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Article history: A series of uni-axial tensile tests were carried out under various low temperatures and strain-rate ranges
Received 8 December 2009 for AISI 300 austenitic stainless steel. The strain-rate dependencies of the materials under investigation
Accepted 22 February 2010 were evaluated at temperatures ranging from ambient to cryogenic. Non-linear mechanical behavior
Available online 1 March 2010
such as phase transformation, discontinuous yielding and micro-damage of four kinds of commercial
stainless steel-based material were quantitatively investigated by measuring transformation induced
Keywords: plasticity (TRIP) and threshold strain for 2nd hardening. In this study, the main properties of each mate-
A. Austenitic stainless steel
rial were analyzed and compared based on the conditions of strain-rates and temperature. Test results
G. Cryogenic tensile test
H. Dependency of strain-rate
showed that all the test materials were strongly dependent on temperature and strain rate. It is expected
that the findings in this study could be used for the cryogenic design and further research of structure
materials under cryogenic environments.
Ó 2010 Elsevier Ltd. All rights reserved.
0261-3069/$ - see front matter Ó 2010 Elsevier Ltd. All rights reserved.
doi:10.1016/j.matdes.2010.02.041
W.S. Park et al. / Materials and Design 31 (2010) 3630–3640 3631
Fig. 2 shows the distribution diagram of the tested 300 series 2.2. Test equipment
stainless steel. The chemical composition of AISI 304L, 316L, 321
and 347 is given in Table 1. In order to investigate the material behavior of austenitic stain-
The test was designed to analyze the strain-rate dependency less steel under cryogenic temperatures, a custom built mechanical
based on the change in strain-rate at each temperature. Table 2 test system was used. A Universal Testing Machine (UH 1000KNI,
summarizes a set of test conditions for each material. SHIMADZU) equipped with a cryogenic chamber (minimum tem-
Taking LNG temperature into consideration, five test tempera- perature up to 73 K) was used for uni-axial tensile tests at various
tures (including room temperature) were chosen. It was assumed temperatures. The cryogenic environment was generated by link-
that the lowest temperature 110 K was representative of the con- ing three thermocouples to a digital control system, which was
ditions related to LNG equipments. Other temperatures were cho- mounted on the cryogenic chamber. Nitrogen gas was used as
sen to simulate the operational conditions related to LNG loading/ the refrigerant the flow was controlled digitally in order to main-
tain the temperature of the experimental condition.
For the precise acquisition of data, the cryogenic extensometer
(3542-050M-100-LT, Epsilon tech), equipped with a specially pro-
duced knife edge for cylindrical specimens, was embedded near
the specimen in the cryogenic chamber. Fig. 3 shows a schematic
of the experimental apparatus. And industrially manufactured
austenitic stainless steel test specimens were fabricated according
to the Korean Industrial Standards (KS B0801 10). Fig. 4 shows the
detail of the specimen shape and dimensions.
Table 2
Conditions of the cryogenic tensile test.
Table 1
Chemical composition of materials.
Fig. 3. Schematic of experimental apparatus. ture.In general, the steels possess metallic properties at room tem-
perature, but as strain-rates increased, the ultimate tensile
strength and yield strength also increased. By contrast, under low
temperature, as strain-rate increased, yield strength increased
The tensile tests were performed on test specimens at thermal (ry1 ? ry2 ), but the ultimate tensile strength decreased (rt1 ? rt2 ).
equilibrium with the chamber. This was achieved by first allowing According to the Olson–Cohen analysis, internal thermal lift,
the chamber to dry, followed by 30 min pre-cooling period at the which is caused by adiabatic heating, lowered the chemical driving
test temperature. force of the c ? a0 transformation, therefore increasing the SFE,
To reduce stresses resulting from thermal contraction, each test work-hardening rate, ultimate tensile strength and decreasing
specimen was secured using only one jig on the upper crosshead the ductility of materials [11]. These characteristic and plastic
during pre-cooling. The specimen was then fixed to the lower (Transformation Induced Plasticity (TRIP)) phenomena were ob-
crosshead after the cooling process was complete, prior to the ini- served in this study.
tiation of the test. Figs. 6a–d and 7a–d show the engineering stress–strain curves
of test specimens deformed at temperatures ranging from 110 K
3. Results and discussion to 293 K and strain-rates ranging from 1.6E4 s1 to 1.0E2 s1,
respectively. And all the test results which is main properties of
3.1. General characteristics of the austenitic stainless in tensile test the tested materials were summarized in Tables 3a–d.
