Вы находитесь на странице: 1из 7
Bouse npupodss naacmupuxamopes va cecSemea mienowwoce samepuasa na oxnbee nasueunursropwe OKypwat opwxnaawolt xm, 2004. T. 77. Bun. 10 i YAK 678:621.64407 BJIMAHHE fPHPOAbI MIACTH®UKATOPOB HA CBOHCTBA [JIEHOUHOrO MATEPHAJIA HA OCHOBE NOJMBHHHIXIOPHIA © B.H.JIuposa, E.A.JhoTuxosa, A.H.Jlerrapesa, B.AJIapnonos, C.H.Jlertapes, B.A.Bepxyta ‘Ypaabexuii rocyaapert yuumepeurer us, A.M.Poppkoro, Exatepun6ypr OAO «Crpofimiacrnosnivep», Exarepssibypr Tloctyniixo » Peaaxwno 23 wots 2004 Memodawu zpasunempuu, mepaozpasunenipun, HK cnekiipockonuu wsyweHo enuanue npupodss undusu- Ayanenerx niaenupuxamopoa w cocmaea Gunapuax nracmupukamopoe Ha noeedeHue nAeHowHo2o Mame- uaa Ha ocHose Norueunurxropuda ¢ eordyunoil u 6odno’ cpedax. Hccaedosano amuanKe amux dpaxmopoe Na MoposocmoilKocms naeHok Mux dusuKo-mexammeckue céoitcniea Tlommvepmuie neni 1a ocone nosmmpmnetopuza (BX) ¢ oswiocropornmn na NaXOZAT Mpinsenenve AK rHupoHoAALN 1 KOPpODt- onnioft samurrot MarnieTpasbambix He*pte-, raa0- M MaTe- puasonponoxon (1, 2}. 91m reHKi OGssaTeMHO cosep- “KAT TUICTHHKATOpHI H ApyTHe HIDKoMoxeKYARpHDAe OGABKH, KOTOpHE B mMportecce >KerLIyATAIUN MOryT MUFpHponaT, B BosIYIIHYTO cpery Ht BaaAHYIO MoNBY. ‘Yucmeune coxepxatus naacrubukatopa p nommMep- HOM MaTepHare MORET MPUBOUIT, K 3aMerHOMY YXY7 IMIcHIO Fo chIOHKO-MEXAIMIYECKHX XapaKTepHCTHK Ht Moposocroitxoctn (3, 4], ynemrveng0 Tpemustoodpa- 2OBAKIA MaTepiiana, "ITO B cBOIO ONepeD MpHPOAHT K apyuterno erviontocrit roxpustiia Ht HoTepe HM 3 urribts cnotiers. Baxuioll xepaxtepHiernxoll tomtep- Horo Matepuiacta, 9KcrUTyaTHpYeMoro vo Br1axktToit pee, anieTea Roxonorouteume, Hinkoe Boronor:ioutenite elder MaTepiiac Nese yMeTHIITeUMEM K cnoficTBe Must pocciiiexomy KimMaTy nKIaM aaMopaxtnaHttn panlopaxupaiuut i enocoGerayeT coxpanicnino 2am Mux enolicra TuIeHOK. Osi 13 crocoGon nonyxents nosmMepHoro MaTepHta- a ¢ 3atarniiMM cBoficTmaMH sBsteTeR Hertom3epaNIHE uM ero motacrmipaKaLH ewect nutacrupuKaTopos (3, 5} B coat c orm saza4a aanotl paGorit cocroaa B 10- nomen Moposoctoitxocrn TIBX-ntettox, emomaye- MOIX MPH MpOsEIBOSICTBE STEHT © JHITIKHIM cxloeM, HyTEM IMpuMenenia ewecell rutacTugancaTopos pascaratoll xu MIMIeCKOF MHP M MOYHEHI TlonesIeHHE 9THX TiTe- OK ® nouyIIOT! H nosHoHL cpemax. OGnexrawtt HecTe- sonata spnamicn TIBX-rnerks, mtactaritupon: MuGomIUTYaNsMmMe MIactuMpiKaTopaMer M-(2-sTHATeK- cuut)-o-pranatom (JOO), am6yroxcHTHtazuenHaToM (AB3A), amOytHrceGargtiarow (IBC) — 11 ux ewecan, Du-Qornarexci/-o-pratar smiseres TpamIMonHN mractupukaropoM noaismmmupstopitaa; JIBIA m JBC, ne comepxauble apowaTHMeckiX rpYMITUAPOBOK, HetON- onan 201 yeemMFeHE MoponocroliKocTH nixeHOK [3,6]. ‘Sweneprmetrranaan yaerh Voyvam muaerunmpovanente TIBX-rvtem, sone ble U8 nlxetOK, MpHMeewbIS MPH MportapoTeTRe text ¢ mITKHIM cToeM, cocrawa 100 Macs. IIBX Ha 45 ac. macrubukatops. {18 mpuroronesia KoMmonu Herioxi208a:1 MpoNbINLIcHEALYe KOMMONHETBI: ¢yerieeIH- owt TIBX Mapxn C-70 1. ruacrupixkaropss LO, AB9A, UBC. Bee Koxmtomnun cosepxam Hantomm- ou Tab 1 cra6wunatop BAC-S-20. Obparm nieHoK NlovysaME MeroqOM mambutenAIMs Ha xaGopaTOpHBIX nambuAX mpi 140°C B TeveHHIE 10 MOTH. Tommma mreok cocran:tiu1a oKo.10 0.3 wa. O6pas ta HeeTexonamMK rIpmnepHo seper 3 Mec MocTe MpHtro- B paGore onpezexum Kommectnennbilt 1 KayectD: nail COCTaB BEMLCCTS, BBULEAMOLUIXCH HD TLICHOK B BO3- AYIINYIO. 1 -BOWHYIO CPeABL TPH pAsAININBIX yoROBUAX. Macconorep pasion 8 BostymmHoft epee npr arso- cchepriom saRaenHM sya n IOTEpMHHECKHIX. YeTO~ stax np 90°C MeroxioM rpapinierpmm. Macconorepit Obpastion # YexoBHIns jHHaMHYecKOrO MOBKUNEHIIA TEM eparypht oF KoMHATHOM 0 300°C mysamt NeTOAIOM reporpasiiverpmit, Tepwinccknii aarti nponosH7m poxytimiofi epee Ha steprmparorpacbe Q-1500 mulewkit 3a Bpews OnBITA B BO-UISHO epeNy, pace Tuiwam no dopmyne ‘mz = [Crip ~ m,/m)-100, Tue mg ~ Mexomast Macca oGpasita, m,~ wacca oGpasiia B KOHIe onuira flocae pBICyINHBANNA jo MOCTOMHOT Macchi mpH Teanepatype 50°C m arwocbepHoM slaB:Te- rant. To suave Am Mi Am, paccuiréieam crenenb HaGyxaHHa oOpasua a (%4) 2a BpeMa ombtra: a = Am — dm, Zax onpenestena KaYeeTHeHHOrO cocTaBA BeIIecT®, BBI- JNATOULIXES H3 TLEHOK B BOY, MPoHsBosMMK BEINApH- Bale Boab MlocsIe onbrTa Mp 50°C uM atwocpepHoM aperiai 10 «cyxoro ocraTka». Cyxoll ocraToK 3am- bam Terparuspodypariom (TT®) m nepertocum Ha ox- vo m9 KBr, TT® wenapamt u cunwamt HK cnexrp cy- xoro ocratka. Kotpomt ynanennia TT® ocymecrna- BM chiekrpockommecks. Bsaumozeticrene KOMMONeHTOR B MUIeHKaX Haya no WoMeHeHINo NapaMerpos Momoe normouteHta GYHKLNO- HaabHbIx rpynn pn HK cnexrpax Monemubix citcTeM nuiactipaKatop-omtep. Mosemubie cHcreMbt roTo- BIT B BILTe FUeHOK Ha I%-HtIx PacTRopon 2 TT na crekisnnofi notoxKe. Terparnmpodypan nenapa pH KowHlaTHO! Tewmepatype HM Mloay¥eHHbIe MICK setxepannaim 7 4 npn 70°C at ynanenna ocraTKoB PacTnopitrens, coaepxaxite KoToporo KoHTpoaMpoBast cnexrpockormveck. HK cnexrpst MojexHBix cHcTeM sanuebinacmt Ha cnexrpomerpe UR-20. 