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DEFINITION OF REDOX :
TRANSFER OF ELECTRON
REDOX EQUATIONS :
HALF EQUATION OF OXIDATION
HALF EQUATION OF REDUCTION
OVERALL (NET) IONIC EQUATION
APPLICATION OF REDOX IN :
1. THE DISPLACEMENT OF METAL
2. ELECTROCHEMISTRY(
p CHEMICAL CELL ,
ELECTROLYSIS & CORROSION OF METAL)
3. DISPLACEMENT OF HALOGENS
4. CHANGES OF Fe →Fe & Fe →Fe
2+ 3+ 3+ 2+
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Redox
OXIDATION REDUCTION
a) Loss of oxygen/hydrogen Gain in oxygen / Loss of Loss of oxygen / Gain in
and gain in oxygen hydrogen hydrogen
/hydrogen
2. a) Oxidising agent - a substance that causes other substances to undergo oxidation and the agent
itself being reduced.
b) Reducing agent - a substance that causes other substances to undergo reduction and the agent itself
being oxidised.
Example 1
Mg + CuO MgO + Cu
Explanation:
Magnesium – undergoes oxidation because _______________________________________________
__________________________________________________________________________
_________________________________________________________________________
Example 2
H2S (g) + Cl2 (g) S (s) + 2HCl (g)
Explanation
Chlorine gas - undergoes _________________ because ________________________________________.
_________________________________________________________________________.
_________________________________________________________________________.
Example (iii)
2
3CuO + 2NH3 N2 + 3H2O + 3Cu
Explanation :
Copper(II) Oxide - undergoes _______________ because ______________________________________.
__________________________________________________________________________.
_________________________________________________________________________.
Example 1
2Na + Cl2 2NaCl
Explanation
Sodium atom with an electron arrangement of 2.8.1 will form a stable octet by losing 1 electron.
Na Na+ + e
2.8.1 2.8
__________________________________________________________________________.
Chlorine with electron arrangement of 2.8.7 will form a stable octet by gaining 1 electron
Cl + e- Cl-
2.8.7 2.8.8
__________________________________________________________________________.
Example (II)
Mg + CuSO4 MgSO4 + Cu
__________________________________________________________________________________.
_______________________ because______________________________________________
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In terms of change in oxidation state
Example
Molecule of Oxidation
Element State
H2 0
O2 0
Cl2 0
Atom Oxidation
State
Cu 0
Na 0
Fe 0
He 0
Example
Ion oxidation Ion Oxidation
state state
Na+ +1 Cl- -1
Cu2+ +2 Br- -1
Fe2+ +2 O2- -2
Fe2+ +3 S2- -2
(v) The oxidation state of the ions from Group 1, 2 and 13 are fixed because the atom of these Groups can form a
stable octet by losing 1 e-, 2e- and 3e- respectively. Therefore, the oxidation state for these ions are +1, +2
and +3.
(vi) The sum of the oxidation state for elements in a neutral compound is 0
(vii) The sum of the oxidation state for elements in a polyatomic ion equals to the charges of the ion.
# The oxidation state of the transition metals and non-metallic elements vary from one compound to another.
KMnO4 =
MnO2 =
CO32- =
CO2 =
4
CO =
NO3- =
NO2 =
NH4+ =
Example:
Formula Charge IUPAC Name Common Name
Fe(OH)2 +2 Iron (II) hydroxide Ferrous hydroxide
Fe(OH)3 +3 Iron (III) hydroxide Ferric hydroxide
PbO +2 Lead (II) oxide Lead monoxide
PbO2 +4 Lead(IV) oxide Lead dioxide
H2SO4 +6 Sulphuric (VI) acid Sulphuric acid
H2SO3 +4 Sulphuric (IV) acid Sulphurrous acid
I. When the oxidation state of a substance increased, the substance is oxidised. It also acts as a
reducing agent.
II. When the oxidation state of a substance decreased , the substance is reduced. It acts as an
oxidising agent.
III. A reaction is not redox if no elements undergo a change in oxidation state.
Oxidation state:
Explanation:
• Magnesium is oxidised because ____________________________________________________.
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10.3 Writing A Redox Equation
♦ A redox equation involved the following:
i. Half equation for oxidation (loss of ē)
ii. Half equation for reduction (gain in ē)
iii. Overall (net) ionic equation can be formed by combining step (i) and (ii):
a) Change the coefficient of both the half equations until the number of electrons are equal.
b) By combining the two half equations, the electrons are cancelled.
Cth :
Reaction Aluminium and Copper (II) Magnesium and silver nitrate
sulphate
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(I) Redox Reaction in the displacement of metals from its salt solution.
a) Electrochemistry Series: A series in the order of the tendency for a metal to form positive ions
(cations).
• The more electropositive a metal, the easier its atom loses electron to form positive ion.
