Ionic Equilibrium

ABOUT EDUCATORS

DR. SHARAD KOTHARI

• MSc., PhD, NET, JRF
• 18 year experience of IIT JEE in Organic Chemistry
• Ex. Senior Faculty of Vibrant Academy, Kota and Bansal Classes, Kota

PIYUSH MAHESHWARI
• BE (Hons.)
• 11 year experience of IIT JEE in InorganicChemistry
• Author of 'Super Problems in Inorganic Chemistry',
• Ex. HOD Bansal Classes, Kota
• Ex. Senior Faculty of Vibrant Academy, Kota and Allen Career Institute, Kota

BRIJESH JINDAL
• BTech Jaipur MNIT
• 11 year experience of IIT JEE in Physical Chemistry
• Ex. Senior Faculty of Vibrant Academy, Kota, Allen Career Institute, Kota and Bansal
Classes, Kota
 IONIC EQUILIBRIUM

EXERCISE-1 (Subjective Questions)

r ts
Calculate the number of H p
r t sIonization Constants and pH
e in one ml of solution whose pH is 13. yEx pe
Q.1
E x +
present
tr changes from 298 K
y
Calculate changerin i s
st K (298) = 10 K (310) = 2.56 × 10 . hem
Q.2 +
concentration of H ion in one litre of water, when temperature
to 310 K. i
m Given –14 –14

e C
w w

Q.3 h
C(i) K for H O is 9.62 × 10 at 60°C. What is pH of water at 60°C.
–14
w 2
(ii) What is the nature of solution at 60°C whose
(a) pH = 6.7 (b) pH = 6.35
ts r ts
p er –14
p e
x
Q.4 The value of K at the physiological temperature (37°C) is 2.56 × 10 . What is the pH at the neutral
x
w
point of water at this temperature?

yE solutions : r y E
Calculate pHtof
s r i s t
(a) 0.1 MiHCl
Q.5 following

e m h e m
Ch(c)(d) 0.110 MMNHHClOH (K = 1.8 × 10 )
(b) 0.1 M CH COOH (K = 1.8 × 10 ) –5

–8
3
4 b
a
–5
C
(e) 10–10 M NaOH
(f) 10–8 M CH3COOH (Ka= 1.8 × 10–5)

r ts
(g) Decimolar solution of Baryta [Ba(OH)2], diluted 100 times.
ts
e r
xp pe
(h) 10–3 mole of KOH dissolved in 100 L of water.

E x
(i) equal volume of HCl solution (pH = 4) + 0.0019 N HCl solution

r y
(j) 10–7 M NaOH
t y E
Calculatei:s s tr
(a)emK for a monobasic acid whose 0.10 M solution has pH ofm 4.50.i
Q.6

Ch(b) K for a monoacidic base whose 0.10 M solutionChasha pHe of 10.50.

a
b

Q.7 Calculate the ratio of degree of dissociation (  ) when 1 M acetic acid solution is diluted to 100
2 1
times. [Given Ka=10–5]

Q.8
t s
Calculate the ratio of degree of dissociation of acetic acid and hydrocyanic acid (HCN) in 1 M their
r
pe
respective solution of acids.[Given K a ( CH COOH)  1.8 105 ; K a ( HCN)  6.2 1010 ]
x 3

ts
r y E e r
Q.9
is t
pH of a dilute solution of HCl is 6.95. Calculate molarity of HCl solution.
p
x = 10 .
Q.10 The m
e r y E –5

t
pH of aqueous solution of ammonia is 12. Find molarity of solution. K (NH OH)
h is K of weak acid.
b 4

C The solution of weak monoprotic acid which is 0.01 M has pHe=m

Q.11 3. Calculate a

Q.12 Boric acid is a weak monobasic acid. It ionizes in waterC as h

B(OH)3 + H2O B(OH ) 4 + H+ : Ka = 5.9 × 10–10
Calculate pH of 0.3 M boric acid. Page # 1
 IONIC EQUILIBRIUM
Q.13 Will the pH of water be same at 4°C and 25°C ? Explain.

r ts
er ts
Mixture of two or more acids / bases
x pe
p
Q.14 Calculate pH of following solutions :
E
x try
(a) 0.08 M H2SO4 (50 ml) + 0.04 M HCl 50 (ml)
E s
try i
(b) 0.1 M HA + 0.1 M HB [ Ka (HA) = 2 × 10–5 ; Ka (HB) = 4 × 10–5 ]

