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Article history: Field, petrographic, and geochemical characterization along with U-Pb zircon geochronology of the
Received 21 February 2017 Jurassic plutons exposed in the Upper Magdalena Valley (Colombia) allowed recognizing distinct western
Received in revised form and eastern suites formed in at least three magmatic pulses. The western plutons crop out between the
8 October 2017
eastern flank of the Central Cordillera and the Las Minas range, being limited by the Avirama and the
Accepted 17 October 2017
Betania-El Agrado faults. The western suite comprises a quartz monzonite e quartz monzodiorite e
Available online 7 November 2017
quartz diorite series and subordinate monzogranites. Chemically, the rocks are high-K calc-alkaline I-
type granitoids (some reaching the shoshonitic series) with metaluminous of magnesium affinity. Trace-
Keywords:
Upper Magdalena Valley (UMV)
element tectonic discrimination is consistent with magmatism in a continental arc environment. Most
Geochemistry rocks of this suite crystallized between 195 and 186 Ma (Early Jurassic, Pliensbachian), but locally some
U-Pb zircon geochronology plutons yielded younger ages between 182 and 179 Ma (Early Jurassic, Toarcian).
Colombia The eastern suite crops out in the eastern margin of the Upper Magdalena Valley, east of the Betania e
Magmatic arc El Agrado fault. Plutons of this unit belong to the monzogranite series with rock types ranging between
syenogranites and granodiorites. They are high-K calc-alkaline continental granitoids, some metal-
uminous and some peraluminous, related to I-type granites generated in a volcanic arc. Crystallization of
the suite was between 173 and 169 Ma (Middle Jurassic, Aalenian-Bajocian), but locally these rocks
contain zircon with earlier inherited ages related to the magmatic pulse of the western suite between 182
and 179 Ma (Early Jurassic, Toarcian).
The evolution of the Jurassic plutons in the Upper Magdalena Valley is best explained by onset or
increase in subduction erosion of the accretionary prism. This explains the eastward migration of the arc
away from the trench. Subduction of prism sediments increased the water flux from the subducting slab,
decreasing solidus temperatures, therefore increasing the volume of magma and the amount of crustal
melts involved in the magma. This is explains the crystallization of older and more primitive quartz-
monzodiorite stocks in the west and the later crystallization of granitic bodies with batholitic di-
mensions in the east.
© 2017 Elsevier Ltd. All rights reserved.
https://doi.org/10.1016/j.jsames.2017.10.012
0895-9811/© 2017 Elsevier Ltd. All rights reserved.
G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30 11
Bustamante et al. (2016) suggest that the arc formed during 40 m.y. 1988; Cediel et al., 2003; Restrepo et al., 2009). However, terranes
of oblique convergence between the Farallon oceanic plate and the in the Colombian Andes are still poorly understood (Etayo et al.,
NW of South America. Some recent studies suggest that there was 1983; Restrepo and Toussaint, 1988; Moreno and Pardo, 2002,
coeval Jurassic arc and rift magmatism; igneous rocks of the Upper Cediel et al., 2003; Restrepo et al., 2009). East of the San Jeronimo
Magdalena Valley, the Central Cordillera, the Serrania de San Lucas Fault, terranes are continental, such as the Chibcha, Tahami, Pan-
and the Sierra Nevada de Santa Marta formed in an allochthonous zenu (Puqui), Anacona (Caldas) (Restrepo et al., 2009; Martens
continental arc setting (Bayona et al., 2010; Villagomez et al., 2015), et al., 2014).
whereas similar igneous rocks from the Eastern Cordillera and the The Chibcha Terrane (as per Restrepo et al., 2009) includes a
Santander Massif formed in a relatively autochtonous position, Grenvillian basement covered by Lower Paleozoic sedimentary
possibly due to rifting (Villago mez et al., 2015). It is worth noting rocks, adjacent to blocks bearing Permian granitoids and Upper
that some authors have proposed that the Jurassic rocks from the Triassic limestone units (Payande Formation). The Tahami Terrane
Eastern Cordillera have an arc origin as well (Mantilla et al., 2013a; is characterized by Triassic metamorphic rocks (Restrepo et al.,
Van der Lelij, 2013). 2009), which represent a significant part of the metamorphic
Paleomagnetic and thermochronological data suggest that some basement of the Central Cordillera. The Panzenu Terrane under-
of the Jurassic rocks migrated as tectonic slivers from a southerly went Carboniferous metamorphism, previous to the event recorded
position northwards for hundreds of kilometers (Bayona et al., in the Tahami (Restrepo et al., 2009). The Anacona Terrane has
2006, 2010). This feature partially masks the original geologic re- Devonian metamorphic ages and was not affected by Triassic
lations and has led to models proposing a single but fragmented metamorphism, suggesting that it had not been amalgamated to
Jurassic arc (Bayona et al., 2010; Villagomez et al., 2015; Zapata the Tahami Terrane during the Triassic orogeny (Restrepo et al.,
et al., 2016). 2009).
This paper presents new U-Pb zircon geochronology and lith- Based on U-Pb geochronology, new metamorphic blocks or
ogeochemical data obtained by the Servicio Geologico Colombiano terranes, whose boundaries have not so far been precisely deter-
(SGC) on the Jurassic plutons that crop out in the Upper Magdalena mined, have been recently proposed within the Central Cordillera.
Valley (UMV; Fig. 1). We integrate these new data with recent work There have been reports of metamorphic Jurassic blocks (156e165
by the SGC and by other authors to produce a new geotectonic Ma) in the Central Cordillera that partially correspond to the Tier-
interpretation of the Jurassic evolution of the NW Andes. This radentro Gneisses and Amphibolites (Rodríguez et al., 2017b) and
model is an alternative to models that propose rollback of the to the La Cocha - Rio Tellez Complex (Zapata et al., 2017). Meta-
subduction zone and westward migration of magmatism (Cochrane morphic blocks with ages straddling the Jurassic - Cretaceous
et al., 2014; Spikings et al., 2015; Bustamante et al., 2016). Our data boundary were also found (Sajonia Mylonitic Schists and Con-
show that the UMV rocks were indeed formed in an arc setting, and cepcion Schists), and they contain inherited igneous zircons prob-
that they correlate with the age-equivalent rocks of the Saldan ~ a Fm. ably from the Jurassic arc (Rodríguez and Correa, 2015). Finally,
(Rodríguez et al., 2016a, b, c, d). Based on petrography and bulk Albian metamorphic blocks with ages ranging 102-98 Ma are rep-
chemistry, we propose an evolution model for the Jurassic arc resented by local gneisses and amphibolites (Santa Elena Am-
magmatism in the UMV that accounts for the shift in its geographic phibolites and the Las Pen ~ as Gneiss; Restrepo et al., 2012;
distribution. Futhermore, based on the distinct ages, the Rodríguez and Correa, 2015).
geochemical character, and the type of intruded basement, we The amalgamation of metamorphic terranes in the Central
suggest that the various pulses and belts of Jurassic magmatism in Cordillera is more complex than had previously been thought.
the NW Andes reflect various distinct juxtaposed arcs. Some of the magmatic arcs possibly traveled and were amalgam-
We consider that a magmatic pulse in an arc is the generation of ated along with the metamorphic basements; this seems to be the
significant volume of magma that crystallizes in the form of case of the Jurassic arc of the Western margin of South America.