K •K Displacement of metals:- The more electropositive metal will lose its ………………. to metal ion which is
Na less electropositive. The more electropositive metal will be …………….. and corrodes while the less
Ca
electropositive metal ion will be ………………… and ……………………..
Mg
Al • Chemical cell :- The more electropositive metal becomes the negative terminal and …………… electron. The
Zn metal undergoes …………………. and corrodes.
Fe -Metal which is less electropositive becomes the …………….. terminal. The ion that is selected for discharge in
Sn
Pb the solution undergoes …………….. and the mass of the positive terminal will increase.
H -The further the distance between two metals in the electrochemical series, the bigger the …………. of the
Cu chemical cell.
Ag
• Electrolysis: The less electropositive metallic ion in the solution will gain electrons and will be discharged and
undergoes …………………….
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agent
Answer these questions:
1).
Carbon electrode
Elektrod X X
karbon Carbon electrode Y
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
.................................................................................................................................
2) X is 0.001 mol dm-3 aqueous sodium chloride. Y is 2.0 mol dm-3 aqueous sodium chloride. Both solutions are
a). Name the products formed at the cathode and anode in the :
c) The products collected at the anode in the electrolysis of solutions X and Y are different. Explain why.
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……………………………………………………………………………………………………………………
d) Write the half equation of the reaction that takes place in the anode :
………………….
3)
.................................................................................................................................
i) negative terminal:............................................................................................
c) Write the ionic equation for the reaction that takes place at the
i) negative terminal:.........................................................................................
d) Write the overall (net) ionic equation for the reaction that takes place in the chemical cell above.
.................................................................................................................................
.................................................................................................................................
f) Name the substance that acts as a reducing agent in the above reaction.
.................................................................................................................................
g) How will the voltmeter reading change if the magnesium electrode in the magnesium sulphate
solution is replaced by zinc electrode in the zinc sulphate solution ?
.................................................................................................................................
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4). The diagram below shows the apparatus set-up for a chemical cell. Answer the following questions accordingly.
(a) Solution X is used as a salt bridge. State a suitable solution for X ……………………
(b) The function of solution X is …………………………………….
(c) Mark on the diagram the positive terminal, the negative terminal and the direction of the electron flow.
a) Write the half equation for the reaction that occurs in:
i. Cell A:………………………………………………………….
ii. Cell B :……………………………………………………
b) State the type of reaction that occurs in
i. Cell A :…………………………………………………..
ii. Cell B :………………………………………………….
c) (i) What is observed in cell B when the reaction occurs ?
……………………………………………………………………………………………………….
………………………………………………………………………………………………………………
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iv) The rate of atmospheric corrosion is accelerated with the presence of electrolyte→metals in the vicinity of
beaches are corroded easily because sea water is an electrolyte.
Rusting of iron
- Corrosion of iron (Fe → Fe2+ + 2e ) is a process that takes place when iron corrodes spontaneously in the
presence of water and oxygen.
- Rusting of iron:
O2
O2
Water
A B A
Iron
Rusting of iron occurs faster in areas exposed to air because the dissolved impurities become electrolytes
which will speed up the flow of electrons.
Example :
- Industrial areas that contain H2S (hydrogen sulphide) and SO2 (sulphur dioxide) gases
- Beach areas that have sodium chloride.
b) Electrochemical corrosion
The process of metal losing electrons to form ions when in contact with different metals in the
presence of a certain electrolyte :
Methods to prevent rusting :
- form an alloy :
- oiling / greasing
- galvanisation
- sacrificial protection
- electroplating
Experiment:
Topic : The effect of other metals on the rusting of iron
Hypothesis:
Manipulated variable :
Respondent variable :
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Fixed variable :
Apparatus :
Chemicals :
Diagram:
Procedure :
Recording of Results:
Inference :
Conclusion :
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Exercise : Answer the following questions.
copper
zinc Magnesium Iron +
+ iron + nail iron nail
nail iron nail
P Q R S
Three iron nails are coiled with stannum , metal Y, and metal Z respectively and placed in three different test tubes.
Each test tube is filled with aqueous sodium chloride. After a few days the following results are obtained.
a). Based on the observations, arrange the metals i.e. stannum, Y and Z in a descending order of their
electropositivity.
………………………….., …………………………., ………………………………..
b). Suggest one possible metal for
Y: ……………………………………. Z: ……………………………………………
c). What is the name of the chemical process that occurs in each test tube?………………………
d). Explain why the iron in test tube B does not rust at all.
…………………………………………………………………………………………..
e). Write the ionic equation for the chemical changes that takes place in test tubes A and C.
…………………… ……………………………………………………………………...
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2. Metal will corrode when it is exposed to the atmosphere over a period of time. The rate of corrosion depends on
the position of the metal in the electrochemical series.
a). Between magnesium and iron, which will corrode faster when exposed to atmosphere? Explain your answer.
…………………………………………………………………………………………...
