𝑙𝑜𝑔(𝑃_𝑠𝑎𝑡 )=𝐴−𝐵/(𝐶+𝑡)

𝑃=𝑅𝑇/(𝑣 ̅−𝑏)−𝑎/𝑣 ̅^2

Psat mmHg
t o
C
Datos VDW CONST ANTOINE
R 8.314 m3 Pa mol-1 K-1 A 7.96681
a 0.5536 Pa m6 mol-2 B 1668.21
b 3.05E-05 m3 mol-1 C 228
T 373 K
Exp Antoine
T°C PsatkPa PsatkPa

5 0.8725 0.635772888077397
10 1.2281 0.652542943967702
15 1.7057 0.675678918618108
20 2.3392 0.707479779510271
25 3.1698 0.751166502776919
30 4.2469 0.811341894494924
8
35 5.6291 0.894745614237456
40 7.3851 1.01150477774544
7

5
Presión kPa

Exp
4 T°C PsatkPa vf
Volumen Fase liquida
3 Volumen Fase vapor
5 0.8725 0.001
2
10 1.2281 0.001
15 1.7057 0.001001
1 20 2.3392 0.001002
25 3.1698 0.001003
0 30 4.2469 0.001004
0.001 0.01 0.1 1 10 100 1000
35 5.6291 0.001006
Volumen m3/mol 40 7.3851 0.001008
(𝐶+𝑡) 𝑙𝑛(𝑃/𝑃_1 )=−
(∆𝐻 ̅)/𝑅(1/𝑇−1/𝑇_1 )

Calor latente 2249.4 kJ/kg

Calor latente 40489.2 J/mol

C-C Antoine C-C

PsatkPa 1/T ln P ln P ln P

0.8725 0.0035971223 -0.1363926249056 -0.45291387 -0.136392625

1.1889999481696 0.0035335689 0.2054682596342 -0.42687833 0.173112574
1.60299068854125 0.00347222222 0.5339755836647 -0.39203729 0.471871065
2.13920233745886 0.00341296928 0.8498089905733 -0.34604623 0.76043302
2.82727030083305 0.0033557047 1.1536684944162 -0.28612794 1.039311688
3.70241918521923 0.00330033003 1.4461893050214 -0.20906574 1.30898644
4.80619407233111 0.00324675325 1.7279495714689 -0.11121583 1.569905518
6.18723638722313 0.00319488818 1.9994644568531 0.011439101 1.822488523

EXP EXP
Exp m3/mol m3/mol VDW VDW liquido
vg vf vg VF VG f(v)=0

147.03 1.8E-05 2.64654 4.20E-03 2.649075877 -1.129228622E-08

106.32 1.8E-05 1.91376 4.27E-03 1.915884805 -1.932494342E-08
77.885 1.8018E-05 1.40193 4.35E-03 1.403812868 -3.422610462E-08
57.762 1.8036E-05 1.039716 4.43E-03 1.041412954 -5.902256817E-08
43.34 1.8054E-05 0.78012 4.51E-03 0.781648204 -9.895302355E-08
32.879 1.8072E-05 0.591822 4.58E-03 0.593202422 -1.612352207E-07
25.205 1.8108E-05 0.45369 4.66E-03 0.454936538 -2.675224096E-07
19.515 1.8144E-05 0.35127 4.74E-03 0.352399661 -4.296889529E-07
 2.5

1.5

1
Exp Exp
ln P

Column K
vf vg 0.5 Column L
Column M
0.001 147.03 0
0.001 106.32 0.0031 0.0032 0.0033 0.0034 0.0035 0.0036 0.0037
0.001001 77.885 -0.5
0.001002 57.762
0.001003 43.34 -1
0.001004 32.879 1/T
0.001006 25.205
0.001008 19.515

vapor 6
f(v)=1 5
Presión

4
6.01676E-05 Datos experimentales
-0.00064421 3 Antonie
-0.00020444 C-C
2
8.05969E-06
3.44681E-05 1

0.00023423 0
-5.207E-05 0 5 10 15 20 25 30 35 40 45
8.16747E-06 Temperatura
 Column K
Column L
Column M

experimentales
e