE RECOMMENDATIONS :
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a
safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area.
Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling
this product never eat, drink or smoke.

ENVIRONMENTAL EXPOSURE CONTROL PRECAUTIONS :


Consider the provision of containment around storage vessels.

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE Liquid

APPEARANCE Clear Amber

ODOR Hydrocarbon

FLASH POINT : 68 - 70 °C PMCC


SPECIFIC GRAVITY 0.918 (15 °C)
SOLUBILITY IN WATER Insoluble
VISCOSITY 15 cst (20 °C)
VISCOSITY 6.74 cst (40 °C) ASTM D-445
POUR POINT -25 °C
BOILING POINT 180 °C

Note: These physical properties are typical values for this product and are subject to change.

10. STABILITY AND REACTIVITY

STABILITY :

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
7 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

Stable under normal conditions.

HAZARDOUS POLYMERIZATION :
Hazardous polymerization will not occur.

CONDITIONS TO AVOID :
Heat and sources of ignition including static discharges.

MATERIALS TO AVOID :
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen,
permanganate) may generate heat, fires, explosions and/or toxic vapors., Contact with strong acids (e.g. sulfuric,
phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxic vapors.,
Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium
hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or
boiling and toxic vapors.

HAZARDOUS DECOMPOSITION PRODUCTS :


Under fire conditions: Oxides of carbon, Oxides of nitrogen

11. TOXICOLOGICAL INFORMATION

No toxicity studies have been conducted on this product. The following results are for the hazardous components.

ACUTE ORAL TOXICITY :


Species: Rat
LD50: 1,932 mg/kg
Test Descriptor: Active Substance

ACUTE DERMAL TOXICITY :


Species: Rabbit
LD50: > 2,000 mg/kg
Test Descriptor: Active Substance

PRIMARY SKIN IRRITATION :


Species: Rabbit
Draize Score: 5.0 /8.0
Test Descriptor: Active Substance

PRIMARY EYE IRRITATION :


Species: Rabbit
Draize Score: /110.0
Test Descriptor: Active Substance
Remarks: Comments: Only one rabbit was tested. Due to severe irritation (corneal opacity, iritis and
conjuctival blistering), the test was terminated after 24 hours.

SENSITIZATION :
This product is not expected to be a sensitizer.

CHRONIC TOXICITY DATA :

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
8 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

A 5-day repeated dose oral toxicity study with the imidazoline derivative resulted in a NOAEL of 100 mg/kg.

CARCINOGENICITY :
This product contains naphthalene. The International Agency for Research on Cancer (IARC) has evaluated
naphthalene and determined it to be possibly carcinogenic to humans (Group 2B, based on sufficient evidence in
experimental animals and inadequate evidence in humans).

TERATOGENICITY AND EMBRYOTOXICITY :


For imidazoline derivative, in a teratology study, doses of 15, 65 and 100 mg/kg/day were administered to pregnant
rats during days 6-15 of gestation by gastric gavage. The doses of 65 and 100 kg/kg/day produced maternal
toxicity but not developmental toxicity. The NOAEL for maternal toxicity was 15 mg/kg/day, while the NOAEL for
developmental toxicity was 100 mg/kg/day.

MUTAGENICITY :
Mutagenicity assays (Ames test, chromosome aberration assay, unscheduled DNA synthesis assay) with the
imidazoline derivative were negative.

For additional information on the hazard of the preparation, please consult section 2 and 12.

12. ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL EFFECTS :

The following results are for the product.

ACUTE FISH RESULTS :


Species Exposure LC50 NOEC Method Test Descriptor
Rainbow Trout 96 hrs 2.7 mg/l 1.5 mg/l Product

ACUTE INVERTEBRATE RESULTS :


Species Exposure LC50 EC50 Method Test Descriptor
Daphnia magna 48 hrs 1.1 mg/l 1.1 mg/l Product

MOBILITY :
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program
interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input
and output. The level III model does not require equilibrium between the defined media. The information provided
is intended to give the user a general estimate of the environmental fate of this product under the defined
conditions of the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the
approximate respective percentages;

Air Water Soil/Sediment


10 - 30% 30 - 50% 30 - 50%

The portion in water is expected to float on the surface.

PERSISTENCY AND DEGRADATION :

The organic portion of this preparation is expected to be inherently biodegradable.