0 Moposocroiixoct# o6pasitos cyan no Teunepatype XpynkoctH, KoTopy1o onpeseram nto TOCT [8] Achopmaumionnmie KpHBhe Moxy¥anH NpH_KoMHaTHOM TeMnepatype Ha parpsimHoll \aumHe PT-250M-2 p uaTepsane Harpys0x 0-0.5 KH. Iupoeo BH. u op. Cropocts pacrwxenns cocrantiia 25 wae- min, O6- past BbIpYGamt w BIULe TONATOK ¢ mApHHOTt PaBouero yaactxa 6.5 ww. Hanpsoxeniie 8 oGpastax paccursisa- mt no dopsyare o = PIS, reo ~ nanpsxcme (Mla), P - narpysKa (XH), 5 ~ monepestioe ceseuite paGouel wacru oGpasuia 8 Ha- wane omurra (0°), Jaw xapaxrepuernn uouKo-Mexariteckix cpotiers OGpasuios uctomsoxam paspyaioulee Hanpaxenue input paapbive 6, t Moxysx» ynpyrocra E, XapaktepHayio- ‘uti xecrkocTh MarepHaa, Koropslli paccsirTEIBam no opwye E = ole rae 6 — Hanpsxenne, ¢ ~ xepopwaluia Ha HayamHoN. ywacrxe Aeopmautonolt xpunell, B raGx. 1 mpunenewst xanie1e © Moposocroiixocrit nuxenox. Bruuio, #70 [IBX-nutenki, cozepxanue IBA, AIBC u ux ewecn ¢ 2O®, netictsirterHo Goce mopo- ocroiikie no cpapHenno ¢ HLIEHKaMet ¢ MEOH ain 00. Aametiuse uectezonana npooaunt ¢ ncinxas, conepxamunan imvoMyNAe uacTIIOKATOPLE 1X execis, MMEIONIMKE TeNMepATYPY XpyMKocTH T4,-50°C. Tipu 970M Gaunt witGpanbt MLIeHKH © MewbuDN cozep- 2xaunen JIBIA w JJEC a csecax, Tax KaK Heriom308- me 9THS nutacruuwKaTopos YBemranBaet CTOMMOCTE Marepiiaia no cpanenmmo ¢ 20%. Ha pc. | npexcransenst tepopansormie Kpambie aeHoK, B TAGs. 2 ~ ux AeopManvontto-mpoyHocTHie xapakrepHcrinen, Brexenne » cocran o6pastton [BIA 1 JBC mpynomrr x JMeHBINEHIO xecTKOCTH TuCHOK E. OsHaKo osoBpe- Meni yMenBmaetes HX Mpo¥HOcTS G5, Tama 1 Baisnne cocrana mactiuikatopa wa Tewneparypy XpyHKOCTH Ty MIeHOK Taacrupinxatop | Coctan, Try °C noo 100 0 HOO-159A Beal 0 70:30 50 50:50 50 BDA 100 50 HO®-25C 89:11 45 70:30 48 50:50 50 JBC 100 50 Brusvaue npupodse naocmupuramopon na ceolemaa MeNowNeee samepuata na oeNeee nonuewnunsrepHda 19 fl 16) 2 4 8 350 100 € 30 1006 Puc. 1. eopsauxomntie Kpusbie raieHoK, conepxausux OD W AB9A (a), TO u MBC (6). ~ nanpaxenue (Mila), © - aehopmatsin (%) 1 - JO@; 2 ~ JO@-N53A; 3 - ABDA; 4, 5 - HO-15C; 6 ~ ABC, Cooruomene maacruskaropon B emecsx (wac%): 2, 4 — 10:30; 5 — 50:50; To xe AIA pile. 2. TaGama 2 Tehopwaimtonnio-nposmoctanie XaparepHcTUKH nieHoK oy Mila Joo 100 182 NO®-159A | 10:30 143 ‘AB3A 100 124 Too-nBc | 10:30 132 50:50 127 ABC 100 na Ha pie. 2 mpimenenst xnieTH¥eckHe 3abriciMocrH noTe- PH Macest oGpamavn » nosmyuiMofl pene npit 90°C atwoopepHow Aapnennm, Ziv ntetox, mmacturnupo- BarNNAX MRUOIBHLIVaMBUBIME TETaCTHCpEKATOpADIEL, Mac- conorep mnenmoter 9 pary 1OO210°C, 50 100 : Puc. 2, Sapueuocrs norepy wacest Am (%) Ha nosayxe oF spewen t (4) mpi 90°C H arocpeption aannenAN 208 rxe- Hox, conepxauux JO (/), HOO-{B9A 2), NEPA), NOO-MBC (4, 5). UBC (9. Visnecrito, ro wurpauwis niacriupaxaropa 113 nommep- Toit mien nksmowacr erasmmt cro zouypysHut 13 oSuesta MoBepXHocTH H Yaamenus ¢ nonepsnoern. Ksmerinka povlecca MUrpalUt Npir paxUIUBIX yexoBNAX MoKeT MINHTHpoBaTHER eKopoerbIo Toll LIK Mhoft crams [9, 10]. Harinase mo Macconotepa TuIeHOK B MoTepwec- xan yenopusx (pie. 1) Soom npencranenss 8 Koopsat- arax. ypannewia MJM,=(4n'?\(DaP)'?, w rae M, - Komm¥ecTBo BbLemBUIeroca NaactHuKaTopa K-MOMGHTY npewcHH £, MpuIHToe paBHton noTepe Maccut obpaaua; M,,~ Havasbtioe conep:xaile TulacTHUKATO- pa p o6pasue; / - Tommvtia ofpaatia; « ~ npeMs or Havia- aaa onbrta; D ~ xoodepmunestr sunppyovm roxacrupunca- Tropa. Ypanvicnne (1) saauteres 4acTHBIM pettentem YpapHettia broporo saKoHia Dinka wis mNpGyoO Ha HasaMBNEIX cramuisx necopGunn (MJM,<0.6) npit onpeserentbtx Hasiambrnrx H rpaniranbsx yetopus (11, 12). Hasmeate MpsMommelinbIx y¥acTKoB Ha sapHemMocTaX MM, =fte") nwa HOD w BIA nromonsier cautraTp, 470 tka THX YHACTKAX MHTpaItH MracTiKpHKaTopos. onpexte aseTes HX sUudypyauiei B OGpastie, H AaeT BOIMOTIOCTE PaccunTaTs sHayerma KoxpuUeHTOR —aNddpysin (ra6z1, 3), KoTopsle B AaHHOM eTyHae sBMAMOTEA 1eKO- ‘Topoii 2ppexTHIOHOR nemratoli, xapakTepmayromelt exopocrs mpouecca sturpanm (13, 14] Bumto, to Dagoq Gomme, eM Daog- Aaa IBC mpa- Moumuelioro y¥aCTKa 3a BpeMa onbira He Habmoza- toch. 370 csiuieremcrayer 0 ToM, ¥ro surpanmis JBC ip nutertxnt mpi 90°C 1 aTMocipepHOM srab:tenA zuIMEETH- pyerea ne ero suysuelt 8 oGpasue, a, no-BUAMMOMY, yaaneinen muacrudukaropa ¢ mopepxHocrH o6pasuta, Te. eTy¥eeTbI0 MactrnpuKaTopa. mo TaGanua 3 Kooper juupybysimt naacrinpuxaropos b TIBX-naenkax neryaecrs macrixuncaTopos par, — | pao? posi wet wer roel) wear? | Gary. amnente) (amu. aaneuse) Joo 03 03 02 BDA 3 uu 1s IBC 13 06 Boum myaenbi Takcke mponecen BbLIENeMA rIacTHps- KaTopon #5 OGpastios & YCIOBIAX HX MpHHYAITETHO- ro yaanenna ¢ nonepsnoctn. Jit yroro 6simt mpone- lesb OMBITHI MpHt 90°C B ABMHAMMHTeCKOM BAKYYME C HfC- olaoRariiem TepMonaKyysHoli KaNepst. Ha pic. 3 npenerantenst HK crektpor petexmomteroea mracrnpe- KaTopa aa nitee, conepxameri HO. Ms pc. 