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YK 669.168 Mapraneu. Dacux M. H.—M.: Meraanypras.— 1992. 608 c. Tipmpenenit aHune o H3HKO-XHMHUeCKHX CBOMicTBAaX Mapraiua, Bsaumonel- CTBHR MapraHua C HeKOTOpHIMH MeTaIaMH H HeMeTaaMy.. Paccmotpenbl BO- Mpockt MHHepanbHO-cupsesol Cask MapraHua, OGoraulewHA MapranUesKX py XDHCTAMOXEMEMeCKOH CIpYKTYPH H-MHNEPAALAWX (a3 PYAHNX MHNepano, TeX- HONOTHR NOATOTOBKA MaprakileBOPYAHHX KONUeHTPATOB' K MeTAAlyprHueckKoMy nepexeny. TIpeactapex o6utapauii Matepnan no MeTasaypruyeckomy nepeqesy Mapraeso-pyAHOTO chIpbA, SJeKTPoMeTayprHH Mapralita H ero ciaBoR. Obobuenw auNEte O Mpoweccax MpuMeHeHHA Mapralilla B CTalenTaBHABHOM MpousBogcrse. OcsellleHb! BOMPOCK SKOMOTHH H PauHOHAAbHOrO NpousBoACTBa W NpHMeHenHa MapraHleanx deppocnazos. Yan HayUIWX paGoTHHKOS NccHeROBATeAKCKNX H MPOCKTHLX HUCTHTYTOB,. cnenvannsupyioulaxcs B oGiacTH TeopH H TexXHOROraH HepHoh H UBeTHOR Me~ ranaypran. Ha. 232. Ta6a. 140, BuOnnorpad. cnucox: 769 ass. Hanauue gunancnponano Huxononbcxus sa80aom dbeppocnnasos. Ravenid 6 ys, | Yui 6, 19969) COREPKAHME Tipeaucaosue See ee ee Taana 1. @HsMKo-xumuueckHe cBOfctea Mapranta . . . sy 1.1. Avommue KOHCTaHTE # MeTaAMHIecKaA BANCHTHOCTS MapraHita 1.2, OcoGenuoctH smextponHoi cTpykTypH MapraHla ... . . 13. Annorponia Mapramta ss. 14. TepMoauwaMaka 4 KHHeTHKa cyOxHMauHH H HenapeHun Map- ranua errr errr rrnny 1.5, [wnamuueckaa # KHHeMaTH¥eCKam BASKOCTb MKHAKOTO MapraHIa 1.6. DnextpHyeckoe compornBmenHe TBeporo H %KZXoro Mapranua Hero. cr1aBOB Ce J.7, Marnatawe cpoficrsa Mapranua H ero coeMHHeHHA . « . Taapa 2, Bsaumogelictane mapranua c MetaaaaMH 2.1. Cuctema Mn—Fe . . 2.2. €ucremss Mn—Co, Mn—Ni : . a 2.3. Cncrema Mn—Cr a) . 24. Cuctea Mn—B Pe ee ee 25. Cuerema Mn—Se So ee ‘2.6, Cuctema Mn—Al Cee eee ete’ 2.7. Knasukpactanawueckat Hxocaampuveckan asa B cnaasax, Mn—Al 4 Mn—Si—Al hoe tone we Paapa 3. Bsaunogefictsne KomnoneHTos B cucteme Mapraniel — Kucadopoa, Se ee 3.1. HwarpamMa papwopecnoro coctosHaA cuctems) Mn—O . 3.2. Kpuctaaamyecke Crpyxtypa OKCHAOB Mapranua =... 3.3. TepMonutamuteckue cBolictpa OKcHOB MapraHlta 3.4, Tepmuteckan AHCCOWMMalHA OXCHAOB MapraHla . . . . Taana 4, Tepmoannamnueckne’ cnojictaa ma Tepmuueckaa nucco- UHAHA THAPOKCHROB, KapGoHaTOS, cy«satTos H HuTpA- TOB MapraHya i ? 4.1, Cpojicrsa m pasmometve rampoKcHAOB Mapranlia . . . . « 42, Croliersa m guccoumanua KapOouaTa, cyabiata HM HuTpata maprauua Fe Taawa 5, Bsanmogefictsne xomnonentos 6 chcremax mapraney, yraepon, mapraveu— xkpemanii, Mapraneu— Kpemauli — yraepon, ee ‘5.1. [Iuarpamma papyonecuoro cocroauua cactema Mn—C . 