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
9 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

BIOACCUMULATION POTENTIAL
Component substances have a potential to bioaccumulate.

13. DISPOSAL CONSIDERATIONS

If this preparation becomes a waste, the final user must define and assign the appropriate European Waste
Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations.

Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance with all applicable
regulations. Do not dispose of wastes in local sewer or with normal garbage. This product is ashless and can be
burned directly in appropriate equipment. Any chemical waste is a potential environmental pollutant and is NOT
suitable for disposal via ground, municipal sewers, drains, natural streams or rivers.

Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed
contractor.

EUROPE WASTE CODE :


16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing dangerous
substances. If this product is used in any further processes, the final user must redefine and assign the most
appropriate European Waste Catalogue Code.

NATIONAL REGULATIONS AUSTRIA :


Waste Code :55352

NATIONAL REGULATIONS CZECH REPUBLIC


Valid and applicable waste legislation in the Czech Republic: Waste Act (No. 185/2001 Coll.), Packaging Act (No.
477/2001 Coll.) and the Decree of the Ministry of the Environment on the Catalogue of Wastes (No. 381/2001
Coll.), as amended

NATIONAL REGULATIONS POLAND :


Waste Code: Regulations of 27 September 2001, Waste catalogue, J. of Laws No. 112, item 1206.
Act of 22 January 2010 amending the Act on waste and certain other acts (J.oL. no. 28, item 145.)
Directive 2006/12/EC of the European Parliament and of the Council of 5 April 2006 on waste.
91/689/EEC Council Directive of 12 December 1991 on hazardous waste.
94/62/EC Directive of the European Parliament and of the Council of 20 December 1994 on packaging and
packaging waste.
Do not dispose into a local sewage system or with normal household waste. Do not dispose into municipal drains,
sewers, soil, natural streams or rivers. The waste product should be disposed of at an authorised incineration plant
or a waste treatment/disposal plant in line with the existing regulations (Act of 27 April 2001 on Waste,
consolidated text annexed to the J. of Laws No. 39, item 251 of 2007). The product incineration produces ash. The
product may be incinerated directly using suitable equipment.
Reclamation, recycling and disposal of packaging waste should comply with the existing regulations (Act of 11 May
2001 on Packaging and Packaging Waste, J. of Laws No. 63, item 638, as amended).
Use the services of appropriately authorised businesses.
Decree about waste of 27.04.2001 (DZ.U nr.62 item 628 with later changes Dz U 2003, nr 7 item 78

14. TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of lading)
specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
10 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

LAND TRANSPORT
Proper Shipping Name : AMINES, LIQUID, CORROSIVE, N.O.S.
Technical Name(s) : Fatty acid amine condensate
UN/ID No : UN 2735
Hazard Class - Primary : 8
Packing Group : III
ADR/RID H.I.n. : 80
CLASSIFICATION CODE : C7

AIR TRANSPORT (ICAO/IATA)


Proper Shipping Name : AMINES, LIQUID, CORROSIVE, N.O.S.
Technical Name(s) : Fatty acid amine condensate
UN/ID No : UN 2735
Hazard Class - Primary : 8
Packing Group : III
IATA Cargo Packing Instructions : 820
IATA Cargo Aircraft Limit : 60 L (Max net quantity per package)
IATA Passenger Packing Instructions : Y818 / 818
IATA Passenger Aircraft Limit : 1L/5L

MARINE TRANSPORT (IMDG/IMO)


Proper Shipping Name : AMINES, LIQUID, CORROSIVE, N.O.S.
Technical Name(s) : Fatty acid amine condensate
UN/ID No : UN 2735
Hazard Class - Primary : 8
Packing Group : III
*Marine Pollutant : Heavy Aromatic Naphtha

OTHER APPLICABLE INFORMATION


CEFIC TREMCARD REFERENCE : 80GC7-II+III
EMERGENCY ACTION CODE : 2X

15. REGULATORY INFORMATION

CLASSIFICATION AND LABELLING :

GOVERNING DIRECTIVE(S): Dangerous Substances Directive 67/548/EEC and Dangerous Preparations


Directive 1999/45/EC.