3 BILINo, "TO Bo RpeMet MponeXosuET yResMrYeHME Komt- ecrsa npitemimmicroek JO®. Anasoritanice xanmte Toxyset1 H JUIN MieHlox, comepwaumtx BDA 1 JIBC. Crexrpockomveckie peayns1a76t MpestcTanci87H1 B BATE sapiteHMoctelt OF BpeMeutt onTuseesolt ruioTHocrH A o-MOH H3 Monoe nortomenns rxacrixbuKaTopa (1720 aia 1O@, ~1130 ait 159A, ~1175 cw! wt BC) (pute. 4, a) Ht xatce » Koopmmarax mpeoSparonaxnoro yparnetis (1): AdAw = U!?\DuP)”, 2 rae 4, oMHMecKax MIOTHOCTE NosoeH ToroMeHE B MoMeHT mpewenH T; A., — OMMAMECKAs MLIOTHOETS TIo- upon BL w op soca NorolleHn, cooTsctcrsyioMas HaYaNLHOMy cO- JepkANIUO MuIaeTuKaTOpa B oGpaaue (pHe. 4, 0). Onruscckue morHocrit Haxomtm ¢ yyeTow Gaxonotl TMH BEIGPAHH NoTOes MoromeHs [15]. Besursny Aq, PACCHITMRAM Mo opMyxe Aa = Agma/tg, Tae 4g ONTHMecKaa NTOTHOCTE MOOCKI TOTTOMEHHA B KOHUC OMIA; My ~ HawabHoe couepIRaKue MIActt Karopa p o6pastte; m, — norepa Maccbi o6pastta 8 KOHUE OMbiTa, MpUKATaN paBHoll KOTUGECTRY MEULENIBUIETOCK naactuuKaropa, Hasausiit nenpavommeiinesit ywacrox xpmmoit na pu. 4, 6 (~16 mam) coman ¢ nepitoxoM yeranon-teHma ‘TeumiepaTypst 8 TepMoBAKyyMiOll KaNepe MPH Mpone- _xettt onbrra (Harpenarite oF KoNHaTHOMt TeMmepaTypBt 310 90°C). B ormime or onkrros mpH arvocipepHoM. AABICHH B YCTODKAX MpHUymTetOrO ysa:teHa RutacrHipimatopa ¢ MOBePXHOCTIE THTEHKM JUTR HEX O6- pastion m Koopumaras ypapnentis (2) HaGmoramies panosmmeiipie y4acran KpHBbrs. ITO cartseTecTAYeT. (© Tom, fo B THX yeroptiAX Mnrpatus ncex TraerHIpr Karopon, p ToM sere 1 ABC, smumurrupyeren nx 2H ysnett » o6panue. 3naverma D nracrnpitkaTopon, p CSUTAHHEIE MO MpaMouMciiubiN YUaeTKAN, mpiMRes Ta6a. 3. B Hesapricmtow oxcneprmerrte 66110 yeraHOn- Reso, 410 sux omMOrO H Toro ke oMBATA Haves D, PACCHIFTAHIIE HO PAIHLIM rontocaM MorsoUteHA MLLIE- nmomterocs nemectna, micior 6uNKKe 3Havem, Ho AaWHEN TAG. 3 BAH, HT Dags4 M Dae GuTKH Mexkay’ coGoii H Gombile, Hem Dagg- Mit npestiono xii ‘itue, ro MPH arMochepHos JanTeMiH MarpanuT BC pb ormime or JO@ 1 [BIA onpescaseres ero erysee- 3600) 2800) 2000) Puc. 3. HIC cnekrpst nerywix seutects, BbuIeKMOMLHKeK 1 rtneMKH, conepxautelt JOO. TI ~ mponyexanue (4), v oaionoe auex0 (ext!) 1 ~ norsowenue oxon KBr; 2 - cnesrp, noayentit Yepen 7 MuH nocre Hayara omeTa; 3 cnekrp, NonysennUs Hepes 245 wan (Cipenka yxavbimaer Nanpannenie YeemIMeMI BpeMent or NaNasta onssTa Brownue npupoou miccmupuxamopos na ceoemen nichounos0 mamepussa Ka oenose nonueunuesoptida mu 4 03 ou Te ees ‘ Soa 