plutonic and volcanic rocks in a constrained period of geologic time, The Jurassic arc comprises a series of dismembered blocks,
with specific compositional features. A pulse can be differentiated possibly transported from the south (Bayona et al., 2006;
from other pulses in the same arc by its crystallization age, its Villago mez et al., 2015) along the western edge of the Chibcha
composition, and in the case of UVM magmatism, the spatial terrane of Restrepo et al. (2009) or the Payande Terrane of Etayo
location of the plutons and volcanic rocks that it produced. This last et al. (1983). The travelled units include the Upper Magdalena
factor is not relevant if multi-pulse plutons are generated, because Valley, the Serrania de San Lucas, the Sierra Nevada de Santa Marta,
despite being composite, these plutons have a single spatial loca- and the Upper Guajira. The Jurassic units comprise intermediate to
tion. This is not the case for the Jurassic arc according to the data acidic volcanic rocks that crop out next to monzodioritic to mon-
obtained in this work, as we will demonstrate below. zogranitic plutons, which intruded metamorphic basement ca. 1 Ga
old, Palaeozoic sedimentary rocks, Permian granitoids, and Triassic
2. Regional geologic setting sedimentary units. This Jurassic arc does not include the tonalitic
rocks of the northern segment of the Ibague Batholith, which are
Tectonic blocks elongated NS and bearing abundant plutonic younger and were emplaced in Jurassic metamorphic rocks that are
and volcanic rocks with ages between 195 Ma and 160 Ma are part of the metamorphic basement of the Central Cordillera. As will
common in the western margin of northern South America. In be discussed below, the northern Ibague Batholith corresponds to a
Colombia, such feature occurs in the eastern flank of the Central distinct arc of Upper Jurassic-Lower Cretaceous time.
Cordillera, the Upper and Medium Magdalena valleys, the Serrania The Santander Massif's monzogranitic to syenogranitic plutons
de San Lucas, the Eastern Cordillera, the Sierra Nevada de Santa predate the Jurassic arc located on the western margin of the Pro-
Marta, and the Upper Guajira (Fig. 1). Slightly older magmatic rocks terozoic basement. This magmatism was generated between 214
with crystallization ages between 214 and 192 Ma occur in the Ma and 192 Ma (Rodriguez et al., 2017c) and it includes both I- and
Santander Massif and the Serrania de Perija (Eastern Cordillera; S-type arc plutons that were produced by melts involving different
Rodríguez et al., 2017c). proportions of continental crust and mantle (Van der Lelij, 2013;
The tectonic blocks bearing Jurassic magmatic rocks have been Rodríguez et al., 2017c). These Triassic-Jurassic rocks are associ-
variously interpreted in the several terrane models proposed for ated with a Paleozoic metamorphic basement, which belongs to the
the Colombian Andes (Etayo et al., 1983; Restrepo and Toussaint, Santander-Norte de Santander Terrane described by Etayo et al.
12 G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30
Fig. 1. Areas with Jurassic plutonic and volcanic units in the Colombian Andes.
Limestones and Sandstones. These sedimentary units unconform- Triassic, and Jurassic rocks was covered by continental and marine
ably overly the Precambrian crystalline basement. Next to this successions at the end of the Mesozoic and during the Cenozoic.
group, some Permian granitoids crop out, such as the La Plata This rock association is faulted and uplifted in blocks limited by
granite (Rodríguez et al., 1998; Velandia et al., 2001; Leal Mejía, thrust and strike-slip faults like the dextral Algeciras Fault
2011; Rodríguez et al., 2017a). Locally, blocks of Triassic lime- (Velandia et al., 2005), the El Betania-El Agrado Fault and La Plata-
stones and clastic sediments of the Luisa and Payande formations Chusma Fault, which partly exposed the Jurassic rocks and the
are also present (Geyer, 1973; Cediel et al., 1980). basement. None of these faults determines the limit of Neo-
The Proterpozoic basement, the Paleozoic sedimentary forma- proterozoic metamorphic basement, which is fragmented and
tions, the Permian arc granitoids, and the Triassic limestones were widely distributed. Similar features are present in the blocks that
intruded by Jurassic plutons and covered by Jurassic volcanic have Jurassic rocks bounding the western margin of the South
products (Fig. 2). The group of Proterozoic, Paleozoic, Permian, American plate, where the Neoproterozoic basement crops out
Fig. 2. Location of Jurassic plutons and volcanic rocks associated with the UMV; numbers correspond to U-Pb ages in Ma.
14 G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30
together with fragments of Permian granitoids and Jurassic arc reference materials the Plesovice, 91500 and M. Dromedry zircons
rocks of comparable ages (Serrania de San Lucas, Sierra Nevada de were used. The ablation points were 20 mm in diameter. For the data
Santa Marta and Upper Guajira). reduction, the Iolite IGROpro software was used. For the base line,
0 s - 38 s integration times were used, whereas for the samples and
3. Analytic methodology standards, 32.5 s - 8 s were used. The final results correspond to the
average data obtained after discriminating at 2 standard deviations.
The analysis of the Jurassic magmatism in the UMV involved Geochronology plots were performed using the Isoplot v3.5 soft-
defining groups of plutons based on their rock type, geochemistry, ware and the correction for common lead was calculated according
crystallization age, and tectonic position. For this purpose, an in- to the evolution model of Stacey and Kramers (1975). Finally, zircon
depth compilation of the existing regional cartography at the SGC data with discordant values above 10% or 15% (depending on the
was carried out, and then field control, sampling for petrography, sample) were eliminated.
geochemistry and geochronology was performed. Importantly, the
petrographic analyses of samples included thin sections from older 4. Compositional characteristics of the UMV Jurassic plutons
SGC projects.
The analysis of the UMV's Jurassic magmatism is carried out on
3.1. Lithogeochemistry the basis of the current location of the plutons and volcanic rocks,
which corresponds to the known position, without losing sight of
Chemical analyses were performed at the laboratory of the SGC the fact that this location most likely does not correspond with the
headquarters in Bogota. Major oxides were determined by X-ray position and disposition of the arc during the Jurassic, taking into
fluorescence, including trace elements of V, Mo, Nb, Ta, W, Zr and account that it is affected by major strike-slip faults, like the
Hf. The REE and other trace elements were measured using Algeciras Fault with a dextral component (Velandia et al., 2005).
inductively coupled plasma mass spectrometry (ICP-MS). For the The plutons were grouped into Western and Eastern plutons
interpretation of the major oxides, a recalculation was made to according to their distribution, current geotectonics, age, and their
account for loss on ignition (LOI). lithological and geochemical characteristics (Fig. 2).
X-ray fluorescence analyses were performed with a Panalytical
AXIOS Mineral spectrometer configured with a specialized soft- 4.1. Western plutons
ware for geological materials. Quantification of major oxides was
performed in molten samples using metaborate and lithium tet- These plutons are located along the western margin of the UMV,
raborate, and the quantification of elements was done in pressed between the eastern flank of the Central Cordillera and the Las
samples. For the analyses of trace elements, a Perkin Elmer NEXION Minas Sierra, within the tectonic boundaries of the Avirama and
inductively coupled plasma mass spectrometer was used. For Betania-El Agrado faults. As part of this group, the following units
adequate dissolution, the samples were attacked with strong are found: the Anchique Quartz Monzonite (1), the Los Naranjos
inorganic acids (HF, HNO3, HClO4 and HCl). The process was carried Quartz Monzonite (3), the San Cayetano Quartz Monzonite (2), the
out in an open system, using various progressions of temperatures El Astillero Quartz Monzodiorite (5), the Las Minas Monzonite (6)
and heating times. and the Paez Quartz Monzodiorite (4) (Fig. 2). These units corre-
spond to the quartz monzonite e quartz monzodiorite e quartz
3.2. U-Pb zircon geochronology diorite series with some monzogranites, and consist of
Pl þ Kfs þ Qtz (<20%) ± Hbl ± Bt ± Cpx ± Opx and apatite, zircon,
Zircon U-Pb geochronology was conducted at Laboratorio de titanite and opaques, as accessory minerals. In general, these plu-
Estudios Isoto picos, Centro de Geociencias, Universidad Nacional tons correspond to stocks.
