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Cinetica de reatores 09/10/20

tempe. (°C) K (S^-1) tempe. (K) 1/T ln(K)


2 0.0126 275.15 0.003634381 -4.37405847 0
0.0031 0.0032 0.0033
10 0.017 283.15 0.003531697 -4.07454193 -0.5
20 0.02 293.15 0.003411223 -3.91202301 -1
25 0.027 298.15 0.003354016 -3.61191841 -1.5
35 0.028 308.15 0.003245173 -3.57555077
-2
40 0.038 313.15 0.003193358 -3.27016912
-2.5
-3

ln (K) K R a E -3.5 f(x) = − 2303.8762


4.0186 55.6231788403 8.3 -2303.9 19122.37
-4
-4.5
legenda -5
calculado
dado

parte 2

conversão (XA) CA0 tempo CA (


11.2 0.112 0.2 13 0.1776 0.600
25.7 0.257 0.2 34 0.1486
f(x) = − 2.50084090045147E-0
36.7 0.367 0.2 59 0.1266 0.500 R² = 0.998409443566581
55.2 0.552 0.2 120 0.0896
0.400

0.300
tempo (XA)
13 0.112 0.200
34 0.257
59 0.367 0.100
120 0.552
0.000
0 20 40 60

tempo "-dXa/dt
13 0.006739
34 0.005689
59 0.004439
120 0.001389
ln(dxa/dt)
-0.9 -0.8 -0.7 -0.6 -0.5 -0.4
ln(dxa/dt)
-0.9 -0.8 -0.7 -0.6 -0.5 -0.4
tempo ln(dxa/dt) ln(1-Xa)
13 -4.999843733 -0.1187835
34 -5.1692207932 -0.2970592
59 -5.4173261531 -0.4572849
120 -6.5791712152 -0.802962

ln(1-Xa) ln(dxa/dt)
-0.118783536 -4.999843733
f(x) = 2.36983599645193 x − 4.548376
-0.297059234 -5.1692207932 R² = 0.93552200662746
-0.457284857 -5.4173261531
-0.802962047 -6.5791712152

ln(kCa0) -4.5484
CA0 0.2
k 0.05292062722
ln(K)
0.0032 0.0033 0.0034 0.0035 0.0036 0.0037

f(x) = − 2303.87629019434 x + 4.01855810181663

0.2
0.18
f(x) = − 7.2062652E-08 x³
0.16 + 0.202245129757
(XA) 0.14 R² = 1
0.12
0.1
CA

f(x) = − 2.50084090045147E-05 x² + 0.007389468205078 x + 0.02457292224828


R² = 0.998409443566581 0.08
0.06
0.04
0.02
0
0 20 40 60
Te

20 40 60 80 100 120 140

dXa/ dt -5E-05 x 0.007389

ln(dxa/dt)
0
-0.6 -0.5 -0.4 -0.3 -0.2 -0.1 0
-1
ln(dxa/dt)
0
-0.6 -0.5 -0.4 -0.3 -0.2 -0.1 0
-1

-2

-3

-4

-5
983599645193 x − 4.54837606316308
52200662746
-6

-7
= − 7.2062652E-08 x³ + 1.85289103E-05 x² − 0.00212447646 x
.202245129757
1

40 60 80 100 120 140


Tempo
Exercicio 2

conversão (XA) CA0 tempo CA (


11.2 0.112 0.2 13 0.1776 0.600
25.7 0.257 0.2 34 0.1486
f(x) = − 2.50084090045147E-05 x² +
36.7 0.367 0.2 59 0.1266 0.500
R² = 0.998409443566581
55.2 0.552 0.2 120 0.0896
0.400

tempo (XA)
0.300
13 0.112
34 0.257 0.200
59 0.367
120 0.552 0.100

tempo "-dXa/dt 0.000


0 20 40 60
13 0.006739
34 0.005689 dXa/ dt
59 0.004439
120 0.001389

tempo ln(1-Xa) ln(dxa/dt)


13 -0.11878354 -4.99984373 ln(d
34 -0.29705923 -5.16922079
-0.9 -0.8 -0.7 -0.6 -0.5
59 -0.45728486 -5.41732615
120 -0.80296205 -6.57917122

ln(kCa0) -4.5484
CA0 0.2
f(x) = 2.36983599645193 x
k 0.05292063 R² = 0.93552200662746
(XA)

2.50084090045147E-05 x² + 0.007389468205078 x + 0.02457292224828


98409443566581

20 40 60 80 100 120 140

"-0,00005x + 0,007389
-5E-05 0.007389

ln(dxa/dt)
0
8 -0.7 -0.6 -0.5 -0.4 -0.3 -0.2 -0.1 0
-1

-2

-3

-4

-5
f(x) = 2.36983599645193 x − 4.54837606316308
R² = 0.93552200662746
-6

-7