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BROCHURE

CONTENTS DAELIM POLYBUTENE INTRODUCTION 02

GENERAL GRADE & TYPICAL VALUE 04

PROPERTIES 05

APPLICATIONS 08

ENVIRONMENT & QUALITY CERTIFICATION 11

SAFETY & PACKAGING TYPE 11


DAELIM POLYBUTENE
INTRODUCTION

BRIEF HISTORY OF DAELIM POLYBUTENE INTRODUCTION OF DAELIM POLYBUTENE CHARACTERISTICS


As a leading company in Korean petrochemical industry, As a result of this success in state-of-the-art technology, Daelim Polybutene implements the role of the world No.1 in Daelim Polybutene is chemically stable and resistant to
Daelim has initially embarked on the research of polybutene Daelim has become only a provider in the world that is able to quality and customer service. oxidation by both light and moderate heat.
in 1986, and hence created greater value in C4 stream. After manufacture both C-PB and HRPB in a single plant. Daelim Polybutene is the environmentally friendly product in All grades are water-white, hydrophobic and non-toxic.
carrying out quality improvement and process development, Currently, Daelim develops and offers diverse grades of human life. It has narrow molecular weight distribution and negligible
Daelim has been supplying Conventional Polybutene polybutene, hence it thrives in enlarging value to its customers Daelim Polybutene has being manufactured in the world class sulfur content.
(C-PB) since 1994. In addition to accomplishment of C-PB, as the second largest polybutene supplier in the global market Yeosu Complex equipped with state-of-the-art facilities.
it successfully launched and dispensed High Reactive with 140,000 MTA Capacity. Daelim’s high technology and
Polybutene (HRPB), and then it has been distributing to all integrity that the company pursues above all others offer the
different areas in the world. benefits to its customers.
GENERAL GRADE & PROPERTIES
TYPICAL VALUE

Daelim Polybutene was granted the KT mark for new localized technology and the Ministry of Science & Technology and the Korea PHYSICAL PROPERTIES
Industrial Technology Promotion Association in November 1994. The company also received the IR52 Chang Young-sil Award for
technological excellence in 1995. Color 
Daelim Polybutene is generally water-white, reaching less than 50 on APHA color scale. (typically less than 10)
Chemical Electrical The product remains very stable after being prolonged exposure to UV light.
Physical Properties Properties Properties
Daelim Polybutene is more stable than conventional mineral oil with same APHA color.
Classification Flash Point Dielectric
Molecular Viny- Color Pour Loss on Acid Total Dielectric Break-
Weight Viscosity
lidene (APHA) Point Heating
Water
Value Sulfur Constant down Tackiness 
(COC) (PM) Volt.
Tackiness increases as the molecular weight and viscosity increase.

cSt cSt Wt- mg Max.


Unit Mn
@ 100℃ @ 40℃
℃ ℃ Wt-% Max. Wt-% Wt-% ppm KOH/g ppm - ㎸ Purity & Toxicity 
Daelim Polybutene has neither additive nor chlorine & sulfur content hence it is famous for high purity and non-toxic characteristic.
ASTM ASTM ASTM ASTM 13C ASTM ASTM KS- ASTM ASTM ASTM ASTM ASTM
ASTM GPC D445 D445 D92 D93B NMR D1209 D97 C2101 D6304 D974 D2785 D924 D149
Stability   
PB300 300 - 27 138 0 - 15 -45 - 30 0.01 1 - - Daelim Polybutene is chemically therefore it contains excellent stability to heat and UV radiation.

PB400 400 10 160 160 125 - 15 -30 0.7 30 0.01 1 2.17 40


Viscosity   
PB560 560 33 620 165 130 - 15 -20 0.67 30 0.01 1 2.18 40 Viscosity of Daelim Polybutene that is measured by Cannon-Fensky capillary viscometer
and Kinematic viscosity is between 10 and 5,000cSt at 100℃.
PB680 680 80 1,700 175 150 - 15 -14 0.64 30 0.01 1 2.18 40 As the average molecular weight rises up, kinematic viscosity increases.