Auto noma de Me xico in Juriquilla. Zircon grains of each sample
were hand picked under a binocular microscope, and then mounted 4.2. Eastern plutons
on 2.5 cm epoxy rings. Zircons were exposed using sandpaper and
then photomicrographed. Internal textures of zircon were charac- This second group of plutons crop out along the eastern margin
terized by cathodoluminescence (CL) images, which were obtained of the UMV, on the Western flank of the Eastern Cordillera, within
using an ELM-3R luminoscope. the tectonic boundaries of the Betania - El Agrado and the Algeciras
Prior to the isotopic measurements, the zircon mounts were faults. This group is represented by the Algeciras Monzogranite (7),
cleaned with HNO3 1M to minimize common Pb on the surface of the hypabyssal Teruel Quartz Latite (8), the Garzon Granite (9), the
the grains. Laser ablation was conducted with a Resonetics Reso- Altamira Monzogranite (10), the Mocoa Monzogranite (12) and the
lution M50 system with a LPX 220 193 nm excimer laser and a spot Sombrerillo Quartz Monzonite (11) (Fig. 2). They correspond to
size of 23 mm. Laser energy density was ~6 J/cm2 per pulse with a monzogranites with lithological variations between syenogranites
repetition rate of 5 Hz. The zircon crystals were ablated inside a cell and granodiorites composed of Kfs þ Pl þ Qtz
in a He atmosphere, which provides an optimal condition for this (>20%) þ Bt ± Hbl ± Cpx and apatite, zircon, titanite,
process (Eggins et al., 1998; Kosler and Sylvester, 2003). The laser opaques ± allanite, as accessory minerals. In general, these plutons
was coupled to a quadrupole inductively coupled mass spectrom- correspond to bodies of batholitic dimensions.
eter (ICP-MS). The material vaporized by the laser was extruded The geological characteristics of each group are summarized in
from the cell of ablation and transported to the mass spectrometer Table 1 and the petrographic classification of each unit according to
in a He flow (700 ml/min) that is mixed with N2 (ca. 3 ml/min) Streckeisen (1976), which shows the modal compositional differ-
together with Ar. Along with unknowns, standard glass (NIST 610) ences between the two groups, is shown in Fig. 3.
and standard natural zircons 91500 (Wiedenbeck et al., 1995) and Towards the North, the Western plutons are composed of rocks
Plesovice (Slama et al., 2008) were measured. with a quartz monzonitic composition, whereas towards the South,
Additional U-Pb dating was performed at the LA-ICP-MS labo- the group shows a quartz monzodirioritic composition. In contrast,
ratory in the SGC headquarters in Bogota. U-Pb dating was per- the Eastern plutons exhibit a homogeneous monzogranitic
formed using in an Element 2 ICP-MS, with an associated Photon composition throughout the UMV.
Machines laser ablation equipment with a 193 nm excimer laser. As The modal quartz contents make a difference between the two
Table 1
Geologic characteristics of the UMV Western and Eastern plutons. Abbreviations for names of rock-forming minerals after Siivola & Schmid (2007).
Pluton Macroscopic Characteristics Lithology Mineralogy Accessory Minerals Associated Dykes Contacts Chemistry Ages
(U-Pb)
Western Plutons
1- Anchique Quartz Equigranular and Quartz monzonite PLþQtzþFps OpþAp±Zr±Ttn Intrusive in the Metaluminous, 183.5 ±3 Ma,
Monzonite inequigranular, locally ± monzonite þHblþBt±Cpx ~ a Formation
Saldan magnesian, Type I, 186.4 ±1.4 Ma
porphyritic, micrographic ± granite high in K calc-
texture alkaline and
shoshonitic series,
arc environment
2- San Cayetano Inequigranular, locally Quartz monzonite PLþQtzþFps±Hbl OpþZrþApþTtn Sienogranite, Intrusive in the Metaluminous, 195.8±1.5 Ma,
Quartz Monzonite porphyritic, micrographic ± monzonite ±Cpx±Opx±Bt andesite y basalt ~ a Formation
Saldan magnesian, Type I, 173.3±1.3 Ma.
texture ± quartz monzodiorite shoshonitic series
3- Los Naranjos Equigranular and Quartz monzonite PLþQtzþFps OpþAp±Zr±Ttn Monzogranite, Intrusive in the Metaluminous, 187.9 ±1.3 Ma
Quartz Monzonite inequigranular, porphyritic ± monzonite ±Hbl±Bt±Cpx monzonite, andesite ~ a Formation,
Saldan magnesian, Type I,
towards the edges, ± quartz monzodiorite the Yavi Formation high in K calc-
15
16 G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30
174.0±1.5 Ma,
180.3±2.9 Ma,
176.3±2.5 Ma,
203.9±2.3 Ma,
171.6±1.2 Ma,
181.8±1.3 Ma,
170.7±2.1Ma
172±3.9 Ma, differentiated rocks containing quartz that in most of the rocks is
171.6±1 Ma
934±15 Ma
greater than 20%.
(U-Pb)
magnesian, Type I,
magnesian, Type I,
alkaline series, arc
Metaluminous to
locally clinopyroxene and an absence of orthopyroxene.
Metaluminous,
high in K calc-
high in K calc-
high in K calc-
peraluminous,
peraluminous,
environment
environment
environment
Both groups of plutons are intruded by dykes which do not
Chemistry
~ a Formation
Intrusive in the
Intrusive in the
monzogranites.
Regarding their textures, the Western plutons range from
Formation.
Granadillo
Contacts
Saldan
5. Lithogeochemistry
micro-diorite
micro-diorite
Sienogranite,
Andesite
OpþTtnþApþZrn
PlþFspþQtz
PlþFspþQtz
Mineralogy
±Bt±Hbl
±Bt±Hbl
±quartz monzonite
Quartz monzonite
Monzogranite
±granodiorite
±granodiorite
±tonalite
the Western and Eastern plutons., The Western plutons are classi-
perthitic, locally micro-
variation to porphyritic
Inequigranular, slightly
plot in the granites field. Based on the SiO2 content, the presence of
Table 1 (continued )
Monzogranite
Monzogranite
11- Sombrerillo
12- Mocoa
some rocks from the Algeciras Monzogranite (7) and the Altamira
Monzogranite (10) plot in the alkaline granites field and four (4)
G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30 17
Fig. 3. Modal composition of the UMV Jurassic plutons. Western plutons in black, Eastern plutons in green. The numbering for each pluton matches the one in Fig. 2.
