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Abstract
This work presents thermoeconomic design for a multi-effect evaporation–mechanical vapor compression (MEE–
MVC) desalination process. Exergy and thermoeconomic mathematical models of the considered process units are
developed and presented in this work. The design data of an existing MEE–MVC (1500 m3/day) desalination process
is used for the present analysis. The effect of using external steam to initiate the evaporation process is investigated.
The MEE–MVC without external steam is investigated under different operating conditions. The developed Visual
Design and Simulation (VDS) package is utilized as a powerful tool for the present analysis. The energy analysis
shows that the thermal performance ratio of the considered system with external steam is 8% less than that the system
without external steam. Thermoeconomic analysis shows the unit product cost is 29% higher in the system of external
steam. The unit product cost of the desalted water at the normal operation (without external steam) is calculated by
1.7 $/m3. For system without external steam, by reducing the pressure ratio of the vapor compressor from 1.35 to
1.15, the capital cost of the compressor is reduced by 16%. The specific power consumption is also reduced by 50%.
Sequentially, the unit product cost is reduced from 1.7 to 1.24 $/m3 (27% reduction). Thermoeconomic results show
that, reducing the splitter ratio of the brine re-circulation flow rate from 0.5 to 0.25 while the compression ratio is
specified by 1.15, the unit product cost decreases to 1.21 $/m3. Using the design condition of the considered MEE–
MVC desalination plant, thermoeconomic results show that the minimum unit product cost is obtained at three
evaporators. As the unit product cost at two evaporators and three evaporators are almost the same and due to the
complexity and maintenance requirements, the system of two evaporators is preferable. By increasing the capacity
of the considered process from 1500 m3/day to 5000 m3/day, the results show that the unit product cost at two and
three evaporators are almost the same. Design calculations show that increasing the required capacity of the
considered system, the unit product cost decreases.
Keywords: Desalination; Multi-effect evaporation (MEE); Mechanical vapor compression (MVC); Exergy;
Thermoeconomics; Unit product cost
*Corresponding author.
and thermoeconomic mathematical model of the suction tube, and a wire mesh mist eliminator. In
process units are developed and presented in this this process, vapor releasing from boiling sea-
work. The design data of an existing MEE–MVC water in one side of the evaporator tubes is
(1500 m3/day) desalination process is used for the compressed by a mechanical compressor. Com-
present analysis. The effect of using external pression raises the pressure and temperature of
steam to initiate the evaporation process is inves- vapor which is returned to the other side of the
tigated. The MEE–MVC without external steam first evaporator tubes to be used as a heating
is investigated under different operating condi- source for producing additional vapor, and thus
tions. The developed Visual Design and Simu- continuing the evaporation process. The latent
lation (VDS) package is utilized as a powerful heats of evaporating and condensing vapor are
tool for the present analysis. very nearly equal. Therefore, the energy required
by the compressor is merely supplied to com-
pensate for losses, boiling point elevation, and to
2. Process description
provide a sufficient driving force for heat transfer
As shown in Fig. 1, the system includes a shell operation. The feed seawater is preheated by the
and tube evaporator/condenser, a mechanical condensed vapor (product) and the rejected brine
compressor, plate type feed preheaters, brine and streams. For start-up purposes, and for main-
product pumps. The compressor and evaporators taining normal operating conditions in some
form one single unit which contains horizontal plants, externally supplied heat is provided as
heat-exchanger tubes, spray nozzles, a vapor shown in Fig. 2.
Fig. 1. MEE–MVC system without external steam (Abu Souma, Red Sea, Egypt), 1500 m3/d.
4 A.S. Nafey et al. / Desalination 230 (2008) 1–15
3. Exergy and the thermoeconomic mathe- The chemical exergy is calculated with respect
matical model the sea water composition as follows:
The specific exergy of a fluid stream with
e ch = − N m RuT0 ⎡⎣ ( xw ln xw + xs ln xs )↓ brine ⎤⎦(1b)
negligible kinetic and potential energies is given
by e = h!h0!T0 (s!s0). Since the saline water is a
where
mixture of pure water and salt, the properties of
C p ,m = N m ( xwC p , w + xs C p , s )
salt must be taken into account with pure water
properties. So the exergy point of saline water,
distillate and vapor streams are calculated based
on the developed relation in [7]. The physical N m = ( N pure + N salt )
exergy of a brine stream is calculated from the
following equation:
⎛ ρ + ρs ⎞
ρ m = N m ⎜ w
e ph
= C p ,m ( T − T0 ) ⎜ ρ * ρ ⎟⎟
⎝ f s ⎠
⎡ ⎛ T ⎞ P − P0 ⎤ (1a)
−T0 ⎢C p ,m ⎜ ln ⎟ − ⎥ By summing Eqs. (1a) and (1b) the following
⎣ ⎝ T0 ⎠ T0ρm ⎦ equation is obtained:
A.S. Nafey et al. / Desalination 230 (2008) 1–15 5
Based on Eqs. (1), (2) and (3), the exergy rate of Annual investment = present value ×
i × (1 + i )
n
each process stream is calculated.