Q.15 Calculate i
h m
[Hs ] and [CHCl COO ] in a solution that is 0.01 M ineHCl
m
+  and 0.01 M in CHCl COOH.

h e(K = 2.55 × 10 ).
Take –2
2
C
2

C
a

+ – –
Q.16 Calculate [H ], [CH COO ] and [ C H O ] in a solution that is 0.02 M in acetic acid and 0.01M
3 5 2 7
in benzoic acid. Ka(acetic) = 1.8 × 10 , Ka (benzoic) = 6.4 × 10–5.
–5

ts r t s
p e r Polyprotic acids & bases
p e
x
Q.17 What are the concentration of +
2 2 4
E x
2

H , H C O , HC O and C O in a 0.1 M solution of oxalic
4 acid ? 2
2
4
[K = 10 and K E
–2

ry = 10 ] –5

tr y
t s
1 2

s
Q.18 What areithe concentrations of H , HSO , SO and H SO in a 0.20
m i
h e m +

he  2
M solution of sulphuric acid ?
4 4 2 4

C Given : H SO  H +
2 4
+
; strong HSO 4 C
HSO 4 H+ + SO 24  ; K2 = 10–2 M

r t s Hydrolysis
ts
p
 e of a 0.08 M solution of CH COONa. [K (CH COOH)=1.8 ×r10
e 5

x
Q.19 What is the OH concentration ]

Q.20 Calculate the pHyofE x p 3 a 3

t r a 0.1 M solution of NH Cl. [K (NH ) = 10 ]

r y E 5

is t
4 b 3

m M solution of pyridinium chloride C H N Cl was found to have ia s

e C H N?


m
Q.21 0.252 +
pH of 2.699. What is K for
h e
5 6 b

C h
pyridine, 5 5

Q.22 Calculate the extent of hydrolysis & the pH of 0.02 M CHC COONH . 3 4
[Kb (NH3)= 1.8 × 105, Ka(CH3COOH)=1.8 × 105]

Calculate the pH of 1.0 ×10–3 M sodium phenolate, (NaOC6H5). Ka for HOC6H5 is 1.05 × 10–10.
s
Q.23

r t
Q.24
x pe
Calculate the percent hydrolysis in a 0.06 M solution of KCN. [Ka(HCN) = 6 × 1010]
ts
r y E e r
p
–10

t
Q.25 Calculate the percent hydrolysis in a 0.0100 M solution of KCN.(K = 6.2 ×10 )
s x
a

Q.26 The acidiionization (hydrolysis) constant of Zn is 1.0 × 10 E

h m
(a)e Calculate the pH of a 0.001 M solution of ZnCl tr y 2+ –9

C (b) What is the basic dissociation constant of Zn(OH) ? emis

2
+

Q.27 Equal volume of 0.2 M CH COOH is mixed with 0.2 N NaOH

3
–5 C h solution then find the pH of resultant
solution [K (CH COOH)=10 ]
a 3

Page # 2
 IONIC EQUILIBRIUM
Buffer solution

r ts
ts pe
Q.28 Determine [OH–] of a 0.050 M solution of ammonia to which sufficient NH4Cl has been added to make

er
the total [ NH 4 ] equal to 0.100.[ K b ( NH3 ) =1.8 × 10–5]
p x
x prepared by mixing 50.0 mL of 0.200 M CHtrCOOH E
y and 50.0 mL of
r yK E i s
i s t
Q.29 Calculate the pH of a solution

e m
3

h
–5

m
0.100 M NaOH.[ =1.8 × 10 ]
a ( CH3COOH)

e C
Chbuffer of pH 9.26 is made by dissolving x moles of ammonium sulphate and 0.1 mole of ammonia into
Q.30 A
100 mL solution. If pKb of ammonia is 4.74, calculate value of x.

