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Nivaldo Tro
• Reactions in which O2 is consumed by combining with
another substance are called combustion reactions.
! Always release heat and/or other forms of energy.
! Produce one or more oxygen-containing compounds.
Chapter 7 • Combustion reactions are a subclass of
Chemical oxidation–reduction reactions.
! aka redox reactions.
Reactions ! Involve the transfer of electrons between atoms.
Reactants ! Products
Roy Kennedy
Massachusetts Bay Community College
Wellesley Hills, MA
4
2009, Prentice Hall
1 2
Evidence of Chemical Change Chemical Equations
• Short-hand way of describing a reaction.
• Provides information about the reaction.
!Formulas of reactants and products.
Release or Absorption of Heat Emission of Light
Color Change !States of reactants and products.
!Relative numbers of reactant and product
molecules that are required.
!Can be used to determine masses of reactants
used and products that can be made.
Formation of a Gas Formation of Solid Precipitate
Tro's "Introductory Chemistry", 7 Tro's "Introductory Chemistry", 10
Chapter 7 Chapter 7
3 4
Combustion of Methane
• Methane gas burns to produce carbon dioxide gas and Chemical Equations, Continued
gaseous water.
! Whenever something burns it combines with O2 (g).
CH4(g) + 2 O2(g) ! CO2(g) + 2 H2O(g)
CH4(g) + O2(g) ! CO2(g) + H2O(g) • This equation is balanced, meaning that there
What incorrect assumption was made when writing this equation? are equal numbers of atoms of each element on
This equation reads “1 molecule of CH4 gas combines with 1 the reactant and product sides.
molecule of O2 gas to make 1 molecule of CO2 O
gas and 1 molecule ! To obtain the number of atoms of an element,
H H
of H2 O gas”.
C + O O C + HO H multiply the subscript by the coefficient.
H H 1"C!1
O 4"H!4
1C+4H + 2O 1C+2O +2H+O 4"O!2+2
1C+2H+3O
We are assuming that all reactants combine 1 molecule : 1 molecule;
and that 1 molecule of each product is made – an incorrect assumption Tro's "Introductory Chemistry",
Chapter 7
16
Combustion of Methane,
Symbols Used in Equations
Balanced
• To show the reaction obeys the Law of Conservation of • Symbols used to indicate state after chemical.
Mass the equation must be balanced. !(g) = gas; (l) = liquid; (s) = solid.
! We adjust the numbers of molecules so there are equal !(aq) = aqueous = dissolved in water.
numbers of atoms of each element on both sides of the arrow.
CH4(g) + 2 O2(g) ! CO2(g) + 2 H2O(g) • Energy symbols used above the arrow for
decomposition reactions.
O O O O
H H H H ! # = heat.
C + + C + + ! h$ = light.
H H
O O O
O H H
!shock = mechanical.
1C + 4H + 4O
!elec = electrical.
1C + 4H + 4O
Tro's "Introductory Chemistry", 14 Tro's "Introductory Chemistry", 17
Chapter 7 Chapter 7
5 6
Writing Balanced Chemical Equations, Example, Continued
Continued • When magnesium metal burns in air, it
4. Find the least common multiple (LCM) of the produces a white, powdery compound
number of atoms on each side. magnesium oxide.
! The LCM of 3 and 2 is 6. Mg(s) + O2(g) ! MgO(s)
5. Multiply each count by a factor to make it equal '" Use factors as coefficients in front of the compound
to the LCM. containing the element.
6. Use this factor as a coefficient in the equation. ! We do not write 1 as a coefficient, its understood.
! If there is already a coefficient there, multiply it by Mg(s) + O2(g) ! 2 MgO(s)
the factor.