As shown in the Figs. 6 and 7, the 2nd hardening phenomenon,
The microstructure of the austenitic stainless steels is com- one of the main characteristics of austenite steels at low tempera-
posed of a metastable austenite phase, and generally possesses tures, was observed and a strong temperature dependency was ob-
low stacking fault energy (SFE). Deformation of the metastable served in all cases. As expected, the yield strength and ultimate
austenite c phase involves the formation of strain-induced e and tensile strength increased as the test temperature decreased. How-
a0 -martensite phases. The transformation sequence has been found ever, in contrast to tests performed at room temperature, as the
to be c ? e ? a0 [9]. The formation of strain-induced a0 -martensite strain-rate increased, the yield strength increased slightly, but
significantly affects the mechanical behavior of austenitic stainless the ultimate tensile strength decreased rapidly.
steels by enhancing work hardening. Substantial strengthening can Dieter has reported that yield strength is slightly influenced by
be obtained in metastable austenitic stainless steels by plastic strain-rate and temperature, but ultimate tensile strength is af-
deformation below MD temperature to produce e and a0 -martensite fected significantly during cryogenic tensile tests [12]. Dobson
[10]. has also reported similar results in experiments with austenitic
As shown in Fig. 5, at below 223 K temperatures, the austenitic stainless steel plates [13]. In these past studies as well as the pres-
stainless steel shows two-stage sigmoidal deformation which is ent paper, the effect of the strain-rate is an important factor that
non-linear hardening behavior that is dependent on tempera- governs the non-linear behavior of stainless steel under cryogenic
Fig. 6a. Stress–strain curves of AISI 304L in 110 K. Fig. 6d. Stress–strain curves of AISI 347 at 110 K.
Fig. 6c. Stress–strain curves of AISI 321 at 110 K. Fig. 7b. Stress–strain curves of AISI 316L at 1.6E4 s1.
3634 W.S. Park et al. / Materials and Design 31 (2010) 3630–3640
Table 3b
Experimental results of AISI 316L (cold worked).
Table 3d
Experimental results of AISI 347 (annealed).
Fig. 7d. Stress–strain curves of AISI 347 at 1.6E4 s1. Temperature (K) e_ (s1) ryield (MPa) rtensile (MPa) efracture
Table 4
Rates of increase of ultimate tensile stress at 110 K (unit: MPa).
[14,15]. In a similar study, the internal thermal lift of the test spec-
imen was rarely observed under yield stress but significantly ob-
served under ultimate tensile stress at a temperature of approx.
120 K [16]. According to their studies, strain-rate dependency does
not appear under yield stress due to there being virtually zero
internal thermal lift during the tensile tests.
It can be concluded that adiabatic heating in the region of strain
concentration zone of test specimen at ultimate tensile strength
section of the stress–strain curve would decrease with ultimate
tensile strength in proportion to the thermal loss.
In addition, the specific heat and thermal conductivity of stain-
less steel under cryogenic environments are 1/200 and 1/20 of
those at room temperature, respectively [8]. Thus, although the
infinitesimal plastic deformation of the test specimen under cryo-
genic temperature was measured, significant local thermal lift phe-
nomena can be observed.
As strain-rate decreased, relatively little thermal lift was gener-
ated because the unit time per work applied to the test specimen
was small. Therefore, since this phenomenon is relatively ineffec- Fig. 10b. Elongation of AISI 316L.
tive in martensitic transformations, the test specimen is expected
Fig. 10a. Elongation of AISI 304L. Fig. 10c. Elongation of AISI 321.
W.S. Park et al. / Materials and Design 31 (2010) 3630–3640 3637
Fig. 10d. Elongation of AISI 347. Fig. 11b. Second hardening ratio of AISI 316L.
Fig. 11a. Second hardening ratio of AISI 304L. Fig. 11d. Second hardening ratio of AISI 347.
3638 W.S. Park et al. / Materials and Design 31 (2010) 3630–3640
Fig. 12a. Threshold strain of AISI 304L. Fig. 12d. Threshold strain of AISI 347.
Fig. 13. Photograph of local necking (left) and fracture form of test specimen
Fig. 12c. Threshold strain of AISI 321. (center and right).
W.S. Park et al. / Materials and Design 31 (2010) 3630–3640 3639
Both AISI 321 and 347 exhibited 2nd hardening ratio increases of
75% and 81% at strain-rates of 1.6E4 s1, 72%, 75.5% at 1.0E3 s1
and each 65%, 63.3% at 1.0E2 s1, respectively. Generally, as the
strain-rate increased, the increments corresponding to the slopes
of the plots in Fig. 11a–d were observed to decrease.
As shown in Fig. 12a–d, the threshold strain decreased with
decreasing temperature at a constant strain-rate. This was attrib-
uted to a reduction in ductility.
4. Conclusions
Acknowledgments
Table 5
Rates of increase of ultimate tensile stress at 1.6E4 s1 (unit: MPa). This research was supported by Basic Science Research Program
through the National Research Foundation of Korea (NRF) funded
AISI 293 K 110 K Increment (%)
by the Ministry of Education, Science and Technology (Grant No:
304L 782.8 1432 83 20090068500) and Advanced Ship Engineering Research Center
316L 659.5 1344.1 104
(ASERC) research program. Authors are thankful for the support
321 684.9 1382.3 102
347 657.5 1455.4 121 of NRF and ASERC.
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