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PAPER 3
PRACTICE PAPER 3
Max 90 marks
1 hour 45 minutes
Name ……………………………………………………………..
The first 10 multiple choice questions have already been used for AS-level resources
Page 1
1. Chlorine is a useful industrial chemical.
(i) Write equations for the following steps in the mechanism for the reaction of chlorine
with ethane to form chloroethane (CH CH Cl). 3 2
Initiation step
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(4)
(ii) Give one essential condition and name the type of mechanism in this reaction of
chlorine with ethane.
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(1)
(ii) Give one large-scale application of the use of chlorine in water. Explain why it is
used in this application even though chlorine is very toxic. Do not include cost.
Example of application….....................................................................
(iii) Two different chlorine-containing compounds are formed when chlorine reacts with
cold, dilute sodium hydroxide solution. One of these compounds is sodium chloride.
Name the other chlorine-containing compound formed.
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(1)
Page 2
(c) Chlorine is used in the extraction of bromine from seawater.
(i) Write the simplest ionic equation for the reaction of chlorine with bromide ions.
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(1)
(ii) Explain why bromine has a higher boiling point than chlorine.
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(2)
(Total 13 marks)
2. The following pairs of compounds can be distinguished by observing what happens in test-tube
reactions.
For each pair, give a suitable aqueous reagent that could be added separately to each
compound.
Describe what you would observe in each case.
Reagent ......................................................................................................
Reagent .......................................................................................................
(3)
Reagent .......................................................................................................
Page 3
(d) Butan-2-ol(l) and 2-methylpropan-2-ol(l)
Reagent …...................................................................................................
3. This question involves calculations about two strong acids and one weak acid.
All measurements were carried out at 25 °C.
(a) A 25.0 cm sample of 0.0850 mol dm hydrochloric acid was placed in a beaker and
3 –3
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(2)
(i) Write an expression for the acid dissociation constant, K , for HX. a
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(1)
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Page 4
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(3)
(c) A 25.0 cm sample of 0.620 mol dm nitric acid was placed in a beaker and 38.2 cm of
3 –3 3
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(6)
(Total 12 marks)
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(1)
(b) In terms of electrons explain how the water molecules, not shown in the diagram, form
bonds to the iron.
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Page 5
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(2)
Page 6
(c) Predict the value of the bond angle between the two bonds to iron that are formed by
these two water molecules.
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(1)
A 1.381 g sample of impure FeC O .2H O was dissolved in an excess of dilute sulfuric acid
2 4 2
potassium manganate(VII).
(i) Use the half-equations given below to calculate the reacting ratio of moles of
manganate(VII) ions to moles of iron(II) ethanedioate.
MnO + 8H + 5e
4
– + –
Mn + 4H O
2+
2
Fe 2+
Fe + e
3+ –
CO
2 4
2–
2CO + 2e 2
–
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(1)
(If you have been unable to answer part (d)(i) you may assume that three moles of
manganate(VII) ions react with seven moles of iron(II) ethanedioate. This is not the
correct ratio.)
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Page 7
(5)
(Total 10 marks)
(a) Consider the following reaction scheme that starts from [Co(H O) ] ions. 2 6
2+
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(9)
Page 8
(b) A flue-gas desulfurisation process involves the oxidation, by oxygen, of aqueous
sulfate(IV) ions (SO ) into aqueous sulfate(VI) ions (SO ). This reaction is catalysed by
3
2–
4
2–
Write an equation for the overall reaction of sulfate(IV) ions with oxygen to form sulfate(VI)
ions.
Suggest a mechanism for the catalysed reaction by writing two equations involving Co 2+
and Co3+ ions. You will need to use H ions and H O to balance these two equations.
+
2
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(4)
(Total 13 marks)
6. Chlorine has two isotopes, 35Cl and 37Cl. The number of molecular ion peaks in the mass
spectrum of a sample of Cl2 is
A 2
B 3
C 4
D 5
(Total 1 mark)
Page 9
7. A brand of fluoride tablets, recommended by a dentist to strengthen the enamel on teeth,
contains 2.2 × 10−3 sodium fluoride per tablet. The total mass of fluoride ion present in 100
tablets is
D
(Total 1 mark)
B C2F4
C (CH3)2CO
D CO2
(Total 1 mark)
Enthalpy data for the reacting species are given in the table below.
Substance CO(g) H2O(g) CO2(g) H2(g)
The standard enthalpy change for this reaction of carbon monoxide and steam is
A +42 kJ mol−1
B −42 kJ mol−1
C +262 kJ mol−1
D −262 kJ mol−1
(Total 1 mark)
Page 10
10. This question is about the Maxwell–Boltzmann distribution of molecular energies in a sample of
a gas shown in the following figure.
(Total 1 mark)
11. When one mole of ammonia is heated to a given temperature, 50 per cent of the compound
dissociates and the following equilibrium is established.