! It must go in front of entire molecules, not between
1 " Mg ! 1
atoms within a molecule. 1x2"O!1x2
7. Recount and repeat until balanced.
Tro's "Introductory Chemistry", 19 Tro's "Introductory Chemistry", 22
Chapter 7 Chapter 7
7 8
Another Example, Continued Another Example, Continued
• Under appropriate conditions at 1000°C (* Recount – N & O not balanced
ammonia gas reacts with oxygen gas to 2 NH3(g) + O2(g) ! NO(g) + 3 H2O(g)
produce gaseous nitrogen monoxide and 2"N!1
steam
6"H!6
NH3(g) + O2(g) ! NO(g) + H2 O(g)
2"O!1+3
#* count the number of atoms of on each side
(* and Repeat – attack the N
NH3(g) + O2(g) ! NO(g) + H2 O(g) 2 NH3(g) + O2(g) ! 2 NO(g) + 3 H2 O(g)
1"N!1 2"N!1x2
3"H!2 6"H!6
2"O!1+1 2"O!1+3
Tro's "Introductory Chemistry", 25 Tro's "Introductory Chemistry", 28
Chapter 7 Chapter 7
9 10
Another Example, Continued Practice #2
Acetic acid reacts with the metal aluminum to make aqueous
(* You can’t have a coefficient that isn’t a whole aluminum acetate and gaseous hydrogen.
number. Multiply all the coefficients by a !Acids are always aqueous.
number to eliminate fractions !Metals are solid except for mercury.
! If ?.5, then multiply by 2; if ?.33, then 3; if ?.25,
then 4
{2 NH3(g) + 2.5 O2(g) ! 2 NO(g) + 3 H2O(g)} x 2
4 NH3(g) + 5 O2(g) ! 4 NO(g) + 6 H2O(g)
4"N!4
12 " H ! 12
10 " O ! 4 + 6
Tro's "Introductory Chemistry", 31 Tro's "Introductory Chemistry", 34
Chapter 7 Chapter 7
11 12
Practice #3, Continued
Combustion of ethyl alcohol (C2H5OH) in Aqueous Solutions
flambé (a brandied flaming dessert). • Many times, the chemicals we are reacting
!Combustion is burning, and therefore, reacts with O2. together are dissolved in water.
!Combustion of compounds containing C and H !Mixtures of a chemical dissolved in water are
always make CO2(g) and H2O(g) as products. called aqueous solutions.
C2H5OH(l) + O2(g) ! CO2(g) + H2O(g) • Dissolving the chemicals in water helps them
to react together faster.
C2H5OH(l) + 3 O2(g) ! 2 CO2(g) + 3 H2O(g) !The water separates the chemicals into individual
molecules or ions.
!The separate, free-floating particles come in
contact more frequently so the reaction speeds up.
Practice #4
Combustion of liquid butane (C4H 10) in a lighter.
Predicting Whether a Reaction
C4H10(l) + O2(g) ! CO2(g) + H2O(g) Will Occur in Aqueous Solution
• “Forces” that drive a reaction:
! Formation of a solid.
! Formation of water.
! Formation of a gas.
! Transfer of electrons.
• When chemicals (dissolved in water) are
mixed and one of the above-noted forces
occur, the reaction will generally happen.
13 14
Dissociation, Continued
• Potassium iodide dissociates in water into Electrolytes, Continued
potassium cations and iodide anions. • In strong electrolytes, all the
KI(aq) ! K+1(aq) + I-1(aq) electrolyte molecules or formula
units are separated into ions.
K I K+1 I-1 • In nonelectrolytes, none of the
molecules are separated into
• Copper(II) sulfate dissociates in water into ions.
copper(II) cations and sulfate anions. • In weak electrolytes, a small
CuSO4(aq) ! Cu+2(aq) + SO4-2(aq) percentage of the molecules are
separated into ions.
Cu SO4 Cu+2 SO4-2
Types of Electrolytes
Dissociation, Continued • Salts = Water soluble ionic compounds.
! All strong electrolytes.
• Potassium sulfate dissociates in water into • Acids = Form H+1 ions and anions in water solution.
! In binary acids, the anion is monoatomic. In oxyacids, the anion
potassium cations and sulfate anions. is polyatomic.