PB800 800 108 2,400 190 160 - 15 -4 0.29 30 0.01 1 2.18 40


01 Kinemaric Viscosity- Temperature Characteristics  02 Blending of Daelim Polybutene   
Conven- PB950 950 220 7,200 200 165 - 15 -1 0.18 30 0.01 1 2.18 40 The viscosity depends on the temperature. When blending two grades of Daelim Polybutene of different viscosity
tional
PB Based on ASTM D341, viscosity changes can be generally to obtain a product of desired viscosity, the following formula can be
PB1300 1,300 645 22,000 210 170 - 15 3 0.11 30 0.01 1 2.19 50 predicted as follows used.

PB1400 1,400 810 27,000 210 170 - 15 5 0.10 30 0.01 1 2.19 50 log log(ν+0.7)=A-BlogT Inν= X1Inv1 + X2Inν2-BlogT

ν: kinematic viscosity ν: kinematic viscosity of the blend ν1: kinematic viscosity of the 1st component
PB2000 2,000 2,600 72,000 230 175 - 15 11 0.08 30 0.01 1 2.20 50 ν2: kinematic viscosity of the 2nd component
A,B : Coefficient
X1: weight fraction of the 1st component X2 : weight fraction of the 2nd component
T : Temperature, K
PB2200 2,200 3,200 120,000 240 182 - 15 13 0.07 30 0.01 1 2.20 50
DAELIM POLYBUTENE KINEMATIC DAELIM POLYBUTENE BLENDING CHART (at 100℃)
PB2400 2,400 4,700 206,000 260 190 - 15 17 0.05 30 0.01 1 2.20 50 VISCOSITY-TEMPERATURE CHARACTERISTICS

Heavier Polymer Weight Ratio(%)


HRPB750 750 90 2,200 210 150 85 15 -10 0.25 30 0.01 1 2.18 40 Viscosity(cSt)

10,000,000 100 90 80 70 60 50 40 30 20 10 0
10,000 10,000

Heavier Polymer Viscosity(cSt)


HRPB1000 1,000 190 4,200 220 170 85 15 -2 0.15 30 0.01 1 2.18 50
HRPB 1,000,000
HRPB1300 1,300 470 14,000 240 175 85 15 0 0.10 30 0.01 1 2.19 50
100,000 D
1,000 1,000
HRPB2300 2,300 1,600 52,000 260 190 85 15 12 0.05 30 0.01 1 2.20 50

Lighter Polymer Viscosity(cSt)


10,000 C
. The above data is a typical value.
PB2400 B
1,000 100 100
PB1400
100 PB950
A
PB680
10 10 10
0 10 20 30 40 50 60 70 80 90 100

Lighter Polymer Weight Ratio(%)


1
20 40 60 80 100 120 140 160
Temperature(℃) A PB450 + PB95 / B PB950 + PB1400 / C PB1400 + PB2400 / D PB950 + PB2400

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PHYSICAL PROPERTIES ELECTRICAL PROPERTIES
Molecular Weight Daelim Polybutene does not contain inorganic materials and conductors; its own insulating property is excellent.
The number average molecular weight(Mn) in Daelim Polybutene ranges from 300 and 2,500.
The Mn can be determined experimentally with gel permeation chromatography.

KINEMATIC VISCOSITY VS MOLECULAR WEIGHT (by VPO)


CHEMICAL PROPERTIES
Molecular Weight(Mn)
3,000
Solubility & Compatibility  
Daelim Polybutene is a non-polar hydrocarbon polymer hence it has high solubility in aliphatic, aromatic and chlorinated solvents.
2,500
It is compatible with a wide variety of organic materials, for instance, synthetic hydrocarboon polymers
2,000
including wax, rosin, asphalt and gum.

1,500 Item Solvent PB950 Item Solvent PB950

1,000 n-Hexane O Benzene O

500 Aliphatic n-Heptane O Toluene O


Aromatic
n-Octane O Xylene O
0
10 100 1,000 10,000
Viscosity(cSt,100℃) Methylacetate X Ethylbenzene O

Esters Eethylacetate △ Methanol X


Density  
Isopropylacetate X Ethanol X
The density of Daelim Polybutene varies with temperature changes as follows.
Carbon
EFFECT OF TEMPERATURE ON DENSITY OF DAELIM POLYBUTENE O Alcohols Isopropylalcohol X
tetrachloride

Density 0 20 40 60 80 100 120 Chlorines Trichloroethane O n-Buthanol X


0.8200

Methylenechloride O i-Buthanol X
0.9000

O : Soluble △: Partially soluble X : Insoluble


0.8800

PB2400
0.8600 PB1400

PB950
0.8400
PB680

0.8200

0.8000
0 20 40 60 80 100 120
Temperature(℃)

Oxidation Stability 
Under normal use, Daelim Polybutene offers great resistance to air oxidation.