HAZARD SYMBOLS

CORROSIVE DANGEROUS FOR THE


ENVIRONMENT

Contains:..Fatty acid amine condensate Naphthalene Heavy Aromatic Naphtha

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
11 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

RISK PHRASES
R34 - Causes burns.
R40 - Limited evidence of a carcinogenic effect.
R65 - Harmful: may cause lung damage if swallowed.
R67 - Vapours may cause drowsiness and dizziness.
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

SAFETY PHRASES
S23 - Do not breathe vapor.
S24/25 - Avoid contact with skin and eyes.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S57 - Use appropriate containment to avoid environmental contamination.
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

NATIONAL REGULATIONS AUSTRIA


Danger classification according to VbF: A III

NATIONAL REGULATIONS CZECH REPUBLIC


This preparation is classified as per Act on Chemical Substances and Chemical Preparations (No. 356/2003 Coll.)
This Safety Data Sheet is drawn up as per Act No. 356/2003 Coll. and per Act 371/2008 Coll.
Occupational exposure limits for the Czech Republic in section 8 are given as per Government's Regulation No.
178/2001 Coll. laying down conditions of health protection of employees at work

NATIONAL REGULATIONS FRANCE


Table of occupational diseases, Article L461-4. Social Security Code- Decree 11/2/2003: Relevant, see table(s):
84, 4, 4 Bis
Special medical supervision - Decree of 11 July 1977: Relevant.
Classified Industrial Sites (ICPE): Relevant. Headings: 1173
Water Discharge: Relevant.

NATIONAL REGULATIONS GERMANY


WGK 2 (Annex 4)

NATIONAL REGULATIONS HUNGARY


Relevant and applicable Hungarian legislation on protection of human health and the environment:
Decree 44/2000. (XII.27.) EüM (Minister of Health Affairs) and its amendments: Decree 33/2004. (IV.26.) ESzCsM
(Minister of Health, Social and Family Affairs) and Decree 26/2007. (VI.7.) EüM (1907/2006/EK - REACH) on
detailed rules of certain procedures and activities related to dangerous substances and preparations.
Joint Ministerial Decree: 25/2000. (IX.30.) EüM-ESzCsM on chemical safety at work.

NATIONAL REGULATIONS POLAND


Act on chemical substances and preparations of 11 January 2001 (J.oL. No. 11, item 84 as amended). Unified text
(J.oL of 2009, No 152, item 1222).
Minister of Health Regulation of 8 February 2010 concerning a list of dangerous substances including classification
and labelling (J.oL. no. 27 item 140).

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
12 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

Minister of Health Regulation of 2 September 2003 concerning criteria and way of classification of chemical
substances and preparations (J.oL. No 171, item 1666 as amended).
Minister of Health Regulation of 5 March 2009 concerning labelling of dangerous substances and preparations
(J.oL. no. 53 item 439).
Regulation of MPiPS [Minister of Labour and Social Policy] dated 29 November 2002 on maximum allowable
concentrations and levels of harmful factors in the working environment (J.oL. No. 217, item 1833 as amended).
Government Statement dated 16 January 2009 on introduction of changes in appendices A and B to European
Agreement on road transport of hazardous goods (ADR) prepared in Geneva on 30 September 1957 (J.oL. No 27,
item 162).
Minister of Economy Regulation of 21 December 2005 on essential requirements for Personal Protective
Equipment (J.oL. No. 259, item 2173 of 2005).Minister of Health Regulation of 20 April 2005 on tests and
measurements of factors hazardous for health in the working environment (J.oL. No. 73, item 645 dated 2005 as
amended).
Regulation 1907/2006/EC concerning Registration, Evaluation, Authorization and Restriction of Chemicals
(REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council
Regulation (EEC) No 793/93 and No 1488/94, as well as Council Directive 76/769/EEC and Commission
Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC
Regulation 1272/2008/EC of the European Parliament and of the Council of 16 December 2008 on the
classification, labelling and packaging of substances and mixtures, amending and repealing Directive 67/548/EEC
and 1999/45/EC and amending Regulation (EC) No 1907/2006.1999/45/EC Directive of the European Parliament
and of the Council of 31 May 1999 concerning the approximation of the laws, regulations and administrative
provisions of the Member States relating to the classification, packaging and labelling of dangerous
preparations.790/2009/EC Commission Regulation of 10 August 2009 amending, for the purposes of its
adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of
the Council on classification, labelling and packaging of substances and mixtures.453/2010/ EC Commission
regulation of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning Registration, Evaluation, Authorization and Restriction of Chemicals (REACH).