18 G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30
samples from the Sombrerillo Quartz Monzodiorite are scattered positive and negative Y anomalies, a behaviour associated with the
with smaller amounts of SiO2 towards the quartz diorites and concentration of the accessory minerals (Winter, 2014).
quartz monzodiorites fields. All of the UMV plutons features discussed above are indicative of
The Western plutons in general are scattered in the high-K calc- rocks formed in a magmatic arc of continental margin environ-
alkaline series, with lower content of SiO2 for the Las Minas Mon- ment; the shoshonitic behaviour is related to a distant environment
zodiorite (6) and the Astillero Quartz monzodiorite (5); some rocks from the trench, where the plate is subducted to great depths and is
from the Paez Quartz Monzodiorite have a calc-alkaline affinity, associated with the dislocation of the arc or with a back-arc (Gill,
while the Los Naranjos, Anchique and San Cayetano Quartz Mon- 1981; Pearce et al., 1984; Baluyev and Perepelov, 1988).
zonites reach the shoshonitic series field. The Eastern plutons are The Ba/Sr ratio is often associated with the crystallization of
concentrated in the high-K calc-alkaline and shoshonitic series for plagioclase and ease of replacement of Ba by K, indicating a greater
rocks from the Altamira Mocoa, and Algeciras Monzogranites, with enrichment in the alkalis (Green, 1980). In the Eastern plutons this
lower concentrations of SiO2 and K2O for the rocks from the Garzon relationship is higher among (0.77e10.22), whereas in the Western
Granite, the Sombrerillo Quartz Monzonite and the Teruel Quartz plutons the relationship is lower between (0.70e5.17). In contrast,
Latite. the Western plutons have a higher content of elements such as Ni
In the Western plutons the metaluminous character pre- (1.2e57.14 ppm) and Co (3.8e44.71 ppm), of higher affinity with
dominates, with aluminosity values (Al2O3/(CaO þ Na2O þ K2O) intermediate to basic liquids, while the Eastern plutons present a
between 0.63 and 0.99 mol and alkalinity values (Al2O3/ lower concentration of these elements (Ni: 0.9e29.5 ppm, Co:
(Na2O þ K2O) between 1.19 and 4.80 mol. Four (4) rock samples 4.1e38.3 ppm).
from the Paez Quartz Monzodiorite (4) associated with a high In general, in the diagram of McDonough and Sun (1995)
content of silica (67.99e77.77%), reflect a peraluminous behavior normalized to the chondrite, the two groups of plutons show a
with (A/CNK) between 1.01 and 1.07 mol. negative slope with similar trends (Fig. 6); the (La/Sm)N relation-
The Eastern plutons exhibit a greater dispersion between the ship in the Eastern plutons is greater between (1.92e23.656) with
metaluminous and peraluminous fields. The Algeciras and Mocoa respect to the Western plutons that have values ranging between
Monzogranites (7, 12 e Fig. 2), the Sombrerillo Quartz Monzodiorite (1.70 and 5.89); this demonstrates an enrichment in LREE in the
(11) and Teruel Quartz Latite (8) behave as subsaturated in the Eastern plutons. The Western plutons show a slight differentiation
metaluminous series with (A/CNK) values between 0.74 and into two groups: rocks with values greater than 100 times the
0.99 mol and higher concentrations in (A/NK) between 1.32 and chondrite, formed by the more intermediate units Anchique Quartz
2.55 mol. In contrast, the rocks from the Garzon Granite (9) and Monzonite (1), Los Naranjos Quartz Monzonite (3) and Las Minas
most of the samples from the Altamira Monzogranite (10), tend Monzodiorite (6), and rocks with values lower or equal to the
toward the oversaturated (peraluminous) series, with contents of chondrite value for the more basic units El Astillero Quartz Mon-
(A/CNK) between 1.011 and 1.21 mol and (A/NK) between 1.14 and zodiorite (5) and the Paez Quartz Monzodiorite (4).
1.85 mol. The two groups of plutons show positive anomalies in europium
According to Barbarin (1999), rocks with a mixed origin (crustal with Eu/Eu* relations for the Western plutons between 0.27 and
and mantle contribution in their origin) may have a peraluminous 1.93 and for the Eastern plutons between 0.5 and 2.6, with the
signature because of one of the following reasons: after the exception of rock sample JGB-392 (sienogranite) from the Altamira
amphibole has been fractionated, by an interaction with volatiles or Monzogranite (10) showing a deflection of the Eu content of
by assimilation of rocks with a pelitic composition; this could also 0.50 ppm, and also rock sample JGB-370 (monzogranite) from the
be associated with the modal content of biotite in these rocks or Paez Quartz Monzodiorite (4) with a Eu content of 0.28 ppm.
due to the contribution of the crustal material that has been
assimilated (Chappell and White, 1974).
An important difference is noted between the Western and 5.3. Discrimination of the tectonic environment
Eastern plutons on the basis of the #Mg analysis. The Western
plutons show an increase in the #Mg in the order of The two groups of plutons exhibit features that range from
29.04e66.91 mol, P2O5 (0.02e0.65%) and minor enrichments in continental margin arcs to Andean arcs (Condie, 1989), plotting into
the TiO2 (0.14e1.2%) content, while the Eastern plutons are acidic to I -Type (Cordilleran) magmas (Whalen et al., 1987), of the magne-
intermediate with #Mg between 0.18 and 62.35 mol, TiO2 sian series (oxidizing magmas) (Frost et al., 2001), with higher
(0.045e1.19%) and P2O5 (0.052e0.67%). enrichments of SiO2 for the Eastern plutons (Fig. 7). In the diagram
of Pearce et al. (1984) the rocks from the two groups fall within the
5.2. Trace elements and REE field of Volcanic Arc Granites with a dispersion of three rocks from
the Western plutons (from the Paez Quartz Monzodiorite (4)) and a
The two groups of plutons exhibit an enrichment in the mobile rock of the Eastern plutons (Sombrerillo Quartz Monzonite (11))
elements Rb, Ba, Pb, and Cs between 100 and 1000 times the that plots in the Intraplate-type Granites.
chondrite values, with a relative differentiation in the eastern pulse The Western plutons plot into the fields of Pre-plate collision
indicated by a lower content of Cs (Fig. 5). There are significant (Batchelor and Bowden, 1985), associated with emplacements
impoverishments for the two groups in Nb, Ce, Sr and Ti, more above subduction zones. According to Barbarin (1999), ACG (arc
evident for the Eastern plutons in rocks classified as sienogranites calc-alkaline granitoids) granites tend to be batholitic bodies which
(IGM 900745 and 900691) from the Altamira and Algeciras Mon- are arranged parallel to the subduction zone, with a volcanic
zogranites (10, 7, Fig. 2), reflecting a shoshonitic behavior. The Ce/ component of andesitic type. The Eastern plutons are distributed
Yb ratio is generally high, attributed to higher concentrations of towards the syn-collision to pre-plate collision type granites, which
Light Rare-Earth Elements (LREE), with a content in the Western according to Barbarin (1999), are related to transitional periods
plutons of (14.51e51.53) and slightly higher in the Eastern plutons from a compressional regime to a tensional one, once the collision
(16.14e56.66). between plates event has ended. In the diagram Hastie et al. (2007)
A negative slope towards the HREE occurs in both sets of plu- Western plutons are concentrated in the field of BA/A (andesitic
tons. Some of the rocks from the Western plutons -El Astillero basalts), while the eastern plutons tend towards the field of dacite
Quartz Monzodiorite (5) and Las Minas Monzodiorite (6)- have -rhyolites.
G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30 19
Table 2
Major oxides in total-rock (%).
