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Part1: CHEMISTRY

Useful Data :
Atomic Mass : H = 1, C = 12, N = 14, O = 16, Na = 23, S = 32, Cl = 35.5, K = 39, Ca=40,
Mn = 55, Fe = 56, Cu = 63.5, Br=80, I = 127.

SECTIONI
Straight Objective Type
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct.

1. Identify the end product in the given sequence :

2 / h alc.
Br
  X KOH
  Y NBS

 Z
(a) 1bromo cyclopentene (b) 2bromo cyclopentene
(c) 3bromo cyclopentene (d) 4bromo cyclopentene

2. The enol form of cyclo hexane1, 3, 5trione represented by :


OH OH
OH
(a) (b)
HO OH OH
OH OH
OH
(c) (d)
HO HO OH

3. A hydrocarbon P on photochlorination gives a mixture containing only one monochloro


and two dichloro derivatives. 3.6 gm of P occupies 1.12 litre at NTP. The hydrocarbon P
is:
(a) npentane (b) 2,2,3,3tetra methyl butane
(c) 2methyl butane (d) 2,2dimethyl propane

4. To prepare 3ethyl3pentanol the reagents needed are :


(a) ethylmethyl ketone and ethylmagnesium bromide followed by hydrolysis.
(b) diethyl ketone and methylmagnesium bromide followed by hydrolysis.
(c) diethyl ketone and ethylmagnesium bromide followed by hydrolysis.
(d) ethylmethyl ketone and propylmagnesium bromide followed hydrolysis.
 Space for rough work
SECTIONII
Multiple Correct Answer Type
This section contains 5 multiple correct answer(s) type questions. Each question has 4
choices (A), (B), (C) and (D), out of which ONE OR MORE is/are correct.
5. Which of the following statements is correct :
(a) The substituents get lower number in comparison to the functional group.
(b) The IUPAC name of acid amides is alkanamide.
(c) The IUPAC name of alkenes ends with the suffixene.
(d) The IUPAC name of isocynide ends with suffixnitrile

6. 8 ml of a hydrocarbon requires 40 ml of dioxygen for complete oxidation under similar


conditions. Hydrocarbon cannot be
(a) propene (b) propyne
(c) propane (d) cyclopropane

7. Which of the following statement(s) is/are incorrect :


(a) Hydrogen atoms of acetylene are neutral while that of ethylene are acidic.
(b) In SN2 bond formation and bond breaking takes place in one step.
(c) The rate of reaction in SN1 depends upon the concentration of substrate and attacking
reagent.
(d) The nuclear reactions of benzene are the example of neucleophilic substitution
reactions.

8. Which of the following is a dissymmetric compound


COOH
COOH
H OH
(a) H OH (b)
HO H
CH3 COOH
(+) form
COOH COOH
(c) H OH (d) HO H
H OH H OH

COOH COOH
() form
9. For the reaction shown below if the concentration of KCN is increased four times, the rate
of the reaction will not be changed by :
Me Me

Cl + KCN aq
.MeOH
 CN + KCl
Me Me
(a) 2 times (b) 4 times
(c) 16 times (d) unchanged
 Space for rough work
SECTIONIII
Matrix Match Type

This section contains 2 questions. Each question contains statements given in two
columns, which have to be matched. The statements in Column I are labeled A, B, C and
D, while the statements in Column II are labelled p, q, r, s and t. Any given statement in
Column I can have correct matching with ONE OR MORE statement(s) in Column II.
The appropriate bubbles corresponding to the answers to these questions have to be
darkened as illustrated in the following example:
If the correct matches are A – p, s and t; B – q and r; C – p and q; and D – s and t; then
the correct darkening of bubbles will look like the following:
p q r s t
A p q r s t

B p q r s t

C p q r s t
D p q r s t
10.
Column-I Column-II
(A) Nucleophile (p) R4N+
(B) Electrophile (q) RN+C
(C) Neither electrophile nor nucleophile (r) SO3
(D) Both nucleophile as well as electrophile (s) CH2=O

11.
Column-I Column-II
(A) pent3en1yne (p) Homocyclic
(B) N, Ndimethylethanamine (q) Hetrocyclic
(C) Ethynylcyclohexene (r) Alkenyne
(D) Oxirane (s) Aliphatic
 Space for rough work
SECTIONIV
Integer Answer Type
This section contains 8 questions. The answer to each of the question is a single digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the following:

12. Find out the total number of sigma and pie bonds in carbon suboxide.
13. How many optically active chloroderivatives can be obtained by the mono chlorination of
isobutane.