Exergy balance analysis of each unit in the (6)
(1 + i )
n
considered process is performed based on the −1
following equation [8]: Using an interest rate, i = 7% and the amorti-
zation year, n = 20 years, then the hourly cost is
E F = E P + E D + E L (4) equal to the annual investment/(365×24×0.9) $/h.
This cost is specified to the VDS program as a
The rate of fuel exergy ( E F ) represents the capital cost for each process unit.
resources expended to generate the product. The
difference between the fuel and product is mainly 3.1. Vapor compressor (Fig. 3)
due to exergy destruction within the system ( E D )
and the exergy loss out of the process ( E L ) [8]. The exergy balance of the vapor compressor is
Thermoeconomic analysis is implemented to developed as follows:
show the expenditure cost and to determine the
unit product cost as well as to point out the unit Wcompressor = E vapor , out − E vapor , in (7)
which needs more improvement. Thermoeco-
E vapor , out − E vapor , in
nomic analysis requires solving energy, exergy ηII = (8)
and cost balance equations of the considered W compressor
6 A.S. Nafey et al. / Desalination 230 (2008) 1–15
Table 1
Cost data of the process units
The purpose of the compressor is to increase the E steam , in + E distilled = E steam , out + E D (10)
pressure at the expense of the electrical power.
T h u s , C F = C power , in a n d C p = C vapor , out + The exergetic efficiency (ηII) is the ratio between
Cvapor , in ; therefore, the cost balance equations for the product and fuel:
vapor compressor can be summarized as follows:
E steam , out
ηII = (11)
( CI+OM ) E steam , in + E
−C power , in − C vapor , in + C vapor , out = Z (9) distilled , in
The purpose of the pump is to increase the The second auxiliary equation states the equal
pressure at the expense of the electrical power. average cost of the heating steam and its con-
Thus, C F = C power , in + Cwater , in and C p = C water , out ; densate, i.e,
therefore:
Fig. 7. Schematic diagram of the distillate/brine heat Fig. 8. Schematic diagram of the feed/brine heat
exchanger. exchanger.
In this unit the distilled water heats the incoming The rejected brine heats the incoming cooling
feed, thus the cost balance equation is represented water; thus,
by the following equation:
C p = C feed , out − C feed , in and C F =
C feed , out − C feed , in = C distilled , in C − C
brine , in brine , out
(23)
−C distilled , out + Z FCI+OM
/D So the cost balance equation can be obtained as
follows:
As the specific cost of the inlet distilled is
equal to the out, an auxiliary equation is written C feed , out − C feed , in = C brine , in
for the feed/distilled exchanger as follows: (27)
−C brine , out + Z FCI+OM
/B
C distilled , in C distilled , out As the specific cost of the inlet brine is equal that
− =0 (24)
E distilled , in E distilled , out of the out, an auxiliary equation is written for the
feed/brine exchanger as follows:
C brine, in C brine, out
− =0 (28)
3.6. Feed/brine heat exchanger (Fig. 8) E brine , in E brine , out
The exergy balance equation balance equation
is written as follows:
4. Calculation methodology
E brine , in − E brine, out = E feed , out − E feed , in + E D , F / B The developed VDS package [6] is utilized to
(25) solve mass, pressure, energy equations iteratively
A.S. Nafey et al. / Desalination 230 (2008) 1–15 9
Table 6
Thermoeconomic variables of MEE–MVC at Cr =1.35 and α = 0.5
Table 7
Thermoeconomic variables of MEE–MVC at Cr = 1.15 and α = 0.50
and feed/brine heat exchangers have the lowest ger is reduced by nearly 20%. Sequentially, the
exergetic efficiency (ηII) and the highest relative unit product cost is reduced from 1.7 to 1.24 $/m3
cost difference (r). Thus it can be concluded that (27% reduction).
a decrease of the exergy destruction in these units Thermoeconomic results also show by reduc-
will reduce the unit product cost of an MEE– ing the splitter ratio (α) of the brine re-circulation
MVC plant. flow rate from 0.5 to 0.25 while the compression
Table 7 illustrates that by reducing the com- ratio Cr is specified by 1.15, the exergy destruc-
pression ratio (Cr) of the compressor from 1.35 to tion in the first evaporation decreased by 15%.