Pluton Sample ID SiO2 TiO2 Al2O3 Fe2O3 MgO CaO Na2O K2O P2O5 MnO FeO LOI #Mg
Western plutons
Anchique Quartz Monzonite 900642 64.59 0.655 14.97 4.77 2.2 3.363 3.404 4.338 0.228 0.161 2.62 1.04 46.173
Anchique Quartz Monzonite 900643 64.1 0.585 15.51 3.91 1.524 3.516 4.275 3.661 0.199 0.218 2.13 2.39 42.141
San Cayetano quartz monzonite 900825 61.2 0.84 16.21 6.04 2.32 3.05 3.6 4.79 0.24 0.2 2.83 2.83 43.824
San Cayetano quartz monzonite 900827 58.26 0.8 17.2 6.4 2.45 5.05 3.55 3.54 0.27 0.18 3.84 3.86 40.34
San Cayetano quartz monzonite 900823 56.72 0.88 19.27 6.16 1.9 5.44 3.54 4.75 0.55 0.2 2.34 2.31 41.068
San Cayetano quartz monzonite 900826 74.78 0.23 12.92 1.92 0.38 1.4 2.92 5.56 0.05 0.07 0.77 0.76 30.336
Los Naranjos Quartz Monzonite 900647 56.494 1.186 16.404 9.997 4.467 6.509 3.374 2.614 0.374 0.364 5.58 1.98 45.16
Los Naranjos Quartz Monzonite 900651 72.587 0.456 14.119 3.214 1.006 1.98 3.431 4.603 0.117 0 1.93 1.7 35.583
Los Naranjos Quartz Monzonite 900641 60.491 0.988 15.95 7.372 3.182 5.231 3.285 4.18 0.345 0.1 3.95 1.28 44.876
Los Naranjos Quartz Monzonite 900649 65.112 0.735 15.578 5.542 2.092 3.874 3.708 4.485 0.222 0.091 3.54 1.63 39.107
Los Naranjos Quartz Monzonite 900650 58.637 1.102 16.072 8.433 3.707 6.456 3.079 3.192 0.399 0.057 5.43 1.3 42.661
Del Paez Quartz Monzodiorite 900658 53.91 0.965 17.42 8.51 4.651 8.001 3.219 1.165 0.265 0.145 5.55 1.57 47.859
Del Paez Quartz Monzodiorite 900664 65.13 0.53 16.34 4.56 1.811 4.476 3.921 2.365 0.223 0.084 2.47 0.36 42.678
Del Paez Quartz Monzodiorite 900665 53 0.673 15.43 8.29 6.842 9.271 2.334 2.005 0.171 0.141 4.85 1.65 59.673
Del Paez Quartz Monzodiorite 900667 65.86 0.71 14.94 4.08 1.278 3.27 3.556 5.149 0.234 0.082 2.5 0.62 35.333
Del Paez Quartz Monzodiorite 900683 49.83 0.733 16.22 8.12 9.217 7.755 2.502 1.569 0.216 0.122 4.93 3.48 66.565
Del Paez Quartz Monzodiorite 900678 48.52 0.89 16.71 10.74 7.99 10.25 1.7 0.63 0.12 0 7.29 2.15 54.932
Del Paez Quartz Monzodiorite 900681 54.44 0.688 12.73 7.86 9.753 7.463 2.443 2.327 0.286 0.159 5.38 1.55 66.914
Del Paez Quartz Monzodiorite 900673 74.05 0.211 13.95 1.66 0.4 1.836 3.496 3.88 0.067 0.057 0.96 0.3 30.312
Del Paez Quartz Monzodiorite 900679 57.82 0.652 14.81 7.99 5.308 7.844 2.648 1.698 0.227 0.138 5.23 0.72 52.679
Del Paez Quartz Monzodiorite 900725 67.99 0.52 15.27 3.47 1.96 3.13 3.92 2.44 0.13 0.77 1.97 0.99 50.755
Del Paez Quartz Monzodiorite 900730 75.08 0.24 13 1.49 0.28 0.9 3.88 4.4 0.05 0.68 0.61 0.5 29.04
Del Paez Quartz Monzodiorite 900737 77.77 0.14 12.22 1.06 <0.10 0.36 3.57 4.44 0.02 0.39 0.13 0.41
Del Paez Quartz Monzodiorite 900738 47.61 1.1 17.96 10.17 5.63 9.3 2.71 1.9 0.23 2.33 5.49 2.96 50.977
Del Paez Quartz Monzodiorite 900722 60.28 0.92 16.53 6.42 3.02 5.65 3.43 2.94 0.24 0.01 3.81 0.27 45.543
El Astillero Quartz Monzodiorite 900719 59.351 0.85 16.92 7.01 2.82 6.05 3.36 2.37 0.283 0.016 3.79 0.71 43.019
El Astillero Quartz Monzodiorite 900720 63.323 0.808 15.932 5.664 2.15 4.321 3.564 3.301 0.197 0.013 2.85 1.4 42.589
El Astillero Quartz Monzodiorite 900721 60.759 0.761 16.59 6.433 2.608 5.185 3.724 2.922 0.252 0.015 3.31 1.89 43.892
Las Minas Monzonite CB0007A* 58.1 0.9 17.2 7.4 3 6 3.7 2.2 0.3 0.1 63.858
Las Minas Monzonite 900752 55.3 1.2 16.57 7.78 3.43 6.25 3.49 2.43 0.55 15.1 4.1 1.08 45.637
Eastern plutons
Altamira Monzogranite 900718 74.9 0.26 13.3 1.48 0.26 1.08 3.31 4.87 0.059 0.04 0.24 0.41 35.41
Altamira Monzogranite 900734 70.5 0.4 14.7 2.56 0.72 1.75 3.59 4.46 0.112 0.06 0.79 0.97 41.126
Altamira Monzogranite 900745 78 0.13 12.4 0.63 0.24 3.61 4.56 <0.024 0.06 0.21 0.4
Altamira Monzogranite 900749 74.7 0.27 13.4 1.42 0.21 1.08 3.28 5.07 0.052 0.04 0.3 0.38 29.823
Altamira Monzogranite CB0005* 63.5 0.6 15.6 5 1.9 3.8 3.7 3.9 0.2 0.1 0 62.352
Algeciras Monzogranite 900691 78.03 0.045 12.37 0.54 0.466 3.62 4.49 <0.024 0 0.17 0.31
Algeciras Monzogranite 900692 74.71 0.23 13.25 1.64 0.433 1.47 3.5 4.26 0.066 0 0.59 0.3 37.97
Algeciras Monzogranite 900694 67.33 0.526 14.72 4.07 1.58 3.19 3.1 4.39 0.186 0.07 1508 0.62 0.186
Algeciras Monzogranite 900697 73.6 0.256 14.04 1.67 0.632 0.31 3.8 4.42 0.09 0.04 0.56 1.17 47.539
Algeciras Monzogranite 900699 65.13 0.52 15.73 4.12 1.34 3.65 3.65 4.43 0.187 0.07 1143 0.9 0.208
Algeciras Monzogranite 900703 66.07 0.545 15.51 4.09 1.48 3.42 3.39 4.54 0.186 0.07 1422 0.43 0.185
Algeciras Monzogranite 900704 75.04 0.217 13.03 1.54 0.4 1.36 3.5 4.15 0.06 0 0.536 0.57 37.939
Algeciras Monzogranite 900706 69.51 0.416 14.46 3.12 1.08 2.59 3.46 4.37 0.139 0.05 1.01 0.58 45.706
Algeciras Monzogranite 900708 67.59 0.468 14.54 3.67 1.36 3.12 3.33 4.33 0.167 0.05 1.283 1.16 46.547
Algeciras Monzogranite 900709 69.25 0.471 14.2 3.56 1.18 2.58 3.27 4.56 0.164 0.07 1.049 0.51 45.636
Algeciras Monzogranite 900711 68.16 0.501 14.33 3.81 1.35 2.69 3.3 4.25 0.169 0.06 1.244 0.89 46.2
Garzon Granite 900715 72.9 0.3 14.1 1.7 0.36 1.4 4.66 3.4 0.08 0 0.41 1 36.729
Garzon Granite 900716 69.7 0.4 14.9 2.82 0.83 1.4 4.42 3.6 0.13 0.01 0.92 1.64 41.639
Teruel Latite 900698 62.94 0.707 15.33 5.32 2.43 4.644 3.267 3.354 0.206 0.104 1.83 1.48 51.95
Teruel Latite 900712 65.96 0.478 15.89 3.87 1.5 3.707 3.836 3.341 0.163 0.09 1.38 0.91 47.433
Teruel Latite 900713 66.35 0.494 15.47 3.63 1.44 2.733 4.379 3.575 0.179 0.109 1.26 1.41 48.323
Sombrerillo Quartz Monzonite 900764 67.613 0.514 16.707 2.779 0.423 2.296 3.917 5.71 0.095 0.059 1.07 0.35 25.462
Sombrerillo Quartz Monzonite 900765 52.932 1.195 18.06 10.382 6.375 9.285 2.845 2.541 0.209 0.177 5.58 3.96 53.623
Sombrerillo Quartz Monzonite 900766 58.662 0.829 16.333 7.671 3.74 6.873 3.254 2.628 0.175 0.161 4.11 0.53 47.906
Sombrerillo Quartz Monzonite 900768 56.883 1.068 17.054 8.886 4.561 7.602 2.99 1.623 0.274 0.196 4.7 1.33 49.377
Sombrerillo Quartz Monzonite 900769 59.819 1.09 16.755 6.773 1.874 4.482 3.83 5.47 0.377 0.114 3.6 0.91 34.397
