𝐴_12=𝑉_2/𝑉_1 𝑒𝑥𝑝 〖−𝑎〗 _12/𝑅𝑇

𝛾_1=exp⁡(⁡(−𝑥_1+𝐴_12
(17)

𝛾_2=exp⁡(⁡(−𝑥_2+𝐴_21
𝐴_21=𝑉_1/𝑉_2 𝑒𝑥𝑝 〖−𝑎〗 _21/𝑅𝑇
(18)

DATOS A12 0.15980121

T (°C) 60 A21 0.34549538
T(K) 333.15
R(Cal/mol K) 1.987 Y1 2.35780811
Z1 0.3 Y2 1.26006876
Z2 0.7

PARAMETROS DE WILSON P BURBUJA(KPA) 105.812878

𝑃_𝑏𝑢𝑟𝑏𝑢𝑗𝑎=𝑥_1 𝛾_1 〖𝑃 _1 〗
V1 (cm3/mol) 40.73 P ROCIO (KPA) 82.3459854
𝑃_𝑟𝑜𝑐𝑖𝑜=1/(𝛾_1/(𝛾_1 〖𝑃 _1 〗
V2 (cm3/mol) 89.41 P(KPA) 94.0794317
a12 (Cal/mol) 1734.42
a21 (Cal/mol) 183.04
𝐾_𝑖=𝑦_𝑖/𝑥_𝑖 =(𝛾_𝑖 〖𝑃 _𝑖 〗 ^𝑠𝑎𝑡)/𝑃 K1 2.11700086
(16)
K2 0.69945464

𝑉=(𝑃_𝑏𝑢𝑟𝑏𝑢𝑗𝑎−𝑃)/(𝑃_𝑏𝑢𝑟𝑏𝑢𝑗𝑎−𝑃_𝑟𝑜𝑐𝑖𝑜
(27) )
V inicial 0.5
V f(V) f'(V) V nuevo Error
0.5 -0.03257282 -0.2910037 0.388067321609 28.8436238
0.3880673216 -0.00439029 -0.25219666 0.3706591276328 4.69655073
0.3706591276 0.000226618 -0.25594219 0.3715445547023 0.2383098
0.3715445547 -9.94391E-06 -3.81532663 0.3715419483954 0.00070148
0.3715419484 -9.24786E-06 -8.06969281 0.37154080239701 0.00030844
0.3715408024 -8.9418E-06 -151.834553 0.3715407435053 1.58507E-05
0.3715407435 -8.92607E-06 -16.2524428 0.3715401942913 0.00014782
0.3715401943 -8.77939E-06 -0.25574995 0.371505866262 0.00924024
0.3715058663 3.88638E-07 -0.25575744 0.3715073858196 0.00040902
0.3715073858 -1.7198E-08 -0.25575711 0.371507318576 1.81002E-05
0.3715073186 7.61058E-10 -0.25575712 0.3715073215517 8.00982E-07
0.3715073216 -3.36787E-11 -0.25575712 0.3715073214201 3.54455E-08
0.3715073214 1.49047E-12 -0.29945451 0.371507321425 1.33976E-09
 𝛾_1=exp⁡(⁡(−𝑥_1+𝐴_12 𝑥_2 ) + 〖 (𝑥 〗 _2 (𝐴_12/(𝑥_1+𝐴_12 𝑥_2 )−𝐴_21/(𝑥_2+𝐴_21(20)
〖−𝑎〗 _12/𝑅𝑇 𝑥_1 )))
(17)

𝛾_2=exp⁡(⁡(−𝑥_2+𝐴_21 𝑥_1 ) − 〖 (𝑥 〗 _1 (𝐴_12/(𝑥_1+𝐴_12 𝑥_2 )−𝐴_21/(𝑥_2+𝐴_21 𝑥_1

−𝑎〗 _21/𝑅𝑇 (22))))
(18)

PARAMETROS DE ANTOINE
Sustancia a b c
METANOL(1) 16.5938 3644.3 239.76
BENCENO(2) 13.8594 2773.78 220.07

Psat 1 84.4709273 〖𝑃 _𝑖 〗 ^𝑠𝑎𝑡 (𝐾𝑝𝑎)=exp[𝐴−𝐵/(𝑇(℃)+𝐶)] (23)

Psat 2 52.2227815
(24)
𝑃_𝑏𝑢𝑟𝑏𝑢𝑗𝑎=𝑥_1 𝛾_1 〖𝑃 _1 〗 ^𝑠𝑎𝑡+𝑥_2 𝛾_2 〖𝑃 _2 〗 ^𝑠𝑎𝑡
𝑃_𝑟𝑜𝑐𝑖𝑜=1/(𝛾_1/(𝛾_1 〖𝑃 _1 〗 ^𝑠𝑎𝑡 )+𝛾_2/(𝛾_2 〖𝑃(25)
_2 〗 ^𝑠𝑎𝑡 ))

P=1/2(𝑃_𝑏𝑢𝑟𝑏𝑢𝑗𝑎 + 𝑃_𝑟𝑜𝑐𝑖𝑜) (26)

V 0.37150732 Z1 0.3
L 0.62849268 Z2 0.7
𝐿=1−𝑉" (28) K1 2.11700086 "
𝑥_𝑖=𝑧_𝑖/(1+𝑉(𝐾_𝑖−1)) (7) K2 0.69945464