Q.31
s
50 mL of 0.1 M NaOH is added to 75 mL of 0.1 M NH4Cl to make a basic buffer. If pKa of NH 4 is
t r ts
9.26, calculate pH.
x p er x pe
Q.32
y Ethe pH of a 0.2 M solution of pyridine C H N . K = 1.5t×r10y E
(a) r
Determine
i 5
is of the equilibrium. Will
st the effect of addition of pyridinium ion C H NH on themposition 5 b
9

m e
(b) Predict +

e h
5 5

Ch(c)C H NHCalculate
the pH be raised or lowered ?

5 5
+
C
the pH of 1.0 L of 0.10 M pyridine solution
Cl, has been added, assuming no change in volume.
to which 0.3 mol of pyridinium chloride

Q.33 Calculate the pH of a solution which results from the mixing of 50.0 ml of 0.3 M HCl with 50.0 ml of

r ts
0.4 M NH3 . [Kb (NH3) = 1.8 × 105]
t s
e r
[ K (NH ) = 1.8 E
xp made by mixing 50.0 ml of 0.2M NH Cl & 75.0 ml of 0.1xpMeNaOH.
Q.34 Calculate the pH of a solution 4
b 3
tr y × 10 ] 5

y E
i s i s tr
e m Acid Base reactions & titrations
m
h e
Q.35 Calculate –
OH concentration at the equivalent point when a solution of 0.1 M acetic acid is titrated with
C Ch
a solution of 0.1 M NaOH. K for the acid = 1.9 × 10 . –5
a

Q.36 Calculate the hydronium ion concentration and pH at the equivalence point in the reaction of 22.0 mL of
0.10M acetic acid, CH3COOH, with 22.0 mL of 0.10 M NaOH. [Ka = 1.8 × 10–5]

Q.37
t s
Calculate the hydronium ion concentration and the pH at the equivalence point in a titration of 50.0 mL
r
e
of 0.40 M NH3 with 0.40M HCl.[Kb = 1.8 × 10–5]
p
E x r ts of
3

tr y 25 ml, 40 ml, 50 ml of NaOH. K of CH COOH is 2 × 10 . pe

Q.38 CH COOH (50 ml, 0.1 M) is titrated against 0.1 M NaOH solution. Calculate the pH at the addition

ibases (50.0mL) was titrated with 0.1 M HCl. The pH of the solutionyEafterxthe addition of
0 ml, 10 ml, 20 ml, –5
a 3

h e m
Q.39 A weak
tr
C the equivalence point. i s
10.0 mL and 25.0 mL were found to be 9.84 and 9.24, respectively. Calculate K of the base and pH at

em
b

Q.40 A weak acid (50.0mL) was titrated with 0.1 M NaOH. The
h
C pH values when 10.0 mL and 25.0 mL of
base have been added are found to be 4.16 and 4.76, respectively. Calculate K of the acid and pH at
a
the equivalence point.
Page # 3
 IONIC EQUILIBRIUM
Q.41 What will be the resultant pH when 200 ml of an aqueous solution of HCl (pH = 2.0) is mixed with
300 ml of an aqueous solution of NaOH (pH = 12.0) ?
r ts
r t s p e
Calculate the degree ofe dissociation of acetic acid in the resulting solution and pHx
Q.42 500 ml of 0.2 M aqueous solution of acetic acid is mixed with 500 mL of 0.2 M HCl at 25°C.
(a)
If 6 g of NaOH isx p r E of the solution.
ythere is no change in
(b)

r yE added to the above solution, determine final pH. Assume

i s t
t
volume on mixing. K of acetic acid is 1.75 × 10 M. (log (1.75) = –5
0.243)
s Solubility & solubility product's em
a

m i heach equal to 4.0×10 . Which salt is

h e
Q.43 The values of K for the slightly soluble salts MX and QX are
sp
C 2
–18

C more soluble? Explain your answer fully.

