Sri Chaitanya IIT Academy., India.

A.P, TELANGNA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON Central Office, Madhapur – Hyderabad
SEC: Sr.Super60 PTA-05 Date: 15-11-2020
TIME: 10.10Am to 01.10Pm 2016-P1 Max. Marks: 186

KEY SHEET
PHYSICS
1 A 2 A 3 A 4 C 5 A
6 AB 7 ABC 8 ABD 9 ABCD 10 AB
11 ABC 12 AC 13 ACD 14 3 15 7
16 2 17 2 18 1

CHEMISTRY
19 B 20 A 21 B 22 A 23 D
24 AD 25 ABCD 26 AD 27 ACD 28 AD
29 BCD 30 ABC 31 BC 32 7 33 3
34 4 35 4 36 1

MATHS
37 D 38 A 39 D 40 D 41 D
42 ACD 43 BCD 44 BCD 45 ABC 46 BCD
47 ABD 48 BD 49 ABC 50 5 51 2
52 9 53 3 54 3
Sri Chaitanya IIT Academy, India 15-11-2020_Sr.Super60_Jee-Adv(2016-P1)_Paper-1_PTA-05_Key & Sol’s
SOLUTIONS
PHYSICS
1. The arrangement is shown in figure. Consider the hemispherical shell of radius r and
thickness dr as shown. Resistance of this shell is ;

2.

(on solving )

3. Inflow and out flow of current in a cell must be same.

x= 0.5A y= 1.5A
therefore VB-VA= 0.5 volts(using kirchoffslaw)
4. In element A, the resistance remains constant upto the potential drop of 10V. Further
increase in the voltage does not increase this current (which is constant at 1A). This
means that the ratio V/R A\  constant and this resistance R A increases linearly with
voltage.
When both A and B are in series, the current in the circuit will increase non linearly
upto 1A when the total voltage drop across A and B becomes 10+ 15 = 25V
Further increase in this voltage does not bring about any change in the current as
shown in solution (C). The voltage drop across A will go on increasing while that
across B remain fixed at 15 V.
5. H  i 2 R t  m S  .

30 2  t  A  d  S  300
A
V
6. Ammeter reading 
R
Voltmeter reading =V

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Sri Chaitanya IIT Academy, India 15-11-2020_Sr.Super60_Jee-Adv(2016-P1)_Paper-1_PTA-05_Key & Sol’s
 20 
7. VMax   75
 5  120  75 
8.  R  2 0.1  12
3x 3y
9. At midpoint   b
2 2
1r2   2 r1
10.  eff 
r1  r2
11.

From eqn. (i) and (ii),

I = 6A

Also current in wire D to earth is 0.

12. AO
B&D are equipotentials
RV  RA RVR
13.  RA 
3 R  RV
2

14.
R R
(i) 1 and 2 is resp
 k  1 ; k
R2 R3 k  k  1
So R3 is 1 ohm.
Then i=
 k  1 / k V 2
0
3
R
=3 A
15. It follows from symmetry considerations that the initial circuit can be replaced by an
equivalent one.
We replace the inner triangle consisting of an infinite number of elements by a resistor
R AB
of resistance , where the resistance R AB is such that R AB  R x and R AB   . After
2
simplification, the circuit becomes a system of series and parallel connected
conductors. In order to find R x , we write the equation

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Sri Chaitanya IIT Academy, India 15-11-2020_Sr.Super60_Jee-Adv(2016-P1)_Paper-1_PTA-05_Key & Sol’s

Solving the equation, we obtain

16. Equivalent resistance between A and E:

For B and E to be equipotential

Solve to get :

Now
17. Potential difference through each resistor is same

3.4
18.  0.04
100 R
3 2
100  R
100  400
V  0.04  V
500

CHEMISTRY

19. For pH of buffers to increases just above 4.00,

 NaF  3.5
 HF
(0.15  x)
For 1st buffer  3.5  x  0.083mol / L
(0.15  x)
0.083  40  350
Mass of NaOH=  1.2g
1000
(0.35  y)
For 2nd buffer  3.5  y  0.194mol / L
(0.35  y)
0.194  40  350
Mass of NaOH=  2.7 g
1000