Lubricity   
With high viscosity index and no residual carbon remained at high temperature,
Daelim Polybutene can be used in blend with other lubricants and oils.

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APPLICATIONS

Food Cosmetic Electrical


Insulation

CAULK & SEALANTS


Caulks & Sealants are materials that are installed into a gap or joint to prevent water, wind, dirt or other contaminants through gap.
Daelim Polybutene is used for caulks and sealant as tackifier and plasticizer with excellent non-drying UV stability and tackiness.
Fly-Trap Tape Hotmelt Adhesive The main use of caulks & sealants with Daelim Polybutene is for construction, automotive, ship-building and refrigerator.

GUM BASE   
Daelim Polybutene passes the standards regulation designated by the Korea Food Additives Board,
FOA LOA
so it can be used as a base material for chewing and bubble gums.
Lubricant
Item PB1300F PB1400F PB1500F

Viscosity (cSt 100℃) 645 810 4700

Characteristics Pass Pass Pass


HIPS Tire Wrap Film
IR Spectrum Pass Pass Pass

Verification Test Bromine Reagent Pass Pass Pass

Heat Test Pass Pass Pass


FUEL & LUBRICANT ADDITIVES
Solubility Pass Pass Pass
Modified polybutene is used for the fuel & lubricant additives.
Chlorine Compound Pass Pass Pass

Fuel Dispersants 
Purity Test Arsenic Pass Pass Pass
Detergents serve to reduce deposits on the engine valve and emit low exhaust smoke, and also prolong the lifetime of engine.
Daelim Polybutene derivative is a performance material added to fuel detergent to provide excellent cleanliness. Heavy Metal Pass Pass Pass

Low Polymer Contents Pass Pass Pass


Lubricant Dispersants  
Dispersants serve to reduce and prevent deposits in engine. Those in commercial use are prepared from polybutene and they
High Heat Residue Pass Pass Pass
minimize engine deposits at low temperature.

ADHESIVES   WRAP FILM  


Daelim Polybutene is used for wide application in the formulation of various types of adhesives such as Pressure Sensitive The addition of Daelim Polybutene to LLDPE improves film properties including elongation,
Adhesive(PSA) and Hot Melt Adhesive(HMA). tear resistance, impact strength, tackiness and low temperature flexibility.
Main application is industrial stretch film, wrap film as well as PB master batch for silage film.
Pressure Sensitive Adhesive(PSA) Hot Melt Adhesive(HMA)
Raw material Raw material
Base polymer : natural rubber, SIS, SBR, PIB etc. Base polymer : EVA, SBS, SIS, APP, PE etc.
Tackifier : hydrocarbon resin, rosin, polybutene etc. Tackifier : hydrocarbon resin, polybutene etc.
Others : filler, antioxidant, solvent etc. Others : paraffin wax, filler, antioxidant etc.

Daelim Polybutene improves the tack and peel strength Daelim Polybutene increases the melt index and gives
of elastomers. Major application of PSA is general & the flexibility at the low temperature. It is well compatible
insulation tapes. with SBS, SEBS, SIS, PE. Major application of HMA is
packaging, book-binding and disposable.

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ENVIRONMENT & QUALITY
CERTIFICATION

LUBRICANTS ISO14001
According to company’s strategy, Daelim has certification of ISO14001 and points to
Two-Stroke Engine Oil not only company development but also sustainable environmental development.
Two-Stroke(2T) engines are used in scooters, lawn mowers, chain saws and boats.
Soot of 2T-engine at high temperature generates smoke in case of rapid acceleration and sudden stop. NSF(National Sanitation Foundation)   
Daelim Polybutene easily depolymerizes at high temperature and leaves almost no carbon residue. Aiming Industrial Safety&Health, Daelim registers Polybutene products on NSF,
Daelim Polybutene results in low carbon deposit formulation and emits low exhaust smoke(JASO FC grade) in the engine exhaust which evaluates suitability of high quality and safety of products.
system.
ROHS (Restriction of Hazardous Substances Directive)   
Lubricant for Rolling and Wire Drawing    Daelim Polybutene does not contain any substances from the list of RoHS.
Traditionally, rolling and drawing oil have been based on mineral oil. Mineral oil must be removed from the metal before heating.
However, Daelim Polybutene is not necessary to be cleaned or removed since it leaves almost no carbon residue. SVHC (Substance of very high concern)   
Unlike mineral oil, Daelim Polybutene does not cause problem in rolling operation and wire drawing involving aluminum and copper. Daelim Polybutene is anti-toxic products, not sustaining the substances of SVHC.