Q.44 The solubility of PbSO in water is 0.038 g/L. Calculate the solubility product of PbSO .
4 4
Q.45 How many mol CuI (Ksp = 5 × 10–12) will dissolve in 1.0 L of 0.10 M NaI solution ?

ts r ts
r pe
Q.46 A solution of saturated CaF2 is found to contain 4.1 × 10–4 M fluoride ion. Calculate the Ksp of CaF2.
Neglect hydrolysis.
p e x
E x y E
The solubility of ML2 (formula weight, 60 g/mol) in water is 2.4 × 10–5 g/100 mL solution. Calculate the
r
Q.47
r y t
t (in mol/L) of Fe(OH) in a solution of pH = 8.0m? [Kisfor Fe(OH) = 1.0 × 10 ]
solubility product constant for ML2.
i ssolubility
m e
Q.48 What is the –36

e h
3 sp 3

h
Q.49 Calculate
C A X , [K = 1.1 × 10 ]
2 3 sp
–23
2 3
C
the solubility of A X in pure water, assuming that neither kind of ion reacts with water. For

Q.50 Determine the solubility of AgCl in 0.1 M BaCl2. [Ksp for AgCl = 1 × 10–10]
Q.51

r ts
What mass of Pb2+ ion is left in solution when 50.0 mL of 0.20M Pb(NO3)2 is added to 50.0 mL of
1.5 M NaCl ?[Given Ksp for PbCl2 = 1.7 ×10–4]
ts
p e e r
of the solution is [K =x p
2+
Q.52 A solution has a Mg concentration of 0.0010 mol/L. Will Mg(OH) precipitate if the OH concentration –

E (b) 10 mol/L ? x
2

(a) 10 mol/Lry
1.2 × 10 ] –11

st of Pb(OH) in water is 6.7 × 10 M. Calculate the solubility

–5
sp
–3

r E
yPb(OH) in a buffer
i
mof pH = 8.
Q.53 The solubility
i s t6 of

h e
solution
2

e m
2

C Simultaneous Solubility h
Q.54 C
Calculate the Simultaneous solubility of AgSCN and AgBr. Ksp (AgSCN) = 1.1 × 10–12,
Ksp(AgBr) = 5 × 10–13.

Q.55
Ksp(SrF2) = 4 × 10–9.
r ts
Calculate F– in a solution saturated with respect of both MgF2 and SrF2. Ksp(MgF2)= 9.5 × 10 –9,

x pe complexation equilibria ts
r E r
y of the complexation of SCN with Fe led of 130, 16, and 1.0 forpeK , K , and
t
s What is the overall formation constant of Fe(SCN) from its E
Q.56 A recent investigation
i
–

x ions, and
3+
1 2

h m
K , respectively.
e
3

t r yof these data ?

what is the dissociation constant of Fe(SCN) into its simplest ions on the basis
component 3

is
3

C How much AgBr could dissolve in 1.0 L of 0.40 M NH ? Assumeem

Q.57 that Ag(NH ) is the only complex +

formed.[K ( Ag( NH ) ) = 1 ×10 ; K (AgBr) = 5 ×10 h

3 3 2

f

3 2
8
C] sp
–13

Page # 4
 IONIC EQUILIBRIUM

EXERCISE-2 (Objective Questions)

r ts
s pe
Single correct
The conjugate acid of NH 2 is
r t
e (D) N H Ex
Q.1
(A) NH3
x p
(B) NH2OH (C) NH 

r y
E t
4 2 4

tr y amphiprotic species are i s

I HPO is H PO emIV
Q.2 Out of the following,

(A) I, m (C) III and IVh

2– II OH – III HCO – –

e
3 2 4 3

h
III, IV (B) I and III
C (D) All

Q.3 CpH of an aqeous solution of NaCl at 85°C should be

(A) 7 (B) > 7 (C) < 7 (D) 0

Q.4
ts
1 cc of 0.1 N HCl is added to 99 cc solution of NaCl. The pH of the resulting solution will be
r ts
(A) 7
x p
(B) 3
er (C) 4 (D) 1
x pe
y E r y E
Q.5
st
10 ml of
M
r H2SO4 is mixed with 40 ml of
M
i s t
H SO . The pH of the resulting solution is

m i
(A) 1
200
(B) 2
200 2 4
(C) 2.3
e m
(D) none of these

Q.6 h
e h
C If pK for fluoride ion at 25° C is 10, the ionisation constant ofChydrofluoric acid in water at this temperature
is :
b

(A) 1.74 × 10-5 (B) 3.52 × 10-3 (C) 10-4 (D) 5.38 × 10-2

Q.7
r ts
The pH of an aqueous solution of 1.0 M solution of a weak monoprotic acid which is 1% ionised is
ts
e r
xp pe
(A) 1 (B) 2 (C) 3 (D) 11

ryE E x
st y
Q.8 Which of the following solution will have pH close to 1.0?

