T 300 K

P 105000 Pa

Zi Hf(KJ/mol) P(Pa) T(K)

Metano 0.6 -74.52 101325 298.15
Etano 0.15 -83.82 101325 298.15
Propano 0.05 -104.68 101325 298.15
Butano 0.03 -125.79 101325 298.15
Nitrógeno 0.02 0 101325 298.15
Etileno 0.1 52.51 101325 298.15
Propileno 0.05 20 101325 298.15

Calculo de la entalpia ideal de la mezcla

(J/mol) (J/mol) (J/mol)
h1 6.626E+01 -7.445E+04 -4.467E+04
h2 97.46534972 -83722.53465028 -12558.38019754
h3 136.79233729 -104543.2076627 -5227.160383135
h4 1.832E+02 -1.256E+05 -3.768E+03
h5 5.386E+01 5.386E+01 1.0771219707497
h6 7.966E+01 5.259E+04 5.259E+03
h7 2.785E+11 2.785E+11 1.392E+10
 Cálculo de la entalpia real

mi alfa i ai bi
metano 0.3915721997 0.8104792708303 0.2022645300628 2.68006E-05
etano 0.5246782541 1.0092034269136 0.6102973042944 4.05336E-05
propano 0.6028272883 1.1233594118744 1.1431362649447 5.63099E-05
butano 0.6722952 1.2266315121592 1.8457398769941 7.24357E-05
nitrogeno 0.4313340995 0.5872137451309 0.0871916169505 2.40784E-05
etileno 0.5067735955 0.9690263466353 0.484309753934 3.62262E-05
propileno 0.5881982531 1.1127433719869 1.0179921251565 5.13078E-05

calculo de "a"
0.2698429743806 0.1171822911 0.0534587753541 0.0407574028772 0.005905645
0.26984297438 0.0728152308226 0.031620818 0.0016904102046 0.0012887824175 0.000186741
0.1171822911 0.0316208179742 0.0137316893 0.000734079296 0.0005596679949 8.10945E-05
0.05345877535 0.0144254749483 0.0062644218 0.0003348883164 0.0002553215621 3.69955E-05
0.04075740288 0.0109980988204 0.0047760458 0.0002553215621 0.0001946592248 2.82056E-05
0.00590564533 0.0015935969019 0.0006920371 3.699545321E-05 2.820563287E-05 4.08693E-06
0.06959236696 0.0187790112951 0.008154993 0.000435955939 0.0003323763353 4.81605E-05
0.0504477979 0.0136129838361 0.0059115885 0.0003160262837 0.0002409409957 3.49117E-05

ENTALPIA RESIDUAL (Pa.m6/mol2.K)

ai bi dai/dT
metano 0.2022645300628 2.680061367E-05 -0.00036794
etano 0.6102973042944 4.053360789E-05 -0.00105319
propano 1.1431362649447 5.63099209E-05 -0.00195196
butano 1.8457398769941 7.243569329E-05 -0.00313731
nitrogeno 0.0871916169505 2.407836228E-05 -0.00025223
etileno 0.484309753934 3.622621838E-05 -0.00085669
propileno 1.0179921251565 5.13077913E-05 -0.00171563
Entropia residual

sR/R -0.004674601539
sR -0.038864637197
Sreal 46558486.22817
𝑠^𝑅/𝑅=ln⁡(𝑍−𝐵)−1/(
ln⁡((𝑣+(1+√2)𝑏)/(𝑣+
 R 8.314 J/mol.K

a0 a1 a2 a3 a4 Tc(K)
4.568 -0.008975 3.631E-05 -3.407E-08 1.091E-11 190.56
4.178 -0.004427 5.66E-05 -6.651E-08 2.487E-11 305.32
3.847 0.0051313 6.011E-05 -7.893E-08 3.079E-11 369.83
5.547 0.005536 8.057E-05 -1.0571E-07 4.134E-11 425.120
3.539 -0.000261 7E-08 1.57E-09 -9.9E-13 126.2
4.221 -0.008782 5.795E-05 -6.729E-08 2.511E-11 282.34
3.834 3.893 4.688 -6.013 2.283 364.9

