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1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture : Sealant
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Response:
P304 + P340 + P312 IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON
CENTER or doctor/ physician if you feel unwell.
P362 + P364 Take off contaminated clothing and wash it be-
fore reuse.
Storage:
P410 + P412 Protect from sunlight. Do not expose to tempera-
tures exceeding 50 °C/ 122 °F.
Additional Labelling:
EUH204 Contains isocyanates. May produce an allergic reaction.
Hazardous components
Chemical Name CAS-No. Classification Classification Concentration
EC-No. (67/548/EEC) (1272/2008/EC) [%]
Registration
number
Diphenylmethanediiso- 9016-87-9 Xn; R20-R48/20 Acute Tox. 4; H332 >= 40 - < 45
cyanate, isomeres and Xi; R36/37/38 Skin Irrit. 2; H315
homologues Carc.Cat.3; R40 Eye Irrit. 2; H319
R42/43 Resp. Sens. 1; H334
Skin Sens. 1; H317
Carc. 2; H351
STOT SE 3; H335
STOT RE 2; H373
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
4,4'-methylenediphenyl 101-68-8 Carc.Cat.3; R40 Acute Tox. 4; H332 >= 0,1 - < 0,2
diisocyanate 202-966-0 Xn; R20-R48/20 Skin Irrit. 2; H315
Xi; R36/37/38 Eye Irrit. 2; H319
R42/43 Resp. Sens. 1; H334
Skin Sens. 1; H317
Carc. 2; H351
STOT SE 3; H335
STOT RE 2; H373
For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
If inhaled : If breathed in, move person into fresh air. Call a physician imme-
diately. Keep patient warm and at rest. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen.
In case of skin contact : Call a physician immediately. In case of contact, immediately flush
skin with soap and plenty of water. Do NOT use solvents or thinners.
Wash off with polyethylene glycol and afterwards with plenty of wa-
ter.
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
In case of eye contact : Protect unharmed eye. If easy to do, remove contact lens, if worn. In
the case of contact with eyes, rinse immediately with plenty of water
and seek medical advice.
If swallowed : If swallowed, seek medical advice immediately and show this con-
tainer or label. If swallowed, DO NOT induce vomiting. If a person
vomits when lying on his back, place him in the recovery position.
4.2 Most important symptoms and effects, both acute and delayed
No data available
4.3 Indication of any immediate medical attention and special treatment needed
No data available
Further information : Standard procedure for chemical fires. Use extinguishing measures
that are appropriate to local circumstances and the surrounding envi-
ronment. In the event of fire and/or explosion do not breathe fumes.
Use water spray to cool unopened containers. Collect contaminated
fire extinguishing water separately. This must not be discharged into
drains. Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations. If the tempera-
ture rises there is danger of the vessels bursting due to the high
vapor pressure.
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Advice on protection against fire : Normal measures for preventive fire protection. Vapours are heavier
and explosion than air and may spread along floors. Vapours may form explosive
mixtures with air. Keep away from heat and sources of ignition. Do
not smoke. No sparking tools should be used. Electrical equipment
should be protected to the appropriate standard.
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SAFETY DATA SHEET
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Keep away from food, drink and animal feedingstuffs. Never allow
product to get in contact with water during storage. Do not store to-
gether with oxidizing and self-igniting products.
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
dimethyl ether 115-10-6 TWA: 1.920 mg/m3, 1.000 ppm 2000/39/EC 2009-12-19
Hand protection
Material : Polyethylene
Glove thickness : 0,025 mm
Break through time: : 10 min
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Hygiene measures : Handle in accordance with good industrial hygiene and safety prac-
tice.
General industrial hygiene practice.
Do not inhale aerosol.
Avoid contact with skin, eyes and clothing.
When using do not eat, drink or smoke.
Wash hands before breaks and at the end of workday.
Follow the skin protection plan.
Take off all contaminated clothing immediately.
Wash contaminated clothing before re-use.
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according to Regulation (EC) No. 1907/2006
10.1 Reactivity
No data available
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SAFETY DATA SHEET
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Vapours may form explosive mixtures with air. Evolution of CO2 in closed containers causes overpressure and pro-
duces a risk of bursting. If the temperature rises there is danger of the vessels bursting due to the high vapor pres-
sure. Reacts violently with water.
No data available
Skin corrosion/irritation
Diphenylmethanediisocyanate, : Severe skin irritation
isomeres and homologues
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Genotoxicity in vivo:
No data available
Carcinogenicity
Remarks
Diphenylmethanediisocyanate, : Carcinogenicity:
isomeres and homologues Suspected human carcinogens
isobutane : Mutagenicity:
Tests on bacterial or mammalian cell cultures did not show mutagen-
ic effects.
Mutagenicity:
Tests on bacterial or mammalian cell cultures did not show mutagen-
ic effects.
Reproductive toxicity
isobutane : Note: No toxicity to reproduction
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
4,4'-methylenediphenyl diiso- : Note: No evidence of adverse effects on sexual function and fertility,
cyanate or on development, based on animal experiments.
Teratogenicity
No data available
4,4'-methylenediphenyl diiso- : May cause damage to organs through prolonged or repeated expo-
cyanate sure.
Aspiration hazard
Aspiration toxicity
No data available
Neurological effects
No data available
Toxicology Assessment
Toxicology, Metabolism, Distribution
No data available
Acute effects
No data available
Further information : Persons allergic to isocyanates, and particularly those suffering from
asthma or other respiratory conditions, should not work with isocya-
nates.
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
12.1 Toxicity
Toxicity to fish
4,4'-methylenediphenyl diiso- : LC0 (Oryzias latipes (Orange-red killifish)): > 3.000 mg/l
cyanate Exposure time: 96 h
4,4'-methylenediphenyl diiso- : EC50 (Daphnia magna (Water flea)): > 1.000 mg/l
cyanate Exposure time: 24 h
Method: OECD Test Guideline 202
dimethyl ether : EC50 (Daphnia magna (Water flea)): > 4,4 mg/l
Exposure time: 48 h
Toxicity to algae
Toxicity to bacteria
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according to Regulation (EC) No. 1907/2006
Biodegradability
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Classification Code : 5F
Labels : 2.1
Limited quantity : 1,00 L
Tunnel restriction code : (D)
RID
Classification Code : 5F
Hazard Identification Number : 23
Labels : 2.1
Limited quantity : 1,00 L
IMDG
Labels : 2.1
EmS Number : F-D, S-U
IATA
Packing instruction (cargo air- : 203
craft)
Packing instruction (passenger : 203
aircraft)
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
VOC : Directive 1999/13/EC
20 %
VOC content less water: 198,50 g/l
Update:
Petroleum products: (a) gaso- 2.500 t 25.000 t
lines and naphthas, (b) kero-
senes (including jet fuels), (c)
gas oils (including diesel
fuels, home heating oils and
gas oil blending streams)
National legislation
Other regulations : Take note of Dir 94/33/EC on the protection of young people at work.
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SAFETY DATA SHEET
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Take note of Dir 92/85/EEC on the safety and health at work of preg-
nant workers.
Further information : Ensure a continuous supply of fresh air during and after operation.
Persons who suffer from allergies or who have a chronic disposition
to respiratory illness must not be required to work with this material.
Reserved for industrial and professional use.
Other information
Apppendix 4 Oxygen Depleting Substances
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specifi-
cation. The information relates only to the specific material designated and may not be valid for such material
used in combination with any other materials or in any process, unless specified in the text.
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