i(A) 100 ml of M/100 HCl + 100 ml of M/10 NaOH

i s tr
em (B) 55 ml of M/10 HCl + 45 ml of M/10 NaOH
m
Ch e
(C) 10 ml of M/10 HCl + 90 ml of M/10 NaOH
(D) 75 ml of M/5 HCl + 25 ml of M/5 NaOH
Ch
Q.9 A solution with pH 2.0 is more acidic than the one with pH 6.0 by a factor of:
(A) 3 (B) 4 (C) 3000 (D) 10000

Q.10
r t s
The first and second dissociation constants of an acid H2A are 1.0 × 10–5 and 5.0 × 10–10 respectively.

(A) 5.0 ×10–5

x pe
The overall dissociation constant of the acid will be :
(B) 5.0 ×1015 (C) 5.0 ×10–15 (D) 0.2 ×105
ts
r E
y contains 0.01 M RNH (K = 2 ×10 ) & 10 M NaOH. pe
Q.11 An aqueoustsolution
r
is of OH¯ is nearly : x
–6 –4

m
e2.414 ×10 (B) 10 M
The concentration
2 b

r y E
C h(A) –4 –4 (C) 1.414 × 10
i s t
–4
(D) 2 × 10 –4

Q.12 The degree of hydrolysis of a salt of weak acid and weak base ine
h m0.1 M solution is found to be 50%.
it’s

(B) 50%
C
If the molarity of the solution is 0.2 M, the percentage hydrolysis of the salt should be
(A) 100% (C) 25% (D) 10%

Page # 5
 IONIC EQUILIBRIUM
Q.13 What is the percentage hydrolysis of NaCN in N/80 solution when the dissociation constant for HCN is
1.3 × 10–9 and Kw = 1.0 × 10–14
r ts
(A) 2.48
r
(B) 5.26
e ts (C) 8.2 (D) 9.6
x pe
Q.14 The compound whose 0.1 M
x p solution is basic is
r yE
r y
(A) Ammonium acetateE (B) Ammonium chloride
i s t
i
(C) Ammonium
s t sulphate (D) Sodium acetate
e m
Q.15 Thee »m C h with 0.1 N HCl is
h1
C(A)
pH of the neutralisation point of 0.1 N ammonium hydroxide
(B) 6 (C) 7 (D) 9

Q.16 If equilibrium constant of

CH3COOH + H2O
t
CH3COO– + H3O+
s r ts
r pe
is 1.8 × 10–5, equilibrium constant for
CH3COOH + OH–
p e CH3COO– + H2O is
(D) 5.55 × 10x
(A) 1.8 ×10–9
E x (B) 1.8 × 109 (C) 5.55 × 10–9
y E 10

r
Q.17 The pK of atweak s r
y acid, HA, is 4.80. The pK of a weak base, BOH, isi4.78.
t The pH of an aqueous
a
s
i the corresponding salt, BA, will be : b
m(D) 9.22
h e m
solution of
h e
C
(A) 8.58 (B) 4.79 (C) 7.01
C –4
Q.18 If 40 ml of 0.2 M KOH is added to 160 ml of 0.1 M HCOOH [K = 2×10 ], the pOH of the resulting
a
solution is
(A) 3.4 (B) 3.7
s
(C) 7 (D) 10.3

er t ts
Q.19
xp
1 M NaCl and 1M HCl are present in an aqueous solution. The solution is
per
r y E
(A) not a buffer solution and with pH < 7
E x
y
(B) not a buffer solution with pH > 7

i st
(C) a buffer solution with pH < 7
i s tr
e m
(D) a buffer solution with pH > 7
m
h
C the acid is ionized is : h e
Q.20 The pK

