Sistema: acetona(1)/metanol(2)/agua(3)

T(°C), P(kPa) PARAMETROS DE NRTL

i A B C bij
1 14.392 2795.820 230.000 Acetona (1) 184.7
2 16.594 3644.300 239.760 Metanol(2)
3 16.262 3799.890 226.350 Acetona (1) 631.05
Agua (3)
P(kPa) R(cal/mol.K) Metanol(2) -253.88
101.330 1.987 Agua (3)

i xi Tsati (°C) Psati (kPa)

1 0.300 16.821 159.52489635
2 0.400 25.822 125.07145666
3 0.300 30.000 31.177456723
t0= 70.000

0 1 2 3 4 5
t (°C) 70.000 63.03108144 66.045748663 65.9023597 65.90901322 65.9087041
T (K) 343.150 336.181 339.196 339.052 339.059 339.059
τ12 0.2708850424 0.2765003965 0.2740429462 0.27415884 0.274153462 0.27415371
τ21 0.3265286727 0.3332975001 0.3303352547 0.33047496 0.330468472 0.33046877
τ13 0.9255116732 0.9446972129 0.9363010353 0.93669701 0.936678626 0.93667948
τ31 1.7561475835 1.7925519208 1.7766202721 1.77737162 1.777336746 1.77733837
τ23 -0.372345937 -0.380064541 -0.376686644 -0.37684595 -0.376838554 -0.3768389
τ32 1.2396033932 1.2652999466 1.2540543508 1.2545847 1.254560085 1.25456123
G12 0.9198534206 0.9182618198 0.9189580137 0.91892517 0.918926693 0.91892662
G21 0.904202949 0.9023173883 0.9031420829 0.90310317 0.903104979 0.90310489
G13 0.609875228 0.6036554319 0.6063695604 0.60624129 0.60624724 0.60624696
G31 0.39128869 0.5753233707 0.5781570746 0.57802312 0.578029339 0.57802905
G23 1.1179318028 1.1205182746 1.1193856201 1.11943901 1.119436533 1.11943665
G32 0.6899492354 0.6769089514 0.6792606432 0.67914955 0.679154708 0.67915447
M1 0.3242474817 0.4449211631 0.442522404 0.44263601 0.442630738 0.44263098
M2 0.3313313839 0.3331177852 0.3310991179 0.33119463 0.331190197 0.3311904
M3 0.0028310469 0.0007337759 0.001660289 0.0016169 0.001618912 0.00161882
N1 0.7790677866 0.3290708133 0.3312362104 0.33113401 0.33113875 0.33113853
N2 0.8829407968 0.8785512313 0.8794655971 0.87942242 0.87942442 0.87942433
N3 0.9301352895 0.9293039394 0.9296651161 0.92964799 0.929648785 0.92964875
Ganma1 1.482738242 1.2975304358 1.3047752948 1.30444078 1.304456323 1.3044556
Ganma2 1.0394359147 0.7973501652 0.8076425335 0.80715929 0.807181729 0.80718069
Ganma3 1.6066106216 1.9810969849 1.971394598 1.97185316 1.971831876 1.97183287
Psat1 117.14486566 134.12818147 133.27568273 133.315138 133.3133052 133.31339
Psat2 91.844466437 105.15980527 104.49142522 104.522359 104.5209222 104.520989
Psat3 22.894727174 26.21393694 26.047325061 26.0550362 26.05467797 26.0546946
t 63.03108144 66.045748663 65.902359744 65.9090132 65.90870413 65.9087185

i xi Psati Ganma i yi
1 0.300 133.313 1.3045 0.5149
2 0.400 104.521 0.8072 0.3330
3 0.300 26.055 1.9718 0.1521
1.0000
 bji α12
222.64 0.3084

1197.41 0.5343

845.21 0.2994

6
65.9087185 T(K) 334.48599737633
339.059 t(°C) 61.335997376328
0.2741537 y1 0.532235253947
0.33046876 y2 0.3663847032515
0.93667944 y3 0.1013800428015 1
1.77733829 τ12 0.2779016253122
-0.3768389 τ21 0.3349865612318
1.25456118 τ13 0.9494846813928
0.91892663 τ31 1.8016360864378
0.9031049 τ23 -0.381990604409
0.60624698 τ32 1.2717121425561
0.57802906 G12 0.9178650888063
1.11943664 G21 0.901847487794
0.67915448 G13 0.6021132880382
0.44263097 G31 0.3818932495063
0.33119039 G23 1.1211646229437
0.00161882 G32 0.6833482848552
0.33113854 M1 0.3272525133199
0.87942433 M2 0.3372295534325
0.92964875 M3 0.0001994622527
1.30445563 N1 0.7753069699695
0.80718073 N2 0.8803640120984
1.97183282 N3 0.9290998355889
133.313386 Ganma1 1.4868097062452
104.520986 Ganma2 1.0410711730312
26.0546938 Ganma3 1.6159377097437
65.9087178 EC1 -7.212529486E-07
EC2 -1.962999236E-07
EC3 -2.473562626E-06
EC4 0
F(t,yi) 3.391115498E-06
Sistema: acetona(1)/metanol(2)/agua(3)
T(°C), P(kPa) PARAMETROS DE NRTL
i A B C bij bji
1 14.392 2795.820 230.000 Acetona (1) 184.7 222.64
2 16.594 3644.300 239.760 Metanol(2)
3 16.262 3799.890 226.350 Acetona (1) 631.05 1197.41
Agua (3)
P(kPa) 101.330 R(cal/mol.K) 1.987 Metanol(2) -253.88 845.21
Ƴi= 1 Agua (3)
i yi Tsati (°C) Psati (kPa) Psatj Ganma i
1 0.300 16.821 173.0499182 231.8167 1
2 0.400 25.822 138.1597673 185.0781 1
3 0.300 30.000 34.91898946 46.7773 1
t0= 72.643

