Resolver el ejercicio 1 de la serie propuesta para el Bloque III, empleando el modelo NRTL

con un valor de alfa de 0.3. Entregar en esta aula en tiempo y forma.

k5
k6
Datos de equilibrio V-L Experimentales
P[Kpa] x1 y1 gamma1* gamma2* Ln gamma1* Ln gamma2* GE/RT* GE/x1x2RT
29.819 0 0 #¡DIV/0! 1 0 0
31.957 0.0455 0.1056 2.67003867 1.00421981 0.98209295 0.00421093 0.04870457 1.12145628
33.553 0.094 0.1818 2.33612678 1.01617746 0.84849434 0.016048 0.09429796 1.10725141
35.285 0.1829 0.2783 1.93280771 1.0451498 0.65897372 0.04416022 0.15660961 1.0479233
36.457 0.2909 0.3607 1.62735527 1.1022626 0.48695617 0.09736498 0.21069705 1.02142682
36.996 0.398 0.4274 1.43022789 1.18009385 0.3578338 0.16559397 0.24210542 1.01047355
37.068 0.5069 0.4885 1.28599849 1.28948625 0.25153545 0.25424388 0.25287098 1.01167657
36.978 0.5458 0.5098 1.24339393 1.33837101 0.21784468 0.29145321 0.25127768 1.01361551
36.778 0.5946 0.5375 1.19685269 1.40709372 0.17969535 0.34152639 0.24530165 1.01763451
35.792 0.7206 0.6157 1.10093046 1.65096123 0.0961557 0.50135768 0.20936913 1.03990099
34.372 0.8145 0.6913 1.05021761 1.91824663 0.04899739 0.65141155 0.16074522 1.06390553
32.331 0.8972 0.7869 1.02081829 2.24758641 0.02060455 0.80985693 0.1017397 1.10308269
30.038 0.9573 0.8916 1.00714509 2.55728626 0.00711969 0.93894664 0.0469087 1.14756537
27.778 1 1 1 0 0

Ln gamma1
1.2

1.1

0.9 Ln gamma1* Ln gamma1

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 Ln gamma2
1.2
1.1
1
Ln gamma2* Ln gamma2
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

GE/RT
0.3

0.25

0.2

0.15

GE/RT* GE/RT
0.1

0.05

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 Título del gráfico
1.2

y = 0.0165x + 1.0505
Ln yi*-GE/RT-GE/x1x2RT

0.8

0.6

0.4

0.2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1
Ln gamma1* Ln gamma2* GE/RT* GE/x1x2RT* Lineal (GE/x1x2RT*)

Ln gamma1inf 1.0505 x1 0 Obtener parámetros Tau t12

Ln gamma2inf 1.067 x1 1 alfa 0.3 t21
G12
G21
a)
A.
P[Kpa] x1 y1 Ln gamma1 Ln gamma2 gamma1 gamma2 GE/RT GE/x1x2RT
29.819 0 0 1.05050033 0 2.85908124 1 0
31.8126833 0.0455 0.10335008 0.95603044 0.00219715 2.60134974 1.00219956 0.04559656 1.04989231
33.4443817 0.094 0.18462742 0.86068456 0.00934389 2.36477897 1.00938768 0.08936991 1.04938603
35.4669462 0.1829 0.2884214 0.69983988 0.03517979 2.01343028 1.03580592 0.15674612 1.04883673
36.8015752 0.2909 0.37223791 0.52784993 0.08855958 1.6952834 1.09259935 0.21634914 1.04882726
37.3731366 0.398 0.43334094 0.38178063 0.16530677 1.4648907 1.17975498 0.25146337 1.04953075
37.4394474 0.5069 0.48659488 0.25759872 0.26793236 1.29381953 1.30725871 0.26269424 1.0509771
37.3542107 0.5458 0.50530514 0.21911118 0.31070336 1.24496969 1.36438443 0.26071235 1.05167353
37.1625517 0.5946 0.52954008 0.17517719 0.36899233 1.19145732 1.44627651 0.25374985 1.05268188
36.1271734 0.7206 0.60270005 0.08413641 0.54394663 1.08777727 1.72279269 0.21260738 1.05598484
34.6072159 0.8145 0.67872757 0.03746326 0.69815102 1.03817386 2.01003276 0.16002084 1.05911117
32.3978667 0.8972 0.77825473 0.01162332 0.85169075 1.01169113 2.34360595 0.09798225 1.06234366
30.0185744 0.9573 0.88764037 0.00202184 0.97417636 1.00202389 2.64898451 0.04353284 1.06497911
27.778 1 1 0 1.06700019 1 2.90664701 0