Sombrerillo Quartz Monzonite 900796 64.277 0.779 17.041 6.131 2.431 4.042 3.46 3.232 0.22 0.109 3.11 1.88 43.548
Sombrerillo Quartz Monzonite 900808 73.317 0.272 14.435 2.319 0.433 1.784 4.355 3.196 0.088 0.06 1.4 0.4 24.754
Sombrerillo Quartz Monzonite 900810 73.62 0.273 14.211 2.405 0.475 1.779 3.952 3.548 0.091 0.07 1.15 0.53 28.406
Sombrerillo Quartz Monzonite 900811 65.305 0.886 15.631 5.92 0.713 4.086 2.996 4.381 0.495 0.134 3.63 0.93 17.36
Mocoa Monzogranite 900781 59.64 1 17.8 5.54 1.85 4.29 4.15 4.42 0.367 0.104 2.66 0.37 40.097
Mocoa Monzogranite 900782 55.58 1.16 17.42 7.76 3.07 6.48 4.08 2.15 0.67 0.116 3.9 1.27 43.614
Mocoa Monzogranite 900784 58.67 1.12 17.36 6.27 2.36 5.12 4.42 3.32 0.502 0.132 3.31 0.45 41.725
Mocoa Monzogranite 900785 70.41 0.36 14.62 2.38 0.75 2.21 3.56 4.58 0.111 0.058 1.06 0.8 39.663
Mocoa Monzogranite 900813 70.12 0.36 14.63 2.58 0.76 2.03 3.35 4.87 0.121 0.104 0.78 0.88 42.466
Mocoa Monzogranite 900815 74.11 0.24 13.77 1.19 0.24 1.24 3.75 4.45 0.054 0.071 0.2 0.75 38.383
Mocoa Monzogranite 900816 74.74 0.21 13.6 1.23 0.18 0.78 3.98 4.34 0.053 0.047 0.46 0.73 24.988
Mocoa Monzogranite 900818 67.83 0.39 16.36 3.05 0.89 3.63 4.29 2.63 0.153 0.068 1.33 0.49 38.097
Mocoa Monzogranite 900819 69.63 0.32 15.22 2.86 0.67 2.37 3.73 3.86 0.127 0.053 1.32 0.92 32.415
Mocoa Monzogranite 900820 68.79 0.41 15.44 2.83 0.68 3.17 3.43 3.97 0.122 0.072 1.2 0.88 33.954
Mocoa Monzogranite 900821 67.29 0.42 16.24 3.19 1.09 3.12 3.98 3.53 0.125 0.06 1.94 0.76 37.449
Mocoa Monzogranite 900822 66.54 0.51 15.66 3.9 1.33 3.22 3.9 3.4 0.154 0.096 1.88 1.11 40.551
Fig. 4. Major oxides diagrams. A) AFM, fields after Irvine and Baragar (1971), B) TAS (Middlemost, 1994), C) Binary diagram, D) Peccerillo and Taylor (1976), E) Shand (1943).
Fig. 5. REE diagram and rare earths N-MORB (Sun and McDonough, 1989) for the two groups of UPM plutons.
G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30 21
Fig. 6. Chondrite-normalized REE diagram for the two groups of UPM plutons.
22 G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30
Fig. 7. Geotectonic environment discrimination diagrams. A. Batchelor and Bowden, 1985. B Pearce et al., 1984 C. Diagram La/Yb vs Th/Yb (after Condie, 1989). D. Frost et al., 2001. E.
Hastie et al., 2007. F. Whalen et al., 1987).
towards the borders of the crystals is common with more obscured data shows a group at 181. 6 ± 3. 4 Ma with MSDW ¼ 2.5, inter-
and homogeneous cores; however, the radiometric ages from the preted as the crystallization age corresponding to the Lower
core and the borders do not reveal differences. Samples GR-6634 Jurassic (Toarcian). Bustamante et al. (2010) reported a U-Pb on
and MIA-499 have several zircon crystals with discordant behav- zircon age for this unit of 187. 4 ± 2. 3 Ma, similar to the ages ob-
iors, which are considered as a loss of common lead and mixing in tained in the other plutons located on the western margin of the
the system (Mezger and Krogstad, 1997). The concordant ages are UMV.
integrated in a range from 170 to 198 Ma, suggesting that the unit is
a multi-pulse batholith with magmatic crystallization ages of 6.2. Plutons from the eastern margin of the UMV
180.2 ± 1.6 Ma, 181.83 ± 0.91 Ma, 181.7 ± 3.8 Ma, 191.9 ± 1.4 Ma and
193.13 ± 1.4 Ma; likewise Leal Mejía (2011) and Bustamante et al. Fig. 10 shows the crystallization ages obtained for the Eastern
(2010) indicate U-Pb LA-MC-ICP-MS ages of 182.7 ± 2.7 Ma, plutons. The Algeciras Monzogranite (7) was dated with four (4)
186.0 ± 3.1 Ma, 188.4 ± 2. 8 Ma, 188.5 ± 3.3 Ma and 189.1 ± 2.9 Ma. rock samples of monzogranitic, granitic and quartz monzonitic
The Astillero Quartz Monzodiorite (5) was dated using the zir- composition, distributed throughout the unit (Fig. 2). The zircons
cons from rock sample GR-6625, which corresponds to a quartz from samples GR-6585 samples (n ¼ 46), GR-6586 (n ¼ 35), GR-
monzodiorite (Fig. 2). The zircons (n ¼ 35) are aprox. 100 mm in size, 6589 (n ¼ 33) are prismatic, with bipyramidal terminations, be-
rounded to short prismatic in shape. In CL images an oscillatory tween 150 and 300 mm in size. CL images show oscillatory zoning
zoning related to their igneous origin is revealed. The concordia and the absence of inherited cores; however, sample GR-6585
diagram shows that some zircon crystals are discordant. The inte- shows an inherited age for a zircon crystal of 1088 Ma and an in-
gration of the concordant ages from each zircon yields a crystalli- terval of ages between 196 and 180 Ma. In sample GZ-6750 (n ¼ 35),
zation age of 187 ± 3.3 Ma with MSWD ¼ 7.8 corresponding to the zircons are usually less than 200 mm in size and in the CL images,
early Jurassic (Pliensbachian), with a Th/U ratio that ranges be- some dark cores with more luminescent outer zones are observed.
tween 0.56 and 1.3 suggesting an igneous origin. The U-Pb ages obtained for this unit are 178. 6 ± 1.2 Ma (GR-
The quartz monzodiorite-derived saprolite sample MIA-482 was 6585), 171.5 ± 2. 5 Ma (GR-6589), 169.6 ± 1.2 Ma (GR-6589) and
used to date the Las Minas Monzodiorite (6 e Fig. 2); the zircons 179 ± 1.9 Ma (GZ-6750), with a MSDW < 4.1 corresponding to the
from this sample (n ¼ 23) are rounded, short prismatic, with sizes range between the Middle Jurassic and early Jurassic (Bajocian to
less than 100 mm and have a slightly brown hue. Under the CL the Toarcian). When the spatial distribution of these ages is
images concentric and “patchy” zoning patterns are observed. In analyzed, the age obtained for sample GZ-6750, located in the
the concordia diagram, the data show a slight discordancy possibly northern part of the pluton and petrographically classified as quartz
indicating high common lead isotopic proportion; however the monzonite, is older than the other ages in the center and South
G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30 23
Table 3
Geochronology of the UMV plutons and volcanic rocks.