K2SO4(aq) ! 2 K+1(aq) + SO4-2(aq) ! Sour taste.
K+1 ! React and dissolve many metals.
K SO4 K SO4-2 ! Strong acid = strong electrolyte, weak acid = weak electrolyte.
15 16
Using the Solubility Rules to Predict an
When Will a Salt Dissolve?, Ionic Compound’s Solubility in Water
Continued • First check the cation: If it is Li+ , Na+ , K+ , or
• Predicting whether a compound will NH4+, then the compound will be soluble in water.
dissolve in water is not easy. ! Regardless of the anion.
• If the cation is not Li+ , Na+, K+ , or NH4+, then
• The best way to do it is to do some
follow the rule for the anion.
experiments to test whether a compound
• If a rule says the compounds are mostly soluble,
will dissolve in water, then develop some then the exceptions are insoluble.
rules based on those experimental results.
• If a rule says the compounds are mostly insoluble,
!We call this method the empirical method. then the exceptions are soluble.
! Note: slightly soluble % insoluble.
Tro's "Introductory Chemistry", 49 Tro's "Introductory Chemistry", 52
Chapter 7 Chapter 7
Solubility Rules:
Compounds that Are Generally Soluble in Water
Determine if Each of the
Following Is Soluble in Water
Compounds containing the Exceptions • KOH
following ions are generally (when combined with ions on the
soluble left the compound is insoluble) • AgBr
Li+ , Na+ , K+ , NH4+ none • CaCl2
NO3–, C2H3 O2– none • Pb(NO3)2
Cl–, Br–, I– Ag+ , Hg22+, Pb2+ • PbSO4
SO42– Ca2+, Sr2+, Ba2+, Pb2+
Solubility Rules:
Compounds that Are Generally Insoluble
Determine if Each of the Following Is
Soluble in Water, Continued
Exceptions
Compounds containing the (when combined with ions on the • KOH Soluble, because the cation is K+.
following ions are generally left the compound is soluble or • AgBr Insoluble, even though most compounds
insoluble slightly soluble) with Br! are soluble, this is an exception.
OH– Li+ , Na+ , K+ , NH4+ , • CaCl2 Soluble, most compounds with Cl! are
Ca2+, Sr2+, Ba2+ soluble.
S2– Li+ , Na+ , K+ , NH4+ , • Pb(NO3 )2 Soluble, because the anion is NO3!.
Ca2+, Sr2+, Ba2+ • PbSO4 Insoluble, even though most compounds
CO32–, PO43– Li+ , Na+ , K+ , NH4+ with SO42! are soluble, this is an exception.
17 18
No Precipitate Formation =
Precipitation Reactions
• Many reactions are done by
No Reaction
mixing aqueous solutions of KI(aq) + NaCl(aq) ! KCl(aq) + NaI(aq)
electrolytes together. All ions still present, & no reaction.
• When this is done, often a
reaction will take place from
the cations and anions in the
two solutions that are
exchanging.
• If the ion exchange results in
forming a compound that is
insoluble in water, it will come
out of solution as a precipitate.
Tro's "Introductory Chemistry", 55 Tro's "Introductory Chemistry", 58
Chapter 7 Chapter 7
19 20
Example 7.7—When an Aqueous Solution of Sodium Practice–Predict the Products and Balance the
Carbonate Is Added to an Aqueous Solution of Equation, Continued
Copper(II) Chloride, a White Solid Forms, Continued.
• KCl(aq) + AgNO3(aq) !
3. Write the formulas of the products. • KCl(aq) + AgNO3(aq) ! KNO3(aq) + AgCl(s)
! Cross charges and reduce.
Na2 CO3(aq) + CuCl2(aq) ! NaCl + CuCO3
4. Balance the equation. • Na2S(aq) + CaCl2(aq) !
Na2 CO3(aq) + CuCl2(aq) ! 2 NaCl + CuCO3 • Na2S(aq) + CaCl2(aq) ! 2 NaCl(aq) + CaS(aq)
• No reaction.