20. It is buffer solution, so

82.2  x 
pH  pK a 2  log
 Na 2CO3 
9.95  11  log(5.6)  log  106   50.4g
 NaHCO3  x 
 84

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Sri Chaitanya IIT Academy, India 15-11-2020_Sr.Super60_Jee-Adv(2016-P1)_Paper-1_PTA-05_Key & Sol’s
nd
21. Nitrogen reactant in 2 equilibrium, so reaction proceeds forward moles decreases.
But in 1 st and 3rd equilibrium reaction moves in the direction to increases number of
moles.
22. nA(g)  A n  g
Initial moles 1 0
x
Equilibrium moles 1–x
n
 x/n
  xV. n 1 x.V n 1
Now, KC   V n  n
  as x  1
 1 x  1  x  .n n
 
 V 
x 1
Now, total moles = 1  x    1  x.   1 
n n 
n.K  1  n 
 1  nC1   1
1  n KC

V  n  V n 1

23.


A(aq)  2B(aq) 
 2C(aq)  D(aq)
t0 3n
t  eq 3n  x x
1 x
 xn
2 3n  x
24. As the formation constant of complex ion increases solubility of sparingly soluble
salts increases.

AgCl(s)  2CN   Ag(CN)2   Cl
 

 s  1.8  1011
1M s s

AgCl(s)  2NH3   Ag(NH3 )2   Cl
 

 s  1.8  1.7  10 3
1M s s
  Ag(S2O3 ) 2 3  Cl 
AgCl(s)  2S2O  2
3
 s  1.8  2.8  103
1M s s
25. For MgF2 ; 4s3  3.2  108  s  2  103
2  103  62
Mass that can be dissolved in 125 mL =  15.5mg
8
4.96
% of saturation is   100  32%
15.5
For CaF2 : 4s3  4  1012  s  104
104  78
Mass that can be dissolved in 100 mL=   0.78mg
10
26. On diluting a solution of weak electrolyte, degree of dissociation increases but
concentration of H + decreases. Because, decrease in concentration compensates
increase in degree of dissociation.
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Sri Chaitanya IIT Academy, India 15-11-2020_Sr.Super60_Jee-Adv(2016-P1)_Paper-1_PTA-05_Key & Sol’s
27.
 2NO  O 2
N 2O4   N 2O5
2NO  O2 
t0 2 t0 2 1
3x 3x
t  eq 1 2  2x 1  t  eq 2  2x 1  x
2 2
Checking through options.
28. Vapour pressure of liquid is dependent on temperature.
29.
 2NO2 (g)
N 2O4 (g) 
t0 a 0
t  eq a(1  ) 2a
46
Vapour density=  30.67    50%
1 
1.5  1.5  0.082  300
Total pressure=  6.75atm
8.2
4 2
Kp  .P  9atm
1  2
138
Density of mixture=  16.83 g / L
8.2
30. As temperature increases endothermic reaction proceeds in forward direction, some
hydrazine again decomposes and also partial pressure of NH3 is decreasing.
31. BOH  H   B  H 2O
a mole b mole 0
1 a a
th run a 0
5 5 5
OH Kb
 B 
Now, for 1/5th reaction, P  P  log
 BOH 
a/5
Or, 14  9   P K b  log
4a / 5
 P  5.6  K b  2.5  106
Kb

