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H3PO4 NaOH

Concentración 0.1 0.1


Volumen inicial 100 0

Volumen (ml) [H] (M) pH


100 0.02511886 1.6
101 0.02269881 1.64399686 CURVA VAL
102 0.02124299 1.67278443
103 0.02034812 1.69147573 14
104 0.0196707 1.70618018
105 0.01906161 1.71984044
106 0.01848149 1.73326298
12
107 0.01792163 1.74662242
108 0.01737984 1.75995432
109 0.0168552 1.77326602
110 0.0163471 1.78655931 10
111 0.01585496 1.79983495
112 0.01537823 1.8130936
113 0.0149164 1.826336 8
114 0.01446895 1.83956296
115 0.01403539 1.85277543

pH
116 0.01361525 1.86597447
6
117 0.01320805 1.87916125
118 0.01281336 1.89233705
119 0.01243073 1.9055033
120 0.01205976 1.91866151 4
121 0.01170002 1.93181335
122 0.01135114 1.94496059
123 0.01101273 1.95810513 2
124 0.01068442 1.97124899
125 0.01036587 1.98439431
126 0.01005673 1.99754339
0
127 0.00975667 2.0106986 50 100 150 200
128 0.00946537 2.02386251
129 0.00918253 2.03703775
130 0.00890785 2.05022715
131 0.00864105 2.06343362
132 0.00838185 2.07666026
133 0.00812998 2.08991028
134 0.0078852 2.10318705
135 0.00764726 2.1164941
136 0.00741592 2.12983511
137 0.00719095 2.14321392
138 0.00697213 2.15663455
139 0.00675925 2.17010119
140 0.00655212 2.18361824
141 0.00635053 2.19719028
142 0.00615429 2.21082209
143 0.00596323 2.22451868
144 0.00577716 2.2382853
145 0.00559593 2.25212743
146 0.00541937 2.26605084
147 0.00524733 2.28006155
148 0.00507965 2.29416591
149 0.0049162 2.30837056
150 0.00475683 2.32268251
151 0.00460141 2.33710914
152 0.00444981 2.35165822
153 0.00430192 2.36633797
154 0.0041576 2.38115708
155 0.00401675 2.39612473
156 0.00387926 2.41125067
157 0.00374503 2.42654527
158 0.00361394 2.44201954
159 0.0034859 2.45768521
160 0.00336082 2.47355483
161 0.00323861 2.48964179
162 0.00311917 2.50596047
163 0.00300244 2.52252628
164 0.00288831 2.53935583
165 0.00277673 2.55646702
166 0.0026676 2.5738792
167 0.00256086 2.59161335
168 0.00245645 2.60969223
169 0.00235429 2.62814066
170 0.00225431 2.64698574
171 0.00215647 2.66625715
172 0.00206069 2.68598751
173 0.00196692 2.70621276
174 0.00187511 2.72697268
175 0.00178521 2.74831141
176 0.00169716 2.77027815
177 0.00161091 2.79292794
178 0.00152643 2.81632262
179 0.00144367 2.84053204
180 0.00136259 2.86563541
181 0.00128315 2.89172306
182 0.00120532 2.91889859
183 0.00112906 2.94728153
184 0.00105436 2.97701063
185 0.00098119 3.0082481
186 0.00090953 3.04118493
187 0.00083937 3.07604771
188 0.00077071 3.11310745
189 0.00070357 3.152691
190 0.00063798 3.19519581
191 0.00057397 3.24110915
192 0.00051164 3.2910326
193 0.00045112 3.34571269
194 0.00039258 3.40607678
195 0.0003363 3.47326971
196 0.0002827 3.54867773
197 0.00023232 3.63390832
198 0.00018592 3.73066761
199 0.00014439 3.84045867
200 0.00010862 3.96407607