Example 7.7—When an Aqueous Solution of Sodium Practice—Write an Equation for the Reaction
Carbonate Is Added to an Aqueous Solution of that Takes Place when an Aqueous Solution
Copper(II) Chloride, a White Solid Forms, Continued. of (NH4)2SO4 is Mixed with an Aqueous
Solution of Pb(C2H3O2)2.
5. Determine the solubility of each product.
Write an (s) after the insoluble products and a
(aq) after the soluble products
NaCl is soluble.
CuCO3 is insoluble.
Na2 CO3(aq) + CuCl2(aq) ! 2 NaCl(aq) + CuCO3(s)
21 22
Ionic Equations
Writing Net Ionic Equations
• Equations that describe the chemicals put into the water and
the product molecules are called molecular equations. • First, identify the spectator ions in the
2 KOH(aq) + Mg(NO3)2(aq) ! 2 KNO3 (aq) + Mg(OH)2(s) complete ionic equation.
• Equations that describe the actual dissolved species are !Identical ions on both sides of the equation.
called complete ionic equations.
• Cancel out the spectator ions—the result is
! Aqueous electrolytes are written as ions.
" Soluble salts, strong acids, strong bases.
the net ionic equation.
! Insoluble substances and nonelectrolytes written in molecule form.
" Solids, liquids, and gases are not dissolved, therefore, molecule form.
2K+1 (aq) + 2OH-1(aq) + Mg+2(aq) + 2NO3-1(aq) ! 2K+1(aq) + 2NO3-1(aq) + Mg(OH)2(s)
Summary
Writing Complete Ionic Equations
• A molecular equation is a chemical
• Rewrite the molecular equation, but dissociate equation showing the complete, neutral
strong electrolytes into individual ions. formulas for every compound in a reaction.
! Strong electrolytes must be aqueous.
" Solids, liquids, or gases cannot be electrolytes. • A complete ionic equation is a chemical
! All soluble ionic compounds are strong electrolytes. equation showing all of the species as they
! Strong acids are strong electrolytes. are actually present in solution.
" HCl, HNO3 , H2 SO4 . .
" Weak acids are not written in the dissociated ion form. • A net ionic equation is an equation
! Molecular compounds do not have ions, leave in the showing only the species that actually
molecular form.
participate in the reaction.
Tro's "Introductory Chemistry", 68 Tro's "Introductory Chemistry", 71
Chapter 7 Chapter 7
• An ionic equation in which the spectator ions are Na2 CO3(aq) + 2 HCl(aq) ! 2 NaCl(aq) + CO2(g) + H2O(l)
removed is called a net ionic equation.
2OH-1(aq) + Mg+2(aq) ! Mg(OH)2(s)
23 24
Practice–Write the Ionic and Net
Ionic Equation. Properties of Bases
K2SO4(aq) + Ba(NO3 )2 (aq) ! 2 KNO3(aq) + BaSO4(s) • A.k.a. alkalis.
2K+ (aq) + SO4 2" (aq) + Ba2+(aq) + 2NO3 " (aq) ! 2K + (aq) + 2NO3 " (aq) + BaSO4 (s)
• Taste bitter.
Ba2+(aq) + SO4-2(aq)! BaSO4(s)
• Feel slippery.
• Change color of vegetable dyes.
Na2 CO3(aq) + 2 HCl(aq) ! 2 NaCl(aq) + CO2(g) + H2O(l) !Different color than acid.
2Na+(aq) + CO32"(aq) + 2H+(aq) + 2 Cl"(aq) ! 2Na+(aq) + 2Cl"(aq) + CO2(g) + H2O(l)
!Litmus = blue.
CO3-2(aq) + 2 H+1(aq) ! CO2(g) + H2O(l) • React with acids to form ionic salts.
!And often water.
!Neutralization.
