12.

18

a)
A B C °C
Metanol 16.5785 3638.27 239.500 64.7
Agua 16.3872 3885.70 230.170 100

𝒍𝒏𝜸_𝟏=−𝒍𝒏(𝒙_𝟏+𝒙_𝟐 𝜦_𝟏𝟐 )+𝒙_𝟐 (𝜦_𝟏𝟐/(𝒙_𝟏+𝒙_𝟐 𝜦_𝟏𝟐

Mezcla
V1 40.73
V2 18.07
𝒍𝒏𝜸_𝟐=−𝒍𝒏(𝒙_𝟐+𝒙_𝟏 𝜦_𝟐𝟏 )−𝒙_𝟏 (𝜦_𝟏𝟐/(𝒙_𝟏+𝒙_𝟐 𝜦_𝟏𝟐
a12 107.38
a21 469.55

P 101.33 𝒚_𝒊 𝑷=𝒙_𝒊 𝑷_𝒊^𝒔𝒂𝒕 𝜸_𝒊

X1 0.3 Y1 0.66243489
X2 0.7 Y2 0.33756524329174
T(K) 351.80 suma 1.000

L12 0.3804778577 L21 1.15140606354928

gamma1 1.3072
gamma2 1.0881

Pst1 171.167
Pst2 44.908

b)

A B C °C
Metanol 16.5785 3638.27 239.500 64.7
Agua 16.3872 3885.70 230.170 100

y1 0.3
y2 0.7

i y1 y2 T ponderada gamma 1
1 0.1 0.9 362.559 1
2 0.2 0.8 366.928 1.6572
 3 0.3 0.7 364.603 1.8680
4 0.4 0.6 364.996 1.8794
5 0.5 0.5 364.948 1.8844
6 0.6 0.4 364.954 1.8847
7 0.7 0.3 364.953 1.8848
8 0.8 0.2 364.953 1.8848
9 0.9 0.1 364.953 1.8848
10 1 0 364.953 1.8848

c) Mezcla T rocio 364.95

V1 40.73 T burbuja 351.8
V2 18.07 T = (T rocio + T burbuja)/2 358.375
a12 107.38
a21 469.55

P 101.33
X1 0.1

X2 0.9
z1 0.3
z2 0.7
L12 0.381552385 L21 1.16569313116504 suma

gamma1 1.7432
gamma2 1.0123

Pst1 215.809 K1 3.71265016933389

Pst2 58.390 K2 0.583304029508391

d) Existen el azeótropo si: ɑ12 =(x1=0)>1 y ɑ12 =(x2=0)>1

Mezcla
V1 40.73
V2 18.07
a12 107.38
a21 469.55

L12 0.381087361 L21 1.15949342232903

〖𝒚𝟏〗 ^∞ 2.2372181885
 〖𝒚𝟏〗 ^∞
〖𝒚𝟐〗 ^∞ 1.6014819738

├ 𝜶_𝟏𝟐 ┤|𝐱𝟏=𝟎 8.3790652878

├ 𝜶_𝟏𝟐 ┤|𝐱𝟐=𝟎 2.3386497181

Estimación inicial para el azeótropo

x1 0.5 x1=y1= 0.5
x2 0.5 y2= 0.5

T promedio x1 x2 y1 gama1
355.5 0.5 0.5 0.5 0.51898704
337.850 0.5 0.5 0.5 1.1154751
358.642 0.2326304784 0.76736952 0.232630478428561 1.1258363
358.910 0.1072377971 0.8927622 0.107237797116594 1.4037383
365.454 0.0396477214 0.96035228 0.039647721408461 1.7164810
371.655 0.0119876968 0.9880123 0.011987696820957 1.9648277
375.952 0.0031664146 0.99683359 0.003166414619502 2.0790964
377.782 0.000790405 0.9992096 0.000790404961387 2.1076651
378.227 0.0001946277 0.99980537 0.000194627656629 2.1122133
378.297 4.782151E-05 0.99995218 4.78215098152731E-05 2.1134360
378.316 1.1743315E-05 0.99998826 1.17433145457415E-05 2.1139346
378.324 2.8830731E-06 0.99999712 2.88307313129475E-06 2.1140491
378.326 7.0777805E-07 0.99999929 7.07778047521583E-07 2.1140619
378.326 1.7375443E-07 0.99999983 1.73754431537318E-07 2.1140657
378.326 4.265539E-08 0.99999996 4.26553903950857E-08 2.1140678
378.326 1.0471563E-08 0.99999999 1.04715632293564E-08 2.1140683
378.326 2.5706859E-09 1 2.57068593357797E-09 2.1140683
 K DETERMINAMOS GRAFICAMENTE EL PUNTO DE BURBUJA:
337.85 T X1 Y1
373.15 373.15 0 0
361.42 0.1 0.4095
355.56
+𝒙_𝟐 (𝜦_𝟏𝟐/(𝒙_𝟏+𝒙_𝟐 𝜦_𝟏𝟐 )−𝜦_𝟐𝟏/(𝒙_𝟐+𝒙_𝟏 𝜦_𝟐𝟏 )) 0.2 0.5695
351.80 0.3 0.6624
348.97 0.4 0.7292
346.63 0.5 0.7837
−𝒙_𝟏 (𝜦_𝟏𝟐/(𝒙_𝟏+𝒙_𝟐 𝜦_𝟏𝟐 )−𝜦_𝟏𝟐/(𝒙_𝟐+𝒙_𝟏 𝜦_𝟐𝟏 )) 0.6
344.59 0.8316
342.74 0.7 0.8759
341.02 0.8 0.9181
ECUACIÓN 10.5: 339.39 0.9 0.9593
𝒚_𝒊 𝑷=𝒙_𝒊 𝑷_𝒊^𝒔𝒂𝒕 𝜸_𝒊 337.85 1 1