SUSTANCIA Zi xi yi Ki
METANOL (1) 0.3 0.21201803 0.448842352 2.11700086 𝑘𝑖=𝑦𝑖/𝑥𝑖
BENCENO (2) 0.7 0.78798197 0.551157648 0.69945464
1 1
𝑦𝑖=𝑘𝑖∗𝑥𝑖 (29)
(5)
 𝐴_12=𝑉_2/𝑉_1 𝑒𝑥𝑝 〖−𝑎〗 _12/𝑅𝑇
(17)

𝐴_21=𝑉_1/𝑉_2 𝑒𝑥𝑝 〖−𝑎〗 _21/𝑅𝑇

(18)

𝛾_1=exp⁡(⁡(−𝑥_1+𝐴_12 𝑥_2 ) + 〖 (𝑥 〗 _2 (𝐴_12/(𝑥_1+𝐴_12 𝑥_2 )−𝐴_21/(𝑥_2+𝐴_21 𝑥_1 )))

𝛾_2=exp⁡(⁡(−𝑥_2+𝐴_21 𝑥_1 ) − 〖 (𝑥 〗 _1 (𝐴_12/(𝑥_1+𝐴_12 𝑥_2 )−𝐴_21/(𝑥_2+𝐴_21 𝑥_1 )))

DATOS A12 0.5347570733

T (°C) 60 A21 0.5738620162
T(K) 333.15 Y1 1.6299745532
R(Cal/mol K) 1.987 Y2 1.1010581848
Z1 0.3
Z2 0.7 P BURBUJA(KPA) 119.86538682
P ROCIO (KPA) 108.67299721
PARAMETROS DE WILSON P(KPA) 114.26919202
𝑃_𝑏𝑢𝑟𝑏𝑢𝑗𝑎=𝑥_1 𝛾_1 〖𝑃 _1 〗
V1 (cm3/mol) 79.84
𝑃_𝑟𝑜𝑐𝑖𝑜=1/(𝛾_1/(𝛾_1 〖𝑃 _1 〗
V2 (cm3/mol) 40.73 K1 1.6082366239
a12 (Cal/mol) -31.19 K2 0.8092897107
a21 (Cal/mol) 813.18
𝐾_𝑖=𝑦_𝑖/𝑥_𝑖 =(𝛾_𝑖 〖𝑃 _𝑖 〗 ^𝑠𝑎𝑡)/𝑃
(16)

𝑉=(𝑃_𝑏𝑢𝑟𝑏𝑢𝑗𝑎−𝑃)/(𝑃_𝑏𝑢𝑟𝑏𝑢𝑗𝑎−𝑃_𝑟𝑜𝑐𝑖𝑜
(27))
Vinicial 0.5
V f(v) f'(v) v nuevo error
0.5 -0.0076495869 -0.11866516 0.4355363724905 14.800974518
0.43553637249 -0.0013339036 -0.12064657 0.4244800818037 2.6046665464
0.424480081804 -0.000228848 -0.1209944 0.4225886887508 0.4475730428
0.422588688751 -3.913389E-05 -0.12105414 0.4222654128682 0.0765575093
0.422265412868 -6.688217E-06 -0.12106436 0.4222101677361 0.013084747
0.422210167736 -1.142944E-06 -0.12106611 0.4222007270739 0.0022360601
0.422200727074 -1.953136E-07 -0.12106641 0.4221991137974 0.0003821127
0.422199113797 -3.337633E-08 -0.12106646 0.4221988381114 6.5297679E-05
0.422198838111 -5.703541E-09 -0.12106647 0.4221987910006 1.1158446E-05
0.422198791001 -9.746539E-10 -0.12106647 0.42219878295 1.9068195E-06
0.42219878295 -1.665544E-10 -0.12106647 0.4221987815743 3.2584822E-07
0.422198781574 -2.846173E-11 -0.12106647 0.4221987813392 5.5682723E-08
0.422198781339 -4.86361E-12 -0.12106647 0.422198781299 9.5151936E-09
_21/(𝑥_2+𝐴_21 𝑥_1 )))
(20)

_21/(𝑥_2+𝐴_21(22)
𝑥_1 )))

parametros de antoine
Sustancia a b c
1 14.2456 2662.78 219.69
2 16.5785 3638.27 239.5

Psat 1 112.745257 〖𝑃 _𝑖 〗 ^𝑠𝑎𝑡 (𝐾𝑝𝑎)=exp[𝐴−𝐵/(𝑇(℃)+𝐶)] (23)

Psat 2 83.9890958

𝑢𝑟𝑏𝑢𝑗𝑎=𝑥_1 𝛾_1 〖𝑃 _1 〗 ^𝑠𝑎𝑡+𝑥_2 𝛾_2 〖𝑃 _2 〗

(24)
^𝑠𝑎𝑡
𝑜=1/(𝛾_1/(𝛾_1 〖𝑃 _1 〗 ^𝑠𝑎𝑡 )+𝛾_2/(𝛾_2 〖(25)
𝑃 _2 〗 ^𝑠𝑎𝑡 ))

P=1/2(𝑃_𝑏𝑢𝑟𝑏𝑢𝑗𝑎 + 𝑃_𝑟𝑜𝑐𝑖𝑜) (26)

V 0.42219878
L 0.57780122 𝐿=1−𝑉" (28) "

𝑘𝑖=𝑦𝑖/𝑥𝑖 (5)
𝑦𝑖=𝑘𝑖∗𝑥𝑖 (29)
SUSTANCIA Zi xi yi Ki
Acetato de metilo 0.3 0.2387021 0.38388943 1.60823662
Metanol 0.7 0.7612979 0.61611057 0.80928971
1 1
𝑥_𝑖=𝑧_𝑖/(1+𝑉(𝐾_𝑖−1))
(7)
"