Tro's "Introductory Chemistry", 73 Tro's "Introductory Chemistry", 76
Chapter 7 Chapter 7
25 26
Process for Predicting the Products of Example 7.11—Write the Molecular, Ionic, and Net-
an Acid–Base Reaction Ionic Equation for the Reaction of Aqueous Nitric
!"Determine what ions each aqueous reactant has. Acid with Aqueous Calcium Hydroxide, Continued.
#"Exchange ions.
! (+) ion from one reactant with (-) ion from the other. 5. Determine the solubility of the salt.
! H+ combines with OH" to make water. Ca(NO3)2 is soluble.
$"Balance charges of combined ions to get formula of
the salt.
a. Write an (s) after an insoluble salt and an (aq)
%"Balance the equation. after a soluble salt.
! Count atoms.
2 HNO3(aq) + Ca(OH)2(aq) ! Ca(NO3)2(aq) + 2 H2O(l)
&"Determine solubility of the salt.
! Use the solubility rules.
! If the salt is insoluble or slightly soluble, it will precipitate.
Tro's "Introductory Chemistry", 79 Tro's "Introductory Chemistry", 82
Chapter 7 Chapter 7
Example 7.11—Write the Molecular, Ionic, and Net- Example 7.11—Write the Molecular, Ionic, and Net-
Ionic Equation for the Reaction of Aqueous Nitric Ionic Equation for the Reaction of Aqueous Nitric
Acid with Aqueous Calcium Hydroxide. Acid with Aqueous Calcium Hydroxide, Continued.
1. Write the formulas of the reactants. 6. Dissociate all strong electrolytes to get complete ionic
HNO3(aq) + Ca(OH)2(aq) ! equation.
a. Determine the ions present when each reactant ! HNO3 is a strong acid, Ca(OH)2 and Ca(NO3) 2 are ionic.
dissociates. ! Not H2O.
(H+
+ NO3 + ")
+ ! (Ca2+ OH" ) 2H+(aq) + 2NO3 "(aq) + Ca2+(aq) + 2OH"(aq) ! Ca2+(aq) +
2NO3"(aq) + H2 O(l)
2. Exchange the ions, H+1 combines with OH" to
make H2O(l). 7. Eliminate spectator ions to get net-ionic equation.
(H+ + NO3") + (Ca2+ + OH") ! (Ca+2 + NO3") + H2O(l) 2 H +(aq) + 2 OH"(aq) ! 2 H2O(l)
H+(aq) + OH"(aq) ! H2O(l)
Tro's "Introductory Chemistry", 80 Tro's "Introductory Chemistry", 83
Chapter 7 Chapter 7
Example 7.11—Write the Molecular, Ionic, and Net- Practice—Complete and Balance These
Ionic Equation for the Reaction of Aqueous Nitric Acid–Base Reactions.
Acid with Aqueous Calcium Hydroxide, Continued. NH4OH(aq) + H2SO4 (aq) !
3. Write the formula of the salt product.
! Cross charges and reduce.
HNO3(aq) + Ca(OH)2(aq) ! Ca(NO3)2 + H2O(l)
4. Balance the equation. Al(OH)3(aq) + H2SO3(aq) !
! May be quickly balanced by matching the
numbers of H and OH to make H2O.
! Coefficient of the salt is always 1.
2 HNO3(aq) + Ca(OH)2(aq) ! Ca(NO3)2 + 2 H2O(l) Ba(OH)2(aq) + H2 SO4(aq) !
27 28
Practice—Complete and Balance These Process for Predicting the Products of
Acid–Base Reactions, Continued. a Gas-Evolving Reaction
!"Determine what ions each aqueous reactant has.
2 NH4OH(aq) + H2SO4(aq) ! (NH4 )2 SO4(aq) + 2 H2O(l) #"Exchange ions.
! (+) ion from one reactant with (-) ion from the other.
$"Balance charges of combined ions to get formula of
each product.