K
337.85
373.15

gamma 2 Psat 1 Psat 2 ɑ x1 x2 L12 L21

1 248.858 68.608 0.12215386 0.87784614 0.38221701 1.17459829
1.0175 287.684 80.831 0.0637649 0.9362351 0.38289583 1.18374764
 1.0052 266.447 74.118 0.06107771 0.93892229 0.38253642 1.17889652
1.0048 269.945 75.219 0.05991863 0.94008137 0.38259748 1.17971966
1.0046 269.516 75.084 0.05985466 0.94014534 0.38259004 1.17961934
1.0046 269.569 75.100 0.05983408 0.94016592 0.38259096 1.17963178
1.0046 269.563 75.098 0.05983269 0.94016731 0.38259085 1.17963025
1.0046 269.564 75.099 0.05983233 0.94016767 0.38259086 1.17963044
1.0046 269.564 75.099 0.0598323 0.9401677 0.38259086 1.17963041
1.0046 269.564 75.099 0.05983229 0.94016771 0.38259086 1.17963042

yi Para xi Para
v =0.30 v = 0.40 v =0.45 v = 0.462 v = 0.462
∑8_𝑖▒𝑧𝑖𝐾𝑖/(1+𝑣(𝑘𝑖−1)) 𝑦𝑖/𝐾𝑖

0.614069 0.534179 0.501553 0.494307 0.133141

0.466648 0.489982 0.502547 0.505659 0.866888
1.080717 1.024161 1.004100 1.0000 suma 1.0000

T promedio 355.5
Pst1 195.246
Pst2 52.131
 gama2 L12 L21 Y1 Y2 〖𝑦 1 〗 ^∞〖𝑦 2 〗 ^∞ alfa 1
1.94376493 0.38108736 1.15949342 1.1154751 1.2023393 2.23721819 1.60148197 8.37906529
1.2023393 0.37807295 1.11991945 1.1258363 1.2161669 2.34608662 1.66307831 8.7868108
1.2161669 0.38159518 1.16626501 1.4037383 1.0558184 2.21916268 1.59137508 8.31144189
1.0558184 0.38163822 1.1668403 1.7164810 1.0139297 2.21763627 1.59052203 8.30572501
1.0139297 0.38266859 1.18067877 1.9648277 1.0020782 2.18126983 1.5702611 8.16952159
1.0020782 0.38361377 1.19348407 2.0790964 1.0001961 2.14821006 1.55194566 8.04570267
1.0001961 0.38425188 1.20218953 2.1076651 1.0000138 2.1260536 1.53972469 7.96271995
1.0000138 0.38451956 1.20585605 2.1122133 1.0000009 2.11679799 1.53463215 7.92805488
1.0000009 0.38458426 1.20674343 2.1134360 1.0000001 2.11456466 1.53340445 7.91969035
1.0000001 0.38459448 1.20688367 2.1139346 1.0000000 2.11421194 1.5332106 7.91836934
1.0000000 0.38459722 1.20692132 2.1140491 1.0000000 2.11411726 1.53315856 7.91801471
1.0000000 0.38459834 1.20693667 2.1140619 1.0000000 2.11407866 1.53313735 7.91787015
1.0000000 0.38459859 1.2069402 2.1140657 1.0000000 2.11406979 1.53313247 7.91783694
1.0000000 0.38459862 1.20694059 2.1140678 1.0000000 2.1140688 1.53313193 7.91783324
1.0000000 0.38459863 1.20694071 2.1140683 1.0000000 2.11406851 1.53313177 7.91783215
1.0000000 0.38459864 1.20694077 2.1140683 1.0000000 2.11406835 1.53313168 7.91783154
1.0000000 0.38459864 1.20694079 2.1140683 1.0000000 2.11406831 1.53313166 7.9178314
gamma 1 recalc. gamma 2 recalc. P1 sat recalc. T1 recalc.
1.6572 1.0175 287.6838 366.928
1.8680 1.0052 266.4473 364.603
1.8794 1.0048 269.9448 364.996
1.8844 1.0046 269.5163 364.948
1.8847 1.0046 269.5694 364.954
1.8848 1.0046 269.5628 364.953
1.8848 1.0046 269.5636 364.953
1.8848 1.0046 269.5635 364.953
1.8848 1.0046 269.5636 364.953
1.8848 1.0046 269.5636 364.953
 alfa2 P calc x1 calc T1 az
2.3386497180754 101.33 0.5 337.850
2.2520318753113 217.791754297401 0.232630478429 358.642
2.3535025807861 219.814720303673 0.107237797117 358.910
2.3547648513879 274.07390880994 0.039647721408 365.454
2.3851481562235 335.135570270329 0.011987696821 371.655
2.4132967208507 383.6242137672 0.00316641462 375.952
2.4324513333323 405.934690530423 0.000790404961 377.782
2.4405232030661 411.512608867176 0.000194627657 378.227
2.4424771745398 412.400623118083 4.78215098E-05 378.297
2.4427859908222 412.639342215256 1.17433145E-05 378.316
2.4428689031626 412.736690583217 2.88307313E-06 378.324
2.442902701656 412.759058319322 7.07778048E-07 378.326
2.4429104664962 412.761556184876 1.73754432E-07 378.326
2.4429113335928 412.762288296977 4.26553904E-08 378.326
2.4429115877336 412.762699710087 1.04715632E-08 378.326
2.4429117305488 412.762791506713 2.57068593E-09 378.326
2.4429117624145 412.762796110521 6.31083053E-10 378.326