14. How many number of chiral centres are present in 3, 4dibromo2pentanol.


15. How many types of dibromo chlorobenzene are possible?
16. How many types of hybrid orbitals are present in vinyl benzene?
17. Find out the total number of cyclic structural as well as stereo isomers possible for a
compound with the molecular formula C5H10 is

18. How many geometrical isomers can be represented by CH3CH=CHCH=CHCH=CHCl.


19. How many moles of valence shell electron pair are present in the carbocation, which is
formed by heterolysis of 190 g of methyl bromide.
 Space for rough work
Part2 : MATHEMATICS
SECTIONI
Straight Objective Type
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct.
a
20. If f x . f a  x   1 , then  log f x  dx is equal to
0
(a) 1 (b) –1
(c) 0 (d) depends upon f(x)

/3
dx
21. Value of  1  e
/6
sin x  cos x 
is equal to

 
(a) (b)
2 4
2 
(c) (d)
3 12

22. 
The solution of y e  x / y dx  xe  x / y  y 3 dy  0 is
(a) e  x / y  y 2  c (b) x e  x / y  y  c
(c) 2e  x / y  y 2  c (d) e  x / y  2 y 2  c

23. If   (0, 4), then the maximum area that can be bounded by the curves y = 2 – |x – 2| and
y = |x – | is
1 3
(a) sq. units (b) sq. units
2 2
5
(c) 2 sq. units (d) sq. units
2
 Space for rough work
SECTIONII
Multiple Correct Answer Type
This section contains 5 multiple correct answer(s) type questions. Each question has 4
choices (A), (B), (C) and (D), out of which ONE OR MORE is/are correct.
1
dx
24. If I n   , n  N , then which of the following statements hold good ?

0 1 x
2 n

 1
(a) 2nI n 1  2  n  2n  1I n (b) I 2  
8 4
 1  5
(c) I 2   (d) I 3  
8 4 16 48
2
 dy  dy x
25. A solutions of the differential equation    (e + ex) + 1 = 0 is given by
 dx  dx
(a) y + ex = C (b) y  ex = C
(c) y + ex = C (d) y ex = C
26. Find the correct statements :
d2y
(a) The order of differential equation 1   x is 1
dx 2
(b) Area bounded by the curve y = f(x)  0 and y = 0 between x = a and x = b,
b
b > a is  f x dx
a

(c) x > 0, x  1, then  log 


e  log x e dx  x log x e  C
2
x

ab
b b
(d)  x f x dx  f x dx
a
2 a

y2
27. The solution of xy + y0
x
(a) x2y = k(2x + y) (b) y(kx2  1) = 2x
(c) x2 = ky(2x + y) (d) y = kx2 (2x + y)
k being an arbitrary constant.

28. The value of integral  x f sin x dx is
0
/2
(a) 0 (b)   f sin x dx
0


f sin x dx
2 0
(c) (d) 

 Space for rough work


SECTIONIII
Matrix Match Type

This section contains 2 questions. Each question contains statements given in two
columns, which have to be matched. The statements in Column I are labeled A, B, C and
D, while the statements in Column II are labelled p, q, r, s and t. Any given statement in
Column I can have correct matching with ONE OR MORE statement(s) in Column II.
The appropriate bubbles corresponding to the answers to these questions have to be
darkened as illustrated in the following example:
If the correct matches are A – p, s and t; B – q and r; C – p and q; and D – s and t; then
the correct darkening of bubbles will look like the following:
p q r s t
A p q r s t

