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CH3
Cl
CH3 H2O
CH3
CH3
OH H CH3
CH3
CH3
OH
HO CH3
H
a. b. c. d. none
2. Arrange the following alkyl bromides in the increasing order of reaction rate towards
nucleophilic substitution with iodide in acetone at 50 degrees?
(i) Allyl bromide ii. Propyl bromide iii. Benzyl bromide iv. Isopropyl bromide
Br
H Ph NaOEt/EtOH, Heat
H Ph
CH3
4. Which alkyl halide and what condition must be used to prepare methylenecyclohexane in good
yield by E2 elimination?
a. 1-Bromo-1-methylcyclohaxane + NaOEt/EtOH
c. Cyclohexylbromomethane + NaOEt/EtOH
5. Which of the following will have the highest ratio of E2 to SN2 products expected in their
reactions with sodium ethoxide in ethyl alcohol?
c. E2 reactions are favoured by alkyl branches at alpha- and beta-carbons in alkyl halides,
by alkyl branches in the base and by stronger bases.
a. Tertiary alkyl halides are more reactive towards solvolysis reactions by SN1 and E1
mechanisms.
9. Which of the following is/ are true about the following observation?
iii) Because primary alkyl halides do not form carbocations, neither SN1 nor E1 is
possible.
iv) If the reaction mixture were heated strongly, some SN2 reactions might occur in
a few days.
10. Match the following heats of hydrogenation (kcal) with the alkenes given.
i. cis-2-butene p. 30.3
a. i-r; ii-q; iii-p; iv-sb. i-q; ii-r;I ii-s; iv-p c. i-s; ii-r; iii-q; iv-p d. i-r; ii-s; iii-q; iv-p
11. What is the major product when E2 elimination converts the diastereo menthyl chloride?
Br Br
Br
Br
a b c d
13. Which of the following has the highest rate of elimination with sodium ethoxide in ethanol at 55
degrees?(MB,302)
14. Which of the following is the major product when 3-methyl-2-butyltosylate undergoes
elimination in n-butanol?(MB 305)
15. Fsdgs
16. Dfgsdgsdfgsad
17. gf