Benceno (1) Tolueno(2) A12 -220.

57
A 6.90565 6.95334 A21 330.69
B 1211.033 1343.943
C 220.79 219.377 R 0.082 L.atm/Kmol
R 3.1878 3.9228 P 760 mmHG
Q 2.4 2.9679

T x1 x2 y1 y2 Pvap1 Pvap2 LN(Gamma1)

C mmHg mmHg
108.75 0.042 0.958 0.089 0.911 1701.10223 720.341904 -0.05474651
108.42 0.047 0.953 0.102 0.898 1686.7343 713.535116 -0.02240593
104.87 0.132 0.868 0.257 0.743 1537.96497 643.468894 -0.03862278
103 0.183 0.817 0.334 0.666 1463.75919 608.81438 -0.05378992
101.52 0.219 0.781 0.395 0.605 1407.00383 582.448918 -0.02608531
97.76 0.325 0.675 0.53 0.47 1270.41438 519.521622 -0.02472815
95.01 0.407 0.593 0.619 0.381 1177.17219 477.018673 -0.01825987
92.76 0.483 0.517 0.688 0.312 1104.89707 444.345711 -0.02041684
90.76 0.551 0.449 0.742 0.258 1043.58433 416.826265 -0.01948367
88.63 0.628 0.372 0.8 0.2 981.226324 389.034278 -0.01341315
86.41 0.712 0.288 0.853 0.147 919.359327 361.668035 -0.00967697
84.1 0.81 0.19 0.911 0.089 858.257216 334.854491 -0.00407676
81.99 0.9 0.1 0.958 0.042 805.262245 311.781547 0.00460345
81.92 0.904 0.096 0.96 0.04 803.549113 311.038636 0.00438405
81.18 0.941 0.059 0.973 0.027 785.612826 303.271849 0.00029529

115
0.014
110
0.012
105
0.01
100
0.008
95
0.006
90
0.004
85
0.002
80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0
0 0.1 0.2
 LN(Gamma2) Ge/RT Phi 1 Phi 2 Tita 1 Tita 2 Tau12 Tau21
Experimental
0.0032875873 0.00085016 0.03440134 0.96559866 0.03423857 0.96576143 1.78168504 0.4206697035
0.0036419454 0.0024177 0.03853312 0.96146688 0.03835158 0.96164842 1.78257522 0.4203547911
0.0109490759 0.00440559 0.10998792 0.89001208 0.10950808 0.89049192 1.79227838 0.4169474917
0.0174555825 0.00441765 0.15399207 0.84600793 0.15335333 0.84664667 1.7974849 0.4151381351
0.0107302544 0.00266765 0.18558182 0.81441818 0.18484068 0.81515932 1.80165327 0.4136989669
0.0184300062 0.0044036 0.2812313 0.7187687 0.2802396 0.7197604 1.81243739 0.4100139927
0.0233677719 0.00642532 0.35804584 0.64195416 0.35691779 0.64308221 1.82050606 0.4072925326
0.0316758578 0.00651508 0.43155714 0.56844286 0.43035274 0.56964726 1.82722515 0.4050491655
0.0465856269 0.01018145 0.49930932 0.50069068 0.49808152 0.50191848 1.8332886 0.4030423269
0.0490744888 0.00983225 0.57839097 0.42160903 0.57719288 0.42280712 1.8398424 0.4008917671
0.0700637799 0.01328836 0.66766494 0.33233506 0.66657429 0.33342571 1.84678116 0.3986356568
0.0612346484 0.00833241 0.77600505 0.22399495 0.77515022 0.22484978 1.85412109 0.396272052
0.0235150929 0.00649462 0.87971668 0.12028332 0.87919602 0.12080398 1.86093493 0.394098693
0.0179325587 0.00568471 0.88442382 0.11557618 0.88392085 0.11607915 1.8611628 0.3940263543
0.1369882594 0.00836018 0.92837097 0.07162903 0.9280437 0.0719563 1.86357894 0.393260698