B p q r s t

C p q r s t
D p q r s t

29.
Column-I Column-II
(A) / 2 3
sin x dx (p) 

0 sin 3 x  cos 3 x
= 2
(B) 1  x  (q) 
Let Fx    e sin x 1  dx and F(0) = 1, if

1 x2  4

k 3 e/ 6
F1 / 2  , then k =

(C) (r) 
Let Fx    2
dx
 
x 1 x  92
 and F(0) = 0, if

 
F 3 
5
36
k, then k =

f x 
(D) /2 (s) 2
The value of the integral  dx is
0 f x   f 
 
  x
2 
 Space for rough work
30.
Column-I Column-II
(A) xdy = y(dx + ydy), y > 0, y(1) = 1 and y(x0) = 3 then |x0| = (p) 10
(B) If the area of the region bounded by x2  y and (q) 14
k
y  x + 2 is , then k =
4
(C) The area enclosed by y = x3, its normal at (1, 1) and x axis is (r) 15
k
=
8
(D) If f(x), g(x) be twice differentiable functions on [0, 2] satisfying (s) 18
f(x) = g(x), f (1) = 2, g(1) = 4 and f(2) = 3, g(2) = 9, then
f(x)  g(x) at x = 4 equals

 Space for rough work


SECTIONIV
Integer Answer Type
This section contains 8 questions. The answer to each of the question is a single digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the following:

 sin 2x  cos 2x dx  sin 2x  a   b , then the value of |[a]|.


1
31.
2

 1 1 1 
32. The value of lim    .....    log 6 must be equal to.
n  n  1 n2
 6n 

33. The degree of differential equation corresponding to the family of curves y = a(x + a)2,
where a is an arbitrary constant is

34. The slope of the tangent to a curve y = f(x) at (x, f(x)) is 2x + 1. If the curve passes
through the point (1, 2). If the area of the region bounded by the curve, the xaxis and the
A
line x = 1 is A, then the value of .
6
 Space for rough work
2
35.  min x  x ,  x   x  dx equals ([x] represents greatest integer less than or equal to x)
2

4 2
sin x
2e sin x
36. Let
d
Fx   e , x  0 . If 1 x dx  Fk   F1, then the values of 2 is.
k
dx x

37.  
If  log 1  x  1  x dx  xf x   Ax  B sin 1 x  C , then the value of A + B.

x
38. Let f : R  R be a continuous function which satisfies f x    f t dt . Then the value of
0
f(ln 5) is
 Space for rough work
Part3 : PHYSICS
SECTIONI
Straight Objective Type
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct.

39. The displacement from the position of equilibrium of a point 4 cm from a source of
sinusoidal oscillations is half the amplitude at the moment t = T/6(T is the time period).
Assume that the source was at mean position at t = 0. The wavelength of the running wave
is
(a) 0.96 m (b) 0.48 m (c) 0.24 m (d) 0.12 m

40. Two waves of sound having intensities I and 4I interfere to produce interference pattern.
The phase difference between the waves is  / 2 at point A and  at point B. Then the
difference between the resultant intensities at A and B is
(a) 2I (b) 4I (c) 5I (d) 7I

41. A wave pulse on a string has the dimension shown in the figure. The wave speed is V = 1
cm/s. If point O is a free and. The shape of wave at time t = 3 sec is
V = 1 cm/s

1 cm

O
1 cm 1 cm 2 cm
O
(a) O (b) 1 cm

1 cm

O
1 cm

(c) (d) 2 cm
1 cm

O 1 cm
 Space for rough work
42. S1 and S2 are two coherent sources of sound having no initial phase S1
difference. The velocity of sound is 330 m/s. No minima will be
formed on the line passing through S2 and perpendicular to the line

3m
joining S1 and S2 if the frequency of both the sources is:
(a) 50Hz (b) 60Hz
(c) 70Hz (d) 80Hz S2

 Space for rough work


SECTIONII
Multiple Correct Answer Type
This section contains 5 multiple correct answer(s) type questions. Each question has 4
choices (A), (B), (C) and (D), out of which ONE OR MORE is/are correct.

43. When a wave is refracted into another medium, which of the following will change?
(a) Amplitude (b) Velocity
(c) Frequency (d) Phase

44. When wave travels in a medium, the particle displacements are given by
y  a sin 2(bt  cx )
Where a, b and c are constants.
(a) The wavelength of wave is c.
b
(b) The velocity of the wave is .
c
1
(c) The maximum particle velocity is twice the wave velocity if c 
a
(d) The frequency of the wave is b.