201 7.92372E-05 4.10107075
202 5.62869E-05 4.24959272
203 3.91854E-05 4.4068758
204 2.69121E-05 4.57005309
205 1.83344E-05 4.73673378
206 1.24411E-05 4.90514063
207 8.43381E-06 5.07397618
208 5.72511E-06 5.24221579
209 3.90018E-06 5.40891578
210 2.67272E-06 5.57304695
211 1.84784E-06 5.73333487
212 1.29395E-06 5.88808378
213 9.22639E-07 6.03496813
214 6.74826E-07 6.17080788
215 5.11153E-07 6.29144893
216 4.05365E-07 6.39215413
217 3.3936E-07 6.46933954
218 2.99293E-07 6.52390296
219 2.73755E-07 6.56263727
220 2.54934E-07 6.59357181
221 2.39169E-07 6.6212953
222 2.25171E-07 6.64748674
223 2.12484E-07 6.67267463
224 2.00886E-07 6.69705035
225 1.90233E-07 6.7207131
226 1.80412E-07 6.74373391
227 1.71328E-07 6.766172
228 1.629E-07 6.78807934
229 1.55059E-07 6.80950234
230 1.47746E-07 6.83048282
231 1.4091E-07 6.85105868
232 1.34504E-07 6.87126444
233 1.2849E-07 6.8911317
234 1.22832E-07 6.91068953
235 1.17499E-07 6.92996476
236 1.12465E-07 6.94898233
237 1.07705E-07 6.96776544
238 1.03196E-07 6.98633587
239 9.89204E-08 7.00471404
240 9.48595E-08 7.02291928
241 9.09976E-08 7.04096993
242 8.73206E-08 7.05888343
243 8.38153E-08 7.07667651
244 8.04701E-08 7.09436525
245 7.72743E-08 7.11196518
246 7.42179E-08 7.12949136
247 7.12921E-08 7.1469585
248 6.84887E-08 7.16438099
249 6.58002E-08 7.181773
250 6.32196E-08 7.19914855
251 6.07405E-08 7.21652157
252 5.83571E-08 7.23390598
253 5.6064E-08 7.25131573
254 5.38561E-08 7.26876489
255 5.17288E-08 7.28626773
256 4.96777E-08 7.30383876
257 4.76988E-08 7.32149282
258 4.57883E-08 7.33924516
259 4.39429E-08 7.35711152
260 4.21591E-08 7.37510822
261 4.04341E-08 7.39325225
262 3.87649E-08 7.4115614
263 3.71489E-08 7.43005433
264 3.55835E-08 7.44875076
265 3.40666E-08 7.46767155
266 3.25958E-08 7.48683891
267 3.1169E-08 7.50627659
268 2.97845E-08 7.52601003
269 2.84402E-08 7.54606667
270 2.71346E-08 7.56647618
271 2.5866E-08 7.5872708
272 2.46328E-08 7.6084857
273 2.34337E-08 7.63015943
274 2.22672E-08 7.65233442
275 2.11321E-08 7.67505761
276 2.00271E-08 7.69838114
277 1.89512E-08 7.72236324
278 1.79032E-08 7.74706929
279 1.68821E-08 7.7725731
280 1.5887E-08 7.79895848
281 1.49169E-08 7.82632118
282 1.3971E-08 7.85477133
283 1.30486E-08 7.88443654
284 1.21488E-08 7.91546577
285 1.12711E-08 7.9480344
286 1.04148E-08 7.98235081
287 9.57933E-09 8.01866505
288 8.76434E-09 8.05728054
289 7.96948E-09 8.09856984
290 7.19455E-09 8.14299654
291 6.43953E-09 8.19114592
292 5.70468E-09 8.24376864
293 4.99064E-09 8.30184395
294 4.29861E-09 8.36667206
295 3.6307E-09 8.44000926
296 2.99046E-09 8.52426197
297 2.38371E-09 8.62274654
298 1.81984E-09 8.73996731
299 1.31317E-09 8.88167753
300 8.82992E-10 9.05404299
301 5.48475E-10 9.2608431
302 3.16789E-10 9.49922968
303 1.74281E-10 9.75874933