6.2. Tepmoammamavecane cpoiicrsa xapOHlon Mapranua H pacnaasos cucremst Mn—C re 5.3. IarpamMa cocrosuua cuctem Mn—Si ..... -5.4. Baaumomefcrene KOMMOHeHTOB B cucTeme’Mn—Si—C. ‘Taana 6, Bsaumonelictsne xoMonentos 8 cucreme maprancel i. , — gochop ww Se ee 6.1. Masopwe papionecun B cueTeMe Mn—P 6.2. Tepoaunamueckne caokerea dociutos Mapraaa mH crma: Bop cHcteMst Mn—P : 63, Axrmanoere ochopa a mapranya p xHaKEx conapax cucremee n— Se ee Taasa 7. Baaxmonelicrave mapratia c sonoponom w jearepHem 7.1. AGcop6was Bonopoma mapraunem ae eee 7.2. AGcopOnaa sonopoma aanoTponRiMn opMaMH = Mapranua 4.3. Bsaumogelicrsie Mapranua ¢ H30TomaMH BOmOpoka 10 10 17 100 100 104 1 144 150 74, JerazaHa MeTanaMueckoro MapraHla B MpOMBIMVIeHHH® yCuO- BHAX nee we eee es 7.5, Mapraneuconepwamue ‘cnaabs!—HakonuteaH Boopona Taasa 8. Bsanmogelictsve Kommonenton B CHCTeEMe Napraneu — azor De 8.1, @asopne papHopecua 8 cucreMe Mn—N te 8.2, Kpucrananyeckue CTpyKTYpbl HHTPHAHBIX das Mapranna . 8.3. TepMomunamuseckne caolicrBa HHTpHAOB Mapraiua 8.4. BsauMozelicraue *XHAKOTO MapraHlla C a30TOM oe 85. Texuosorna nomyyenia asoruposantiore mapranua 1 enaasoa na ero ocHoBe fe toe Taapa 9, Bsaumonelicrave Komnonenton B cuctemax wapranen — agp, Mapraney — xneaopox — yraepen—xA0p Mm Map ranen — drop bo eee oe . TepmoamiamiveckHe cpoficraa coenutennit B cHeTemax Mn—Cl u Mn—O-C—Cl. . : 9.2. Tepmoymiamuucckue caojiersa cocauuennit » chereme Mn—F ~ Taasa 10. Baaumoneictse KommovenToR B CHCTeMaxX MapraHey — xaabKoren (Mapraneu— cepa, mapranell — KHcaopox — cepa, Mapraney —cesen, mapraneu—veaayp) . . . 10.1. DMarpawma paptosecHoro cocromiia cHcTemst Mn—S 102. Tepwoamnanmeckne caoficrpa eymupraon H xzKHX paerno- OB cepht B Mapranue : 10.3, Pannonecue chaz p cucreme cymmpua sapranua — eyansar Mapranua . . : 10.4 BaauMogelicrane B cucreme Mn—Se | ° Do 10.5. Baauwozelicrane B cucrewe Mn—Te . 2... Taapa 11. Suomouna pynoo6pasovanta maprama . . . N14, Tpouecest pyacospasonauna x gopunposanne mecropomae- nut Mapratiua 11.2, Kaaccupxauin KonTHieHtanaibix Méctopox edn Maprama Taapa 12, Feoxnmua, matepanorna Metanaypraa oKeanHyecKHX 2KeegOMAPraHWeBbIx KOHKpeUMit Lo 12.1. OGumaa xapakrepuctHka xkenesoMapranuesblx KOHKpenHii 12.2. Feonorka 4 reoxuMus 2kestesoMapranmessix KONKpeunit 12.3. Maposwe Mectopoxmerus >esesoMapraHiesbix KOHKpeltiii 124. Munepanorus xxenesomapraiuesbix KOUKpeuMi 2... 12.5. OusuieckHe cBoficrBa xeresoMapranuesbX KOHKpeLyA . . 126, Cpoliersa 2xeaesoMapranuteniix KOUKpeuHi Kak BbICOKOCeMeK- TuBHuX copéeHTOB. ww we Taapa 13. Xummueckne, raapomeraaaypraveckne muKpoGHoao- Tu¥ecKHe MeTORH OGoramlena —MapranueBopynHoro CHpbH, maaMoB OGoralleHHA PYA M miaKOB nponsson- cT#a Mapramuessix cnaason. ee 13.1, XuwuveckHe MeToab BiemaduBaHHa Mapraneuconepxaunx BuAOB chippa : Le - 13.2. Tpoueccst Bimerainaanna ixeaesomapraiuecenix KonKpeutHii 13.3, MuxpoOnoaornucckoe abuenaunBaiue GexNBix MapraHnesuix pya 13.4. Fampomeraaaypriueckue meron aehocpopaunn m o6oraute- BHA MapraHUeBbx py H KOHUeHTpaToR . . : Taana 14, asopne pasnosecun 1 TepmoaunamaKa coeamenn 8 GHHAPHEIX H TepHApHEX cHCTeMAX Ha OCHOBE OKCH- wos mapramua we 152 153 158 158 162 162 163 17! 