Especie A B C P [bar]

a Etanol 12.2917 3803.98 -41.68

1
b Agua 11.6834 3816.44 -46.13

Sistema Ideal Puntos Burbuja

xa xb T [K] Pa sat [bar] Pb sat [bar] P calc burb [bar]
0 1 372.784913 2.2321265094 1.00000002 1.0000000151304
0.1 0.9 369.549144 1.9928610147 0.88968219 1.0000000714648
0.2 0.8 366.675264 1.798540687 0.80036484 1.0000000103507
0.3 0.7 364.095724 1.6377609436 0.72667397 1.0000000646079
0.4 0.6 361.759741 1.5026406506 0.66490609 0.9999999132851
0.5 0.5 359.628289 1.3875688662 0.61243114 1.0000000025165
0.6 0.4 357.670758 1.2884455958 0.56733182 1.0000000838538
0.7 0.3 355.86275 1.2022089651 0.52817939 1.0000000927523
0.8 0.2 354.184523 1.1265278366 0.49388833 0.9999999349976
0.9 0.1 352.619913 1.0595977947 0.46361998 1.0000000129422
1 0 351.1555 1.0000000178 0.4367161 1.0000000178133

Sistema Ideal Puntos de rocío

ya yb T [K] Pa sat [bar] Pb sat [bar] P calc roc [bar]
0 1 372.784912 2.2321264344 0.99999998 0.9999999805319
0.1 0.9 371.202804 2.1123368122 0.9447241 0.9999999798135
0.2 0.8 369.536928 1.9919997533 0.88928575 1.0000000202046
0.3 0.7 367.776594 1.8710618232 0.83366741 0.9999998539776
0.4 0.6 365.90885 1.7494612385 0.77784892 1.0000001660166
0.5 0.5 363.917691 1.6271199083 0.72180403 0.999999778961
0.6 0.4 361.783143 1.5039467961 0.66550241 1.0000000559197
0.7 0.3 359.479603 1.3798236139 0.60890365 0.9999999978826
0.8 0.2 356.973592 1.2546014585 0.55195656 0.9999999510917
0.9 0.1 354.219955 1.1280834707 0.4945925 1.0000000499609
1 0 351.155501 1.0000000452 0.43671611 1.0000000451523
Suma
 Diagrama Txy ideal
a 375
P sist [bar] Rest Pburb [bar]
1 1.513040915E-08 370
1 7.146474701E-08
1 1.035065278E-08 365

1 6.460786794E-08
360
1 8.671492924E-08

T [k]
1 2.516449715E-09 355
1 8.385382544E-08
1 9.275229185E-08 350
1 6.500240191E-08
1 1.294215535E-08 345

1 1.781327619E-08
340
Suma 5.231490066E-07 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0

xa-ya

Rest Proc [bar]

1.94680607E-08
2.01865331E-08
2.02046235E-08
1.46022448E-07
1.66016579E-07
2.21039014E-07
5.59196669E-08
2.11740958E-09
4.89083369E-08
4.99608612E-08
4.51522548E-08
7.94995788E-07
Diagrama Txy ideal

Líquido
Vapor

0.4 0.5 0.6 0.7 0.8 0.9 1

xa-ya
 Especie A B C P [bar]
a Etanol 12.2917 3803.98 -41.68
1
b Agua 11.6834 3816.44 -46.13

Sistema Ideal Puntos Burbuja

xa xb T [K] Pa sat [bar] Pb sat [bar] gamma a
0 1 372.784636 2.23210505 0.99999011 4.6596905142865
0.1 0.9 359.408706 1.37614317 0.60722764 3.205929536813
0.2 0.8 355.612835 1.19067709 0.52295002 2.2890903612502
0.3 0.7 354.126934 1.12400317 0.49274557 1.7474661987955
0.4 0.6 353.296135 1.0881047 0.47650505 1.4236167158252
0.5 0.5 352.649709 1.0608406 0.46418151 1.2281189663106
0.6 0.4 352.08759 1.03759907 0.45368374 1.1117353550259
0.7 0.3 351.632561 1.01909878 0.44533258 1.0461623222269
0.8 0.2 351.328877 1.00690605 0.43983121 1.0137042533129
0.9 0.1 351.186525 1.00123288 0.43727216 1.0017893066482
1 0 351.155242 0.99998978 0.43671148 1

Sistema Ideal Puntos de rocío

ya yb T [K] Pa sat [bar] Pb sat [bar] gamma a
0 1 372.784554 2.23209875 0.99998719 4.6596920806106
0.1 0.9 369.715476 2.00461943 0.89509513 3.1034818138127
0.2 0.8 365.888578 1.74817836 0.77726063 2.2364646413853
0.3 0.7 361.837365 1.50697668 0.66688577 1.7268048884596
0.4 0.6 358.10435 1.30987588 0.57707375 1.4168813781229
0.5 0.5 355.122576 1.16832318 0.5128175 1.2263629453248
0.6 0.4 353.086894 1.0792162 0.47248636 1.1114021288677
0.7 0.3 351.919537 1.03073401 0.45058427 1.0461238236993
0.8 0.2 351.375308 1.00876227 0.44066861 1.01370243007
0.9 0.1 351.188467 1.00131011 0.437307 1.0017892967431
1 0 351.155362 0.99999455 0.43671363 1
Suma
ja
gamma b P calc burb [bar] P sist [bar] Rest Pburb [bar] R (J/mol k) 8.3145
1 0.9999901072319 1 9.892768137E-06 A (J/mol) 3590
1.02253025599 0.9999995762265 1 4.237735505E-07 B (J/mol) -1180
1.08728817195 0.9999913882754 1 8.611724645E-06
1.19083848067 0.9999935356057 1 6.464394332E-06
1.33045844257 0.99999971998 1 2.800200355E-07 gam
1.50185987829 0.999987019832 1 1.298016802E-05 5
1.69646234055 0.9999842882442 1 1.571175583E-05 4.5
1.89882056932 0.9999819242061 1 1.807579386E-05 4
2.08514925531 0.9999866974423 1 1.330255769E-05 3.5
2.2243733446 0.9999876108351 1 1.238916486E-05 3

gamma
2.5
2.28286869068 0.9999897805182 1 1.021948184E-05
2
Suma 0.0001083516028
1.5
1
0.5
gamma b P calc roc [bar] Rest Proc [bar] 0
0 0.1 0.2 0.3 0.4 0.5
1 0.9999871949452 1.28050548E-05
x
1.02189534142 0.999990084469 9.91553103E-06
1.08473573427 0.999991737571 8.26242903E-06
1.18641465694 0.9999867238289 1.32761711E-05
1.32536765106 0.9999925893425 7.4106575E-06
1.49761254971 0.9999900479125 9.95208753E-06 Dia
1.69392652677 0.9999910154385 8.98456153E-06 375
1.89782793796 0.9999919301795 8.06982055E-06
2.08494679198 0.9999865792478 1.34207522E-05 370
2.22436350903 0.99997946646 2.053354E-05
2.28286804646 0.9999945486919 5.45130814E-06 365

0.00011808191
360
T [k]

355

350

345

340
0 0.1 0.2 0.3
 gamma

gamma a
gamma b

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x

Diagrama Txy NO ideal

Líquido
Vapor

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

xa-ya
 Diagrama Txy ideal
375

370

365

360
Líquido
T [k]

Vapor
355

350

345

340
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

xa-ya
 Diagrama Txy NO ideal
375

370

365

360
Líquido Líquido
T [k]

Vapor Vapor
355

350

345

340
1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

xa-ya
 Líquido
Vapor