(A) 4.5
of
a a weak acid (HA) is

(B) 2.5
4.5. The pOH of an
C
aqueous

(C) 9.5
buffered solution of HA in which 50% of

(D) 7.0

Q.21 The solubility of A2X3 is y mol dm–3. Its solubility product is

(A) 6 y2
r
(B) 64 y4
ts (C) 36 y5 (D) 108 y5

p e
Q.22
x
If Ksp for HgSO4 is 6.4 ×10–5, then solubility of this substance in mole per m3 is
E r ts
(A) 8 ×10–3
tr y (B) 6.4 ×10–5 (C) 8 × 10–6 (D) None of these
pe
Q.23
mis yE x
The solubility of a sparingly soluble salt AB2 in water is 1.0 × 10–5 mol L–1. Its solubility product is:

he (A) 10–15 (B) 10–10 (C) 4 × 10–15

i s tr (D) 4 × 10–10
C
Q.24 Which of the following is most soluble in water?
em
(B) ZnS (Kh= 7×10 )
(D) Ag C
(A) MnS (K = 8×10 ) –37 –16
sp sp
(C) Bi S (K = 1×10 ) –72 (PO ) (K = 1.8×10 ) –18
2 3 sp 3 4 sp

Page # 6
 IONIC EQUILIBRIUM
Q.25 When equal volumes of the following solutions are mixed, precipitation of AgCl (Ksp = 1.8 × 10–10) will
occur only with:
r ts
r
(A) 10–4 M (Ag+) and 10–4 M (Cl¯ )
e ts (B) 10–5 M (Ag+) and 10–5 M (Cl¯ )
x pe
x p
(C) 10–6 M (Ag+) and 10–6 M (Cl¯ )
E
(D) 10–10 M (Ag+) and 10–10 M (Cl¯ )

(K = 1.7 × 10 ) is obtained when equal volumes oftr

y
(A) 10 M Catry
Q.26 The precipitate of CaF E 2 sp
(B) 10 M Ca + 10 iM
–10
sF the following are mixed

i sCa + 10 M F +m
–4 2+
+ 10 M F –4 – –2 2+ –3 –

(D) 10 M Ca e
m
(C) 10 M
e
–5 2+ –3 –

C h 10 M F –3 2+ –5 –

h
C[Ag ] in resultant solution is : [Given : K (AgBr) = 5 × 10 ]
Q.27 50 –5
litre of a solution containing 10 mole of AgNO is mixed with 50 litre of a 2 × 10 M HBr solution.
+
3
–13
–7

sp
(A) 10–5 M (B) 10–6 M (C) 10–7 M (D) None of these

ts r ts
r pe
Q.28 Solid Ba(NO3)2 is gradually dissolved in a 1.0 × 10–4 M Na2CO3 solution. At what concentration of Ba2+

p e
will a precipitate begin to form ? (Ksp for BaCO3 = 5.1 × 10–9)
x
(A) 4.1 × 10–5 M
x (B) 5.1 × 10–5 M (C) 8.1 × 10–8 M
E of MX is S mol/litre is related by : y E
(D) 8.1 × 10–7 M

Q.29 K of MX t r ysolubility t r
isS = [K /128]
sp
i s /256] (B) S = [128 K ] (C) S = [256 K ] m(D)
and 4 4

m
(A) S = [K
e SP
1/5
SP
h e 1/4
SP
1/5
SP
1/4

Q.30 h
The pH of 0.1 M solution of the following salts increases inC
C (A) NaCl < NH Cl < NaCN < HCl
4
the order
(B) HCl < NH Cl < NaCl < NaCN 4
(C) NaCN < NH4Cl < NaCl < HCl (D) HCl < NaCl < NaCN < NH4Cl

Q.31
r ts
An aqueous solution of 6.3 g oxalic acid dihydrate is made up to 250 mL. The volume of 0.1 N NaOH
ts
e r
xp pe
required to completely neutralise 10 mL of this solution is
(A) 40 mL

r y E (B) 20 mL (C) 10 mL (D) 4 mL

E x
Q.32 For sparinglytsoluble salt ApBq, the relationship of its solubility product (Ls) withyits solubility (S) is
s
(A) Ls =iS , p . q (B) Ls = S , p . q (C) Ls = S , p . q
i s tr
e m p+q p q p+q p p

m
(D) pq
Ls = S , (p.q) p q pq p+q

ChMnS,
Q.33 A solution which is 10 M each in Mn , Fe , Zn and Hg ish
–3
–15
2+
–23
FeS, ZnS and HgS are 10 , 10 , 10 and 10 respectively, C
2+e with 10 M sulphide ion. If K ,
treated
–20
2+
–54
2+

which one will precipitate first ?