Calculo de la entropía ideal de

h 1.392E+10 J/mol
Calculo del aentropia por el ca

s1
s2
s3
s4
s5
s6
s7

Rln(P/P0)
 a 0.277703503108792
b 3.38185548769E-05

zi*raiz(ai) zi*bi
0.269842974 1.60803682025E-05
0.117182291 6.08004118295E-06
0.053458775 2.81549604484E-06
0.040757403 2.17307079858E-06
0.005905645 4.81567245621E-07
0.069592367 3.62262183751E-06
0.050447798 2.56538956484E-06

0.069592367 0.050447797899326 A 0.004687141963

0.002200568 0.013612983836108 B 0.001423682248
0.000955621 0.005911588538616
0.000435956 0.00269687749501
0.000332376 0.002056121223251
4.81605E-05 0.000297926802143 polinomio z^3
0.000567525 0.003510781663822 1
0.000411401 0.002544980312891

P -0.330551190604469
q -0.073152431603203
∆>0 1.390101094015E-07
Z 0.996748964673781

a.m6/mol2.K) zi*(dai/dT)/raiz(ai)
zi*raiz(ai) -0.0004908750435 -0.000202221551 -9.12831984E-05 -6.927763577786E-05 -1.7084125E-05
0.269842974 -0.00013245918179 -5.45680648E-05 -2.46321298E-05 -1.869408329636E-05 -4.6100311E-06
0.117182291 -5.75218622394E-05 -2.36967847E-05 -1.06967743E-05 -8.118112082199E-06 -2.0019569E-06
0.053458775 -2.62415786774E-05 -1.08105165E-05 -4.879888E-06 -3.703497568113E-06 -9.1329641E-07
0.040757403 -2.00067919103E-05 -8.24202523E-06 -3.72046609E-06 -2.823576511779E-06 -6.9630457E-07
0.005905645 -2.89893390894E-06 -1.19424876E-06 -5.39086195E-07 -4.091291463014E-07 -1.0089278E-07
0.069592367 -3.41611561596E-05 -1.40730764E-05 -6.35261384E-06 -4.821194651296E-06 -1.1889247E-06
0.050447798 -2.47635649883E-05 -1.02016319E-05 -4.60503635E-06 -3.494904168665E-06 -8.6185649E-07

(da/dT )mezcla -0.000655071458211

 hR/RT -0.011269774075989
hR -28.1090705003304 J/mol
hreal 1.392E+10

𝑅/𝑅=ln⁡(𝑍−𝐵)−1/(2^1.5 𝑏𝑅) [𝑑𝑎/𝑑𝑇]

(𝑣+(1+√2)𝑏)/(𝑣+(1−√2)𝑏))
 Tr= T/ Tc

(J/mol)
Pc(Pa) w Tr sf (j/mol) -Rziln(zi)
4599000 0.011 1.5742742596 186.27 2.548355789
4872000 0.099 0.9825756583 229.12 2.366040617
4248000 0.152 0.8111835168 270.2 1.245400799
3796000 0.200 0.7056831012 309.91 0.874658269
3390000 0.037 2.3771790808 191.5 0.650530306
5041000 0.087 1.0625487001 219.2 1.914484376
4600000 0.142 0.8221430529 266.6 1.245400799

lo de la entropía ideal de la mezcla

-Rziln(zi)
10.84487095554

lo del aentropia por el cambio de temperatura y presion

Integral Integral +sf
0.22153902813 186.4915390281
0.32588966508 229.4458896651 s ideal 46558486.27
0.45738504772 270.6573850477
0.61266216929 310.5226621693
0.18007613091 191.6800761309
0.26634939953 219.4663493995
931165348.956 931165615.5555

-0.2962043549
 a*Z^2 b*z c
-0.9985763178 0.001833696854 -4.64324E-06

-0.0001231008 -8.50199562E-05
-3.3217893E-05 -2.29420379E-05
-1.4425237E-05 -9.96283326E-06
-6.5808193E-06 -4.54506274E-06
-5.0172699E-06 -3.46519261E-06
-7.2698981E-07 -5.02097707E-07
-8.5668777E-06 -5.91673999E-06
-6.2101655E-06 -4.28906957E-06

v 0.023677059692
𝐻^𝑅/𝑅=𝑍−1−1/(2^1.5 𝑏𝑅𝑇) [𝑎−𝑇 𝑑𝑎/𝑑𝑇]
ln⁡((𝑣+(1+√2)𝑏)/(𝑣+(1−√2)𝑏))