1.15, the capital cost of the compressor is reduced The sum of the desuperheater also experiences a
accordingly by 16%. The specific power con- further reduction of 36%. By reducing the brine
sumption is also reduced by 50%. Because the splitter ratio (α) from 0.5 to 0.25, the unit product
inlet vapor temperature of the compressor is fixed cost decreases to 1.21 $/m3.
at 60EC, the compressor outlet temperature is Table 9 shows the effect of the evaporator
reduced from 95 to 75EC. This in turn reduces the number variation under the same specified vari-
desuperheater exergy destruction by 77%. Also ables of the considered desalination plant. The
the sum of the desuperheater is reduced by 84%. numerical results show that there is no visible
The amount of the first evaporator is reduced by solution for the considered system using eight
22%. The sum of the heat recovery heat exchan- evaporators or above. Yet this limitation will be
12 A.S. Nafey et al. / Desalination 230 (2008) 1–15
Table 8
Thermoeconomic variables of MEE–MVC at Cr = 1.15 and α = 0.25
Table 9
Number of evaporator variations at 1500 m3/day
Number of effects
1 2 3 4 6 8
a
Tcompressor, in , EC 60 60 60 60 60 NVSb
Theating steam , ECa 70 70 70 70 70 NVS
Tf, EC 61 57.2 57 56.9 56.7 NVS
Distillate product, m3/ha 62.5 62.5 62.5 62.5 62.5 NVS
NVS
Total surface area, m2 2260 3860 6202 9650 23796 NVS
Performance ratio (PR), ηI 3.28 6.5 8.5 10.5 14 NVS
Pressure ratio 1.35 1.35 1.35 1.35 1.35 NVS
Specific power, kWh/m3 17.9 9.4 7.2 5.5 4 NVS
Exergetic efficiency, ηII 3.84 5.75 6.6 7.5 8.4 NVS
Unit product cost, $/m3 2.13 1.7 1.68 2 3.88 NVS
a
Specified parameters.
b
No visible solution.
changed if the specified variables changed. This in the power consumption. The heating surface
table shows that the thermal performance ratio of area of the evaporators increases with the increase
the the MEE–MVC system increases with the of the effect number. This is due to the decrease
increase of the number of the evaporators. This is, of the temperature drop per evaporator. The
on one hand, due to the increase of the reuse of inverse effect of the exergetic efficiency and the
the vapor, and on the other hand, due to the required surface area gives numerically a mini-
decrease in the compressor power consumption as mum unit product cost at three evaporators as
shown in Table 9. The decrease in the power shown in Table 9. The unit product cost at two
consumption is mainly due to the decrease of the evaporators and three evaporators are almost the
induced vapor flow rate. The system exergetic same. From the complexity and maintenance
efficiency increases with the increase of the point of view, the system of two evaporators is
number of evaporators as a result of the reduction preferable.
A.S. Nafey et al. / Desalination 230 (2008) 1–15 13
Table 10
Evaporator number variations on the MEE–MVC plant of 5000 m3/day
No. of evaporators
1 2 3 4 6
Seawater temperature, EC 27 27 27 NVSb
Tcompressor, in a, EC 60 60 60 60 NVS
Theating steam, EC 70 70 70 70 NVS
Distillate producta, m3/h 208 208 208 208 NVS
Total surface area, m2 7523 12,848 20,642 32,118 NVS
NVS
Pressure ratioa 1.35 1.35 1.35 1.35
NVS
Total SPC, kWh/m3 17.9 9.9 7.23 4.7 NVS
Performance ratio (PR), ηI 3.4 6.5 9.35 12 NVS
Exergetic efficiency, ηII 3.8 5.75 6.6 7.5 NVS
Unit product cost, $/m3 2 1.67 1.64 2 NVS
a
Specific parameters.
b
No visible solution.
Table 10 shows the evaporator number vari- and 10 show that by increasing the system capa-
ations for the considered MEE–MVC system city under the same operating conditions, the unit
under the same specified variables of the con- product cost accordingly is reduced.
sidered desalination process when the capacity is
changed from 1500 m3/day to 5000 m3/day. The
numerical results show that there is no visible
6. Conclusions
solution for the system at six evaporators or
above. This limitation will be changed if the Using the design data of an existing MEE–
specified variables changed. This table shows MVC plant (1500 m3/day), the following results
also that both thermal performance ratio (PR) and are obtained:
exergetic efficiency (ηII) of the MEE–MVC C The energy analysis shows that the thermal
system increase with an increasing number of performance ratio of the considered system
evaporators. This is because of the decrease in the with external steam is 8% less than that the
compressor power consumption, as shown in system without external steam.
Table 10. The decrease in the power consumption C Thermoeconomic analysis shows the unit pro-
is mainly due to the decrease of the induced duct cost is 29% higher in the system of
vapor flow rate. The system heating surface area external steam. The unit product cost of the
increases with increasing the number of evapora- desalted water at the normal operation (with-
tors. The inverse effect of the exergetic efficiency out external steam) is calculated by 1.7 $/m3.
and the required surface area gives a minimum C For a system without external steam, by re-
unit product at three evaporators as shown in ducing the pressure ratio of the vapor com-
Table 10. Also, the unit product cost at two and pressor from 1.35 to 1.15, the capital cost of
three evaporators is almost the same. From the the compressor is reduced by 16%. The speci-
complexity and maintenance point of view, the fic power consumption is also reduced by
system of two evaporators is preferable. Tables 9 50%. Sequentially, the unit product cost is
14 A.S. Nafey et al. / Desalination 230 (2008) 1–15
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