G de exceso vs X1
0.014

0.012

0.01

0.008

0.006

0.004

0.002

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 G comb G residual Ge/RT
Calculado
-0.00080755 0.00754362 0.00673606
-0.00089954 0.00830576 0.00740621
-0.00232631 0.01765746 0.01533115
-0.00305578 0.02044484 0.01738906
-0.00351227 0.02133102 0.01781874
-0.00456846 0.02023258 0.01566411
-0.00508179 0.01672437 0.01164258
-0.00531251 0.01247168 0.00715917
-0.00531289 0.00833367 0.00302078
-0.00507111 0.00387925 -0.00119186
-0.00450441 -0.00013011 -0.00463452
-0.0034287 -0.00288631 -0.00631502
-0.00203168 -0.00307465 -0.00510633
-0.00196024 -0.00301765 -0.00497789
-0.00126094 -0.002249 -0.00350993
 Benceno (1) Tolueno(2) A12 -220.57
A 4.72583 4.07827 A21 330.69
B 1,660.652 1343.943
C -1.461 -53.773 R 0.08314
R 3.1878 3.9228
Q 2.4 2.9679

T x1 x2 y1 y2 Pvap1 Pvap2 LN(Gamma1)

383.75 0 1 0 1 2.40912793 1.01258523
379.35 0.1 0.9 0.203 0.797 2.14427399 0.8920503 -0.04184901
375.35 0.2 0.8 0.372 0.628 1.92426904 0.7925814 -0.02105346
371.75 0.3 0.7 0.507 0.493 1.74214501 0.71076897 -0.01747236
368.45 0.4 0.6 0.619 0.381 1.58765831 0.64180775 -0.01270322
365.45 0.5 0.5 0.713 0.287 1.45700606 0.58384342 -0.00859414
362.55 0.6 0.4 0.791 0.209 1.24012285 0.48847056 0.07407409
359.95 0.7 0.3 0.857 0.143 1.15409906 0.45098236 0.0719538
357.55 0.8 0.2 0.912 0.088 1.07957111 0.41868338 0.06738065
355.35 0.9 0.1 0.959 0.041 1.01213621 0.3896158 0.06434938
353.25 1 0 1 0 #NUM! 1.1781E+29 0

Chart Title
390 2.5

2
380

1.5
370

1
360
0.5

350
0
0 0.2
340 -0.5

330
0 0.2 0.4 0.6 0.8 1 1.2
 LN(Gamma2) Ge/RT Phi 1 Phi 2 Tita 1 Tita 2 Tau12 Tau21
0.000409527 0.01306595 0 1 0 1 1.77673115 0.4224294202
0.0056088953 0.0272216 0.08281506 0.91718494 0.08244278 0.91755722 1.78861565 0.4182282446
0.0033047354 -0.04889775 0.16885428 0.83114572 0.16816615 0.83183385 1.79973279 0.4143609949
0.0037529073 -0.08081251 0.2583097 0.7416903 0.25736989 0.74263011 1.81000363 0.4108408243
0.0022524265 -0.1142557 0.35138889 0.64861111 0.35027036 0.64972964 1.8196478 0.4075805799
-0.0040872 -0.19265178 0.4483166 0.5516834 0.44710222 0.55289778 1.82861209 0.4045886573
0.0802619994 2.30737871 0.54933655 0.45066345 0.5481204 0.4518796 1.83746159 0.4016707861
0.0683054443 2.12055249 0.65471349 0.34528651 0.6536024 0.3463976 1.84555409 0.3990330904
0.0625759624 1.97443926 0.76473552 0.23526448 0.76385076 0.23614924 1.85316084 0.3965799418
0.0639122628 1.89983365 0.87971668 0.12028332 0.87919602 0.12080398 1.86025202 0.3943156177
0 1 0 1 0 1.86712905 0.3921401878