–16
sp

(A) FeS (B) MnS (C) HgS (D) ZnS

More than one may be correct

r ts
Q.34 Which of the following statement(s) is/are correct ?

pe
(A) the pH of 1.0 × 10-8 M solution of HCl is 8
x
(B) the conjugate base of H2PO4- is HPO42-
ts
yE r
r pe
(C) autoprotolysis constant of water increases with temperature

is t x
(D) when a solution of a weak monoprotic acid is titrated against a strong base, at half-neutralization

m
point pH = (1/2) pKa .
e ryE
h
C Which of the following is true for alkaline aqueous solution? emis
Q.35
t
(A) pH >
pk w
2
(B) pH > pOH (C) pOH C< h (D) pH < pOH pk w
2
s

Page # 7
 IONIC EQUILIBRIUM
Q.36 A buffer solution can be prepared from a mixture of
(A) sodium acetate and acetic acid in water
r ts
e r t s
(B) sodium acetate and hydrochloric acid in water
x pe
x p
(C) ammonia and ammonium chloride in water
(D) ammonia and sodium hydroxide in water.
r y E
r E
ytype questions i s t
i
Assertion & Reasoningt
s : pH of 10 M NaOH solution exists between e m
e m
Q.37 Statement-1 –7

C h 7 to 7.3 at 25°C.

C(A) h
Statement-2 : Due to common ion effect ionization of water is reduced.
Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.

ts
(D) Statement-1 is false, statement-2 is true.
r ts
p er p e
Q.38 Statement-1 :
xMoles of Sr 2+
furnished by sparingly soluble substance
E
Sr(OH) x due
decreases

r y E to dilution in its saturated solution. tr y 2

Statement-2t :
i s i s by dilution.
m
Solubility product constant of Sr(OH) is not affected
m e
2

h e
(A) Statement-1
h
is true, statement-2 is true and statement-2 is correct
C
explanation for statement-1.

C (C) Statement-1 is true, statement-2 is false.

(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.

(D) Statement-1 is false, statement-2 is true.

Comprehension
r ts ts
e r
xp pe
Paragraph for Question Nos. 39 to 41

ryE E x
1.2 g of a monoprotic acid HA, is titrated with 0.222 M NaOH solution. The pH of the solution is

i st try
monitored with pH meter. A portion of the titration curve is shown in the diagram.

em Expanded titration
i s
m
Ch e
12.00 curve of

Ch
11.00 HA vs NaOH
10.00

pH 9.00
8.00
7.00

r ts
6.00

pe
5.00

x s
15 16 17 18 19 20

y E Volume of NaOH (mL)

e r t
s trof NaOH is required to bring about the titration to its equivalence point p
x
(A) 4.00i
Q.39 How many mL ?

e m (B) 9.00 (C) 19.00

r y E
(D) None of these
h
C (A) i s t
em (D) 5.00
Q.40 What is the pH of solution at the equivalence point ?
3.50 (B) 7.00 (C) 8.40
C h
Q.41 What is the molar mass of HA ?
(A) 180 (B) 222 (C) 284 (D) None of these
Page # 8
 IONIC EQUILIBRIUM
Match the column
Q.42 Column I Column II
r ts
r ts
e (strong diacidic base)
(At 25°C)
xpH ~ 3.7 pe

x p r E
y 
(A)
 + yE
 10 litre of 0.03

r
N X(OH) 2

i s t (P)

 is

5 t
litre of 0.08 M HNO
em
em +
3

C h
Ch 
 485 litre of 0.01 M NaNO
3

(B)  10 ml of 0.5 M RNH3Cl (Kh = 10–9) (Q) pH ~

 111


+
ts r ts
r pe
 40 ml of 0.125 M KOH

p e xpH ~ 7

x E
E try
100 ml of 0.8 M HCO3
(C) 
r
 y s
(R)

i s100t ml of 0.4 M CO
+
i
em 

2

h em
Ch = 4C
3


(for H CO , use2 3
K a1 = 4 × 10–7 & K a 2 –11
× 10 )


