Paragraph – II

ABCD is a square of side . At A and C point masses of mass m are placed. At B and D point masses
of mass 2m are placed. Masses at A, B and D are fixed where as the mass at C is movable.

17. The gravitational field generated by the four particles at P is (if C is also fixed)
6Gm Gm  2 5Gm 
A) zero B)
 2 
C) 3  2 2 

D) 
 
2 

18. The initial acceleration of the mass at C is
9Gm 2 2Gm Gm  4 2  1 5Gm
A) B) C) D)
 2
2  2  2  2

CHEMISTRY Max Marks: 62

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
1
19. AB3 g  is dissociates as AB3 g   AB2 g   B2  g  . When the initial pressure of AB3 is 800 torr and the
2
total pressure developed at equilibrium is 900 torr. What percentage of AB3 g  is dissociated?
A) 10% B) 20% C) 25% D) 30%
20. 

In the dissociation of AB2 as AB 2  g  
 AB  g   B  g , the equilibrium pressure of AB2 is 400 mm and
equilibrium constant is 100 mm. The initial pressure of AB2 was
A) 600 mm B) 200 mm C) 400 mm D) 800 mm
21. 

Reactants A and B are mixed in the molar ratio 1 : 1.5 to establish the equilibrium A  2B 
 2C  D .
At equilibrium the concentrations of A and B are found to be equal. The equilibrium constant KC for
the reaction is
A) 0.25 B) 4 C) 1 D) 2
22. The conjugate acid of NH 2 is
A) NH3 B) NH2OH C) NH4+ D) N2H4
23. 1 cc of 0.1 N HCl is added to 99cc solution of NaCl. The pH of the resulting solution will be
A) 7 B) 3 C) 4 D) 1
24. A 110.00g sample of a mixture of CaCl2 and NaCl is treated with Na2CO3 to precipitate the calcium as
calcium carbonate. This CaCO3 is heated to convert all the calcium to CaO and the final mass of CaO
is 11.2 gm. The % by mass of CaCl2 in the original mixture is
Na CO
2 3  CaC 2  
 CaCO3  2NaC; CaCO3   CaO  CO 2 
A) 15.2% B) 32.1% C) 20.18% D) 20.9%
 SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases
25. Which of the following are true for H3PO2?
A) It is a tribasic acid
B) One mole of it is neutralized by 0.5 mole of Ca(OH)2
C) it’s 100 ml of M/3 neutralised by 100 mlof 1 M NaOH
D) NaH2PO2 is normal salt
26. For pure water at 25C and 50C the incorrect statement(s) is/are
A) pH250 C  pH200 C B) pH250 C  pH500 C
C) pOH250 C  pOH500 C D) pOH250 C  pOH500 C
27. Which of the following solution will have pH = 13 ?
A) 2g NaOH in 500 mL solution B) 100 mL solution of 0.05 M Ca(OH)2
C) 100 mL solution of 0.1 N Ca(OH)2 D) 4g NaOH in 500 mL solution.
28. Which among the following statements is/are correct ?
A) pH of 10 –8 M HCl is equal to 8
B) Conjugate base of H2PO4 is HPO24
1
C) pH of 0.1 M NaCl (aqueous solution) = pK w
2
D) Conjugate acid of OH– is O2–
29. Which of the following solutions will be acidic?
A) 0.1M FeSO4 B) 0.1M  NH 4 2 SO4 C) 0.1M CH3COONa D) 0.1M NH 4OH
30. Which of the following is an amphoprotic anion
A) HCO3 B) H2PO4 C) HS  D) HPO23
31 Equal weight of ‘X’ (At. Wt : 36) and Y (At Wt : 24) are reacted to form the Compound X2Y3. Then
incorrect statement is.
A) ‘X’ is the excess reagent
B) ‘Y’ is the limiting reagent
C) Mass of ‘X2Y3’ formed is mass of ‘X’ taken.
D) Mass of ‘X2Y3’ formed is double the mass of ‘X’ taken.
32. Which of the following cases concentration of solution is more than 1M
A) 20g NaOH in 200 ml sol. B) 1 mole of Ba(OH)2 in 500 ml sol.
C) 8% w/v NaOH aqueous sol. D) 20% w/v sol of Al(NO3)3

SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph -I
The shape of the molecule is determined by bond pairs as well as lone pairs. If molecule has only bond
pairs then there is no distortion hence geometry & shape both are equal.
33. In which of the following, bond angle is maximum?
A) NH3 B) NH4 C) PC 3 D) SC 2
34. Which of the following structure is most expected for the molecule SF4 ?
A) Trigonal bi-pyramidal B) Square pyramidal
C) T-shape D) See-saw
Paragraph -II
Chemical equilibrium is a particular state of a reversible reaction in which the forward and backward
reactions occur at the same rate and the concentrations at all reactants and products remain constant.
The attainment of equilibrium is recognised by constancy of certain observable properties such as
colour of the reaction mixture, pressure, concentration of reactants or products, specific rotation etc.
equilibrium can be obtained in a closed vessel only.
35. 
Which of the following statement is correct for the equilibrium A  B   C  D?
A) At equilibrium both forward and backward reactions come to stand still
B) The concentration of A, B, C and D are must equal
C) Equilibrium can be attained only by mixing A and B and not C and D
D) The concentration of A, B, C and D do not change with time
36.  2 HI, at a certain stage Qc  K c . (Qc  reaction coefficient,
For the reaction H 2  I 2 
(g) (g) (g)

K c  equilibrium constant) This indicates that

A) The reaction will proceed from left to right
B) The reaction will proceed from right to left
C) The reaction will be at equilibrium
D) The reaction will stop

MATHEMATICS Max Marks: 62

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
n a 

37. If an and bn are positive integers and an  2bn  2  2 , then lim  n   n  b
 n
A) 2 B) 2 C) e 2
D) e2
sin 2 x
 n 2 
38. Lt   r cos ec x  
x 0  r 1 

1
A) 0 B)  C) n D)
n
a tan x  a sin x
39. lim is equal to  a  0 
x  0 tan x  sin x

A) log e a B) 1 C) 0 D) 
1  1 
40. lim [ . ]  denotes greatest integer function
1
x  x  x 
3
A) –9 B) –12 C) –6 D) 0
41. A function f ( x ) is defined by ,
[ x 2 ]  1
 2 , for x 2  1
 x 1
f ( x)   Where[.] denotes GIF
0 , for x2  1


A) Continuous at x  1 B) Discontinuous at x  1
C) Left Continuous Only at x  1 D) Right Continuous Only at x  1