304 9.41607E-11 10.0261302
305 5.13575E-11 10.2893961
306 2.9014E-11 10.537392
307 1.74698E-11 10.7577128
308 1.15704E-11 10.9366514
309 8.61964E-12 11.0645107
310 7.15023E-12 11.1456798
311 6.32742E-12 11.1987731
312 5.75237E-12 11.2401533
313 5.28999E-12 11.2765451
314 4.89898E-12 11.3098946
315 4.56179E-12 11.3408645
316 4.26764E-12 11.3698119
317 4.0087E-12 11.3969962
318 3.77898E-12 11.4226252
319 3.57379E-12 11.4468711
320 3.38939E-12 11.469878
321 3.22278E-12 11.4917687
322 3.07151E-12 11.512648
323 2.93355E-12 11.5326064
324 2.80723E-12 11.5517227
325 2.69113E-12 11.5700658
326 2.58407E-12 11.5876963
327 2.48503E-12 11.6046679
328 2.39316E-12 11.6210283
329 2.3077E-12 11.6368201
330 2.22802E-12 11.6520817
331 2.15354E-12 11.6668474
332 2.08378E-12 11.6811483
333 2.01831E-12 11.6950128
334 1.95674E-12 11.7084665
335 1.89875E-12 11.7215328
336 1.84402E-12 11.7342332
337 1.79231E-12 11.7465874
338 1.74336E-12 11.7586134
339 1.69696E-12 11.7703279
340 1.65293E-12 11.7817463
341 1.61108E-12 11.792883
342 1.57126E-12 11.803751
343 1.53334E-12 11.8143628
344 1.49717E-12 11.8247297
345 1.46264E-12 11.8348625
346 1.42965E-12 11.8447711
347 1.39809E-12 11.8544649
348 1.36788E-12 11.8639526
349 1.33893E-12 11.8732423
350 1.31117E-12 11.8823419
351 1.28452E-12 11.8912585
352 1.25893E-12 11.899999
353 1.23433E-12 11.9085698
354 1.21066E-12 11.9169771
355 1.18788E-12 11.9252266
356 1.16594E-12 11.9333237
357 1.14479E-12 11.9412736
358 1.12439E-12 11.9490811
359 1.10471E-12 11.956751
360 1.08571E-12 11.9642877
361 1.06734E-12 11.9716953
362 1.0496E-12 11.9789778
363 1.03243E-12 11.9861391
364 1.01582E-12 11.9931828
365 9.99741E-13 12.0001123
366 9.84168E-13 12.006931
367 9.69076E-13 12.013642
368 9.54447E-13 12.0202483
369 9.40258E-13 12.0267529
370 9.26492E-13 12.0331585
371 9.13129E-13 12.0394678
372 9.00154E-13 12.0456833
373 8.87549E-13 12.0518075
374 8.75301E-13 12.0578426
375 8.63394E-13 12.0637911
376 8.51814E-13 12.069655
377 8.4055E-13 12.0754365
378 8.29588E-13 12.0811375
379 8.18917E-13 12.0867599
380 8.08526E-13 12.0923058
381 7.98405E-13 12.0977767
382 7.88543E-13 12.1031745
383 7.78931E-13 12.1085009
384 7.6956E-13 12.1137575
385 7.60421E-13 12.1189457
386 7.51507E-13 12.1240672
387 7.42808E-13 12.1291234
388 7.34318E-13 12.1341157
389 7.2603E-13 12.1390454
390 7.17937E-13 12.1439139
391 7.10031E-13 12.1487225
392 7.02308E-13 12.1534724
393 6.94761E-13 12.1581647
394 6.87384E-13 12.1628007
395 6.80172E-13 12.1673815
396 6.73119E-13 12.1719082
397 6.66221E-13 12.1763818
398 6.59472E-13 12.1808033
399 6.52869E-13 12.1851738
400 6.46406E-13 12.1894943
401 6.4008E-13 12.1937657
402 6.33886E-13 12.1979888
403 6.2782E-13 12.2021647
404 6.21879E-13 12.2062941
405 6.16059E-13 12.2103779
406 6.10356E-13 12.214417