0 4 & 12 tl? Puc, 4, Sasucusoers oniieexoit nrorHoent Ay nono No THOMLLHHR Vos (~1720 em!) B IK enextpax miactudmKato~ a OF BpeNeN © (uk) (a) ee orHocUTENKO! onTIseCKO rizomoern ® xoopmitarax spannennis (2) (B) 20 ERK conepaanet 100. Toi0. B cBssit ¢ oTHM GHLM HByNCHEE NoTepH Maccht HO BpeMCHH HHUIBMAVANIEHEIM TeacTHO>HKaTopaMH ptt 90°C m arwoopepHoM AasiteHH H no MlomyNCHHEIM xan Hoi paccanrrana aerysecrhs seiacrixpuikaTopon xa 10 4 (ra6x. 3). Slerysecrs JIBC oxasa:1ack » 3 pasa Menbute, em BDA. Sro canicremerayer w omsy mpestion0- eH o MHMETUpyIoUeHt pom -Tery¥eeTH LBC Mpa MHr- Panui v3 TIBX-tcrxi np ykasaHMnix yorosnax. Wpnectito [4, 13], #70 passe » Koxdxpmtentrax ZaNd ys napay co crepHyeckmat ¢baxtopam MoxCT Gute ob yexossteHo xMUNMECKoH MpMPO.IO! mppysaHra H, B-MacTHocTHs, paamraHiew Ho BauIMozelicTBH ero Mo- TeKY € MaxpoMoncey:tawm nomtucpa. Ha pile. 5 mpi- ener MK crextppt 8 oGxAcTH rrostoc MorsOMteHNs 8 TeHTHBX KOGAN KapOOHILIBHO TpYTITEL Vouo MH Jumrxyamonerx mxacraibuKaropon (xpuste 1) HB cHte- ‘Teme TIBX-mtacturuxarop (xpitasie 2). Tonocst nor: EHH Vouo TIACTHOpKATOPOB HMEIOT CTORHYIO GOP- My, TO cBASAHO ¢ CYUIeCTBOBAHHEM pasmIEHEIX 0 Mposoers acconatos Hx Morexy [7, 16, 17]. B npn eyTernmt IIBX 218 weex entcrew HaGaomaeres nepepac- Mpenenene ueTeHcHBHOCTH onoe MoTTOMLeHE B TOTS 3Y HIBKOYACTOTHIX cOCTABAMOMES KaPGOHIETEHO Mo- stocet. Tlosmreive HIDKOYACTOTHEIS cocTaRIMOUHK 10- Oe Vezo, BOIMORHO, cHEIAHO C OGparonantien H-cBsH MexkAY cloxHoxpupHuneat C=O-rpyrimaya mracriduKa- ‘Topos # CHCLrpynnasts TIBX [18]. Oasako Ha aHHOM. aTaMe He YZAcTeM ONNOSHAHO CYAIITE 0 REsEIUHHE TOTO Boanwonelicreiia Ta pasHbix Motacrixpi«aTopos, Ha- pary c oGpasonannen H-cnssett 8 cucteme [IBX-0® BoIMOKHO TaKKE sLoNOMUTTeMHOE BsaHMONeHiCTBME 3a cer oGpasonaima s7cKTpoH-toMOpHO-aKtleMTOpHEAS cnsseli Meury T-oneKrpoteMit GemomHoro Koma JOO n cnoGormentt 3d-opSwrraaaun aTowos Cl Maxpo- woaexya TIBX [19]. Bowoxtto, Gommee cymmaproc msaiproneficreue O® c [BX a crepreckie sarpysHe- 1720 1800 Pic. 5. HK enexspst nnactixpuxaropos (/) mekox TIBX- nmacmiduxarop (2) » oGnacrit ¥ TI ~ nornoweme, v ~ noaosoe wero (ex). Tiaacrupuxerop: a ~ 0%, 6 ~ JIB9A, @ ~ JBC. a MpH ero sndpy3H 8 MoTeHKe 3a eNeT Hams B MO- eKyne GertomHOTO KONBUA H PAsBETRICHHBIX YFIERO- AJOpOsINBIX pajnIKaNION MPHBOIUT K YMEHBIIICHITIO sHawe- sui xosppimuicxta muxhrpysim [OO no cpanenmo c AIB9A AIBC. Pesymsratst TepMorpansMerpsicckoro axasita TLne- MOK, COACpAAMUNN