…………………………………………………………………………………………...
b). Why are goods made of iron and plated with zinc provides better protection as compared to iron plated with tin?
…………………………………………………………………………………………...
…………………………………………………………………………………………...
c). Why are goods made of aluminium self-protected from corrosion?
………………………………………………………………………………………….
…………………………………………………………………………………………..
d).Besides being plated with tin and zinc, suggest two other ways to prevent iron from corrosion.
…………………………………………………………………………………………..
………………………………………………………………………………………….
2) The diagram below shows the experiment conducted to study the effect of metals on the corrosion of iron nails.
nails
Y Z
Stannum
A B C
b) State your observation for each test tube P, Q, R and S when they are left for a few moment.
i) Test tube P
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iv) Test tube S
c) Arrange the four metals i.e. iron, zinc, magnesium and copper according to their position in the
electrochemical series. The most electropositive metal is to be mentioned first.
d)
i) Name the type of reaction that takes place when iron rusts.
f) Name another type of metal that can accelerate the rusting of iron process.
2). In an experiment, iodine is formed when bromine water is added to potassium iodide solution.
c) How do you confirm the formation of iodine in the experiment?
………………………………………………………………………………………..
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d) Write the half equation for the chemical change that takes place in
i) bromine water :………………………………………………………………
ii) potassium iodide:…………………………………………………………..
iii) reducing agent :…………………………………………………………
iv) the substance that has been reduced…………………………………………
e) Write the overall (net) ionic equation for that reaction.
………………………………………………………………………………………..
ii. Write the redox equation for the reaction between chlorine water and iron (II) sulphate solution.
Example : Reaction between zinc powder and iron (III) sulphate solution.
Zn Zn2+ + 2e ( )
Fe3+ + e- Fe2+ ( )
___________________________________________
V
Apparatus set-up
Reducing agent
Oxidising agent
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COMPLETE THE TABLE BELOW TO SHOW THE ELECTRON TRANSFER REACTIONS
Reactants Oxidising Reducing Write the half equation for Write the half equation for Write the overall (net) redox Draw the diagram and mark
agents agents oxidation, (releases electron / reduction, (gains electron/ equation The direction of electron flow
negative terminal) observations positive terminal) Positive/ negative terminal
and confirmatory test observations and
confirmatory test
Iron(II) sulphate
and bromine
water
Potassium
iodide and
acidic potassium
permanganate(V
II)
Iron(II) sulphate
and acidic
potassium
dichromate(VI)
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(VI) Redox in Reactivity Series
a) Reactivity series : A series that arranges metals in accordance to the reactivity of their reactions with
oxygen to form metal oxides
K
Na • More reactive in their reaction with oxygen to form metal oxide.
• The more reactive metal is able to reduce metal oxide that ………….. reactive. The more reactive
Ca
metal will undergo………………. because it gains ……………… while the less reactive metal
Mg .
oxide undergo……………… because it…………………oxygen .
Al
• Metals that are located below carbon in the reactivity series can be extracted from their ores using
C carbon as carbon is cheap and is released as carbon dioxide gas after the reaction: Metal oxide(s) +
Zn Carbon(s) → Metal(s) + Carbon dioxide(g) ↑
• Metals that are more reactive than carbon in the reactivity series can be extracted from their ores by
H using the electrolysis process, e.g. extraction of aluminium metal from aluminium oxide.
Fe
• The empirical formula for metals that are more reactive than hydrogen in the reactivity series
Sn .
such as magnesium can be determined by heating the metal strongly in a crucible.
Pb
• The empirical formula for metals that are less reactive than hydrogen eg. copper can be
Cu determined by passing through hydrogen gas to the strongly heated metal oxides in a combustion tube.
b) 3 important experiments:
i) To construct the reactivity series.
ii) To determine the position of carbon in the reactivity series
iii) To determine the position of hydrogen in the reactivity
series.
# Prepare a report for each of the above stated experiments. Your report must contain:
- The hypothesis
- Constant variable, manipulated variable and responding variable
- Apparatus and substances.
- A labeled diagram of the apparatus set- up
- Procedure
- Observations
- Precautionary measures
- Equations of reaction
c) Uses of the reactivity series.
To predict whether a metal can reduce the oxide of another metal. If metal X is more reactive than
metal Y, then metal X can displace oxygen from the metal Y oxide.
Extraction of metals - (i) Iron - in industries
(ii) Tin - in industries
Determine whether the following reactions occur. If the reaction occurs, mark ‘/’ and if not, mark ‘x’.
a) Zinc oxide + Hydrogen ( ) b) Iron (II) oxide + Hydrogen ( )
b) Hydrogen oxide + Copper ( ) d) Carbon + Silver oxide ( )
c) Magnesium oxide + Carbon ( ) e) Copper + Zinc oxide ( )
d) Aluminium + Carbon dioxide ( ) f) Iron + Lead (II) oxide ( )
e) Argentum + Hydrogen oxide ( )
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