Correlación basada en la densidad Ecuación lineal múltiple

X
ymedido A B C
T, K P, Mpa ρ, g/L y2, fracción molar ln(y2P) unidad 1/T ρ/T
313 9.5 573.71 1.51E-05 -8.84952402 1 0.00319489 1.8329393
313 14.8 775.99 0.000131 -6.24568605 1 0.00319489 2.47920128
313 19.8 838.43 0.000197 -5.54662489 1 0.00319489 2.6786901
313 24.3 875.04 0.000278 -4.99741309 1 0.00319489 2.79565495
313 29.8 909.79 0.00036 -4.53489813 1 0.00319489 2.90667732
333 10.6 332.34 2.74E-06 -10.4466986 1 0.003003 0.99801802
333 11.2 369.78 4.4E-06 -9.91799224 1 0.003003 1.11045045
333 14.8 594.43 5.05E-05 -7.19891004 1 0.003003 1.78507508
333 20 725.01 0.00018 -5.62682143 1 0.003003 2.17720721
333 22.5 756.38 0.000268 -5.11100827 1 0.003003 2.27141141
333 24.2 777.7 0.0003063 -4.90459291 1 0.003003 2.33543544
333 26.5 800.69 0.000377 -4.60612064 1 0.003003 2.40447447
333 29.8 829.19 0.000414 -4.39513619 1 0.003003 2.49006006
353 10.5 243.61 1.94E-06 -10.8014473 1 0.00283286 0.69011331
353 14.8 423 2.77E-05 -7.79945096 1 0.00283286 1.19830028
353 19.8 589.78 0.000151 -5.81254878 1 0.00283286 1.67076487
353 23.6 662.12 0.000282 -5.01235677 1 0.00283286 1.87569405
353 26.8 708.96 0.000401 -4.53314724 1 0.00283286 2.00838527
353 29.8 744.41 0.000482 -4.24305805 1 0.00283286 2.1088102
368 8 145.83 4.75E-07 -12.4805095 1 0.00271739 0.39627717
368 15 352.47 2.18E-05 -8.02555039 1 0.00271739 0.95779891
368 19.8 506.52 0.000125 -6.00151488 1 0.00271739 1.37641304
368 23.8 588.19 0.00028 -5.01103537 1 0.00271739 1.59834239
368 26.6 635.93 0.000463 -4.39687229 1 0.00271739 1.72807065
368 29.8 680.83 0.000515 -4.17683526 1 0.00271739 1.85008152

Datos de: Li, Varadarajan and Hartland. Fluid Phase Equilibria, 68 (1991) 263-280.
 Mínimos cuadrados

ycalculado
ln(y2P) y2, fracción molar
-9.13620187 1.13363784783E-05
-6.17776733 0.00014020646018
-5.26455468 0.00026119674504
-4.72911723 0.00036355005107
-4.22088309 0.00049280771595
-10.9675739 1.62756113201E-06
-10.4528848 2.57722173309E-06
-7.36461279 4.27885520227E-05
-5.5695246 0.0001906146179
-5.13828003 0.00026078993064
-4.84519318 0.00032504535936 Xt
-4.52914879 0.0004071644008 1 1 1 1
-4.13735821 0.00053573731197 0.003194888179 0.00319489 0.003194888179 0.00319488818
-10.6119637 2.34473304039E-06 1.832939297125 2.47920128 2.678690095847 2.79565495208
-8.28560396 1.70351595398E-05
-6.12277278 0.00011072568527 Xt*X
-5.18465546 0.00023736721908 25 0.07329998 45.72434675575
-4.57722643 0.00038370814976 0.073299979883 0.00021564 0.135862447209
-4.11750485 0.00054647978233 45.72434675575 0.13586245 94.33248586135
-10.7591414 2.65628265608E-06
-8.18862761 1.85196576346E-05 (Xt*X)\
-6.2723111 9.53464897942E-05 16.79605487884 -6265.02968 0.881919155045
-5.25637102 0.00021908372342 -6265.02967609 2386992.35 -401.1156113673
-4.66250572 0.00035499142187 0.881919155045 -401.115611 0.160828702646
-4.1039688 0.00055392724983
Xt*Y
-160.6757533759 Chart
-0.470349147186 0.0006
-263.532546246

b=(Xt*X)\Xt*Y 0.0005
A 15.61819332787
B -10374.43442801
C 4.577763558236 0.0004

0.0003

0.0002

0.0001
0.0003

0.0002

0.0001

0
100 200 300 400 500
 1 1 1 1 1 1 1 1
0.00319489 0.003003 0.003003 0.003003 0.003003 0.003003 0.003003 0.003003
2.90667732 0.99801802 1.11045045 1.78507508 2.17720721 2.27141141 2.33543544 2.40447447

Chart Title
300 400 500 600 700 800 900 1000
 1 1 1 1 1 1 1 1
0.003003 0.00283286 0.00283286 0.00283286 0.00283286 0.00283286 0.00283286 0.00271739
2.49006006 0.69011331 1.19830028 1.67076487 1.87569405 2.00838527 2.1088102 0.39627717
 1 1 1 1 1
0.00271739 0.00271739 0.00271739 0.00271739 0.00271739
0.95779891 1.37641304 1.59834239 1.72807065 1.85008152