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Carbon Disulfide
Section 1. Identification
GHS product identifier : Carbon Disulfide
Chemical name : carbon disulphide
Other means of : Carbon disulfide; Carbon bisulfide
identification
Product use : Synthetic/Analytical chemistry.
Synonym : Carbon disulfide; Carbon bisulfide
SDS # : 001113
Supplier's details : Airgas USA, LLC and its affiliates
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253
Date of issue/Date of revision : 1/23/2017 Date of previous issue : 11/25/2015 Version : 0.02 1/13
Carbon Disulfide
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Carbon Disulfide
Specific hazards arising : Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
from the chemical and the container may burst, with the risk of a subsequent explosion. The vapor/gas is
heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back.
Runoff to sewer may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
sulfur oxides
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
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Carbon Disulfide
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated
incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
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Carbon Disulfide
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
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Carbon Disulfide
Odor : Characteristic.
Odor threshold : Not available.
pH : Not available.
Flash point : Closed cup: -22°C (-7.6°F)
Burning time : Not applicable.
Burning rate : Not applicable.
Evaporation rate : 10.9 (butyl acetate = 1)
Flammability (solid, gas) : Highly flammable in the presence of the following materials or conditions: oxidizing
materials.
Lower and upper explosive : Lower: 0.6%
(flammable) limits Upper: 50%
Vapor pressure : 47.9 kPa (359.280538645 mm Hg) [room temperature]
Vapor density : 2.63 (Air = 1)
Specific Volume (ft /lb)3
: 0.7899
Gas Density (lb/ft 3) : 1.266
Relative density : 1.26
Solubility : Not available.
Solubility in water : 2.16 g/l
Partition coefficient: n- : 1.94
octanol/water
Auto-ignition temperature : 90°C (194°F)
Decomposition temperature : Not available.
SADT : Not available.
Viscosity : Dynamic (room temperature): 0.0164 mPa·s (0.0164 cP)
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
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Carbon Disulfide
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
carbon disulphide Category 1 Not determined Not determined
Aspiration hazard
Not available.
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Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
carbon disulphide 1.94 19.5 low
Mobility in soil
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Carbon Disulfide
Packing group I I I I I
Environment No. No. No. No. No.
Additional Reportable quantity Product classified as - - Passenger and Cargo
100 lbs / 45.4 kg [9. per the following AircraftQuantity
information sections of the
4735 gal / 35.861 L] limitation: 0 Forbidden
Package sizes shipped Transportation of Cargo Aircraft Only
in quantities less than Dangerous Goods Quantity limitation: 0
the product reportable Regulations: 2.18-2.19 Forbidden
quantity are not subject (Class 3), 2.26-2.36
to the RQ (reportable (Class 6).
quantity) transportation
requirements. Explosive Limit and
Limited Quantity Index
Limited quantity 0
Yes.
ERAP Index
Packaging instruction 1000
Passenger aircraft
Quantity limitation: Passenger Carrying
Forbidden. Ship Index
Forbidden
Cargo aircraft
Quantity limitation: Passenger Carrying
Forbidden. Road or Rail Index
Forbidden
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Carbon Disulfide
“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.”
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
Clean Air Act (CAA) 112 regulated toxic substances: carbon disulphide
Clean Air Act Section 112 : Listed
(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
SARA 302 TPQ SARA 304 RQ
Name % EHS (lbs) (gallons) (lbs) (gallons)
carbon disulphide 100 Yes. 10000 947.3 100 9.5
SARA 304 RQ : 100 lbs / 45.4 kg [9.5 gal / 35.9 L]
SARA 311/312
Classification : Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
Name % Fire Sudden Reactive Immediate Delayed
hazard release of (acute) (chronic)
pressure health health
hazard hazard
carbon disulphide 100 Yes. No. No. Yes. Yes.
SARA 313
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Carbon Disulfide
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts : This material is listed.
New York : This material is listed.
New Jersey : This material is listed.
Pennsylvania : This material is listed.
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.
Ingredient name Cancer Reproductive No significant risk Maximum
level acceptable dosage
level
carbon disulphide No. Yes. No. No.
International regulations
International lists
National inventory
Australia : This material is listed or exempted.
Canada : This material is listed or exempted.
China : This material is listed or exempted.
Europe : This material is listed or exempted.
Japan : This material is listed or exempted.
Malaysia : Not determined.
New Zealand : This material is listed or exempted.
Philippines : This material is listed or exempted.
Republic of Korea : This material is listed or exempted.
Taiwan : This material is listed or exempted.
Canada
WHMIS (Canada) : Class B-2: Flammable liquid
Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
CEPA Toxic substances: This material is not listed.
Canadian ARET: This material is not listed.
Canadian NPRI: This material is listed.
Alberta Designated Substances: This material is not listed.
Ontario Designated Substances: This material is not listed.
Quebec Designated Substances: This material is not listed.
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Carbon Disulfide
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)
3 Flammability
Health 2 0 Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
Flam. Liq. 2, H225 Expert judgment
Skin Irrit. 2, H315 Expert judgment
Eye Irrit. 2A, H319 Expert judgment
Repr. 2, H361 (Fertility) Expert judgment
Repr. 2, H361 (Unborn child) Expert judgment
STOT RE 1, H372 Expert judgment
History
Date of printing : 1/23/2017
Date of issue/Date of : 1/23/2017
revision
Date of previous issue : 11/25/2015
Version : 0.02
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
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