SISTEMA ACETONA-CLOROFORMO A 25°C Y 77.

32187kPa
ECUACIÓN DE ANTOINE lnP=A-B/(t+C)
CONSTANTES DE ANTOINE
COMPONENTE A B C T eb(°C) P
ETANOL 16.8958 3795.17 230.918 71.53844688 77.321872367 EL ETANOL ES EL MAS VOLATIL
n-BUTANOL 15.3144 3212.43 182.739 110.1942342 77.321818196

T(°C) P°A P°B X(A) Y(B) P(bar)= 77.32187

110.194234169 320.51564606 77.321818196 1.616258E-07 6.699736E-07
107.19 290.34590548 69.016283442 0.03752587 0.140910749
105.19 271.58647785 63.903788718 0.064608569 0.226932091
103.19 253.83604715 59.106337312 0.093542648 0.307086417
120
101.19 237.05269198 54.608973011 0.124492622 0.381668359
99.19 221.19560976 50.39719084 0.157640096 0.450962931 110
97.19 206.22511162 46.45693528 0.193185748 0.51524559
95.19 192.10261661 42.774598064 0.231351573 0.574782302 100
93.19 178.79064503 39.337015548 0.272383405 0.629829629
90
91.19 166.25281107 36.131465652 0.316553785 0.680634813
89.19 154.45381474 33.145664388 0.36416519 0.727435883 80
87.19 143.35943297 30.367761965 0.41555371 0.770461762
85.19 132.93651008 27.786338487 0.471093207 0.809932388 70
83.19 123.15294746 25.390399246 0.531200053 0.846058847
81.19 113.9776926 23.169369614 0.596338514 0.879043508 60
0 0.1 0.2 0.3 0.4 0.5
79.19 105.38072736 21.113089555 0.667026891 0.909080173
77.19 97.333055629 19.21180774 0.743844522 0.936354232 ETANOL BUTANOL
75.19 89.806690271 17.456175314 0.827439787 0.961042829
73.19 82.774639464 15.837239287 0.91853927 0.98331503
71.5384468785 77.321872367 14.597314431 0.999999962 0.999999993
A= -0.000381
B= 1.3966
gramos Gramos
(g/etOH) (l/etOH)

7.6377952756 6.692913386
8.188976378 5.118110236
6.3254593176 3.517060367
5.7480314961 2.17847769
3.5958005249 1.338582677
1.1023622047 0.183727034

Teb / ⁰C η vapor η líquido %etanol (g) %etanol (l)

PM(butOH)= 74.121
PM(etOH)= 46.07 71.3 --- ---
 75.4 1.3675 1.3711 76.377952756 66.92913386
79.1 1.3654 1.3771 81.88976378 51.18110236
84.5 1.3725 1.3832 63.254593176 35.17060367
89.3 1.3747 1.3883 57.480314961 21.7847769
96.4 1.3829 1.3915 35.958005249 13.38582677
105.4 1.3924 1.3959 11.023622047 1.837270341
111.5 --- ---
ETANOL ES EL MAS VOLATIL

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

ETANOL BUTANOL X Y

gramos gramos mol mol mol mol

n total
(g/butOH) (l/butOH) (g/etOH) (l/etOH) (g/butOH) (l/butOH)

2.36220472 3.30708661 0.16578674 0.14527704 0.03186957 0.0446174 0.19765632

1.81102362 4.88188976 0.17775074 0.11109421 0.02443334 0.06586379 0.20218408
3.67454068 6.48293963 0.13730105 0.07634166 0.04957489 0.08746428 0.18687594
4.2519685 7.82152231 0.12476734 0.04728625 0.05736523 0.1055237 0.18213258
6.40419948 8.66141732 0.0780508 0.02905541 0.08640196 0.11685511 0.16445276
8.8976378 9.81627297 0.02392798 0.003988 0.12004206 0.13243579 0.14397005

X Y
1 1
0.83876268 0.73499823
0.87915299 0.54947062
0.73471763 0.40851519
0.68503584 0.25962546
0.47460926 0.17667936
0.16620112 0.02770019
0 0