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2d. What is the change in the internal energy of the rod when
it is stretched at constant temperature an amount Xo beyond its
natural length ?
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4b. Use the expression from part a to calculate the change in
temperature of a Van der Waals gas undergoing free expansion from
V to 2V. The Van der Waals equation of state is (P.+v%") (v-b) = RT,
where v = V/n is the volume per mole of the gas.
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Qual Review, Meeting 2:
Statistical Mechanics
1. "The Dreamer" For a photon gas, show that:
la. ~ = aT4, where a is some constant, T is the temperature, U is
the internal energy, and V is the volume of the system.
lb. p = k~, where p isthe pressure.
lc. Find the adiabatic equation of state for this photon gas.
2. "The Law" A zipper has N > > 1 links. EaCh link has two
states: state 1, in which it is closed and .has energy 0, and state 2,
in which it is open with energy €. The zipper can only unzip from
the left end and the 8th link can'not open unless all the links to its
left (1,2, ..., 8 - 1) are already open.
2a. Find the partition function for the zipper ..
2b. Find the mean number of open links. Evaluate your result in
both the high and low temperature limits.
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4. "The Boss" Two dipoles, with dipole moments M1 and
M2, are held apart at a separation R, but are allowed to rotate
freely. They are in thermal equilibrium with the environment at
temperature T. Compute the meanforce F between the dipoles for.
the high temperature limit ~t~j « 1. (Hint: the potential energy
between two dipoles is
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