HILUIBILVasHBLE THIacTHIpUEKATOPEL, nokasamt, ro oGpasuss, coxepxannuse IBC, HasamaroT ‘TepaTh Macey Mpit Gonee HHAKoii Tewnepatype (~100°C) no epanemo ¢ o6pastaun ¢ O@ (~170°C) # BIA (160°C). Onnaxo tepwoctoiixocts ncex oGpasttos (10 ‘euneparype nloreptt 10% waccsi Ha xpitubix TT) waito paxurvaeres. TIpnwenetbte xamubte cnnuteTeABCTBYIOT 0 TOM, TO 06- panuni, coxepxamure JIBC, merce cra6itbrnst TIpH 2xc- TuryaTanuM 8 nosAyImHoll cpene No epaBHeHINy € MIE Kann, conepxairunan JIBIA HW O°. am 400 500 feumoers anwenena waccei Am (°0) 8 Bose oT epe- Meni t (¥)apit KoMaTHOIE TeMMIepaType Akts HLIeHOK, cozep- xaumix JO (J), OO-NBC (2, 3), UBC (4), LO-259A (). AB9A (6), Cootuourentte nlacruuixaropos B cMecax (wac% 70:30; 3 ~ $0:50, PesyssTaTet HIySCHLN HOMCHEHI MACcKI THIEHOK B BOE pH KOMHATHOM Tevmepatype mMprenenor Ha pric. 6. Thaenxry, conepxaumie JLO® 1 J{BC, ynemramaror waccy no ppenctm (~1%o). Tipit yneracran concpaanns IBC 8 IIcHKe NIpH JUUFTe:IbHOM BSLTEpHBAHH Macca OGpastta jenHoro ywennmacres. Trem, cosepxamne JIBIA 1 caece JO 4 BIA, TepstoT maccy (~2%). Hametterme MACCHI MTEHOK B BONE MOKCT OMIT PesyBTATOM BY MpotimonoroxHMN Mpottcccon: yReMMCHHS Maccét 3a cHeT HaGyxania o6paation 1s yMeHBUTeHIIa Macchi 3a C¥er BUMEIBAHHX KOMMOHeHTOR. PexymTaTst parnereHHs THX Mpotieccon 01a KOHEAHOH TOSKH TpahinKon (pH. 6) Mpmpexetut m Ta6x. 4 Brumio, sro nce ofpasuis MpuMepHo osuiHaKoRO HaGy- XaIOT # poze, HO MPH 9TOM KowMosHIIH, comep:aMne TIBIA, suasirremuo Tepmot maccy. Anam MK crext- POR CYXHX OcTaTKoR NOKasa, 4TO RBUIeIMOINMHCR BeIecTBaMH sRIAIOTCA TLTACTHCpUKATODEL, a TARE THAD okeinieomepxamee cocsuMneH, BXOsMCE R COCTaB cra Simnatopa. Bowoxso, 470 Gombuuee nbIMEIMAHHIE muactaxpukaTopon i TeIenok, conepxanutx JIBIA, cas gaHo ¢ Hamanien 8 ero erpyktype MoaspHbr C-O-C- IpYMMpOROK, TOCTYTMN sR MaKIMOrEiicTBNR ¢ RO- oll, 8 ormmsue oT JO®, w Menbatel erloasppioft wac- Tagawa 4 Bmtanne nppomst reractuurkaTopa Ha waMenerme MACCBI TLICHOK B Bose NpH KoMHaTHOH TeNMepaType 3a 1000 T Taacruxpuatop |Cocran, %| Am, % | Amy, % | a, % Low 100 09 08 Ww Yoo-152a | 70:30 | 24 40 16 BDA 100 24 4 1 goo-nBc | 70:30 08 ta 19 50:50 os 08 13 BC 100 o4 Lo 14 O—LT—E Iupoea Bt. u op, Tuo Morexyast JB9A [(CH,),-] m0 epantetido ¢ JBC HCH))e-1. Buon 1, Cuoticrpa yoyseuntx nomHBIMMUTTOpHABIETX HIEHOK, cONepRAUINX MRUDIBHLAVAMSHBLE MTACTHpAKATOPEE Ht eME- cH racriipuikaropon, MUTpauia miacriKbiKaTopoD 1 auteHOK B BosAVUNEYIO H BONHYIO epesBI B aHasHETEN- Holl cTeneMHt 1aBueAT OF xsDMHeCKOH| MpuposB MuIACTH- duxaropos. 