45. The length, tension, diameter and density of a wire B are double than the corresponding
quantities for another stretched wire A. Then.
1
(a) Fundamental frequency of B is times that of A.
2 2
1
(b) The velocity of wave in B is times that of velocity in A.
2
(c) The fundamental Frequency of A is equal to the third overtone of B.
(d) The velocity of wave in B is half that of velocity in A.

46. Figure, shows a stationary wave between


two fixed point P and Q. Which point(s)
of 1, 2 and 3 are in phase with the point
x? P x 1 2 3 Q
(a) 1,2 and 3 (b) 1 and 2 only

(c) 2 and 3 only (d) 3 only

47. Two interfering waves have the same wavelength, frequency, and amplitude. The are
traveling in same direction but are 90o out of phase. Compared to the individual waves, the
resultant wave will have the same.
(a) amplitude and velocity but different wave length
(b) amplitude and wavelength but different velocity
(c) wavelength and velocity but different amplitude
(d) amplitude and frequency but different velocity
 Space for rough work
SECTIONIII
Matrix Match Type
This section contains 2 questions. Each question contains statements given in two
columns, which have to be matched. The statements in Column I are labeled A, B, C and
D, while the statements in Column II are labelled p, q, r, s and t. Any given statement in
Column I can have correct matching with ONE OR MORE statement(s) in Column II.
The appropriate bubbles corresponding to the answers to these questions have to be
darkened as illustrated in the following example:
If the correct matches are A – p, s and t; B – q and r; C – p and q; and D – s and t; then
the correct darkening of bubbles will look like the following:
p q r s t
A p q r s t

B p q r s t

C p q r s t
D p q r s t

48. Equation of a wave is given as y = 0.02 sin 2 (10t  5x) , then


Match the followings:
Column-I Column-II(only magnitude in SI units)
(A) Speed of wave (p) 10
(B) Frequency of wave (q) 0.4 
(C) Wavelength of wave (r) 2
(D) Maximum particle speed (s) 0.2
 Space for rough work
49. Two sources of sound having same intensity & same frequency are situated as shown in
the figure.
y

S1

5
2

x
S2(0,0)
A man is walking from   to   and observes different intensities at different locations.

Match the following column.


Column (I) Column (II)
(A) Number of maxima 9
(i) 
16
(B) Number of minima (ii) 4
(C) xcoordinate of first minima (iii) 5
(D) xcoordinate of second maxima (iv)  6

(a) A  (ii), B  (iii), C  (iv), D  (i) (c) A  (ii), B  (iii,) C  (i), D  (iv)
(b) A  (iii), B  (ii), C  (i), D  (iv) (d) A  (i), B  (iii), C  (ii), D  (iv)
 Space for rough work
SECTIONIV
Integer Answer Type
This section contains 8 questions. The answer to each of the question is a single digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the following:

50. Find the ratio of time periods of two identical springs if they are first joined in series &
then in parallel & a mass m is suspended from them:

51. A body undergoing SHM about the origin has its equation is given by x = 0.2 cos 5 t .
Find its average speed from t = 0 to t = 0.7 sec.
 Space for rough work
52. Potential Energy(U) of a body of unit mass moving in a onedimension conservative force
 
field is given by, U = x 2  4x  3 . All units are in S.I.
Find the equilibrium position of the body.

53. Three coherent waves of equal frequencies having amplitude 10  m, 4  m, and 7  m



respectively, arrive at a given point with successive phase difference of . The amplitude
2
of the resulting wave in mm is given by.

54. A person standing at a distance of 6m from a S


source of sound receives sound wave in two ways,
one directly from the source and other after
5m
reflection from a rigid boundary as shown in the
figure. The maximum wavelength for which, the
person will receive maximum sound intensity
6m

4m

55. A closed organ pipe and an open organ pipe of same length produce 4 beats when they are
set into vibrations simultaneously of the length of each of them were twice their initial
lengths, the number of beats produced will be.

56. Consider two sound sources s1 and s2 having


same frequency 100 Hz and the observer O
located between them. All the three are
S1 30m/s O 30m/s S2 30m/s
moving with same velocity in same direction.
the beat frequency of the observer is

57. Two monoatomic ideal gases 1 and 2 of molecular masses m1 = 3 and m2 = 27


respectively are enclosed in separate container kept at the same temperature. The ratio of
the speed of sound in gas 1 to that in gas 2 is given by.
 Space for rough work

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