407 6.04767E-13 12.2184121
408 5.99289E-13 12.2223639
409 5.93918E-13 12.2262734
410 5.88652E-13 12.2301412
411 5.83488E-13 12.233968
412 5.78423E-13 12.2377545
413 5.73454E-13 12.2415014
414 5.68579E-13 12.2452094
415 5.63795E-13 12.2488791
416 5.59099E-13 12.2525113
417 5.5449E-13 12.2561063
418 5.49965E-13 12.259665
419 5.45522E-13 12.2631879
420 5.41159E-13 12.2666755
421 5.36873E-13 12.2701285
422 5.32663E-13 12.2735473
423 5.28527E-13 12.2769325
424 5.24464E-13 12.2802847
425 5.2047E-13 12.2836043
426 5.16545E-13 12.2868918
427 5.12687E-13 12.2901478
428 5.08894E-13 12.2933727
429 5.05165E-13 12.2965671
430 5.01498E-13 12.2997312
431 4.97891E-13 12.3028657
432 4.94344E-13 12.3059709
433 4.90854E-13 12.3090473
434 4.87422E-13 12.3120952
435 4.84044E-13 12.3151152
436 4.8072E-13 12.3181076
437 4.77449E-13 12.3210728
438 4.7423E-13 12.3240111
439 4.71061E-13 12.3269231
440 4.67941E-13 12.329809
441 4.64869E-13 12.3326692
442 4.61845E-13 12.3355041
443 4.58866E-13 12.338314
444 4.55933E-13 12.3410993
445 4.53043E-13 12.3438602
446 4.50197E-13 12.3465972
447 4.47393E-13 12.3493106
448 4.44631E-13 12.3520006
449 4.41909E-13 12.3546676
450 4.39226E-13 12.357312
451 4.36582E-13 12.3599339
452 4.33977E-13 12.3625337
453 4.31408E-13 12.3651116
454 4.28876E-13 12.3676681
455 4.2638E-13 12.3702032
456 4.23919E-13 12.3727174
457 4.21492E-13 12.3752109
458 4.19098E-13 12.3776839
459 4.16738E-13 12.3801368
460 4.1441E-13 12.3825697
461 4.12114E-13 12.3849829
462 4.09848E-13 12.3873767
463 4.07614E-13 12.3897513
464 4.05409E-13 12.3921069
465 4.03233E-13 12.3944438
466 4.01086E-13 12.3967622
467 3.98968E-13 12.3990623
468 3.96877E-13 12.4013444
469 3.94813E-13 12.4036086
470 3.92776E-13 12.4058553
471 3.90765E-13 12.4080845
472 3.8878E-13 12.4102966
473 3.8682E-13 12.4124916
474 3.84884E-13 12.4146699
475 3.82973E-13 12.4168315
476 3.81086E-13 12.4189768
477 3.79223E-13 12.4211058
478 3.77382E-13 12.4232188
479 3.75564E-13 12.425316
480 3.73768E-13 12.4273976
481 3.71994E-13 12.4294636
482 3.70242E-13 12.4315144
483 3.68511E-13 12.43355
484 3.668E-13 12.4355707
485 3.6511E-13 12.4375766
486 3.63439E-13 12.4395679
487 3.61789E-13 12.4415447
488 3.60158E-13 12.4435073
489 3.58546E-13 12.4454557
490 3.56952E-13 12.4473901
491 3.55377E-13 12.4493107
492 3.5382E-13 12.4512176
493 3.52281E-13 12.453111
494 3.50759E-13 12.454991
495 3.49255E-13 12.4568577
496 3.47767E-13 12.4587114
497 3.46296E-13 12.4605521
498 3.44842E-13 12.4623801
499 3.43404E-13 12.4641953
500 3.41981E-13 12.465998
Ka pKa
H3PO4 + H2O  =  H2PO4- + H3O+ 0.00631 2.2
H2PO4- + H2O  =   HPO42- + H3O+ 6.3E-08 7.2 Kw 1E-14
HPO42- + H2O  =   PO43- + H3O+  4E-13 12.4

CURVA VALORACIÓN DE H3PO4 CON NaOH


14

12

10

8
pH

0
50 100 150 200 250 300 350 400 450 500 550

Volumen (ml)
500 550