0 1 2 3 4 5
t 70.0000 73.9111 74.1998 74.2461 74.2545 74.2561
T 343.1500 347.0611 347.3498 347.3961 347.4045 347.4061
x1 0.1311 0.0650 0.0522 0.0475 0.0456 0.0448
x2 0.2190 0.2362 0.2172 0.2082 0.2043 0.2026
x3 0.6499 0.6988 0.7305 0.7443 0.7501 0.7526
τ12 0.2709 0.2678 0.2676 0.2676 0.2676 0.2676
τ21 0.3265 0.3228 0.3226 0.3225 0.3225 0.3225
τ13 0.9255 0.9151 0.9143 0.9142 0.9142 0.9142
τ31 1.7561 1.7364 1.7349 1.7347 1.7346 1.7346
τ23 -0.3723 -0.3681 -0.3678 -0.3678 -0.3678 -0.3678
τ32 1.2396 1.2256 1.2246 1.2245 1.2244 1.2244
G12 0.9199 0.9207 0.9208 0.9208 0.9208 0.9208
G21 0.9042 0.9052 0.9053 0.9053 0.9053 0.9053
G13 0.6099 0.6133 0.6135 0.6136 0.6136 0.6136
G31 0.3913 0.3954 0.3958 0.3958 0.3958 0.3958
G23 1.1179 1.1165 1.1164 1.1164 1.1164 1.1164
G32 0.6899 0.6928 0.6931 0.6931 0.6931 0.6931
M1 0.5112 0.5489 0.5650 0.5718 0.5747 0.5759
M2 0.5885 0.6095 0.6329 0.6433 0.6478 0.6498
M3 -0.0171 -0.0606 -0.0599 -0.0588 -0.0583 -0.0580
N1 0.5834 0.5551 0.5380 0.5306 0.5274 0.5261
N2 0.7880 0.7802 0.7716 0.7678 0.7662 0.7655
N3 0.9747 1.0024 1.0051 1.0059 1.0062 1.0063
Ganma1 2.5628 3.1490 3.4533 3.5979 3.6626 3.6908
Ganma2 1.1772 1.2645 1.3168 1.3417 1.3528 1.3576
Ganma3 1.1806 1.1157 1.0930 1.0841 1.0804 1.0789
Psat1 182.5937 184.8273 185.1873 185.2530 185.2650 185.2672
Psat2 145.7793 147.5626 147.8500 147.9025 147.9120 147.9138
Psat3 36.8448 37.2955 37.3681 37.3814 37.3838 37.3843
t(°C) 73.9111 74.1998 74.2461 74.2545 74.2561 74.2564

i yi Psati(KPa) xi
1 0.300 185.26764 0.0442
2 0.400 147.91417 0.2014
3 0.300 37.38435 0.7544
1.0000
 α12
0.3084