Field ID Longitud Latitud Clasification Unit Age U-Pb (Ma) Inherited ages
Western plutons
MIA-438 75 080 26.76100 3 330 46.18400 Monzonite Anchique Quartz Monzonite 183.5±3
MIA-440 75 060 20.69300 3 390 47.77200 Monzonite Anchique Quartz Monzonite 186.4±1.4
JGB-357 75 100 51.43700 3 410 17.67700 Quartz Monzonite with px San Cayetano Quartz Monzonite 173.3±1.3
JGB-356 75 100 16.66500 3 390 52.89400 Quartz Monzonite with px San Cayetano Quartz Monzonite 195.8±1.5
JGB-345 75 200 38.04100 3 210 58.50500 Monzodiorite Los Naranjos Quartz Monzonite 187.9±1.3
GR-6634 75 550 35.22600 2 390 57.30500 Granodiorite Del Paez Quartz Monzodiorite 180.2±1.6
GR-6639 75 440 07.81200 2 370 45.61100 Tonalite Del Paez Quartz Monzodiorite 181.83±0.91
GR-6645 75 580 19.47000 2 150 07.84800 Granite Del Paez Quartz Monzodiorite 191.9±1.4
MIA-454 75 300 41.60300 2 560 37.24200 Monzodiorite Del Paez Quartz Monzodiorite 193.13±1.4
MIA-499 75 490 56.78500 2 320 51.60900 Quartz Monzodiorite Del Paez Quartz Monzodiorite 181.7±3.8
GR-6625 75 440 44.61800 2 200 19.44000 Monzodiorite Astillero Quartz Monzodiorite 187±3.3
MIA-482 75 510 27.02100 2 110 43.39500 Quartz Monzodiorite Las Minas Monzodiorite 181.6±3.4
Eastern plutons
GR-6585 75 190 09.10300 2 360 17.33100 Aplite in granodiorite Algeciras Monzogranite 178.6±1.2
GR-6586 75 160 49.98000 2 350 59.23900 Granodiorite Algeciras Monzogranite 171±2.5
GR-6589 75 240 58.34400 2 280 22.94600 Granite Algeciras Monzogranite 169.6±1.2
GZ-6750 75 110 48.82400 2 450 36.70100 Quartz Monzonite Algeciras Monzogranite 179±1.9
MIA-458 75 300 46.99300 2 460 25.62600 Quartz Monzonite Teruel Quartz Latite 170.50±1.10 181.1±1.70
MIA-460 75 320 25.93300 2 440 08.77800 Quartz Monzonite Teruel Quartz Latite 174.1±2.0
GR-6619 75 360 36.63200 2 100 01.28400 Granite Garzon Granite 170.8±2.4
GR-6652 76 010 25.94400 1 440 56.85900 Granite Altamira Monzogranite 171.6±1
JGB-390 75 540 31.72600 1 500 36.12100 Granite Altamira Monzogranite 172±3.9
MIA-478 75 530 44.79300 1 530 05.85500 Monzogranite Altamira Monzogranite 169.4±3.2
GZ-6780 76 510 39.28900 1 100 04.83200 Quartz Monzodiorite Sombrerillo Quartz Monzonite 173.8±2.2
MIA-512 76 170 34.19500 1 480 42.75800 Granodiorite Sombrerillo Quartz Monzonite 176.3±2.5
MIA-525 76 080 48.01400 1 540 17.46000 Monzogranite saprolite Sombrerillo Quartz Monzonite 181.5±4.0
GR-6672 76 440 12.71900 1 040 17.18600 Quartz Monzodiorite Mocoa Monzogranite 171.6±1.2
MIA-538 76 460 16.61800 1 040 08.32800 Granite saprolite Mocoa Monzogranite 181.8±1.3 939±40
MIA-543 76 400 54.75200 1 120 06.11600 Granite saprolite Mocoa Monzogranite 170.7±2.1
portion of the unit (which are classified as monzogranites), sug- zoning. The analysis of U-Pb data reveals the presence of an
gesting that the pluton represents at least two magmatic pulses. inherited crystal, with age of ca. 1000 Ma probably from the
The Th/U ratio of the zircons from rock sample GR-6585 varies metamorphic basement that is intruded by this pluton. The
between 0.73 and 1.7, between 0.32 and 1.75 for rock sample GR- remaining group of zircons has moderately scattered ranges that
6586, between 0.22 and 1.25 for rock sample GR-6589 and be- can be integrated in a representative age value of 170.8 ± 2.4 Ma
tween 0.70 and 1.67 for rock sample GZ-6750; all of these are values with MSWD ¼ 4.7, that corresponds to the Middle Jurassic. The Th/
around 1.0 which is related to an igneous origin. This observation is U ratio for the zircons range from 0.61 to 1.15 ppm, the majority of
supported by the prismatic form and the oscillatory character of the values are around 1 ppm which relates to an igneous origin; this
zircons observed in the CL images. observation is supported by the short prismatic shape of the zircons
The hypabyssal Teruel Quartz Latite (8) was dated using zircons and the concentric oscillatory zoning.
from the quartz latite-derived saprolite MIA-458 (n ¼ 33) and from The geochronologic analysis of the Altamira Monzogranite (10)
the rock sample MIA-460 (n ¼ 22), which was petrographically took into account its spatial layout, since it crops out in two strips
classified as a dacite (Fig. 2). In general the zircons exhibit prismatic with a NE-SW direction. Bustamante et al. (2010), present a U-Pb
forms, elongated, euhedral, with less than 200 mm in size. The CL zircon date of 178. 97 ± 0. 4 Ma located in the extreme North of the
images show zoning patterns related to a magmatic origin. body. In this study we analyzed rock sample MIA-478 and saprolite
The concordia diagram for rock sample MIA-458 shows sample JGB-390, located in the center of the unit, and rock sample
concordant crystals with a dispersion in the age range between 170 GR-6652 which is located in the southern portion of the unit and is
Ma and 190 Ma; these ages are grouped into two populations, the part of the second strip of the pluton (Fig. 2). The zircon crystals
first one is formed by ages between 177,7 Ma and 189.2 Ma with a have sizes between 100 and 300 mm, colorless to brown with
weighted age of 181.10 ± 1.70 Ma and a single zircon with age of prismatic forms that range from long to short; the CL images show
195.2 Ma, which represent the oldest material and were interpreted concentric zoning and absence of inherited cores. U-Pb ages ob-
as inherited zircons. The other population is formed by a younger tained in the central part of the body for are 169.4 ± 3.2 Ma MSWD
group of zircons with ages between 169.6 Ma and 171.6 Ma, 3.7 for sample MIA-478 and 172 ± 3.9 Ma MSWD of 4.8 for sample
weighted age of 170.50 ± 1. 10 Ma and MSWD ¼ 0.11 related to the JGB-390, both rocks exhibit the oldest zircons in the range of
crystallization processes of the pluton. The rock sample MIA-460 185e190 Ma. In the southern part of the pluton sample GR-6652
yielded a crystallization age of 174.1 ± 2.0 MSWD ¼ 1.9 with a yields an age of 171, 6 ± 1 with an MSWD ¼ 2.6. All the ages
range of ages from 166.22 to 180.48 Ma. In both cases the ages correspond to the Lower to medium Jurassic range (Toarcian to
correspond to the Middle Jurassic (Bajocian-Aalenian). The Th/U Bajocian).