1

At equivalent point: P H  7  P K b  log C
2

1
Or, 4.5  7   5.6  log C   C  0.25 M
2
Now, n HCl used  n B formed
V  0.5 100  V   0.25
Or,   VHCl  100 mL
1000 1000
Finally, n BOH takes  n HCl used for equivalent point
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Sri Chaitanya IIT Academy, India 15-11-2020_Sr.Super60_Jee-Adv(2016-P1)_Paper-1_PTA-05_Key & Sol’s
w 100  0.5
Or,   w  2.25 gm
45 1000
2.25
 Percentage purity of base =  100  90%
2.5
32. Milli moles of Ag  in 100 mL sat.soln of AgCl is = 100 K sp  1.4  103
m.moles of Ag   m .moles of SCN -
1.4  103  105  V  V  140mL
33. Let millimoles of acid & salt present initially are ‘x’ .
 pH 1  pK a
(a  0.1)
 pH 2  pK a  log
(a  0.1)
(a  0.1)
 pH 1   pH 2  0.3  log
(a  0.1)
a = 0.3 and 0.1V  0.3  V  3mL
34.
 CO2 (g)  H 2 (g)
CO(g)  H 2O(g) 
t0 1 1
t  eq 1  x 1 x x x
x2 3
9 x 
(1  x) 2 4
Assume some pure CO2 is present another vessel, then, at new equilibrium
 CO 2 (g) 
CO(g)  H 2O(g)  H 2 (g)
1 1 1 1 3 1 3 1
  a 
4 4 4 4 4 4 4 4
Solving
a=4
since, moles ratio=volume ratio at constant pressure and temperature.
Volume of CO2 vessel=4 L
35. Solubility of Zn  OH  2 is
2 K sp 2
S=  Zn 2    Zn(OH)4  =  K f  OH  
  2  
 OH  
 
In case of minimum solubility
dS
0
d OH  
 

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Sri Chaitanya IIT Academy, India 15-11-2020_Sr.Super60_Jee-Adv(2016-P1)_Paper-1_PTA-05_Key & Sol’s
2K sp
  2K f OH    0
3  
OH  
 

OH    104
 
pOH=4
36. At equilibrium, Pressure in left and right side chambers is same.
In left chamber, PHe  2 atm
42
 PNH3  PH 2S   1 atm
. 2
 K p  1  1  1 atm 2

MATHEMATICS
2
37. G.I    x   x x
e
  e   e  ee
38. f  x    sin 3 x cos3 x.cos 2x.ln  sin 2x  dx
1
   sin 2x  3 .ln  sin 2x  . 2cos 2x  dx
16
Put sin 2x  t
1
  t 3 .ln t.dt
16
1  t4 1 t4  1  t4 t4 
 ln t.   . dt   ln t    c
16  4 t 4  16  4 16 
t4  1
  ln t    c
64  4

x   t 1
4
c0
5
x  t 1
4
 5  1
f  
 4 256
1
c0 GE  
256
x cos x x sin x
39. G.I   dx   dx
x sin x  cos x x cos x  sin x
x sin x  cos x     
 ln c  f     ln  
x cos x  sin x   
2   2
Cleary c  0  f      ln 

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Sri Chaitanya IIT Academy, India 15-11-2020_Sr.Super60_Jee-Adv(2016-P1)_Paper-1_PTA-05_Key & Sol’s
40. Using by parts
1
G.E  tan x.ln 1  sin 2 x   
1  sin 2 x

.2sin cos x.tan xdx

 
 tan x.ln 1  sin 2 x  2x  2 tan 1 2 tan x  c  
  7
h  0  0  c  0 & h    3 ln    2 tan 1
 3  4  6   23
2
 G.E  
3
1
41. 
G.I   3x 5  2x 3  2x 5 x 6  x 4  x 4  4
dx
Put x 6  x 4  x 4  t
2 5/4

 x 6  x 4  x 4
5
c c0 
5/4
2 1
 f  2   26  24  4 
5 2 
1 5/4
 1281  GE  80
80

42.

tan 4   1  1 
 1  tan 2  dx
1
   sec2  d   d
1  tan 2 
cos 2 
  tan    d
cos 2
1 1  cos 2
  tan    d
2 cos 2
1
  tan    1  sec 2  d
2
 1
  tan    ln sec 2  tan 2  c
2 4
(But c=0) since f  0  0
  1
Clearly it is odd, Also f     3   ln 2  3  0
 3 6 4
 
43.
x 2

 1 tan 1 x  x ln x ln  ln x 
  
x x 2  1 ln x
dx

 1 1 
   tan 1 x.  ln  ln x   dx
 x ln x 1 x2 
 ln  ln x  .tan 1 x  c
  e  0  c  0

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ln  ln x  .tan 1 x  ln  ln x    
 G.E : lim  .lim  
x 1  x 4 x1  x  
tan   tan  
 2  2
1  x
cos 2  
 x  ln x  1  2   0
 lim  lim  
4 2  x  2 ln x 0
x 1 x 1
sec  
 2 2