0.5343

0.2994

T(K) 346.36541691
6 7 t(ºC) 73.215416914
74.2564 74.2564 x1 0.0963289328
347.4064 347.4064 x2 0.2863301517
0.0445 0.0443 Comp. Rocío x3 0.6173409155
0.2018 0.2015 τ12 0.2683703331
0.7537 0.7542 τ21 0.3234974064
0.2676 0.2676 τ13 0.9169198631
0.3225 0.3225 τ31 1.7398447243
0.9142 0.9142 τ23 -0.368889335
1.7346 1.7346 τ32 1.2280957729
-0.3678 -0.3678 G12 0.920567077
1.2244 1.2244 G21 0.9050486316
0.9208 0.9208 G13 0.6126813598
0.9053 0.9053 G31 0.3947119439
0.6136 0.6136 G23 1.1167754462
0.3958 0.3958 G32 0.6923304736
1.1164 1.1164 M1 0.5077831479
0.6931 0.6931 M2 0.5486912993
0.5764 0.5766 M3 -0.063842805
0.6506 0.6509 N1 0.5991434776
-0.0579 -0.0579 N2 0.8024113242
0.5255 0.5253 N3 0.9961263399
0.7652 0.7650 Ganma1 1.7920657251
1.0063 1.0063 Ganma2 1.0029490864
3.7029 3.7081 Ganma3 1.3763270245
1.3597 1.3606 EC1 6.336712E-08
1.0782 1.0779 EC2 6.621899E-07
185.2676 185.2676 EC3 2.222988E-07
147.9141 147.9142 EC4 0
37.3843 37.3844 F(t,yi) 9.478558E-07
74.2564 74.2564 T rocío
Sistema: acetona(1)/metanol(2)/agua(3), realizar los cálculos evaporación insantanea P= 101.33KPa
T=1/2(tb+tr) y la composición de entrada z1=0.3, z2=0.4.
T(°C), P(kPa) PARAMETROS DE NRTL
i A B C bij bji
1 14.392 2795.820 230.000 Acetona (1) 184.7 222.64
2 16.594 3644.300 239.760 Metanol(2)
3 16.262 3799.890 226.350 Acetona (1) 631.05 1197.41
Agua (3)
P(kPa) 101.330 R(cal/mol.K) 1.987 Metanol(2) -253.88 845.21
T(°C) 70 Agua (3)
T(K) 343.150
τ12 τ21 τ13 τ31 τ23 τ32
0.27088504 0.3265286727 0.92551167 1.75614758 -0.37234594 1.23960339
G12 G21 G13 G31 G23 G32 Gii
0.91985342 0.904202949 0.60987523 0.39128869 1.1179318 0.68994924 1

i zi Psati (kPa) Ganma i Ki yi xi

1 0.300 159.524896 1 1.57431063 0.42143 0.2676911
2 0.400 125.071457 1 1.2342984 0.47055 0.3812286
3 0.300 31.1774567 1 0.30768239 0.10802 0.3510803 v
1.00000 1 F(v)

n 0 1 2 3 4 5
x1 0.2677 0.1333 0.1007 0.0903 0.0861 0.0842 0.0834
x2 0.3812 0.3231 0.3102 0.3007 0.2960 0.2939 0.2929
x3 0.3511 0.5436 0.5891 0.6090 0.6179 0.6219 0.6237
M1 0.3538 0.4689 0.4964 0.5073 0.5120 0.5141 0.5151
M2 0.3670 0.4982 0.5289 0.5434 0.5499 0.5529 0.5542
M3 -0.0076 -0.0592 -0.0722 -0.0742 -0.0747 -0.0748 -0.0748
N1 0.7498 0.6381 0.6117 0.6005 0.5955 0.5933 0.5923
N2 0.8697 0.8208 0.8093 0.8039 0.8015 0.8004 0.7999
N3 0.9405 0.9861 0.9973 1.0002 1.0013 1.0018 1.0020
Ganma1 1.5762 2.2057 2.4656 2.5850 2.6401 2.6654 2.6771
Ganma2 1.0388 1.1035 1.1421 1.1615 1.1707 1.1749 1.1769
Ganma3 1.5245 1.2565 1.2046 1.1854 1.1773 1.1737 1.1721
K1 2.4815 3.4725 3.8817 4.0695 4.1563 4.1962 4.2145
K2 1.2822 1.3620 1.4096 1.4336 1.4449 1.4502 1.4526
K3 0.4691 0.3866 0.3706 0.3647 0.3622 0.3611 0.3606
f(v) 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
v 0.8441 0.8001 0.8063 0.8098 0.8116 0.8124 0.8127
y1 0.3308 0.3498 0.3504 0.3502 0.3501 0.3500 0.3500
y2 0.4142 0.4225 0.4239 0.4244 0.4246 0.4247 0.4248
y3 0.2550 0.2277 0.2257 0.2254 0.2253 0.2252 0.2252
1.0000
 α12
0.3084

0.5343

0.2994

T(K) 340.15
t(ºC) 67
v 0.6412
x1 0.1278
0.21015603 x2 0.3544
-1.66E-08 y1 0.3964
y2 0.4255
x3 0.5178 1.0000
y3 0.1781 1.0000
τ12 0.2733
τ21 0.3294
τ13 0.9337
τ31 1.7716
τ23 -0.3756
τ32 1.2505
G12 0.9192
G21 0.9034
G13 0.6072
G31 0.3881
G23 1.1190
G32 0.6877
M1 0.4615
M2 0.4774
M3 -0.0765
N1 0.6489
N2 0.8280
N3 0.9920
Ganma1 2.1644
Ganma2 1.0915
Ganma3 1.2745
EC1 0.0000
EC2 0.0000
EC3 0.0000
EC4 0.0000
EC5 0.0000
EC6 0.0000
EC7 0.0000
EC8 0.0000
F(v,yi,xi) 0.0000