Compressor Oil     
Daelim Polybutene is free of sulfur and other impurity, therefore it serves to remove the danger of catalytic poison and other problem.

Viscosity Index Improvers


As a viscosity index improver, Daelim Polybutene minimizes change in lubricant oil viscosity affected by temperature.

ISO9001 ISO1401 SVHC RoHS NSF REACH KFDA


ELECTRICAL INSULATION 
Daelim Polybutene has been applied to electrical applications because it does not contain inorganic material, sulfur and conductors.
Daelim Polybutene shows excellent electrical properties.

Cable Jelly Compound 


Because it has great heat stability, waterproof and low power factor, Daelim Polybutene is used for petroleum jelly compound.

Insulation Oil for Condenser   


Daelim Polybutene has been applied to low voltage condenser as a insulation oil because of outstanding electrical properties,
SAFETY & PACKAGING TYPE
heat stability and oxidation stability.

OTHERS SAFETY PACKAGING TYPE


Asphalt Modifier Daelim Polybutene is safe to use, because it is non-toxic. Drum
IBC Iso-container
Daelim Polybutene serves low temperature flexibility, waterproof, tackiness in the case of asphalt sheet. Daelim Polybutene is allowed by the FDA for a wide variety of (open/ closed type)

applications as components of articles. 200 / (180kg) 1kl (0.85MT) 24kl (20MT)


Resin Plasticizer CAS Number : 9003-27-4
Daelim Polybutene increases melt index and strength in the case of olefinic and styrenic resin.

Rubber Modifier 
Daelim Polybutene improves tackiness, low temperature brittleness as a modifier.

Dispersing Agent 
Daelim Polybutene can be used as a useful dispersing agent for the pigments, inks.
Also, Daelim Polybutene is used as the assistant material of foaming agent of synthetic resin including PS, PE and PP.

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Daelim Polybutene is made by Daelim Industrial Co. Ltd., and
distributed by Dealim Corporation.
For more information about Daelim Polybutene or product samples, please contact us.

HEAD OFFICE DAELIM CORP. GUANGZHOU OFFICE


10Fl., KCCI Building, 45, 4-ga, Rm 2112, Citic Plaza, Tianhe North Rd(E)
Namdaemun-ro Chung-gu, Seoul, 100-743 Korea Guangzhou, P.R.C
TEL : 82-2-3708-3261   TEL : 86-20-3877-3455
FAX : 82-2-754-1142 FAX : 86-20-3877-3805
E-mail : ckcho@daelimcorp.co.kr E-mail : shmoon@daelimcorp.co.kr

DAELIM CORP. SHANGHAI OFFICE DAELIM CORP. SINGAPORE BRANCH


1708 Tower B City Center of Shanghai 10 Hoe Chiang Road #04-07 Keppel Towers
No. 100 Zunyi Rd., Shanghai, 200051 Singapore 089315
TEL : 86-21-6237-0099 TEL : 65-6327-9330
FAX : 86-21-6237-0019 FAX : 65-6327-9350
E-mail : wasnam@daelimcorp.co.kr E-mail : esbee@daelimcorp.co.kr

DAELIM CORP. HOCHIMINH OFFICE


8F Osic Building 8 Nguyen Hue Street,
District 1, Hochiminh City, Vetnam
TEL : 84-8-3822-8683
FAX : 84-8-3822-8685
E-mail : yschoi@daelimcorp.co.kr
VALUE CREATOR FOR BETTER LIFE

DAELIM INDUSTRIAL CO., LTD.


10Fl., KCCI Building, 45, 4-ga, Namdaemun-ro Chung-gu, Seoul, 100-743 Korea
TEL : 82-2-3708-3261 | FAX : 82-2-754-1142 | E-mail : ckcho@daelimcorp.co.kr
www.daelimcorp.co.kr