1  sin   x  .
 .lim 2  1  0  0
2 x1 1 2
x
  
cos x  2.sin  x   x 
 3 
44.       2 dx
 2sin  x  3   1
   
cos x  2sin  x   cos x  2cos  x   .sin x
 3  3
 2
dx
   
 2sin  x  3   1
sin x
 c
 
2sin  x    1
 3
 f  0  0& c  0
   x   sin x
tan 2  .cos 2  .sec 2  d
45.   x   2
e x  tan 
 cos  tan   .cos  sin  tan   .sin  
tan 2 
 2
d
cos  tan     
  sec 2  tan     .tan 2  d

  
 tan  tan      c : tan e x  tan 1 e x  c
   tan1  1
  0  tan 1    c0
 4  1  tan1

   x   tan e x  tan 1 e x  
A  1, B  1, C  1
f  x 2t dt  t 
46. Put  1  t 2  h  x   2  2 tan 1  c
g  x t 2 t   2 

 f  x  g  x 
 2 tan 1   c
 2g  x  

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Sri Chaitanya IIT Academy, India 15-11-2020_Sr.Super60_Jee-Adv(2016-P1)_Paper-1_PTA-05_Key & Sol’s
Clearly c  0  m  2 and n  2
 3      
1  x  x  1  2x  m  x  mx  n 3x  1
2 2

47. g ' x    2 
9
 x3  x  1   
2
 2 1
 x  3x  
3
Comparing with 2
x 3
 x 1 

coefficient of x 4 :  1    9
9
m  3m
coefficient of x 3 :  6  m  3n  54  m  27
9
mn 1
Constant :   n  26
9 9
1
48. I    sin10x  5sin 8x  10sin 6x  10sin 4x  5sin 2x  dx
32
1  5cos 2x 10cos 4x 10cos 6x 5cos8x cos10x 
       c
32  2 4 6 8 10 
x x 1
49. A) By parts  x. dx    .tan 1 x  c  c  0
1 x 2 2
 2 1 x 2
2   
 1
  1  
8 4
x e
B)  cos  3ln x  dx 
10
 cos  3ln x   3sin  3ln x      e   cos3  3sin 3
10
3
 tan x 
C) By parts  g  x   4x sin 4 x  4  tan x   g     4
 3 
sin 2x sin 4x  
D) GI     cos 2x  cos 4x  1 dx     x  h   
2 4  2 2
1 1
50. GI   7/6
dx   dx
x 5/6
 x  2 x 3/4
 x  25/4
x x
 36  2. 4
x2 x2
f  3  3. 3  2. 3
6 4

A3
B  2
A  B 5

51.
 x  2x  1 x  1
2 2

(Divide with x 3 , Numerator & denominator)

 x  1 x  x  1 dx
2
 2 4 2

SEC: Sr.Super60 Page 11

Sri Chaitanya IIT Academy, India 15-11-2020_Sr.Super60_Jee-Adv(2016-P1)_Paper-1_PTA-05_Key & Sol’s
 1  1
 x   2 1  2  1
x x
 dx x t
 1
2
 1
2 x
 x    x    1
x x
t2 1 dt
 dt   dt  2
2 2 2 2
t t 1 t t 1 t t2 1
1 t 3
 sec t  2 dt
1  t 2
 tan 1  
t 2  1  2 1  t 2  c

t2 1
 tan 1  t2  1  2
t
ck  2

 
1 x
52.   x   GI  e  x
1
 3
 c
 2
  2
x 1  2
 2
x 1  
c0
 1 1  3e
  1  e      1 
 2 2 2 2 2
8 2
 2  1   9
e
53. Put 1  e x  x.e  x  t  A  1, B  1,C  1
54. Using by parts
1   1    1  2x  
I1   2  x  x2      dx
x  x  2 2  x  x 
2

1 1 1 1
I2   2  x  x2   dx   dx
x 2xx 2 2 x  x  x2
1 1  2x  1
 I1  I2   2  x  x 2  sin 1  c
2 x  3 
 f  x
 1
Given f  1  2  sin 1    c  0
 3
 1 1 1  3
f     2 2    0  2   3
 2 2 4  2

SEC: Sr.Super60 Page 12