2 Al(OH)3(aq) + 3 H2SO3(aq) ! Al2(SO3)3(s) + 6 H2O(l) %"Check to see if either product is H2S.
&"Check to see if either product decomposes. If so,
rewrite as H2O(l) and a gas.
! See Table 7.4
Ba(OH)2(aq) + H2 SO4(aq) ! BaSO4(s) + 2 H2O(l) '"Balance the equation.
("Determine solubility of other product in water.
Tro's "Introductory Chemistry", 85 Tro's "Introductory Chemistry", 88
Chapter 7 Chapter 7
29 30
Example—When an Aqueous Solution of Sodium
Sulfite Is Added to an Aqueous Solution of Nitric Other Patterns in Reactions
Acid, a Gas Evolves, Continued. • The precipitation, acid–base, and gas evolving
6. Balance the equation. reactions all involved exchanging the ions in the
Na2SO3(aq) + 2 HNO3(aq) ! 2 NaNO3 + SO2(g) + H2O(l) solution.
7. Determine the solubility of other product. • Other kinds of reactions involve transferring
electrons from one atom to another. These are called
NaNO3 is soluble.
oxidation–reduction reactions.
a. Write an (s) after the insoluble products and an ! Also known as redox reactions.
(aq) after the soluble products. ! Reactions of materials with O2 are redox reactions.
Na2SO3(aq) + 2 HNO3 (aq) ! 2 NaNO3(aq) + SO2 (g) + H2O(l)
! Unlike the others, many of these reactions are not done by
dissolving the reactants in water.
Tro's "Introductory Chemistry", 91 Tro's "Introductory Chemistry", 94
Chapter 7 Chapter 7
31 32
Combustion as Redox, Continued Ionic Compound Formation
• Even though the following reaction does not involve ion
formation, electrons are still transferred. as Redox
CH4(g) + 2 O2(g) ! CO2(g) + 2 H2O(g) • In the reaction:
• The carbon atoms are oxidized. Mg(s) + Cl2(g) ! MgCl2(s)
C'4 ! C+4 + 8 e'
! These are not charges, they are called oxidation numbers, but • The magnesium atoms are oxidized.
they help us see the electron transfer. Mg0 ! Mg2+ + 2 e'
• The oxygen atoms are reduced.
O0 + 2 e' ! O'2
• The chlorine atoms are reduced.
Cl0 + 1 e' ! Cl'
33 34
Practice—Decide Whether Each of the Following Combustion Products
Reactions Is a Redox Reaction, Continued.
• To predict the products of a combustion
2 Al(s) + 3 Br2 (l) ! 2 AlBr3(s)—Yes, metal + nonmetal. reaction, combine each element in the other
CaSO3(s) + 2 HCl(aq) ! CaCl2(aq) + SO2(g) + H2O(l)—No, this
reactant with oxygen.
Reactant Combustion product
is a gas evolving
Contains C CO2 (g)
reaction. Contains H H2O(g)
Contains S SO2(g)
Fe2O3(s) + C(s) ! 2 Fe(s) + 3 CO(g)—Yes, the Fe is reduced
Contains N NO(g) or NO2(g)
and the C gets Contains metal M2O n(s)
35 36
Classifying Reactions Decomposition Reactions
• One way is based on the process that happens. • A large molecule is broken apart into
smaller molecules or its elements.
!Precipitation, neutralization, formation of a gas, or
!Caused by addition of energy into the molecule.
transfer of electrons.
• Have only one reactant, make 2 or more
products.
37 38
Practice—Classify the Following Reactions as
Synthesis, Decomposition, Single Displacement, or
Displacement of Copper by Zinc Double Displacement.
Zn(s) + CuCl 2 (aq) ! Cu(s) + ZnCl2
3 Mg(s) + 2 FeCl3(aq) ! 3 MgCl2(aq) + 2 Fe(s)
CaCO3 ( s ) !heat
!!" CaO( s ) + CO 2 ( g )
39 40