1.2
NRTL
1.1
1
0.9
y = 0.0162x + 1.0455
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Ln gamma1 Ln gamma2 GE/RT GE/x1x2RT Lineal (GE/x1x2RT)
C)
DIAGRAMA P-XY

P X₁ X₂ Y₁ Y₂
29.819 0 1 0 0.93155371
31.774895 0.0455 0.9545 0.10976902 0.83629699
33.3670996 0.094 0.906 0.19604945 0.7614235
35.3237214 0.1829 0.8171 0.30616373 0.66586718
36.5957984 0.2909 0.7091 0.39521342 0.58859054
37.1247702 0.398 0.602 0.46066661 0.53179077
37.1593565 0.5069 0.4931 0.51866454 0.48146061
37.0632379 0.5458 0.4542 0.53932295 0.4635334
36.8570262 0.5946 0.4054 0.5662829 0.44013776
35.8997882 0.7106 0.2894 0.64089482 0.37539011
34.2419659 0.8145 0.1855 0.73348909 0.29503751
32.0804101 0.8972 0.1028 0.8425315 0.20041135
29.8322135 0.9573 0.0427 0.9585583 0.09972419
27.778 1 0 1 0

39
38 Diagrama P-x,y
37
36
35
34
33
P [Kpa]

32
31
30
29
28
27 x1 exp. y1 exp.
26 x1 teórico y1 teórico
25
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x,y
 d)

P [Kpa] x1 Ln gamma1* Ln gamma2* ln(y1*/y2*) Ln gamma1 Ln gamma2 Ln(y1/y2) delta ln(y1/y2)

29.819 0 0 0 0 1.05050033 0 1.050500328 1.050500328
31.8126833 0.0455 0.98209295 0.00421093 0.97788202 0.95603044 0.00219715 0.953833297 -0.024048723
33.4443817 0.094 0.84849434 0.016048 0.83244633 0.86068456 0.00934389 0.851340672 0.018894338
35.4669462 0.1829 0.65897372 0.04416022 0.61481349 0.69983988 0.03517979 0.664660083 0.04984659
36.8015752 0.2909 0.48695617 0.09736498 0.38959119 0.52784993 0.08855958 0.439290347 0.049699159
37.3731366 0.398 0.3578338 0.16559397 0.19223982 0.38178063 0.16530677 0.216473861 0.024234037
37.4394474 0.5069 0.25153545 0.25424388 -0.00270843 0.25759872 0.26793236 -0.010333635 -0.007625203
37.3542107 0.5458 0.21784468 0.29145321 -0.07360852 0.21911118 0.31070336 -0.091592181 -0.017983657
37.1625517 0.5946 0.17969535 0.34152639 -0.16183104 0.17517719 0.36899233 -0.19381514 -0.0319841
36.1271734 0.7206 0.0961557 0.50135768 -0.40520198 0.08413641 0.54394663 -0.459810223 -0.054608239
34.6072159 0.8145 0.04899739 0.65141155 -0.60241416 0.03746326 0.69815102 -0.660687758 -0.058273597
32.3978667 0.8972 0.02060455 0.80985693 -0.78925238 0.01162332 0.85169075 -0.840067429 -0.050815049
30.0185744 0.9573 0.00711969 0.93894664 -0.93182696 0.00202184 0.97417636 -0.972154519 -0.040327563
27.778 1 0 0 0 0 1.06700019 -1.067000187 -1.067000187
Promedio abs 0.011392276
Grado elevado de consistencia termodinámica.