GASEOUS STATE AND LIQUID STATE

1. In the equation of state of an ideal gas PV = nRT , the value of universal gas constant
would depend only on
a) the nature of the gas b) the units of measurement c) the pressure of the gas d) the
temperature of the gas
2. 273mL of a gas at STP was taken to 27°C and 600mm pressure. The final volume of
gas would be
a) 273mL b) 300mL c) 380mL d) 586mL
3. 3.2 g of oxygen (at. mass = 16) and 0.2g of hydrogen (at. mass = 1) are placed in a
1.12 litre flask at 0°C. The total pressure of the gaseous
mixture will be
a) 1 atm b) 2 atm c) 3 atm d) 4 atm
4. If 4g of oxygen diffuse through a very narrow hole, how much hydrogen would have
diffused under identical conditions?
a) 16g b) 1g c) g
4
1
d) 64g
5. Density of neon will be highest at
a) STP b) 0°C, 2 atm c) 273°C, 1 atm d) 273°C, 2atm
6. A helium atom is two times heavier than a hydrogen molecule. At 298K, the average
kinetic energy of a helium atom is
a) two times that of a hydrogen molecule b) four times that of a hydrogen molecule
c) half that of a hydrogen molecule d) same as that of a hydrogen molecule
7. The value of van der Waals’ constant ‘a’ for gases O2
, N2 NH3
and CH4
are 1.360, 1.390, 4.170 and 2.253 litre
2
atm mol
-2
respectively.
The gas which can be most easily liquified is
a) O2
b) N2
c) NH3
d) CH4
8. At STP, the order of root mean square velocity of molecules of
2 O,N,H 2 2
and HBr is
a) H N O HBr
2 > 2 > 2 > b) HBr > O2 > N2 > H2
c) HBr > H2 > O2 > N2
d) N O H HBr
2>2>2>
9. A bottle of ammonia and a bottle of dry hydrogen chloride connected through a long
tube are opened simultaneously at both ends, the white
ammonium chloride ring first formed will be
a) at the centre of the tube b) near the hydrogen chloride bottle
c) near the ammonia bottle d) throughout the length of the tube
10. A flask containing air (open to atmosphere) is heated from 300 toK 500K. The
percentage of air escaped to the atmosphere is nearly
a) 6.16 b) 40 c) 60 d) 20
11. If 500ml of a gas A at 1000torr, and 1000ml of gas B at 800 torr are placed in a L2
container, the final pressure will be
a) 100torr b) 650torr c) 1800torr d) 2400torr
12. The temperature at which RMS velocity of SO2
molecules is half that of He molecules at 300K is
a) 150K b) 600K c) 900K d) 1200K
13. The rate of diffusion of two gases X and Y is in the ratio of 5:1 and that of Y and Z
in the ratio of 6:1 . The ratio of the rate of diffusion
of Z with respect to X is :
a) 65 b) 301 c) 56 d) 30
AIEEE
and other Entrance Exams
CHEMISTRY Practice Assignments
Chapter – 5
14. How much should the pressure be increased in order to decrease the volume of a gas
by %5 at a constant temperature ?
a) %5 b) 26.5 % c) 10% d) 26.4 %
15. Equal weights of methane and hydrogen are mixed in an empty container at 25°C .
The fraction of the total pressure exerted by hydrogen is
a) 1/2 b) 8/9 c) 1/9 d) 1/16
16. At 27°C a gas was compressed to half of its volume. To what temperature must it be
now heated so that it occupies just its original volume.
Pressure remains constant ?
a) 54°C b) 327°C c) 600°C d) 200°C
17. A gas diffuses 1/5 times as fast as hydrogen. Its molecular weight is
a) 50 b) 25 c) 25 2 d) 50 2
18. 10.0 gm of oxygen, assumed ideal, is introduced into an evacuated vessel of 5 litre
capacity at 47°C. What is the pressure of the gas in the
container ? (R = 0.0821 litre atm.
11
K mol
−−
(
a) 5.25 atm b) 3.28 atm c) 1.64 atm d) 0.24 atm
19. For a gas, maximum deviation from ideal gas behaviour is observed at
(a) 0 C
o
and atm0.1 (b) 100 C
o
and atm0.2 (c) 100 C
o
− and atm0.2 (d) 100 C
o
− and atm0.5
20. V versur T curves at constant pressure P1 & P2
for an ideal gas are shown in figure.
Which of the following statements is correct
a) P1 > P2
b) P1 < P2
c) P1 = P2
d) cannot be correlated
1
P
2
P
v↑
T→
21. Two separate bulbs contain ideal gases A and B . The density of A is twice as that of
gas .B The molecular mass of gas A is half as
that of .B If two gases are at same temperature, the ratio of the pressure of A that of B is
(a) 2 (b) 21 (c) 4 (d) 41
22. At what temperature will both Celsius and Fahrenheit scales read the same value?
(a)
o
100 (b)
o
180 (c)
o
40 (d)
o
− 40
23. The density of phosphorus vapour at .P.T.S is
1
54.5 gL
−
: Hence, molecular formula of phosphorus is .
(a) P2
(b) P3
(c) P4
(d) P8
24. Hg1
2
and Ogx
2
gas exert a total pressure of atm5 at a given temperature partial pressure of O2
gas is O,
2
atm4 in the mixture is :
(a) 1mol (b) 2mol (c) 3mol (d) 4mol
25. In the following reaction, we start with 2mole of N2
and 5mole of H2
exerting a total pressure of atm7 at a given temperature in
a closed vessel. When 50% of N2
is converted into NH3
, N2 + H3
2 → NH2
3
partial pressure of NH3
is :
(a) atm8.2 (b) atm2 (c) atm2.3 (d) atm4
26. At higher altitude the boiling point of water lowers because
(a) atmospheric pressure is low (b) temperature is low
(c) atmospheric pressure is high (d) none of these
27. Which of the following liquid will exhibit highest vapour pressure?
(a) C H OH )(
52
l (b) NH )(
3
l (c) HF l)( (d) H2
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Exams.
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13
ANSWERS
1. b 2. c 3. d 4. b 5. b 6. d 7. c 8.a 9. b 10. b
11. b 12. d 13. d 14. b 15. b 16. b 17. a 18. c 19. d 20. a
21. c 22. d 23. c 24. b 25. b 26. a 27. b 28. b 29. a