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Guess Paper – 2011

Class – XII
Subject – Chemistry
PART-I (Answer all questions)
1. a) Fill in the blanks choosing words from the following:-

[5]
[More, period, non, less, identical, fastest, Raoult’s law,

slowest, independent, high, solute]
(i) _________ hybrid orbitals of nitrogen are involved in the

formation of ammonium ions.
(ii) Half-life ____________ for a first order reaction is

___________ of initial concentration.
(iii) According to ___________, the relative lowering of vapour

pressure is equal to mole fraction of ________ in the
solution.
(iv) In a reaction involving more than on elementary

reaction, the ________ elementary step is the rate
determining reaction.
(v) Amines are _________ basic than water but __________

basic than hydroxide.
b) State whether each of the following is true or false. If false

correct them:- [5]
(i) A reaction with zero activation energy is practically

independent of temperature.
(ii) The average speed of reaction increases with time.

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(iii) Benzaldehyde undergoes aldol condensation in an alkaline

medium.
(iv) The --OH group present at the meta position in benzoic acid
has an acid weakening effect.
(v) The collection of ozone is done by brodie’s ozonizer.
c) Give balanced equations for the following reactions and

also name the products formed:- [5]
(i) Cuprous oxide and cuprous sulphide are heated together.
(ii) Bromine and sulphur dioxide in presence of water.
(iii) Formaldehyde with ammonia.
(iv) Aniline and acetic anhydride.
(v) Acetaldehyde with hydroxyl amine.
d) Answer the following questions in brief:- [5]
(i) What kinds of isomerism, if any, do the compounds

CH3CH=CHCH3 and CH3OC3H7 exhibit?
(ii) Name the monosaccharides that constitute starch. By what

type of reaction are they linked?
(iii) What happens when acetaldehyde is treated with conc.

sulphuric acid below 00 C?
(iv) How do starch and cellulose differ w.r.t the linkage of their
monomer?
(v) Give a suitable test to distinguish between 1-propanol and 2-

propanol.
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PART-II
SECTION-A (Answer any two questions)
2. a) (i) At 300 K, a first order reaction is 50% complete in 20

min. At 350 K, the same reaction is 50% complete in 5 min.
Calculate the activation energy of the reaction.
(ii) What are the factors on which rate constant of a

reaction depends? [3]
b) (i) Why calcium chloride is used to clear snow on roads?
(ii) The freezing point of ether was lowered by 600C on

dissolving 20 gm of phenol in 100 gm of ether. Calculate the
molar mass of phenol and comment on the result. [Kf (ether)
= 5.12 K mol-1] [4]
c) Derive Ostwald’s law of dilution and state the Arrhenius

equation. [3]
3. a) (i) Calculate the work of expansion 1.5 kg of air from 10

atm to 1 atm at 270C isothermally and reversibly.
(ii) Give the relationship between free energy and emf of

a cell. [3]
b) A metal M (atomic mass 50) has a bcc crystal lattice. The

density of the metal is 5.91 gm cm-3. Find out the volume of
the unit cell. [3]
c) At 00C ice and water are in equilibrium and enthalpy

change is 6 kJ mole-1 for the process. What will be the
entropy change and Gibb’s free energy change for the
conversion? [4]
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4. a) (i) On electrolysis of an aq. Electrolye between copper

electrodes it is observed that cuprous oxide is formed at
the anode. What will be the mass of the cuprous oxide
formed if a current of 0.965 amp is passed for 2500
seconds? (at. Mass of Cu = 63.5)
(ii) How does electrochemical cell differ form electrolytic

cell? [4]
b) (i) Write the cell reaction for the cell:
Cu | Cu2+ | | Ag+ | Ag
(ii) A buffer soln. contains 0.2 gm mole of acetic acid and

0.25 gm mole of sodium acetate per litre. Calculate the
change of pH of the solution if 0.5 mole of N HCl is added to
it. The dissociation constant of acetic acid at room
temperature is 1.8 x 10-5. [3]
c) Show the molecular orbital diagram of O2+ molecule.

State whether it is paramagnetic or diamagnetic.
[3]
SECTION- B (Answer any two questions)
5. a) Describe the gradation in the following physio-chemical

properties of transition metals:
(i) Metallic character, (ii) Ionic radii, (iii) Complex formation

[3]
b) Write chemical equations for the conversion of:
(i) chromite ore to sodium chromate
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(ii) pyrolusite to potassium permanganate

[2]
6. a) Outline the steps involved in the extraction of copper from

copper pyrites.[4]
b) Give the chemical formula of potassium hexacyano ferrate

(II). [1]
7. a) Predict the probable structure of IF5.