NATIONAL REGULATIONS RUSSIAN FEDERATION


The law of Russian Federation "About the sanitary-epidemiological safety of the population", 30 March 1999 N
52-FZ.
The law of Russian Federation "About the safety of the dangerous industrial objects", 21 July 1997 No. 116-FZ.
The law of Russian Federation "About protection of the rights of the consumers", 07 February 1992 N 2300-1.
The law of Russian Federation "Basics of the legislation of
The law of Russian Federation "About the industrial regulation", 27 December 2002 N 184-FZ.
The law of Russian Federation "On Environmental Protection", 10 January 2002, N 7-FZ.
GOST 30333-2007: Chemical production safety passport. General requirements.
GOST 19433-88: Dangerous goods. Classification and marking.
GOST 12.1.007-76 (Occupational safety standards system. Noxious substances. Classification and general safety
requirements).

PRODUCT REGISTRATION NUMBER


France 81241

INTERNATIONAL CHEMICAL CONTROL LAWS


EUROPE

The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.

Safety Data Sheet according to Regulation (EC) No 1907/2006.

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
13 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restriction of CHemicals
(REACH) regulation. It is our intention to pre-register all chemical substances that we manufacture or import into
European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment.
Should you require any further information on Nalco's REACH programme please contact us at reach@nalco.com
or visit our website.

UNITED STATES :
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

CANADA :
The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).

JAPAN
All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical
Substances and are listed on the Existing and New Chemical Substances list (ENCS).
16. OTHER INFORMATION

LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 3


R10 - Flammable.
R20 - Harmful by inhalation.
R22 - Harmful if swallowed.
R34 - Causes burns.
R36/37/38 - Irritating to eyes, respiratory system and skin.
R40 - Limited evidence of a carcinogenic effect.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 - Harmful: may cause lung damage if swallowed.
R66 - Repeated exposure may cause skin dryness or cracking.
R67 - Vapours may cause drowsiness and dizziness.
- REVISED INFORMATION: section(s):
-8

This product material safety data sheet provides health and safety information. The product is to be used in
applications consistent with our product literature. Individuals handling this product should be informed of the
recommended safety precautions and should have access to this information. For any other uses, exposures
should be evaluated so that appropriate handling practices and training programs can be established to insure
safe workplace operations. Please consult your local sales representative for any further information.

EMERGENCY TELEPHONE NUMBER(S)

Trans-European +32-(0)3-575-5555
Belgium / Luxembourg +32-(0)3-575-0330
Bulgaria +359 (0)2-946-16-06
Croatia +385 (0)91-1-25-75-23
Czech Republic +420-602-669421
Denmark +47-22-33-69-99
Finland +358-(0)9-471 977
France / French Switzerland +33-(0)6-11-07-32-81
Germany / Austria / German Switzerland +49-(0)6232-130128
Hungary +36-30-9-506-447

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
14 / 15
SAFETY DATA SHEET
PRODUCT

NALCO® EC1021A

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

Italy / Italian Switzerland +39-333-210-7947


Latvia +32-(0)3-575-5555 & Local emergency telephone number 112
The Netherlands +32-(0)3-575-0330
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626 (SGS) / +48(0)14 637 40 81 (SPOT)
Portugal +351-91-911-1399
Romania +40-744 -34-14-53
Russia / Belarus +7-812-449-0474
Saudi Arabia +966-(3)847-1515
Serbia +32-(0)3-575-5555
Slovak Republic +421-(0)905-585-938
Slovenia +386-41-634-916
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
UK and Republic of Ireland +44-(0)7071-223-738
Nalfleet International +32-(0)3-575-5555

POISON CONTROL CENTER TELEPHONE NUMBERS

Belgium +32-70-245245
Czech Republic +420 224 91 92 93
France +33-(0)145-42-59-59 ORFILA
Hungary +36-80-201-199 (ETTSZ, 1096 Budapest, Nagyvárad tér 2)
Latvia + 371 67042473
Slovak Republic +421 (0)2 5477 4166

Prepared By : SHE Department


Date issued : 23.11.2010
Version Number : 2.21

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1 tenth
and 0.001 = 1 thousandth

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
15 / 15