Chart Title
2.5

1.5

0.5

0
0 0.2 0.4 0.6 0.8 1 1.2

-0.5
G comb G residual Gex/RT
#DIV/0! 0 #DIV/0!
-0.0018198 0.01490639 0.0130866
-0.00327743 0.02093947 0.01766205
-0.00435869 0.02090535 0.01654665
-0.00504856 0.01710949 0.01206092
-0.00533108 0.01146692 0.00613584
-0.00518928 0.00544354 0.00025426
-0.00460514 0.00040026 -0.00420488
-0.00355943 -0.0026938 -0.00625324
-0.00203168 -0.00303428 -0.00506596
#DIV/0! 0 #DIV/0!
 Benceno (1) Tolueno(2) A12 -220.57
A 6.90565 6.95334 A21 330.69
B 1211.033 1343.943
C 220.79 219.377 R 0.082 L.atm/Kmol
R 3.1878 3.9228 P 760 mmHG
Q 2.4 2.9679

T x1 x2 y1 y2 Pvap1 Pvap2 LN(Gamma1)

C mmHg mmHg
80.1 1 0 1 0 760 0 0
85 0.78 0.22 0.9 0.1 877 345 -8.7715E-05
90 0.581 0.419 0.777 0.223 1016 405 0.0003794
95 0.411 0.589 0.632 0.368 1168 475 0.00056645
100 0.258 0.742 0.456 0.544 1344 557 -0.00055386
105 0.13 0.87 0.261 0.739 1532 645 -0.00402496
110.6 0 1 0 1 1800 760

G de exceso vs X
0.01

0.005

0
0 0.2 0.4 0.6

115 -0.005

110
-0.01
105

100 -0.015

95

90

85

80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 LN(Gamma2) Ge/RT Phi 1 Phi 2 Tita 1 Tita 2 Tau12 Tau21
Experimental
0 1 0 1 0 1.86712905 0.3921401878
0.0013166559 0.00649763 0.74234483 0.25765517 0.74140434 0.25859566 1.85124665 0.397194889
-0.001267782 -0.00925421 0.52981588 0.47018412 0.52859226 0.47140774 1.83561554 0.4022765675
-0.000339616 0.00098948 0.36185831 0.63814169 0.36072499 0.63927501 1.82053568 0.4072825955
0.000353197 0.00364657 0.22030939 0.77969061 0.21946693 0.78053307 1.8059789 0.4122142753
0.0008728258 0.00732148 0.10827984 0.89172016 0.10780654 0.89219346 1.7919189 0.4170729017
0 0 0 1 0 1 1.77673115 0.4224294202

G de exceso vs X1

0.4 0.6 0.8 1 1.2

 G comb G residual Ge/RT
Calculado
#DIV/0! 0 #DIV/0!
-0.00380646 -0.00222369 -0.00603015
-0.0052497 0.0065819 0.0013322
-0.00509988 0.0165674 0.01146752
-0.00395135 0.02147904 0.0175277
-0.00229574 0.01751736 0.01522162
#DIV/0! 0 #DIV/0!
RT 8134 J/M

n0 V1 V2 E1 E2 nk
CH4 2 -1 -1 0.5 0.5 1

H20 3 -1 -2 1.5

CO 0 1 0 0.5

CO2 0 0 1 0.5

H2 0 3 4 3.5

G -642747.302
yk uk
0.14285714 3891.96685

0.21428571 -204949.98

0.07142857 -221706.092

0.07142857 -417256.092

0.5 -5638.05917
A + 2B AB2
4 4 4
2B
Reacciona Me quedan G.Avance Conversion Reacciona
2 2 1 0.5 1
3 1 1.5 0.75 1.5
4 0 2 1 2
5 -1 2.5 1.25 2.5
6 -2 3 1.5 3
7 -3 3.5 1.75 3.5
8 -4 4 2 4
Me quedan G.Avance
3 1
2.5 1.5
2 2
1.5 2.5
1 3
0.5 3.5
0 4