2, Jobanzenne mibyruacGanmara 1 mu6yroKeHoTHIA- sunnnara x u1-(2-sTuMeKcH)-o-pranaty ysemrunpaer MoporocToliKOcTD TUIeHOK H YMeHbUlAeT HX KeCTKOCTE. 3. B nosxyumoit epexe Gonee craGuabins tera, conep- cxaumnie eect sm1(2-sTHUIrexett1_o-pramata ¢ J1GyTOK- cITIUTaMMMATOM, B To BpeNs KAK B YoHOBHX AOI TemHoro nosaelieToNA BAATIE MpeMMOGTHTENBHO He- Tomsonars 8 xavecTRe oGankit miGyTineesauweTan. PaGora nbinocmena mpi nosmepxKe rparra US CRDF. N EK-005-XI. Cumcox snrreparypi (1) TY 952822-92, Jenra nomnunserxaopaatan TexwiecKaR 2) Cnpasounune no nacruecki Macca J Tlox pea. MULCap6apa, M.C.Axynima, H.M.Eropona. M. its, 1967. 462 «. (8) Tye K Tnacrupuxatopet / Tlep. ¢ new. nom pea. E.B.Tpocravexoro. M. JL: Ximuts, 1964. 916 © (| Wimaprnan 6.11. Txacripuxauns nomeunnaxaopAsa. Me Xana, 1975. 248 e. (9) Eeopoe AH, Xanuyatun A.K ll Tnact. wacces, 2002 M5. C. 4844 (6) Bapumein PC, Kupurosws BL, Hocoeekut 10.5. Txecruguatops 20 nomuMepon. M.: Xunwns, 1982, 200 «. (7) Aupowa BIL, Momuxova E.A., Meronus AFL, Toaeose nosa JI. If Beicoxowonexyap. coesinentis, 2002 T. 445, Se 2. C. 363-368. TOCT 16214-86. Jlerra nomiuserxnopiumtas anexrpo: moammionnas: Textiveckite yenoBtt (91 Hasapoe BI, Hed0" A.B, Cenenoe A.A. I! BucoKoMo~ rexynap. coetimenns. 1991. T. 335. ¥8 12. C. 927-933. U0] Haxepoe BI, Hledoe A.B. Il Buicoxomonexyasp. oes nents. 2002. T. 44B. Ne 4, C. 729-732. [0] Marun 4, Yarix AE, Juvbbyats a pasxocrs nom ‘Mepos: Meron inMepemia. M.: Xinuis, 1979. 304 c. (12) Mpo6nests du 1 xuwusn TepaOrO coeTOsKIKA opra- uwieexsix coemmnenni: Tlep. © ana, M.: Mup, 1968. 416 c. 8 Bouenne npupoder nzacmupuramopon Ko cmokcmea naenowNos0 samepuasa no dcnoKe nosuewuasnepiia ins [13] Harix A.£. Jtuhpyous » nomwepnx everewax. M Xmnewg, 1987. 312 [4] Peimaucep CA. TIpommaenocts nonimeprix ware- puazos. M: Xusts, 1974. 272 US) Cum A, Hpwcnanan cnexrpockomix / ep. © aura, nox ea. A.AMamuiena. M: Mup, 1982. 328 © U6] Mosexynspasie moanoneiicraus / Tox per. TParait- woxa, YOpsunTowaca J Wep. ¢ anta. non pen 9 Kypaias npinantes xian, woin. 10, 2004 A.M.Bponexoro. M: Mup, 1984. 600 « 117) Supowa BH, Hoxpuna HH, Shomuoaa EA. u op. It DKTIX, 1996. T. 69, Nb 2, C. 306-314 U8} Ganaik Baijayantimata, Sivaram Swaminathan i Macro- molecules. 1996, V. 29. N 1. P. 185-190. 9] 1Ouxo0a C.M., Tazep A.A., Becconoa 10.C. x ap. I Brsco- xowoeryaap. coeimens. 1982. T. 248. Ne 7. c. 1373-1377,