ratio obtained for the saprolite sample MIA-458 varies between The difference in age reported by Bustamante et al. (2010) for
0.79 and 1.17, which is associated with an igneous origin. the northern area of the pluton and the three ages obtained in this
Bustamante et al. (2010) reported a U-Pb zircon date of 173.9 ± 1. work for the central and southern areas, indicate the existence of
6 Ma. for the Garzon Granite (9). Additionally, rock sample GR-6619 two magmatic pulses, which are registered in the inherited ages of
(monzogranite) was dated (Fig. 2). The zircons (n ¼ 24) have some of the Eastern UMV plutons (Fig. 11).
elongated prismatic shape and in CL images exhibit an oscillatory The Sombrerillo Quartz Monzonite (11) exhibits a diversity in its
24 G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30
lithological composition. This pluton was dated using the zircons The ages obtained for the Mocoa Monzogranite indicate that the
extracted from rock samples GZ-6780 (n ¼ 37) which corresponds crystallization event occurred during the Lower to Middle Jurassic
to a quartz monzodiorite, MIA-512 (n ¼ 12) classified as granodi- period (Aalenian to Toarcian). An age of 171.6 ± 1.2 Ma MSWD ¼ 3
orite and monzogranite-derived saprolite sample MIA-525 (n ¼ 10) was obtained for sample GR-6672; zircons in this sample fall on the
(Fig. 2). In general, the zircon crystals are euhedral to subhedral, concordia line. Saprolite sample MIA-538 yielded an age of
colorless to pale brown, with a prismatic form that ranges from 181.8 ± 1.3 Ma MSWD ¼ 1.4 interpreted as the crystallization age,
short to elongated and have sizes between 50 and 200 mm (the with five (5) zircons behaving consistently with Neoproterozoic
larger crystals are seen in sample MIA-512). The CL images show inherited older ages of 939 ± 40 Ma MSWD ¼ 6.9 and one (1)
concentric zoning patterns for the crystals. In the concordia dia- discordant zircon with an age of 210.72 Ma. The zircons that
gram, the analyzed samples show a behavior that ranges from correspond to sample MIA-543 have a disperse behavior near the
concordant to slightly discordant, with ages between ca. 166 and ca. concordia line, with ages in the range of 160 Ma to 181 Ma; the age
180 Ma. Rock samples GZ-6780 and MIA-525 have inherited zircons 170.7 ± 2.1 Ma, with an MSWD ¼ 3.3 is considered as the age of
with ages of 191.11 Ma and 260.94 Ma respectively. The ages ob- crystallization. Six (6) zircons from this sample reflect inherited
tained are 173. 8 ± 2.2 MSWD ¼ 2.5 for sample GZ-6780 and 176. patterns with ages of 216.9 Ma, 551.8 Ma, 741.4 Ma, 936.8 Ma and
3 ± 2.5 with MSWD ¼ 1.3 for sample MIA-512 and 181.5 ± 4.0 1237.1 Ma. Additionally, Zapata-Henao et al. (2016) presented an
MSWD ¼ 1.5 for sample MIA-525. age of 180. 4 ± 1.6 for this unit.
Three U-Pb zircon ages were obtained for the Mocoa Mon- A summary of the reported ages for the Western and Eastern
zogranite (12). Samples GR-6672 (n ¼ 48), MIA-538 (n ¼ 31) and plutons is shown in Fig. 11; this figure demonstrates the grouping of
MIA-543 (n ¼ 33) corresponds to saprolites derived from quartz the ages according to their spatial position within the UMV. The
monzodiorite and granites, respectively (Fig. 2). The zircons vary in different groups of ages indicate at least three magmatic pulses. The
shape from euhedral, elongated prismatic forms to multifaceted, Western plutons mark a main magmatic pulse in the range between
with pale pink hue to colorless and have an average size of about 193 Ma and 186 Ma, with some ages in the interval between 182 Ma
100 mm. CL images show similar patterns of magmatic growth and 178 Ma, while the Eastern plutons indicate restricted crystal-
zoning; some zircons from sample MIA-538 show that such zoning lization ages between 173 Ma and 169 Ma, with some inherited and
is interrupted by inherited cores. crystallization ages between 182 Ma and 179 Ma.
G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30 25
Fig. 9. Concordia diagrams, TeraeWasserburg, mean and standard deviation for the UMV Western plutons.
26 G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30
Fig. 11. U-Pb zircon ages for the Jurassic plutons of the UMV. The blue bars indicate the different magmatic pulses.
La Batalla Limestones and Sandstones in the UMV, La Cristalina et al., 2017a,b,c). These plutons intruded metamorphic basement
Formation), blocks of the Permian arc with ages around 270 Ma (La comprising gneisses and amphibolites (Tierradentro Gneisses and
Plata Granite in the UMV, Nechi Gneiss of in the Serrania de San Amphibolites), which yielded U-Pb metamorphic ages from 160 Ma
Lucas and mylontic granitoids in the SNSM), and Upper Triassic to 156 Ma (Rodríguez et al., 2017b). Interestingly, the metamorphic
limestones like the Payande Formation in the UMV. The Jurassic unit was thought to be Precambrian (Barrero and Vesga, 1976) or
rocks in these blocks correspond to plutons constituted by mon- Triassic (Bustamante et al., 2016). This Jurassic basement unit can
zodiorites, quartz monzodiorites, monzonites, quartz monzonites, be correlated with Jurassic metamorphic rocks of the Cajamarca
granites, Type I alkali feldspar granites and volcanic units of an- complex described by Blanco-Quintero et al. (2014) and by
desites, quartz latites, dacites, rhyolites and tuffs formed in an arc Villago mez et al. (2015)
environments, with U-Pb crystallization ages within the range of Due to the significant differences in petrographic features,
195 to 160 Ma. In the three blocks there is a correlation in ages of geochemistry, geochronology, and the host wallrocks between
the plutons and the volcanic units. Jurassic rocks of the UMV and the North Ibague Batholith
The North Ibague Batholith comprises tonalite and granodiorite (Villagomez et al., 2011; Leal Mejía, 2011; Bustamante et al., 2016),
I-type plutons with metaluminous character, which were formed we propose that Jurassic magmatism in each of these areas was the
between 158 Ma and 138 Ma (Early Jurassic - Late Cretaceous) product of two different arcs. A comparison with the bulk of the
(Bustamante et al., 2016 y Rodríguez et al., 2017b). These plutons central Ibague Batholith is as yet not possible due to the scarcity of
were produced in a continental arc that migrated from west to east data.
but without significant changes in magma composition (Rodríguez
28 G. Rodríguez et al. / Journal of South American Earth Sciences 81 (2018) 10e30
Fig. 12. Evolution model of the UMV and the NBIB arcs.
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