A 1.5
B 2.0
C 2.5
D 3.0
(Total 1 mark)
Page 11
12. Which substance is not produced in a redox reaction when solid sodium iodide reacts with
concentrated sulfuric acid?
A H2S
B HI
C SO2
D I2
(Total 1 mark)
A 5
B 4
C 3
D 2
(Total 1 mark)
14. Consider the reaction between propene and hydrogen bromide to form the major product.
B CH3–CHBr–C+H2
C CH3–C+H–CH3
D CH3–CH2–C+H2
(Total 1 mark)
Page 12
15. This question is about a method that can be used to prepare ethylamine.
CH3CH2Br + 2NH3 CH3CH2NH2 + NH4Br
(Total 1 mark)
16. How many structural isomers, which are esters, have the molecular formula C4H8O2?
A 2
B 3
C 4
D 5
(Total 1 mark)
17. In a titration, 0.52 g of a diprotic acid, H2X, reacts exactly with 100 cm3 of 0.10 M sodium
hydroxide.
A ethanedioic
B propanedioic
C butanedioic
D pentanedioic
(Total 1 mark)
Page 13
18. This question is about the following reaction scheme which shows the preparation of polymer P.
A 64
B 66
C 68
D 70
(Total 1 mark)
19. Which one of the following pairs reacts to form an organic product with only 2 singlets in its
proton n.m.r. spectrum?
20. The percentage of iron in a sample of impure iron(II) sulphate crystals can be determined by
titrating solutions, made from separate weighed samples acidified with dilute sulphuric acid,
against a standard solution of potassium manganate(VII).
Which one of the following statements explains why dilute hydrochloric acid is unsuitable for
use in this titration?
Page 14
21. The percentage of iron in a sample of impure iron(II) sulphate crystals can be determined by
titrating solutions, made from separate weighed samples acidified with dilute sulphuric acid,
against a standard solution of potassium manganate(VII).
Which one of the following would lead to the greatest error in the calculation of the percentage
of iron(II) in the sample?
A an error of 0.005 g made when weighing out a sample of mass 0.987 g
D using the average of the titration values 25.4, 25.7 and 25.9 when the correct value is
25.5 cm3
(Total 1 mark)
22. Which one of the following statements about the reaction below is false?
23. In which one of the following reactions is H2O2 behaving as a reducing agent?
Page 15
24. In the table below, which one of the following complex ions has a correct shape, co-ordination
number and oxidation state?
Co-ordination Oxidation state of
Complex Shape
number central cation
A [Ag(CN)2]− Linear 2 –1
B [CuCl4]2− Tetrahedral 4 –2
C [Cr(C2O4)3]3− Octahedral 3 +3
D [Cu(NH3)4(H2O)2]2+ Octahedral 6 +2
(Total 1 mark)
25. Use your knowledge of the chemistry of transition metals to predict which of the following will
convert [Mn(H2O)6]2+ into MnO
Enthalpy data for the reacting species are given in the table below.
Substance CO(g) H2O(g) CO2(g) H2(g)
C The entropy change is more positive when the water is liquid rather than gaseous.
D The enthalpy change is more positive when the water is liquid rather than gaseous.
(Total 1 mark)
Page 16
27. The vanadium does not have an oxidation state of +3 in
A [V(H2O)6]3+
B [V(C2O4)3]3−
C [V(OH)3(H2O)3]
D [VCl4]3−
(Total 1 mark)
28. Propanone can be reduced to form an alcohol. A functional group isomer of the alcohol formed
is
A CH3CH2CH2OH
B CH3CH2CHO
C CH3OCH2CH3
D CH3COCH3
(Total 1 mark)
30. In which one of the following reactions is a heterogeneous catalyst not used?
B CO + NO → CO2 + N2
C CO2 + C → 2CO
D SO2 + O2 → SO3
(Total 1 mark)
Page 17
Page 18
31. Which one of the following is a correct procedure for isolating a sample of hydrated copper(II)
sulphate from a mixture of hydrated copper(II) sulphate and barium sulphate?
C add water, filter, dry the solid left on the filter paper
32. The following information concerns the equilibrium gas-phase synthesis of methanol.
At equilibrium, when the temperature is 68 °C, the total pressure is 1.70 MPa.
The number of moles of CO, H2 and CH3OH present are 0.160, 0.320 and 0.180, respectively.
ΔH / kJ mol−1
Substance S / J K-1 mol-1
H2(g) 0 131
Page 19
33. An aqueous solution contains 4.0 g of sodium hydroxide in 250 cm3 of solution.
(Kw = 1.00 × 10−14 mol2 dm−6)
A 13.0
B 13.3
C 13.6
D 13.9
(Total 1 mark)
34. Which one of the following pairs of reagents reacts to form an organic product that shows only 2
peaks in its proton n.m.r. spectrum?
35. In which one of the following reactions does the metal species undergo reduction?
Page 20