[1]
b) (i) How is chlorine prepared from sodium chloride?
(ii) Write balanced equation when chlorine is passed through

hot and conc. Sodium hydroxide?
(iii) Explain why bleaching action of chlorine is an oxidizing

reaction. [3]
c) Explain how [Fe(CN)6]3- is weakly paramagnetic, while

[Fe(CN)6]4- is diamagnetic.
[1]
SECTION-C (Answer any two questions)
8. a) A and B, two isomeric compounds with molecular formula

C3H6O behave in the following ways:
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(i) A can be easily oxidized to an acid whose calcium salt

when distilled forms C which does not reduce Tollen’s reagent.
(ii) B when treated with iodine and sodium hydroxide forms

crystals of yellow colour.
Assign structures to A and B. Is there any isomeric

compounds to these? [4]
b) Give one chemical test to distinguish between the following:

[3]
(i) Acetaldehyde and benzaldehyde
(ii) Phenol and acetic acid
(iii) Glucose and fructose
c) (i) What is an optical activity? What characteristics are

required in an organic compound to exhibit optical activity?
Explain with an example. [3]
9. a)(i) What is addition polymerization?
(ii) What are the chemical characteristics of the monomer?
(iii) What is the type of catalyst used in addition

polymerization?
(iv) Give one example for addition polymerization.

[4]
b) Convert:-
[6]
(i) formic acid to acetic acid
(ii) acetylene to acetone
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(iii) nitrobenzene to o-dinitrobenzene
(iv) Aniline to chlorobenzene
(v) Acetaldehyde to isopropyl alcohol
(vi) Sorbitol to glucose
10. a) Give reasons in support of amphoteric nature of glycine.

Mention the pH value of isoelectric point.
[3]
b) Explain the following name reactions:-

[6]
(i) Cannizaro reaction
(ii) Reimer-Tiemann reaction
(iii) Cross-aldol condensation
c) Predict the product (Y) for the reaction and also write the
general name:-[1]
OH
+ 3HNO3 Conc. H2SO4 Y
Paper Submitted By:
Name Mr. MRINAL JANA
Email Id mr.mrinal_2010@rediffmail.com
Telephone No. 9474606933

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Guess Paper – 2011

PART-I (Answer all questions)

1. a) Fill in the blanks choosing words from the following:-

[More, period, non, less, identical, fastest, Raoult’s law,

(i) _________ hybrid orbitals of nitrogen are involved in the

(ii) Half-life ____________ for a first order reaction is

(iii) According to ___________, the relative lowering of vapour

(iv) In a reaction involving more than on elementary

(v) Amines are _________ basic than water but __________

b) State whether each of the following is true or false. If false

(i) A reaction with zero activation energy is practically

(ii) The average speed of reaction increases with time.

(iii) Benzaldehyde undergoes aldol condensation in an alkaline

(v) The collection of ozone is done by brodie’s ozonizer.

c) Give balanced equations for the following reactions and

(i) Cuprous oxide and cuprous sulphide are heated together.

(ii) Bromine and sulphur dioxide in presence of water.

(iii) Formaldehyde with ammonia.

(iv) Aniline and acetic anhydride.

(v) Acetaldehyde with hydroxyl amine.

d) Answer the following questions in brief:- [5]

(i) What kinds of isomerism, if any, do the compounds

(ii) Name the monosaccharides that constitute starch. By what

(iii) What happens when acetaldehyde is treated with conc.

(v) Give a suitable test to distinguish between 1-propanol and 2-

SECTION-A (Answer any two questions)

2. a) (i) At 300 K, a first order reaction is 50% complete in 20

(ii) What are the factors on which rate constant of a

b) (i) Why calcium chloride is used to clear snow on roads?

(ii) The freezing point of ether was lowered by 600C on

c) Derive Ostwald’s law of dilution and state the Arrhenius

3. a) (i) Calculate the work of expansion 1.5 kg of air from 10

(ii) Give the relationship between free energy and emf of

b) A metal M (atomic mass 50) has a bcc crystal lattice. The

c) At 00C ice and water are in equilibrium and enthalpy

4. a) (i) On electrolysis of an aq. Electrolye between copper

(ii) How does electrochemical cell differ form electrolytic

b) (i) Write the cell reaction for the cell:

(ii) A buffer soln. contains 0.2 gm mole of acetic acid and

c) Show the molecular orbital diagram of O2+ molecule.

SECTION- B (Answer any two questions)

5. a) Describe the gradation in the following physio-chemical

(i) Metallic character, (ii) Ionic radii, (iii) Complex formation

b) Write chemical equations for the conversion of:

(i) chromite ore to sodium chromate

(ii) pyrolusite to potassium permanganate

6. a) Outline the steps involved in the extraction of copper from

b) Give the chemical formula of potassium hexacyano ferrate

7. a) Predict the probable structure of IF5.

b) (i) How is chlorine prepared from sodium chloride?

(ii) Write balanced equation when chlorine is passed through

(iii) Explain why bleaching action of chlorine is an oxidizing

c) Explain how [Fe(CN)6]3- is weakly paramagnetic, while

SECTION-C (Answer any two questions)

8. a) A and B, two isomeric compounds with molecular formula

(i) A can be easily oxidized to an acid whose calcium salt

(ii) B when treated with iodine and sodium hydroxide forms

Assign structures to A and B. Is there any isomeric

b) Give one chemical test to distinguish between the following:

(i) Acetaldehyde and benzaldehyde

(ii) Phenol and acetic acid

(v) Amines are _ basic than water but __