175, 175 182 183. 183 185: 189 191 193 198. 198 209 221 221 226 228 233: 239 243 246 246 262 269 274 285 14.1, Masopbe paBHoBecHa B OHHApHeIX cHCTeMax OKCHAB Mapran- Ma —oKcnAb MeTaatoB (HeMeTan0n) — 142, Dasoane pasiosechs B rpolisitix cuctemax MnO—Me (Fe, Ca, Mg, Al)O—SiO, M43. Mabranen » etpyerypax "oxcnaniax BuCOKOTeMMepaT ypliEIx caepxmpononuaKos an Paava 15, Oxanxo-xammsecete caoicrsa pacnaasos uaaxonux cicTem npowsBogcrea Mapranuesbix eppocnsazon 15.1, Mozenn crpyxtypsi waKoBux pactuianon 4 byHaaMenrasmpubte coorHomenns cocras — cBolicrBo 15.2. Bausnne cepi ApyeHx npHMecHix KoMmOHeHTOR Ha cBofi- ctBa MaprateuconepXamHx UaKOBEIX paciauos . Taana 16, Kpycrasaoximvieckne crpyktypit 4 npespamenns mi- wepambubix a3 B MonemBHEIX cHctemax CaO—MnOz, Ca0O—MnO—Si0, % B® MpoMMUIAcHHIX araomepaTe iH maaKax : 16.1. KpucransoxuMuueesue crpyktypit B Mogeabusix cnaanax cucren CaO—MnO,, Ca0—MnO—SiO, 16.2. Kpncraadoxnmuyecxie npenpauenin Ca,SiO, 16.3. Crpyxrypa Apyxkabunenoro ciiukata B OcuoBHix waaKax cucremt! CaQ0—MnO—SiO» Da Parana 17. Mapranuesopyanan Gasa eppocnaasnore npowssoa- etna Le 17.1. Dunawuxa nponspogeraa Mapranuepeix pys 172. PusnKo-xuMuseckat mpHpoda pochopa B Mapraiiucanix pyax 173. OGorauenue Maprauiensx py rpaBuralHonHo-MarHiTHO- aorauuonnumn MeToaMn . Taaea 18. Mpougecu oxyckonanna w nepochopaumn wapranuensix kouueHrparos toe Loe 18.1. TpeGosanun « KavecrBy Mapraniepsix KOHILeHTpaToR 18.2 Araomepauns, Gpxerhposanne m oKaTbiRaNHe Mapranuentix KouuenTpaton 183. Saexnpomeranayprvecnsn nepocpopaunsa aprantenix KOH” yeHnTpatoR . Taana 19. Yraepogorepmuveenne npoueccis noaysewiin sucoKo- YraeponHeTbix MapraHueByx cnaazop) . . . . . 19.1. Baanmonelicrave Komnonentos B cicrene Mn—O—C . . . 182, Paswosecne » cterewe sucoxoyraeponueris: Peppomapraiied — OcHOBHOM waaK . wae 19.8. Texnoaorn 2omentioro eppomapranua tt 19.4, TexHonoru snextponeuioro suicoKoyraepoaueTora beppo- mapraiua Lo Loe fe Taawa 20, Yracponorepmmveckwe mpoucces noaysenna cnamwonap- rama Le 20.1. TpeGonanua Kk Kavecray cnanxowapranua ae 20.2. SnexrpueckHe Tew HW uMxTOBKe MaTepHaaDI tl 20.3. TexwoaorHs Buintaskn cuamkoMapranua Le Lt Paapa 21. Cuankorepmuneckne npouecc noayyenua meranane- ckoro Mapranua # _ ¢penseyraepoaneroro ‘beppomap- ranua . 21.1. TepMoauwamuKa peakunii B CHcTeme Mno — Si0;— Cad woe 21'2, Texnoaorus noayueHia Metaanuseckoro Maprantia 213, Texnoaorua noayseia cpeaieyraepoancroro cbeppomapranua 285 304 314 319 319 326, 337 341 347, 350 3a) 356 371 387 387 391 402 408 403 a 413 425 A442 442 443 444 453 453, 454 460 o