(D) Saturated aqueous solution of Co(OH)3 (Ksp = 2.7 × 10–43) (S) pH ~

 10

r ts ts
e r
E xp x pe
ry yE
i st i s tr
em m
Ch Ch
e

r ts
xpe ts
yE r
is tr x pe
em ryE
C h i s t
hem
C
Page # 9
 IONIC EQUILIBRIUM

r ts
e r t sEXERCISE-1 xpe
Q.1 ×107
(i) 6.51 ; (ii) (a) Basic , x
6.022
p Q.2 0.6 ×10 –7

r E
y ] = 6.18 ×10 ;
Q.3
y E (b) Acidic Q.4 6.81
i s t
pH = 7.209str
Q.5 (a) +1, (b) 2.87, (c) 11.13 (d) 6.97, (e) 7, (f) 6.97, (g) 11.30 (h) 9 , (i) 3, (j)+[H –8

i e m
h2.31×10 M
Q.6
Q.8
h e m
( a )
170.4
K =
a
10 ,
–8
(b) K b
= 10–6

C
Q.9
Q . 7
–8
1 0

Q.10C10.01 M Q.11 1.11 × 10 –4

Q.12 4.87 Q.13 No it will be > 7

Q.14 (a) 1 , (b) 2.61
Q.15
s
[H+] =1.612 × 102M, [CHCl2COO–] = 6.126 × 10–3M
t r ts
Q.16
Q.17
x p er
[H+] = 103M, [CH3COO] = 3.6 × 104M, [C7H5O2] = 6.4 × 104M
0.027 M, 0.073 M, 0.027 M, 10–5 M
x pe
Q.18 0.2091 M, 0.1909 M, 0.0091 M, 0
E
E try
Q.19 [OH] = 6.664 × 106 Q.20 pH = 5
ry s
st
10

i
Q.21 Kb = 6.25 × 10 Q.22 0.56%, pH = 7
Q.23
mi pH = 10.42
em
Q.24 1.667%
Q.25
e 4.0%
h
Q.26 (a) 6, (b) 1 × 10–5

Ch C
Q.27 9 Q.28 [OH–] = 9.0 ×10–6
Q.29 4.74 Q.30 0.05 mol
Q.31 9.56
Q.32 (a) pH = 9.239 (b) lowered (c) pH = 4.699
Q.33 8.7782
r ts Q.34 9.7324
ts
e r
Q.35 5.12 ×10 M –6 Q.36 8.71
Q.37 4.98
E xp x pe
Q.38
ry
(i) 2.85, (ii) 4.0969, (iii) 4.5229, (iv) 4.699, (v) 5.301, (vi) 8.699

yE
st
Kb = 1.8 × 10–5, 5.27
r
Q.39 Q.40 8.73
Q.41
mipH = 11.3010
i s t
Q.42 (a) 0.0175%, pH = 1 , (b) 4.757
Q.43
e QX2 is more soluble
m
Q.44 1.6 × 10–8

Ch Ch
e
Q.45 +
[Cu ] = 5 × 10 M –11 Q.46 3.4 × 10–11
Q.47 2.6 ×10–16 Q.48 1.0 × 10–18 M
Q.49 1.0×10–5 mol/lit Q.50 5 × 10–10 M
Q.51 12 mg
Q.52 (a) no precipitation will occur, (b) a precipitate will form
Q.53 s = 1.203 × 10-3M
r ts
pe
Q.54 4 × 10–7mol/L AgBr, 9 × 10–7 mol/L AgSCN
Q.56 Kd = 1/Kf = 4.8 × 10–4
x
Q.55 [F–] = 3 × 10–3M
Q.57 2.8 × 10 M–3
E r ts
tr y EXERCISE-2
pe
mis E x Q.7
y Q.14
Q.1
he A Q.2 C Q.3 C Q.4 B Q.5

i s
B
tr Q.6 C B

C
Q.8
Q.15
D
B
Q.9
Q.16 B
D Q.10 C
Q.17 C
Q.11 D
Q.18 D
Q.12

e
Q.19
m
B
A
Q.13
Q.20
Q.21
A
C
D
D
Q.22
Q.29
D
A
Q.23 C
Q.30 B
Q.24 D
Q.31 A
Q.25 A
Q.32 A C h
Q.26
Q.33
B
C
Q.27
Q.28
Q.34
Q.35
C
BC
B
ABC
Q.36 ABC Q.37 A Q.38 D Q.39 C Q.40 C Q.41 C
Q.42 (A) P, (B) Q, (C) S, (D) R
Page # 10